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Task
Candidate
Signature
Date
Mark
Section A
Section B
Chemistry
Unit 6T
TOTAL
(max 50)
CHM6T/Q11/test
Time allowed
l 1 hour
Instructions:
l Use black ink or black ball-point pen.
l Fill in the boxes at the top of this page.
l Answer all questions.
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l Do all rough work in this book. Cross through any work you do not
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Information
l The marks for questions are shown in brackets.
l The maximum mark for this paper is 30.
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organise information clearly
use scientific terminology accurately.
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Signature of teacher ................................................................................................................... Date ..........................................
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WMP/Jun11/CHM6T/Q11/test
CHM6T/Q11/test
Do not write
outside the
box
Section A
These questions are about the task, some reactions of iron(II) and iron(III) compounds.
You should use your Task Sheet and your Candidate Results Sheet to answer them.
Answer all questions in the spaces provided.
The iron(III) salt used in the Task was in excess. The 10.0 cm3 solution of potassium
hexacyanoferrate(II) had a concentration of 0.75 mol dm3. The equation for the
formation of Prussian Blue from iron(III) sulfate and potassium hexacyanoferrate(II)
is shown below.
2K4[Fe(CN)6] + Fe2(SO4)3
2KFe[Fe(CN)6] + 3K2SO4
Calculate the maximum amount, in moles, of Prussian Blue that could have been
formed in the reaction.
Show your working.
............................................................................................................................................
............................................................................................................................................
............................................................................................................................................
(2 marks)
4
Use your answers to Question 2 and Question 3 to calculate the percentage yield of
Prussian Blue obtained in this experiment.
............................................................................................................................................
............................................................................................................................................
(1 mark)
WMP/Jun11/CHM6T/Q11/test
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3
5
Prussian Blue dye is an insoluble solid and when prepared as described in Part 1 it is
impure.
Suggest how the impurities present in the dye could be removed.
............................................................................................................................................
............................................................................................................................................
(1 mark)
Give the formula for each of the iron-containing products formed in Test 2.
Product using iron(II) sulfate solution ................................................................................
Product using iron(III) nitrate solution ...............................................................................
(2 marks)
Write an ionic equation for the reaction of aqueous [Fe(H2O)6]3+ ions with hydroxide
ions to form a brown precipitate.
............................................................................................................................................
(1 mark)
9
Turn over for the next question
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WMP/Jun11/CHM6T/Q11/test
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4
Section B
Answer all questions in the spaces provided.
Introduction
Complexes containing transition elements have a wide variety of uses including acting as dyestuffs
like Prussian Blue.
Cisplatin is a platinum-based chemotherapy drug used to treat various types of cancers. It was
the first member of a class of anti-cancer drugs that react with DNA in tumour cells.
Cisplatin is prepared from K2PtCl4 according to the following scheme.
All the reactions shown are reversible.
Cl
Cl
excess KI
K2
K2
Pt
Pt
NH3
Pt
Reaction 1
Cl
I
NH3
Reaction 2
Cl
NH3
I
Reaction 3
Cl
H 2O
H 2O
NH3
NH3
2+
excess KCl
Pt
Pt
Reaction 4
Cl
NH3
H 2O
NH3
cisplatin
8
Name the type of reaction occurring in all four steps of the scheme.
............................................................................................................................................
(1 mark)
WMP/Jun11/CHM6T/Q11/test
Do not write
outside the
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5
10 (a)
10 (b)
Calculate the percentage atom economy for the formation of K2PtI4 in Reaction 1.
Show your working.
............................................................................................................................................
............................................................................................................................................
............................................................................................................................................
............................................................................................................................................
(2 marks)
11
11 (a)
Write the simplest ionic equation for the reaction of iodide ions with silver nitrate.
............................................................................................................................................
(1 mark)
11 (b)
Suggest why addition of silver nitrate improves the yield of product from Reaction 3.
............................................................................................................................................
............................................................................................................................................
(1 mark)
12
Suggest two reasons, other than poor practical technique, why the overall yield of
cisplatin in this synthesis may be low.
Reason 1 ............................................................................................................................
............................................................................................................................................
Reason 2 ............................................................................................................................
............................................................................................................................................
(2 marks)
Turn over
WMP/Jun11/CHM6T/Q11/test
6
13
The cisplatin formed in Reaction 4 is impure. Outline how the impure solid is purified
by recrystallisation.
............................................................................................................................................
............................................................................................................................................
............................................................................................................................................
............................................................................................................................................
............................................................................................................................................
(3 marks)
14
14 (a)
14 (b)
Suggest a suitable precaution that should be taken by medical staff when using
cisplatin.
............................................................................................................................................
(1 mark)
15
Other metal ions are also toxic to humans. A substance that can be used to treat such
poisoning contains the ion EDTA4
EDTA4 forms very stable complexes with metal ions. These complexes are not toxic.
15 (a)
Write an equation for the reaction of EDTA4 with aqueous copper(II) ions,
[Cu(H2O)6]2+
............................................................................................................................................
(1 mark)
WMP/Jun11/CHM6T/Q11/test
Do not write
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7
15 (b)
Do not write
outside the
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16
17
21
END OF QUESTIONS
WMP/Jun11/CHM6T/Q11/test
WMP/Jun11/CHM6T/Q11/test
3300 3500
3230 3550
2850 3300
2500 3000
2220 2260
N H
(amines)
O H
(alcohols)
O H
(acids)
750 1100
1000 1300
1620 1680
1680 1750
Wavenumber
/cm1
Bond
Table 1
Infrared absorption data
1.0 4.5
1.2 1.4
1.4 1.6
RNH2
R2CH2
R3CH
O
R
R C O
RCH2Cl or Br
R O C
O H
10.0 12.0
9.0 10.0
4.5 6.0
3.7 4.1
3.1 4.2
3.1 3.9
2.1 2.6
0.7 1.2
RCH3
0.5 5.0
ROH
R C
/ppm
Type of proton
Table 2
1H n.m.r. chemical shift data
R C
R C
aldehydes
or ketones
esters or
acids
N
alcohols,
ethers or
esters
Cl or Br
R C C
Type of carbon
190 220
160 185
110 160
110 125
90 150
50 90
25 60
20 50
10 70
5 40
/ppm
Table 3
13C n.m.r. chemical shift data
Turn over
WMP/Jun11/CHM6T/Q11/test
(3)
38
37
41
89
actinium
90 103 Actinides
104
rutherfordium
Rf
(6)
(7)
Mn
54.9
25
Tc
[98]
43
Pr
Ce
(8)
(9)
(10)
Pt
77
(11)
Sm
150.4
109
Pa
protactinium
91
Th
thorium
90
U
92
uranium
93
neptunium
Np
[237]
61
94
plutonium
Pu
[244]
62
60
238.0
59
231.0
58
78
Ds
[281]
Rg
[280]
79
gold
Au
197.0
47
silver
Ag
107.9
29
copper
Cu
63.5
95
americium
Am
[243]
63
europium
Eu
152.0
110
96
curium
Cm
[247]
64
gadolinium
Gd
157.3
111
Mt
[276]
platinum
Ir
iridium
195.1
46
palladium
Pd
106.4
28
nickel
Ni
58.7
192.2
45
rhodium
Rh
102.9
27
cobalt
Co
58.9
samarium
Pm
[145]
108
hassium
Hs
[270]
76
osmium
Os
190.2
44
ruthenium
Ru
101.1
26
iron
Fe
55.8
232.0
cerium
144.2
140.9
140.1
Nd
107
bohrium
Bh
[272]
75
rhenium
Re
186.2
106
seaborgium
Sg
[271]
74
tungsten
183.8
42
molybdenum technetium
Mo
96.0
24
chromium manganese
Cr
52.0
105
dubnium
Db
73
tantalum
Ta
180.9
[268]
Lanthanides
88
87
* 58 71
Ra
radium
Fr
Nb
niobium
72
57
[227]
Ac
56
[226]
55
[223]
francium
23
92.9
[267]
Hf
vanadium
hafnium
La *
178.5
40
zirconium
Zr
91.2
(5)
50.9
lanthanum
Ba
barium
Cs
caesium
39
138.9
137.3
132.9
yttrium
Sr
strontium
Rb
rubidium
21
88.9
20
87.6
19
85.5
22
Ti
titanium
Sc
Ca
calcium
potassium
(4)
47.9
(12)
97
berkelium
Bk
[247]
65
terbium
Tb
Ge
49
81
thallium
Tl
204.4
82
lead
Pb
207.2
50
tin
Sn
In
indium
118.7
32
germanium
114.8
31
gallium
Ga
14
72.6
13
69.7
83
bismuth
Bi
209.0
51
antimony
Sb
121.8
33
arsenic
As
15
74.9
phosphorus
31.0
nitrogen
14.0
(15)
84
polonium
Po
[209]
52
tellurium
Te
127.6
34
selenium
Se
16
79.0
sulfur
32.1
oxygen
16.0
(16)
85
astatine
At
[210]
53
iodine
126.9
35
bromine
Br
17
79.9
chlorine
Cl
35.5
fluorine
19.0
(17)
86
radon
Rn
[222]
54
xenon
Xe
131.3
36
krypton
Kr
18
83.8
argon
Ar
39.9
10
neon
Ne
2
20.2
Es
[252]
67
holmium
Ho
164.9
98
99
californium einsteinium
Cf
[251]
66
dysprosium
Dy
162.5
100
fermium
Fm
[257]
68
erbium
Er
167.3
101
mendelevium
Md
[258]
69
thulium
Tm
168.9
102
nobelium
No
[259]
70
ytterbium
Yb
173.1
103
lawrencium
Lr
[262]
71
lutetium
Lu
175.0
158.9
80
mercury
Hg
200.6
48
cadmium
Cd
112.4
30
zinc
Zn
65.4
Si
silicon
aluminium
Al
6
28.1
27.0
scandium
45.0
12
40.1
11
39.1
Mg
magnesium
Na
sodium
24.3
23.0
12.0
carbon
Be
beryllium
Li
lithium
10.8
boron
symbol
9.0
6.9
(14)
helium
(13)
(18)
hydrogen
4.0
He
1.0
name
(2)
(1)
Key