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5 5

TC = (T – 32.0) = (98.6 – 32.0) = 37.0°C

9 F 9

T = TC + 273 = 310 K

P2 T2

imply that =

P1 T1

(a) P2 = = = 1.06 atm

T1 (273 + 20.0)K

(b) T3 = = = 149 K = –124°C

P1 (0.980 atm)

19.3 Since we have a linear graph, the pressure is related to the temperature as P = A + BT, where

A and B are constants. To find A and B, we use the data

A = 1.272 atm

2 Chapter 19 Solutions

5

19.4 Let us use TC = (T – 32.0) with TF = – 40.0°C. We find

9 F

5

TC = (– 40.0 – 32.0) = – 40.0°C

9

9 9

19.5 (a) TF = TC + 32.0°F = (–195.81) + 32.0 = –320°F

5 5

100°C = a(60.0°S) + b

a = 1.33 C°/S°

b = 20.0°C

∆T = 450 C° = 450 C°

212°F – 32.0°F

19.7 (a) = 810 F°

100°C – 0.00°C

Chapter 19 Solutions 3

–

∆L = Li α (T – Ti)

–

α ≈ α(20.0°C) = 1.70 × 10–5 (C°)–1 for Cu.

Goal Solution

G: Based on everyday observations of telephone wires, we might expect the wire to expand by

less than a meter since the change in length of these wires is generally not noticeable.

O: The change in length can be found from the linear expansion of copper wire (we will assume

that the insulation around the copper wire can stretch more easily than the wire itself).

From Table 19.2, the coefficient of linear expansion for copper is 17 × 10–6 (°C)–1.

L: This expansion is well under our expected limit of a meter. From ∆L, we can find that the wire

sags 0.757 m at its midpoint on the hot summer day, which also seems reasonable based on

everyday observations.

Lf = 3.0058 m

Lf = 2.9986 m

LAl – LBrass

∆T =

LBrass α Brass – LAl α Al

(10.01 – 10.00)

∆T =

(10.00)(19.0 × 10 –6) – (10.01)(24.0 × 10 –6)

4 Chapter 19 Solutions

(10.02 – 10.00)

(b) ∆T =

(10.00)(19.0 × 10 –6) – (10.02)(24.0 × 10 –6)

∆L = αLi ∆T

T = 55.0°C

(b) The length of each side of the hole has increased. Thus, this represents an increase in

the area of the hole.

19.16 ∆V = (β – 3α)Vi ∆T

= 0.548 gal

(30.0)(π)(1.50)2

(c) ∆V = 3α V i ∆T = 3(9.00 × 10–6/°C) cm3(65.0°C) = 0.0930 cm3

4

Chapter 19 Solutions 5

= = =

∆V flask βflask 3(3.20 × 10 –6) 6.40 × 10–2

19.19 (a) and (b) The material would expand by ∆L = αLi ∆T,

∆L

= α ∆T, but instead feels stress

Li

F Y ∆L

= = Yα ∆T = (7.00 × 109 N/m2) 12.0 × 10–6 (C°)–1(30.0 C°)

A Li

19.20 (a) and (b) The gap width is a linear dimension, so it increases in "thermal enlargement" by

so Lf = 1.603 cm

F Y ∆L

19.21 In = require ∆L = αLi ∆T

A Li

F

= Yα ∆T

A

F 500 N

∆T = =

AY α (2.00 × 10–4 m 2)(20.0 × 10–10 N/m 2)(11.0 × 10–6/C°)

∆T = 1.14°C

6 Chapter 19 Solutions

F ∆L

19.22 ∆L = αLi(∆T) and =Y

A Li

∆L

F = AY = AYα (∆T)

Li

N

(11.0 × 10–6/C°)(70.0°C)

m2

F = 199 kN

99.4 cm3

so the fraction lost is = 4.71 × 10–2

2108 cm3

and this fraction of the cylinder's depth will be empty upon cooling:

T = 437°C

(5.000 cm)[1 + (24.0 × 10–6 °C–1)∆T] = (5.050 cm)[1 + (19.0 × 10–6 °C–1) ∆T]

*19.25 (a) n= = = 3.00 mol

RT (8.315 N · mol K)(293 K)

Chapter 19 Solutions 7

4

19.26 PV = NP'V' = π r 3 NP'

3

3PV (3)(150)(0.100)

N= = = 884 balloons

4π r 3P' (4 π )(0.150) 3(1.20)

Goal Solution

G: The given room conditions are close to Standard Temperature and Pressure (STP is 0°C and

101.3 kPa), so we can use the estimate that one mole of an ideal gas at STP occupies a volume

of about 22 L. The volume of the auditorium is 6000 m3 and 1 m3 = 1000 L , so we can estimate

the number of molecules to be:

N ≈ (6 × 103 m3) ≈ 1.6 × 1029 molecules of air

1 m3 22 L 1 mol

A: The equation of state of an ideal gas is PV = nRT so we need to solve for the number of moles to

find N.

n= = = 2.49 × 105 mol

RT (8.315 J/mol ⋅ K)(293 K)

molecules

= 1.50 × 1029 molecules

mol

L: This result agrees quite well with our initial estimate. The numbers would match even better

if the temperature of the auditorium was 0°C.

=

nRT 9.00 g 8.315 J 773 K = 1.61 MPa

19.28 P= = 15.9 atm

V 18.0 g/mol mol K 2.00 × 10–3 m 3

8 Chapter 19 Solutions

m3 Tin

283

1– = 0.400

Tin

283

0.600 = Tin = 472 K

Tin

Goal Solution

G: The air inside the balloon must be significantly hotter than the outside air in order for the

balloon to have a net upward force, but the temperature must also be less than the melting

point of the nylon used for the balloon’s envelope (rip-stop nylon melts around 200°C),

otherwise the results could be disastrous!

O: The density of the air inside the balloon must be sufficiently low so that the buoyant force is

greater than the weight of the balloon, its cargo, and the air inside. The temperature of the

air required to achieve this density can be found from the equation of state of an ideal gas.

B

Fg Fg

of 200 kg of air

A: The buoyant force equals the weight of the air at 10.0°C displaced by the balloon:

Since B > Fg, the balloon has a chance of lifting off as long as the weight of the air inside the

balloon is less than the difference in these forces:

Fg(air) 2940 N

The mass of this air is mair = = = 300 kg

g 9.80 m/s2

Chapter 19 Solutions 9

To find the required temperature of this air from PV = nRT, we must find the corresponding

number of moles of air. Dry air is approximately 20% O2, and 80% N2. Using data from a

periodic table, we can calculate the molar mass of the air to be approximately

m 300 kg 103 g

so the number of moles is n = = = 1.0 × 104 mol

M 29 g/mol 1 kg

The pressure of this air is the ambient pressure; from PV= nRT, we can now find the minimum

temperature required for lift off:

T= = = 471 K = 198°C

nR (1.0 × 104 mol)(8.315 J/(mol K))

L: The average temperature of the air inside the balloon required for lift off appears to be close

to the melting point of the nylon fabric, so this seems like a dangerous situation! A larger

balloon would be better suited for the given weight of the balloon. (A quick check on the

internet reveals that this balloon is only about 1/10 the size of most sport balloons, which

have a volume of about 3000 m3).

If the buoyant force were less than the weight of the balloon and its cargo, the balloon would

not lift off no matter how hot the air inside might be! If this were the case, then either the

weight would have to be reduced or a bigger balloon would be required.

Even though our result for T is shown with 3 significant figures, the answer should probably be

rounded to 2 significant figures to reflect the approximate value of the molar mass of the air.

P2

*19.30 (a) T2 = T1 = (300 K)(3) = 900 K

P1

P2 V2

(b) T2 = T1 = 300(2)(2) = 1200 K

P1 V1

n= = = 41.6 mol

RT (8.315 J/mol ⋅ K)(293 K)

(b) m = nM = (41.6 mol)(28.9 g/mol) = 1.20 kg , in agreement with the tabulated density of

1.20 kg/m3 at 20.0°C.

PV

*19.32 (a) PV = nRT n=

RT

m = nM = =

RT (8.315 J/mol ⋅ K)(300 K)

m = 1.17 × 10–3 kg

10 Chapter 19 Solutions

(d) The molecules must be moving very fast to hit the walls hard.

0.280 × Pf 313.15 K

= giving Pf = 3.95 atm or

1.00 atm 283.15 K

Pf = 4.00 × 10 5 Pa(abs.)

Pd = 1.121Pf = 4.49 × 10 5 Pa

4

*19.34 Let us use V = π r 3 as the volume of the balloon, and the ideal gas law in

3

Pf Vf Pi Vi

the form =

Tf Ti

to give, r i = (20.0 m) 3

200 K 1.00 atm

ri = 7.11 m

P2V2 = n2RT2

PV PV

n1 – n2 = –

RT1 RT2

n1 – n2 = –

8.315 J/mol K 291 K 298 K

n1 – n2 = 78.4 mol

Chapter 19 Solutions 11

P 0V M 1 1

m1 – m2 = –

R T1 T 2

P 0V f Tf

=

(P 0 + ρ gh)V i Ti

Tf P 0 + ρ gh

Vf = Vi

Ti P0

Vf = 1.00 cm3

278 K 1.013 × 105 Pa

Vf = 3.67 cm3

*19.38 My bedroom is 4.00 m long, 4.00 m wide, and 2.40 m high, enclosing air at 100 kPa and 20.0°C =

293 K. Think of the air as 80.0% N2 and 20.0% O2.

m= =

RT (8.315 J/mol ⋅ K)(293 K)

m = 45.4 kg ~ 102 kg

19.39 PV = nRT

= , so mf = mi

mf nf PfVf RTi Pf Pf

= =

mi ni RTf PiV i Pi Pi

∆m = mi – mf = mi

P i – P f

= (12.0 kg)

41.0 atm – 26.0 atm

= 4.39 kg

i

P 41.0 atm

12 Chapter 19 Solutions

molecule

–9 Pa)(1.00 m3)(6.02 × 1023)

PVN A (10 mol

19.40 N= = = 2.41 × 1011 molecules

RT 8.315 J (300 K)

K ⋅ mol

19.41 PV = nRT

V= = = 22.4 L

P 1.013 × 105 N/m2 1.00 m3

19.42 (a) Initially the air in the bell satisfies P 0V bell = nRT i

where x is the height the water rises in the bell. Also, the pressure in the bell, once it is

lowered, is equal to the sea water pressure at the depth of the water level in the bell.

The approximation is good, as x < 2.50 m. Substituting (3) into (2) and substituting nR

from (1) into (2),

Tf

[P0 + ρg (82.3 m)](2.50 m – x)A = P0Vbell

Ti

kg

Using P0 = 1 atm = 1.013 × 105 Pa and ρ = 1.025 × 103

m3

ρg(82.3 m) – 1

x = (2.50 m) 1 –

Tf

1+

T0 P0

= (2.50 m) 1 –

277.15 K

1+

293.15 K 1.013 × 105 N/m2

x = 2.24 m

Chapter 19 Solutions 13

(b) If the water in the bell is to be expelled, the air pressure in the bell must be raised to the

water pressure at the bottom of the bell. That is,

Pbell = P0 + ρg(82.3 m)

kg

9.80 2 (82.3 m)

m

m3 s

m = ρV = 730

kg

(10.0 gal)

0.00380 m3

= 27.7 kg

m3

1.00 gal

10.0 gal =

10.0 gal

(27.7 kg) = 27.2 kg

10.192 gal

14 Chapter 19 Solutions

Chapter 19 Solutions 15

v v

*19.46 The frequency played by the cold-walled flute is fi = = .

λ i 2Li

v v v fi

ff = = = =

λ f 2Lf 2L i(1 + α ∆T) 1 + α ∆T

∆f = fi – ff = fi 1 –

1

1 + α ∆T

v α ∆T v

∆f = ≈ (α ∆T)

2Li 1 + α ∆T 2Li

∆f ≈ = 0.0943 Hz

2(0.655 m)

V

∆h = β ∆T

A

4 0.250 cm 3

π

3 2

∆h = (1.82 × 10–4/C°)(30.0°C) = 3.55 cm

π (2.00 × 10–3 cm) 2 Ti Ti + ∆T

19.48 (a) The volume of the liquid increases as ∆Vl = Vi β ∆T. The volume of the flask increases as

∆V g = 3αV i ∆T. Therefore, the overflow in the capillary is V c = V i ∆T(β – 3α); and in the

capillary V c = A ∆h.

Vi

Therefore, ∆h = (β – 3 α ) ∆T

A

(b) For a mercury thermometer β(Hg) = 1.82 × 10–4/°C and for glass, 3α = 3 × 3.20 × 10–6/°C.

Thus β – 3α ≈ β, or α « β

m m

19.49 (a) ρ= and dρ = – dV

V V2

m ∆V

∆ρ = – = –ρβ ∆T

V V

16 Chapter 19 Solutions

The negative sign means that any increase in temperature causes the density to decrease

and vice versa.

Chapter 19 Solutions 17

β= = = 5 × 10–5/°C

ρ ∆T (1.0000 g/cm3)(10.0 – 4.00)C°

P 0V P'V'

19.50 (a) =

T T'

V' = V + Ah k

kh 250°C

P' = P0 + h

A 20°C

A T

m2 m3

= 1.013 × 105

N

(5.00 × 10–3 m3)

523 K

m

2

293 K

–2013 ± 2689

h= = 0.169 m

4000

(b) P' = P + = 1.013 × 105 Pa +

A 0.0100 m2

P' = 1.35 × 10 5 Pa

19.51 (a) We assume that air at atmospheric pressure is above the piston.

mg

In equilibrium Pgas = + P0. Therefore,

A

nRT mg nRT m

= + P0 or h = where

hA A (mg + P 0A)

Gas

h

(b) From the data given,

h=

(20.0 kg)(9.80 m/s2) + (1.013 × 105 N/m2)(0.00800 m2)

= 0.661 m

18 Chapter 19 Solutions

Li(α 2 – α 1 )∆T r2

∆r = r2 – r1 =

θ r1

1 θ

∴ r2 – r1 = [Li + Liα2 ∆T – Li – Liα1 ∆T]

θ

∆T

θ = L i (α 2 – α 1 )

(r 2 – r 1 )

(b) θ → 0 as ∆T → 0 θ → 0 as α 1 → α 2

19.53 From the diagram we see that the change in area is ∆A = l ∆w + w ∆l + ∆w ∆l. Since ∆l and

∆w are each small quantities, the product ∆w ∆l will be very small. Therefore, we assume

∆w ∆l ≈ 0. Since ∆w = wα ∆T and ∆l = lα ∆T, we then have ∆A = lwα ∆T + wlα ∆T and since

A = lw, we have ∆A = 2 α A ∆T . The approximation assumes ∆w∆l ≈ 0, or α ∆T ≈ 0. Another

l

w Ti w + ∆w TTi + ∆T

l + ∆l

1 R

– 1 = 89.0 – 1 = 422°C

1

(b) T=

A R 0 1.85 × 10 (C°) 50.0

–3 –1

Chapter 19 Solutions 19

Li

19.55 (a) Ti = 2π

g

2

T i g (1.000 s)2(9.80 m/s2)

Li = = = 0.2482 m

4π2 4π2

L i + ∆L 0.2483 m

Tf = 2π = 2π = 1.0000949 s

g 9.80 m/s2

∆T = 9.49 × 10–5 s

= 7.00

d 86 400 s s lost

9.49 × 10–5 = 57.4 s lost

week 1.00 d s

I=⌡

= (1 + α ∆T)2, thus ≈ 2α ∆T

I(T i) I(T i)

∆I

= 2(17.0 × 10–6/°C)(100°C) = 0.340%

I

∆I

= 2(24.0 × 10–6/°C)(100°C) = 0.480%

I

ρgP0Vi ρgP0Vi

B= =

P' (P 0 + ρ gd)

(The volume of the balloon becomes smaller with increasing pressure.)

20 Chapter 19 Solutions

(c) = = =

2 B(0) ρgP0Vi/P0 P 0 + ρgd

P0 + ρgd = 2P0

d= = = 10.3 m

ρg (1.00 × 103 kg/m3)(9.80 m/s2)

19.58 (a) Let m represent the sample mass. Then the number of moles is n = m/M and the density is

ρ = m/V. So PV = nRT becomes

m m

PV = RT or PM = RT

M V

m PM

Then, ρ = =

V RT

(b) ρ= = = 1.33 kg/m3

RT (8.315 J/mol ⋅ K)(293 K)

19.59 For each gas alone, P1 = and P2 = and P3 = , etc.

V V V

(N 1 + N 2 + N 3 . . .)kT = PV

Also, V1 = V2 = V3 = . . . = V, therefore P = P 1 + P 2 + P 3. . .

19.60 (a) Using the Periodic Table, we find the molecular masses of the air components to be

75.52 g

n(N2) = = 2.696 mol

28.01 g/mol

23.15 g

n(O2) = = 0.7234 mol

32.00 g/mol

1.28 g

n(Ar) = = 0.0320 mol

39.95 g/mol

0.05 g

n(CO2) = = 0.0011 mol

44.01 g/mol

Chapter 19 Solutions 21

The total number of moles is n0 = ∑ni = 3.453 mol. Then, the partial pressure of N2 is

2.696 mol

P(N2) = ⋅ (1.013 × 105 Pa) = 79.1 kPa

3.453 mol

Similarly,

(b) Solving the ideal gas law equation for V and using T = 273.15 + 15.00 = 288.15 K, we find

V= = = 8.167 × 10–2 m3

P 1.013 × 105 Pa

m 100 × 10–3kg

Then, ρ = V = 8.167 × 10–2 m3 = 1.22 kg/m

3

(c) The 100 g sample must have an appropriate molar mass to yield n0 moles of gas: that is

100 g

M(air) = = 29.0 g/mol

3.453 mol

∆L = αLi ∆T

F ∆L

in =Y = (20.0 × 1010 N/m)(2.50 × 10–5) = 5.00 × 106 N/m2

A Li

(b) Fraction of yield strength = = 9.58 × 10–3

52.2 × 107 N/m2

22 Chapter 19 Solutions

nR

19.62 (a) T

P

d V nR V

= =

dT P T

Thus, β ≡

1 dV 1 V 1

= , or β =

V dT V T T

1

(b) At T = 0°C = 273 K, this predicts β = = 3.66 × 10–3/K

273 K

Experimental values are: βHe = 3.665 × 10–3/K and βair = 3.67 × 10–3/K

Lf, y, and the original 125 m length of this span form a right triangle with y as the altitude.

Using the Pythagorean theorem gives:

19.64 After expansion, the length of one of the spans is Lf = L(1 + α ∆T). Lf, y, and the original length

L of this span form a right triangle with y as the altitude. Using the Pythagorean theorem

2

gives L f = L2 + y2, or

2

y= L f – L2 = L (1 + α ∆T)2 – 1 = L 2 α ∆T + ( α ∆T)2

Since α ∆T << 1, y ≈ L 2 α ∆T

α c L c ∆T = α s L s ∆T

αc Lc

Ls =

αs

αc Lc

∆L = – Lc

αs

∴ Lc = = = 9.17 cm

( α c – α s ) (17.0 × 10–6/C° – 11.0 × 10–6/C°)

∆L α c

= 5.00 cm

17.0

and Ls = = 14.2 cm

(α c – α s) 6.00

Chapter 19 Solutions 23

24 Chapter 19 Solutions

T = constant, so PV = P0Vi

50.0 cm

or P(Ah 0 ) = P 0 (Ah i)

With A = constant, P = P0

hi

(a)

0

h

mpg ∆h

But, P = P0 + , where mp is the mass of

A

the piston. hi

= P0 , which reduces

mpg hi

Thus, P0 +

A 0

h (b) (c)

to

hi 50.0 cm

h0 = = = 49.81 cm

m pg (20.0 kg)(9.80 m/s2)

1+ 1+

P 0A (1.013 × 105 Pa)π (0.400 m) 2

With the man of mass M on the piston, a very similar calculation (replacing mp by

mp + M) gives:

hi 50.0 cm

h' = = = 49.10 cm

(m p + M)g (95.0 kg)(9.80 m/s2)

1+ 1 +

P 0A (1.013 × 105 Pa)π (0.400 m) 2

(b) P = const, so = or = , giving

T Ti T Ti

T = Ti

h 0

= (293 K)

49.81

= 297 K (or 24°C)

h ' 49.10

Chapter 19 Solutions 25

dL

19.67 (a) = αdT

L

⌠ i d L ⇒ ln L f = α ∆T ⇒ Lf = Lieα ∆T

Ti L

⌠

⌡TiαdT = ⌡ Li L L i

L f – L'f

= 2.00 × 10–6 = 2.00 × 10–4%

Lf

L f – L'f

= 59.4%

Lf

19.68 At 20.0˚C, the unstretched lengths of the steel and copper wires are

Under a tension F, the length of the steel and copper wires are

L's = Ls 1 +

F

L'c = Lc 1 +

F

where L's + L'c = 4.000 m

Y A s Y A c

Since the tension, F, must be the same in each wire, solve for F:

(L's + L'c ) – (L s + L c )

F=

Ls Lc

+

Y sA s Y cA c

Recall Ys = 20.0 × 1010 Pa and Yc = 11.0 × 1010 Pa. Substituting into the equation for F, we obtain

F=

1.99956 m 1.99932 m

+

(20.0 × 10 10 Pa)(3.140 × 10 –6) m 2 (11.0 × 10 10 Pa)(3.139 × 10 –6) m 2

F = 125 N

26 Chapter 19 Solutions

125 N

(20.0 × 1010 N/m 2)(3.140 × 10–6 m 2)

19.69 (a) µ = πr2ρ = π(5.00 × 10–4 m)2(7.86 × 103 kg/m3) = 6.17 × 10–3 kg/m

v T 1 T

(b) f1 = and v= so f1 =

2L µ 2L µ

L = Lnatural 1 +

T L

so Lnatural =

A Y 1 + T/AY

T 632

Therefore, = = 4.02 × 10–3, and

A Y (7.854 × 10 –7)(20.0 × 10 10)

(0.800 m)

Lnatural = = 0.7968 m

(1 + 4.02 × 10 –3)

Since L = L30°C 1 +

T'

, where T' is the tension in the string at 30.0˚C,

A Y

L 0.800

30°C

L 0.79706

= so f 1' = (200 Hz) = 192 Hz

f1 T 632 N

Chapter 19 Solutions 27

19.70 Let 2θ represent the angle the curved rail subtends. We have

Li/2 L i h

sin θ = = Li/2 Li/2

R 2R

Li

Thus, θ = (1 + α ∆T) = (1 + α ∆T) sin θ R R

2R

θ

and we must solve the transcendental equation

Li(1 – cos θ)

Now, h = R – R cos θ =

2 sin θ

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