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43.1 (a) F= = N = 0.921 × 10 − 9 N toward the other ion.

4 π e0 r 2 (5.00 × 10 −10 )2

(b) U= = − J ≈ – 2.88 eV

4 π e0 r 5.00 × 10 −10

and C l + e − → C l − + 3.6 eV

or C l − → C l + e − − 3.6 eV

K + 4.3 eV → K + + e −

or the ionization energy of potassium is 4.3 eV

16

dU 2A

= −12Ar −13 + 6Br −7 = 0, yielding r0 =

dr B

A B 1 1 B2 B2

(b) E=U −U r = r0= 0 − − = − − =

r=∞ 2

4A B

2

2A B 4 2 A 4A

This is also the equal to the binding energy, the amount of energy given up by the two atoms

as they come together to form a molecule.

( )

16

2 0.124 × 10 −120 eV ⋅ m12

(c) r0 = = 7.42 × 10 −11 m = 74.2 pm

1.488 × 10 −60 eV ⋅ m 6

(1.488 × 10 )

−60 2

eV ⋅ m 6

E= = 4.46 eV

4(0.124 × 10 −120

eV ⋅ m12 )

kBT ≈ 10 −3 eV = 10 −3 1.6 × 10 −19 J )

1.6 × 10 −22 J

T≈ ~10 K

1.38 × 10 −23 J K

546 Chapter 43 Solutions

43.5 µ=

m1m2

=

132.9(126.9)

m1 + m2 132.9 + 126.9

( )

1.66 × 10 − 27 kg = 1.08 × 10 − 25 kg

(I ω )2 J(J + 1)h2

(a) E = 21 I ω 2 = =

2I 2I

J = 0 gives E = 0

h2 (6.626 × 10 − 34 J ⋅ s)2

J = 1 gives E = = = 6.41 × 10 − 24 J = 40.0 µ eV

I 4 π 2 (1.74 × 10 − 45 kg ⋅ m 2 )

h f = 6.41 × 10 − 24 J − 0 to f = 9.66 × 10 9 Hz

E1 h2 h

(b) f= = = ∝ r− 2 If r is 10% too small, f is 20% too large.

h h I 4 π 2µ r 2

h2 h2 h2

43.6 h f = ∆E =

2I

[ 2( 2 + 1)] − [1(1 + 1)] =

2I 2I

( 4)

4( h 2 π )

2

h 6.626 × 10 −34 J ⋅ s

I= = = = 1.46 × 10 − 46 kg ⋅ m 2

2h f (

2 π 2 f 2 π 2 2.30 × 1011 Hz )

43.7 For the HCl molecule in the J = 1 rotational energy level, we are given

r 0 = 0.1275 nm.

h2

Erot = J(J + 1)

2I

h2 1 2 2h2 h

Taking J = 1, we have Erot = = 2 Iω or ω= 2

= 2

I I I

2 mm 2

The moment of inertia of the molecule is given by Equation 43.3. I = µr0 = 1 2 r0

m1 + m2

(1 u)(35 u) 2

I= r 0 = (0.972 u)(1.66 × 10 −27 kg / u)(1.275 × 10 −10 m)2 = 2.62 × 10 −47 kg ⋅ m 2

1 u + 35 u

h 1.055 × 10 −34 J ⋅ s

Therefore, ω= 2 = 2 = 5.69 × 1012 rad / s

I 2.62 × 10 −47 kg ⋅ m 2

Chapter 43 Solutions 547

Goal Solution

An HCl molecule is excited to its first rotational-energy level, corresponding to J = 1. If the distance

between its nuclei is 0.127 5 nm, what is the angular speed of the molecule about its center of mass?

G: For a system as small as a molecule, we can expect the angular speed to be much faster than the few

rad/s typical of everyday objects we encounter.

O: The rotational energy is given by the angular momentum quantum number, J . The angular speed

can be calculated from this kinetic rotational energy and the moment of inertia of this one-

dimensional molecule.

A : For the HCl molecule in the J = 1 rotational energy level, we are given r0 = 0.1275 nm.

h h2 1 2 2h2 h 2

Erot = J ( J + 1) so with J = 1, Erot = = Iω and ω= =

2I I 2 I2 I

mm (1 u)(35 u) 2

The moment of inertia of the molecule is given by: I = µ r0 2 = 1 2 r0 2 = r0

m1 + m2 1 u + 35 u

1.055 × 10 −34 J ⋅ s

Therefore, 2 2

= 5.69 × 1012 rad / s

2.62 × 10 kg ⋅ m

-47

L : This angular speed is more than a billion times faster than the spin rate of a music CD, which rotates

at 200 to 500 revolutions per minute, or ω = 20 rad / s to 50 rad / s.

2 2

43.8 I = m1r 1 + m2 r 2 where m1r 1 = m2 r 2 and r1 + r 2 = r

m2 r 2 m2 r 2 m1r

Then r1 = so + r2 = r and r2 =

m1 m1 m1 + m2

m1r 1 m1r 1 m2 r

Also, r2 = Thus, r1 + =r and r1 =

m2 m2 m1 + m2

I = m1 + = = = µ r2

(m1 + m2 )2 (m1 + m2 )2 (m1 + m2 )2 m1 + m2

22.99( 35.45)

43.9 (a) µ=

(22.99 + 35.45) (

1.66 × 10 −27 kg = 2.32 × 10 −26 kg )

( )( )

2

I = µ r 2 = 2.32 × 10 −26 kg 0.280 × 10 −9 m = 1.81 × 10 − 45 kg ⋅ m 2

hc h2 h2 3h2 h2 2h2 2h 2

(b) = 2( 2 + 1) − 1(1 + 1) = − = =

λ 2I 2I I I I 4π 2 I

λ=

c 4π 2 I

=

( )

3.00 × 108 m / s 4 π 2 1.81 × 10 − 45 kg ⋅ m 2 (

= 1.62 cm

)

2h (

2 6.626 × 10 −34 J ⋅ s )

548 Chapter 43 Solutions

43.10 ( )

The energy of a rotational transition is ∆E = h2 I J where J is the rotational quantum

number of the higher energy state (see Equation 43.7). We do not know J from the data.

However,

∆E =

hc

=

( )(

6.626 × 10 −34 J ⋅ s 3.00 × 108 m s 1 eV )

−19

λ λ 1.60 × 10 J

λ (mm ) ∆E (eV )

0.1204 0.01032

0.0964 0.01288

0.0804 0.01544

0.0690 0.01800

0.0604 0.02056

( )

2

h2 1.055 × 10 −34 J ⋅ s 1 eV

and I= = −19

= 2.72 × 10 −47 kg ⋅ m 2

E1 (0.00256 eV) 1.60 × 10 J

I 2.72 × 10 −47

For the HCl molecule, the internuclear radius is r= = m = 0.130 nm

µ 1.62 × 10 −27

m1m2 35

43.11 µ= = × 1.66 × 10 −27 kg = 1.61 × 10 −27 kg

m1 + m2 36

∆E vib = h

k

µ

(

= 1.055 × 10 −34 ) 480

1.61 × 10 −27

= 5.74 × 10 −20 J = 0.358 eV

1 kA 2

2

= 21 h f : A = = = 1.18 × 10 −11 m = 0.0118 nm

k 320 N / m

(b) For HF, A= = 7.72 × 10 −12 m = 0.00772 nm

970 N / m

Chapter 43 Solutions 549

43.13 (a) The reduced mass of the O 2 is µ=

(16 u) + (16 u) ( )

kg = 1.33 × 10 −26 kg

( )( )

2

The moment of inertia is then I = µ r 2 = 1.33 × 10 −26 kg 1.20 × 10 −10 m = 1.91 × 10 −46 kg ⋅ m 2

( )

2

h2 1.055 × 10 −34 J ⋅ s

= J ( J + 1) = J ( J + 1)

( )

The rotational energies are E rot

2I 2 1.91 × 10 −46 kg ⋅ m 2

Thus (

E rot = 2.91 × 10 −23 J) J(J + 1)

(b)

1

E vib = v + h

k

= v+

2 µ

1

2

(

1.055 × 10 −34 J ⋅ s ) 1177 N / m

8(1.66 × 10 −27 kg)

E vib = v +

1

2

(

)

3.14 × 10 −20 J

1 eV

1.60 × 10 −19

= v+

J

1

2

(0.196 eV)

43.14 In Benzene, the carbon atoms are each 0.110 nm from the axis and each hydrogen atom is

(0.110 + 0.100 nm) = 0.210 nm from the axis. Thus, I = Σmr 2 :

( )( ) ( )( )

2 2

I = 6 1.99 × 10 −26 kg 0.110 × 10 −9 m + 6 1.67 × 10 −27 kg 0.210 × 10 −9 m = 1.89 × 10 −45 kg ⋅ m 2

( )

2

1.055 × 10 −34 J ⋅ s

Erot =

h2

2I

J ( J + 1) =

(

2 1.89 × 10 −45 kg ⋅ m 2

( ) (

J ( J + 1) = 2.95 × 10 −24 J J ( J + 1) = 18.4 × 10 −6 eV J ( J + 1)

) )

Erot = (18.4 µ eV) J ( J + 1) where J = 0, 1, 2, 3, . . .

The first five of these allowed energies are: Erot = 0, 36.9 µ eV, 111 µ eV, 221 µ eV, and 369 µ eV

h2

43.15 hf = J where the rotational transition is from J – 1 to J ,

4π 2 I

J= = = 558

h 6.626 × 10 − 34 J ⋅ s

550 Chapter 43 Solutions

*43.16 The emission energies are the same as the absorption energies, but the final state must be

below ( v = 1, J = 0) . The transition must satisfy ∆J = ±1, so it must end with J = 1. To be

lower in energy, it must be ( v = 0, J = 1) . The emitted photon energy is therefore

hf photon = E vib + E rot − E vib + E rot = E vib − E vib − E rot − E rot

v=1 J = 0 v=0 J = 1 v=1 v = 0 J =1 J = 0

Thus, f photon = f vib − f rot = 6.42 × 1013 Hz − 1.15 × 1011 Hz = 6.41 × 1013 Hz

( )

2

*43.17 The moment of inertia about the molecular axis is I x = 25 mr 2 + 25 mr 2 = 54 m 2.00 × 10 −15 m

( )

2 2

R R m 2

The moment of inertia about a perpendicular axis is I y = m +m = 2.00 × 10 −10 m

2 2 2

( )

The allowed rotational energies are E rot = h2 2I J ( J + 1) , so the energy of the first excited state

is E1 = h I . The ratio is therefore

2

(h I ) = I ( ) = (10 )

2

m 2.00 × 10 −10 m

2 1

E1, x x y 5 5 2

= = 2

= 6.25 × 10 9

E1, y (h I ) I

2

y x

4

5 (

m 2.00 × 10 −15 m ) 8

3

10 −4 m

The number of atoms is −9 ~ 1017

0.261 × 10 m

3

310 −4 m

This number of salt crystals would have volume (10 −4

)

m −9

0.261 × 10 m

~ 10 5 m 3

α ke e 2 1 (1.60 × 10 −19 )2 1

43.19 U= − 1− = −(1.7476)(8.99 × 10 9 ) 1− = − 1.25 × 10 −18 J = – 7.84 eV

r0 m (0.281 × 10 )

−9

8

43.20 Visualize a K+ ion at the center of each shaded cube, a C l– ion at the center of each white one.

The distance ab is 2 ( 0.314 nm) = 0.444 nm

Chapter 43 Solutions 551

ke e 2 ke e 2 ke e 2 ke e 2 ke e 2 ke e 2 ke e 2 ke e 2 2k e 2 1 1 1

43.21 U= − − + + − − + + − ... = − e 1− + − + . . .

r r 2r 2r 3r 3r 4r 4r r 2 3 4

x2 x3 x4

But, ln(1 + x ) = 1 − + − + ...

2 3 4

2ke e 2 e2

so, U= − ln 2, or U = − ke α where α = 2 ln 2

r r

23

h 2 3ne

EF = = (3 / 8 π ) n

23 23

43.22

2m 8 π 2(9.11 × 10 −31

kg)(1.60 × 10 −19

J / eV)

23

h 2 3ne

43.23 The density of conduction electrons n is given by EF =

2m 8 π

[ ]

− 31 3/2

8 π 2 mEF

3/2

8 π 2(9.11 × 10 kg)(5.48)(1.60 × 10 −19 J)

or ne = = = 5.80 × 10 28 m -3

3 h2 3 (6.626 × 10 − 34 J ⋅ s)3

1 atom

(

nAg = 10.6 × 10 3 kg / m 3 )

1u

108 u 1.66 × 10 − 27

kg

= 5.91 × 10 28 m -3

5.80

So an average atom contributes = 0.981 electron to the conduction band

5.91

2

v= − 31

= 1.57 × 106 m/s

9.11 × 10 kg

(b) Larger than 10– 4 m/s by ten orders of magnitude. However, the energy of an electron at

1

room temperature is typically kBT = eV .

40

552 Chapter 43 Solutions

(a) ne =

NA ρ

=

(

6.02 × 10 23 electrons mol 0.971 g cm 3 )( )

M 23.0 g mol

(6.626 × 10 ) 3 (2.54 × 10 )

2 2 3

h 2 3ne 2 3 −34

J⋅s 28

m −3

EF = = = 5.05 × 10 −19 J = 3.15 eV

2 (9.11 × 10 kg )

(b)

2m 8 π −31 8π

(c) vF =

2E F

=

(

2 5.05 × 10 −19 J )= 1.05 × 106 m s

−31

m 9.11 × 10 kg

*43.26 The melting point of silver is 1234 K. Its Fermi energy at 300 K is 5.48 eV. The approximate

fraction of electrons excited is

kBT

=

(

1.38 × 10 −23 J K (1234 K )

≈ 2%

)

EF (

( 5.48 eV) 1.60 × 10 −19 J eV )

[ ]

−1

f = e(

E − EF ) kBT

+1 = 0.950

e(

E − EF ) k B T

= (1/ 0.950) − 1 = 0.0526

E − EF

= ln(0.0526) = − 2.94

kBT

E − EF = − 2.94 = − 0.203 eV or E = 5.28 eV

1.60 × 10 −19 J / eV

Chapter 43 Solutions 553

Goal Solution

Calculate the energy of a conduction electron in silver at 800 K if the probability of finding an electron i n

that state is 0.950. The Fermi energy is 5.48 eV at this temperature.

G: Since there is a 95% probability of finding the electron in this state, its energy should be slightly less

than the Fermi energy, as indicated by the graph in Figure 43.21.

O: The electron energy can be found from the Fermi-Dirac distribution function.

A: Taking EF = 5.48 eV for silver at 800 K, and given f (E) = 0.950, we find

e( E−EF )

1 1

f (E) = = 0.950 or k BT

= − 1 = 0.05263

e ( E−EF ) k BT

+1 0.950

E − EF

kBT

= ln(0.05263) = −2.944 so (

E − EF = −2.944kBT = −2.944 1.38 × 10 −23 J / K (800 K ) )

E = EF − 3.25 × 10 −20 J = 5.48 eV − 0.203 eV = 5.28 eV

L: As expected, the energy of the electron is slightly less than the Fermi energy, which is about 5 eV for

most metals. There is very little probability of finding an electron significantly above the Fermi

energy in a metal.

( )

3

43.28 d = 1.00 mm , so V = 1.00 × 10 −3 m = 1.00 × 10 −9 m 3

8 2 π m3 2

The density of states is g(E) = CE 1 2

= E1 2

h3

( )

3 2

8 2 π 9.11 × 10 −31 kg

or g (E) = ( 4.00 eV)(1.60 × 10 −19 J eV )

(6.626 × 10 )

−34 3

J⋅s

So, the total number of electrons is

( ) (

N = [ g(E)]( ∆E)V = 1.36 × 10 28 m −3 ⋅ eV −1 (0.0250 eV ) 1.00 × 10 −9 m 3 = 3.40 × 1017 electrons )

∞

43.29 Eav = 1 ∫0 EN (E) dE

ne

Since f (E) = 1 for E < E F and f (E) = 0 for E > E F , we can take N(E) = CE1/2

1 EF C EF 2C 5

Eav = ∫0 CE 3/2 dE = ∫0 E 3 2 dE = 2

E

ne ne 5ne

But from Equation 43.24, = EF , so that Eav = E E = EF

ne 2 5 2 F F 5

554 Chapter 43 Solutions

Therefore, sin kxL = 0 and k xL = π , 2π , 3π , . . .

Similarly, sin kyL = 0 and k yL = π , 2π , 3π , . . .

sin kzL = 0 and kzL = π , 2π , 3π , . . .

nx π x ny π y nz π z

ψ = A sin sin sin

L L L

d 2 ψ d 2 ψ d 2 ψ 2me

From + + 2 = 2 (U − E)ψ , we have inside the box, where U = 0,

dx 2 dy 2 dz h

n2 π 2 ny2 π 2 n2 π 2 2me h2 π 2 2

− 2 − 2 − 2 ψ = 2 (−E)ψ E= (nx + ny2 + nz2 ) nx , ny , nz = 1, 2, 3, . . .

x z

L L L h 2me L2

3h2 π 2

The minimum energy state inside the box is nx = ny = nz = 1, with E =

2me L2

g(8.50 eV ) C (8.50)

1 2

Hence, the required ratio is = = 1.10

g(7.00 eV ) C (7.00) 1 2

CE 1 2

(b) From Eq. 43.22, the number of occupied states having energy E is N (E) =

e ( E−EF ) kBT +1

N (8.50 eV ) (8.50)

1 2 e(7.00 − 7.00 ) kBT

+ 1

Hence, the required ratio is = 8.50 − 7.00

N (7.00 eV ) (7.00) 1 e( )

2 kBT

+ 1

N (8.50 eV ) (8.50)

1 2

2.00

At T = 300 K , kBT = 4.14 × 10 −21 J = 0.0259 eV , = (1.50 ) 0.0259

N (7.00 eV ) (7.00) 1 2

e + 1

N (8.50 eV )

And = 1.55 × 10 − 25

N (7.00 eV )

Comparing this result with that from part (a), we conclude that very few states with E > EF are

occupied.

c 3.00 × 108 m / s

(b) c = λf; λ= = = 1.09 × 10 −6 m = 1.09 µm (in the infrared region)

f 2.75 × 1014 Hz

Chapter 43 Solutions 555

43.33 Photons of energy greater than 2.42 eV will be absorbed. This means wavelength shorter than

λ= = = 514 nm

E 2.42 × 1.60 × 10 −19 J

All the hydrogen Balmer lines except for the red line at 656 nm will be absorbed.

43.34 Eg = = J ≈ 1.91 eV

λ 650 × 10 − 9 m

E≥

hc

=

(6.626 × 10 −34

)( )

J ⋅ s 3.00 × 108 m s 1 eV

= 1.24 eV

−6 −19

λ max 1.00 × 10 m 1.60 × 10 J

Thus, the energy gap for the collector material should be Eg ≤ 1.24 eV . Since Si has an

energy gap Eg ≈ 1.14 eV , it will absorb radiation of this energy and greater. Therefore,

Si is acceptable as a material for a solar collector.

Goal Solution

Most solar radiation has a wavelength of 1 µ m or less. What energy gap should the material in a solar

cell have in order to absorb this radiation? Is silicon appropriate (see Table 43.5)?

G: Since most photovoltaic solar cells are made of silicon, this semiconductor seems to be an

appropriate material for these devices.

O: To absorb the longest-wavelength photons, the energy gap should be no larger than the photon

energy.

hf =

hc

=

( )(

6.63 × 10 −34 J ⋅ s 3.00 × 108 m / s ) 1 eV

= 1.24 eV

-19

λ 10 m-6

1.60 × 10 J

Therefore, the energy gap in the absorbing material should be smaller than 1.24 eV.

L: So silicon, with gap of 1.14 eV < 1.24 eV, is an appropriate material for absorbing solar radiation.

*43.36 If the photon energy is 5.5 eV or higher, the diamond window will absorb. Here,

(h f )max = λ hc

= 5.50 eV : λ min =

hc

=

( )(

6.626 × 10 −34 J ⋅ s 3.00 × 108 m s )

min 5.5 eV (

( 5.5 eV) 1.60 × 10 −19 J eV )

λ min = 2.26 × 10 −7 m = 226 nm

556 Chapter 43 Solutions

43.37 (

I = I 0 e e ( ∆V ) kBT

)

− 1 Thus, e e ( ∆V ) kBT

= 1 + I I0

ln(1 + I I 0 )

kBT

and ∆V =

e

At T = 300 K , ∆V =

(1.38 × 10 −23

)

J K ( 300 K ) I I

ln 1 + = ( 25.9 mV ) ln 1 +

1.60 × 10 −19 C I0 I0

The basic idea behind a semiconductor device is that a large current or charge can be

controlled by a small control voltage.

43.38 The voltage across the diode is about 0.6 V. The voltage drop across the resistor is

(0.025 A)(150 Ω) = 3.75 V. Thus, E − 0.6 V − 3.8 V = 0 and E = 4.4 V

)

− 1 , given that I = 200 mA when ∆V = 100 mV and

T = 300 K .

e( ∆V )

=

(

1.60 × 10 −19 C (0.100 V ) )= 3.86 so I0 =

I

=

200 mA

= 4.28 mA

kBT (

1.38 × 10 −23 J K ( 300 K ) ) e e ( ∆V ) k B T

−1 e 3.86 − 1

e( ∆V )

If ∆V = −100 mV, = − 3.86 ; and the current will be

kBT

(

I = I 0 e e ( ∆V ) kBT

) ( )

− 1 = ( 4.28 mA ) e − 3.86 − 1 = – 4.19 mA

(b) For a surface current around the outside of the cylinder as shown,

B= or NI = = = 10.7 kA

l µ0 (4 π × 10 −7 ) T ⋅ m / A

Chapter 43 Solutions 557

∆Φ B ∆I ∆B

43.41 By Faraday’s law (Equation 32.1), =L =A .

∆t ∆t ∆t

2

Thus, ∆I = = = 203 A

L 3.10 × 10 −8 H

The direction of the induced current is such as to maintain the B – field through the ring.

Goal Solution

Determine the current generated in a superconducting ring of niobium metal 2.00 cm in diameter if a

0.0200-T magnetic field in a direction perpendicular to the ring is suddenly decreased to zero. The

inductance of the ring is 3.10 × 10-8 H.

G: The resistance of a superconductor is zero, so the current is limited only by the change in magnetic

flux and self-inductance. Therefore, unusually large currents (greater than 100 A) are possible.

O: The change in magnetic field through the ring will induce an emf according to Faraday’s law of

induction. Since we do not know how fast the magnetic field is changing, we must use the ring’s

inductance and the geometry of the ring to calculate the magnetic flux, which can then be used to find

the current.

2

∆Φ B ∆B ∆I

ε = =A =L or ∆I = = = 203 A

∆t ∆t ∆t L 3.10 × 10 −8 H

The current is directed so as to produce its own magnetic field in the direction of the original field.

L : This induced current should remain constant as long as the ring is superconducting. If the ring failed

to be a superconductor (e.g. if it warmed above the critical temperature), the metal would have a non-

zero resistance, and the current would quickly drop to zero. It is interesting to note that we were able

to calculate the current in the ring without knowing the emf. In order to calculate the emf, we would

need to know how quickly the magnetic field goes to zero.

43.42 (a) ∆V = IR

Slope =

1

=

∆I

=

(155 − 57.8) mA = 43.1 Ω −1

R ∆V ( 3.61 − 1.356) mV

R = 0.0232 Ω

(c) Expulsion of magnetic flux and therefore fewer current-carrying paths could explain the

decrease in current.

558 Chapter 43 Solutions

*43.43 (a) Since the interatomic potential is the same for both molecules, the spring constant is the

same.

Then f =

1 k

where µ 12 =

(12 u)(16 u) = 6.86 u and µ 14 =

(14 u)(16 u) = 7.47 u

2π µ 12 u + 16 u 14 u + 16 u

Therefore,

k µ 12 µ 12

f 14 =

1

2π

k

=

1

µ 14 2 π

µ 12 µ 14

= f 12

µ 14

(

= 6.42 × 1013 Hz ) 6.86 u

7.47 u

= 6.15 × 1013 Hz

µ 14 µ 14

I14 = µ 14 r 2 = µ 12 r 2 = I12

µ 12 µ 12

I14 =

7.47 u

6.86 u ( )

1.46 × 10 −46 kg ⋅ m 2 = 1.59 × 10 −46 kg ⋅ m 2

(c) The molecule can move to the ( v = 1, J = 9) state or to the ( v = 1, J = 11) state. The energy it

can absorb is either

hc h2 h2

∆E =

λ

( )

= 1 + 21 h f 14 + 9(9 + 1)

2I14

1

( )

− 0 + 2 h f 14 + 10(10 + 1) ,

2I14

hc h2 1 h f + 10(10 + 1) h .

2

or ∆E =

λ

( )

= 1 + 21 h f 14 + 11(11 + 1) −

2I14

0 + 2 14( )

2I14

c c

λ= or λ =

f 14 − 10h ( 2 π I14 ) f 14 + 11h ( 2 π I14 )

3.00 × 108 m s

λ= = 4.96 µ m

( )

These are:

10 1.055 × 10 −34 J ⋅ s

6.15 × 1013 Hz −

(

2 π 1.59 × 10 −46 kg ⋅ m 2 )

3.00 × 108 m s

λ= = 4.79 µ m

( )

and

11 1.055 × 10 −34 J ⋅ s

6.15 × 1013 Hz +

(

2 π 1.59 × 10 −46 kg ⋅ m 2 )

Chapter 43 Solutions 559

For a rotational state sufficient to allow a transition to the first exited vibrational state,

J(J + 1) = hω so J(J + 1) = = = 1410

2I h 1.055 × 10 −34

Thus J = 37

43.45 ∆Emax = 4.5 eV = v + hω so ≥ v+

2 (1.055 × 10 −34

J ⋅ s)(8.28 × 10 s )

14 −1

2

43.46 With 4 van der Waal bonds per atom pair or 2 electrons per atom, the total energy of the solid

is

6.02 × 10 23 atoms

E = 2(1.74 × 10 −23 J / atom) = 5.23 J/g

4.00 g

ke e 2 B

43.47 The total potential energy is given by Equation 43.16: U total = − α + m

r r

The total potential energy has its minimum value U 0 at the equilibrium spacing, r = r 0 . At

this point, dU dr r = r0

= 0,

dU d k e2 B ke e 2 mB

or = −α e + m =α 2

− m+1

=0

dr r = r0 dr r r r0 r0

r = r0

ke e 2 m − 1

Thus, B=α r

m 0

ke e 2 k e2 m − 1 1 k e2 1

Substituting this value of B into U total , U0 = − α + α e r0 m = −α e 1−

r0 m r r m

0 0

depth of the well below the dissociation point. We see h f = 0.520 eV , so the depth of the well

is

1 h f + 4.48 eV = 1 (0.520 eV ) + 4.48 eV = 4.74 eV

2 2

560 Chapter 43 Solutions

dU

dx

= 0:

d

dx

( )

Ax −3 − Bx −1 = − 3Ax −4 + Bx −2 = 0

−2

x → ∞ describes one equilibrium position, but the stable equilibrium position is at 3Ax0 = B.

x0 =

3A

=

(

3 0.150 eV ⋅ nm 3 )= 0.350 nm

B 3.68 eV ⋅ nm

A B AB 3 2 BB 1 2

(b) The depth of the well is given by U0 = U x = x = − = −

0 x03 x0 3 3 2 A 3 2

31 2A1 2

2 ( 3.68 eV ⋅ nm )

3 2

2B 3 2

U0 = U x = x = − = − = – 7.02 eV

( )

3 2 1 2 1 2

0 3 A 33 2

0.150 eV ⋅ nm 3

dU

(c) Fx = − = 3Ax −4 − Bx −2

dx

dFx

To find the maximum force, we determine finite xm such that =0

dx x = xm

[ ]

1 2

6A

Thus, −12Ax −5 + 2Bx −3 =0 so that xm =

x = x0 B

Fmax = 3A

B

−B

2

B

= −

B2

= −

(3.68 eV ⋅ nm) 2

( )

Then

6A 6A 12A 12 0.150 eV ⋅ nm 3

eV 1.60 × 10 −19 J 1 nm −9

or Fmax = − 7.52 − 9 = −1.20 × 10 N = −1.20 nN

nm 1 eV 10 m

dU

dx

= 0:

d

dx

( )

Ax −3 − Bx −1 = −3Ax −4 + Bx −2 = 0

−2

3Ax0 = B or x0 = 3A B

A B AB 3 2 BB 1 2 B3

(b) The depth of the well is given by U0 = U x = x = 3

− = 3 2 3 2

− = −2

0 x0 x0 3 A 3 A11 2 2

27A

dU

(c) Fx = − = 3Ax −4 − Bx −2

dx

[ ]

2

dFx B B B2

= −12Ax −5 + 2Bx −3 =0 then Fmax = 3A −B = −

dx x = xm x = x0 6A 6A 12A

Chapter 43 Solutions 561

dU −a( r e − r 0 ) −a( r e − r 0 )

*43.51 (a) At equilibrium separation, r = re , = − 2aB e − 1 e =0

dr r = re

We have neutral equilibrium as re → ∞ and stable equilibrium at e

(

−a r e −r 0 ) = 1,

or re = r 0

(c) We expand the potential in a Taylor series about the equilibrium point:

( ) (r − r 0 ) + 21 ddrU2 (r − r 0 )

2

dU 2

U (r ) ≈ U r 0 +

dr r = r0 r = r0

−2( r − r 0 ) − ( r − r 0 ) −2( r − r 0 )

U (r ) ≈ 0 + 0 + 21 ( − 2Ba)−ae ( ) ( )

2 2

− ae e − 1 r − r0 ≈ Ba2 r − r 0

r = r

0

( )

2

This is of the form 1 kx 2

2

= 21 k r − r 0

1 k a 2B a B

Then the molecule vibrates with frequency f= = =

2π µ 2π µ π 2µ

1 hω ha B

(d) The zero-point energy is = 21 h f =

2 π 8µ

ha B

Therefore, to dissociate the molecule in its ground state requires energy B−

π 8µ

562 Chapter 43 Solutions

43.52

T=0 T = 0.1T F T = 0.2T F T = 0.5T F

E TF E TF E TF E TF

−1 −1 −1 −1

E / EF

e EF T f (E) e EF T f (E) e EF T f (E) e EF T f (E)

−∞ −10.0 −5.00 −2.00

0 e 1.00 e 1.000 e 0.993 e 0.881

−∞ −5.00 −2.50 −1.00

0.500 e 1.00 e 0.993 e 0.924 e 0.731

−∞ −4.00 −2.00 −0.800

0.600 e 1.00 e 0.982 e 0.881 e 0.690

−∞ −3.00 −1.50 −0.600

0.700 e 1.00 e 0.953 e 0.818 e 0.646

−∞ −2.00 −1.00 −0.400

0.800 e 1.00 e 0.881 e 0.731 e 0.599

−∞ −1.00 −0.500 −0.200

0.900 e 1.00 e 0.731 e 0.622 e 0.550

0 0 0 0

1.00 e 0.500 e 0.500 e 0.500 e 0.500

+∞ 1.00 0.500 0.200

1.10 e 0.00 e 0.269 e 0.378 e 0.450

+∞ 2.00 1.00 0.400

1.20 e 0.00 e 0.119 e 0.269 e 0.401

+∞ 3.00 1.50 0.600

1.30 e 0.00 e 0.0474 e 0.182 e 0.354

+∞ 4.00 2.00 0.800

1.40 e 0.00 e 0.0180 e 0.119 e 0.310

1.50 e +∞ 0.00 e 5.00 0.00669 e 2.50 0.0759 e1.00 0.269

Chapter 43 Solutions 563

contribution of these ions to the electrostatic

potential energy is − 6 ke e 2 r 0 .

contribution to the electrostatic potential energy is

+12 ke e 2 2 r 0 . Next, there are 8 Cl − ions at distance

r = 3 r 0 . These contribute a term of − 8 ke e 2 3 r 0 to

the electrostatic potential energy.

12 8 ke e 2 k e2 ke e 2

U = −6 + − = − 2.13 e or U = −α with α = 2.13

2 3 r0 r0 r0

(b) The fourth term consists of 6 Na+ at distance r = 2r0 . Thus, to four terms,

ke e 2 k e2

U = ( − 2.13 + 3) = 0.866 e

r0 r0

So we see that the electrostatic potential energy is not even attractive to 4 terms, and that the

infinite series does not converge rapidly when groups of atoms corresponding to nearest

neighbors, next-nearest neighbors, etc. are added together.

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