12

th
(Date: 23-09-2012) ReviewTest-5
(JEEMAINS)
Code-B
ANSWER KEY
PHYSICS
SECTION-1
PART-A
Q.1 C
Q.2 D
Q.3 B
Q.4
8
A
Q.5
9
A
Q.6
10
C
Q.7
4
A
Q.8
5
A
Q.9
6
B
Q.10
7
A
Q.11 C
Q.12 A
Q.13 B
Q.14
16
B
Q.15
17
C
Q.16
18
A
Q.17
19
C
Q.18
14
D
Q.19
15
B
Q.20 D
Q.21 B
Q.22
24
B
Q.23
25
D
Q.24
26
B
Q.25
22
C
Q.26
23
D
Q.27 D
Q.28
32
C
Q.29
33
C
Q.30
28
D
Q.31
29
A
Q.32
30
A
Q.33
31
B
CHEMISTRY
SECTION-2
PART-A
Q.1
11
D
Q.2
12
D
Q.3
13
A
Q.4
14
B
Q.5
15
B
Q.6
16
A
Q.7
17
B
Q.8
18
A
Q.9
19
D
Q.10
20
D
Q.11
21
A
Q.12
22
A
Q.13
23
C
Q.14
24
B
Q.15
25
D
Q.16
26
A
Q.17
27
C
Q.18
28
A
Q.19
29
B
Q.20
30
B
Q.21
31
C
Q.22
32
D
Q.23
33
A
Q.24
1
D
Q.25
2
D
Q.26
3
A
Q.27
4
B
Q.28
5
A
Q.29
6
C
Q.30
7
A
Q.31
8
C
Q.32
9
B
Q.33
10
C
MATHS
SECTION-3
PART-A
Q.1 B
Q.2 C
Q.3 B
Q.4
7
A
Q.5
8
B
Q.6
9
C
Q.7
4
D
Q.8
5
B
Q.9
6
D
Q.10
13
A
Q.11
14
C
Q.12
15
A
Q.13
10
B
Q.14
11
C
Q.15
12
B
Q.16
19
A
Q.17
20
C
Q.18
21
B
Q.19
16
A
Q.20
17
A
Q.21
18
A
Q.22
25
D
Q.23
2
C or D
Q.24
27
B
Q.25
22
C
Q.26
23
D
Q.27
24
B
Q.28
31
D
Q.29
32
D
Q.30
33
C
Q.31
28
D
Q.32
29
D
Q.33
30
D
Code-B Page # 1
PHYSICS
PART-A
Q.1
[Sol. Violates newton's 3
rd
law ]
Q.2
[Sol. v
0
= 12
2 . 1
2t
= 20t
32 =
2
2
) 20 (
x 10
2
1
t

10
400 64
2
t
= x
2
8 20 = 160 m ]
Q.3
[Sol. Perpendicular vector cannot give sumequal to zero. ]
Q.4
[Sol.
PO
V m P D H

= ]
Q.5
[Sol. F =mg sin 30
FR=
2
1
mR
2
o
R
30 sin g 2
]
Q.6
[Sol. gh 2 v = = 4 10 2 = 5 2 2
5 4 v =
]
Q.7
[Sol.
) i

2 . 0 ( 6 ) i

8 . 1 ( 4 +
=
) i

4 . 1 ( 6 ) i

6 . 0 ( 4 +
velocity of approach = 1.8 + 0.2 = 2
velocityof separation = 1.4 + 0.6 = 2 ]
Q.9
[Sol. k 0.06 =
1
2 3 . 0
2

k = 20 ]
Q.11
[Sol. Q = nC
p
AT
= 9
6 . 1
25 R 6 . 1
200 = 40000 ]
Code-B Page # 2
PHYSICS
Q.12
[Sol. C
3
become short after closing S
1
and S
2
. ]
Q.13
[Sol. t = pE = 10
12

2
10
8

]
Q.14
[Sol. W = qEx = 8 10 10 10
2
]
Q.15
[Sol. Fromrarer to denser, rayshould bend towards normal ]
Q.16
[Sol. This question is most easilyanswered if you have a picture of second harmonic motion in your head.
Most of these standing wave problems, here and sound waves , are best solved byknowing what they
look like. The string vibrates the most at a distance of L/4 fromeither end the string. ]
Q.17
[Sol.
dt
dQ
= mc |
dt
dT
+ ]
Q.18
[Sol. C=
v
Q
= k
|
.
|

\
|e
d
A
0
, slope heigher k heigher ]
Q.19
[Sol. Animportant point toremember about electricfields is that theyemanate
frompositive charges and point towards negative charges. With this in
mind, we knowchoicesAand Care incorrect. The next question is to
judge the straightness or curvature of the lines between the plates.
+ + + + + + +

Imagine a point placed directlybetween two parallel plates (see the diagramto the right). It will have a
net electric field determined byall the individual electric fields generated byeverycharge on the two
plates. For clarity, onlyfive electric field lines are shown in the diagram. If these field lines are added
vectorially, all the horizontal components will cancel each other out; a net field oriented vertically
downward will remain (the field lines shown in the choices are the possible net electric fields). The
cancellation is due to the symmetry of the point in space with respect to the charges on the plates.
However, this horizontal component cancellation continues onlyuntil one approaches the left andright
edges of the plates. Here, thefield lines bowout, muchlike those arounda dipole (the parallel plates are
like several dipoles positioned next to each other). Remember, between parallel plates of opposite
charge, the field lines are straight. Theyare also constant in strength throughout the interplate region.
Thus, a parallel plate arrangement is agooddesignfor capacitors, electrophoresis equipment, andcharge
accelerators. The correct choice is B. ]
Code-B Page # 3
PHYSICS
Q.22
[Sol.
2
gh
1
=
2
gh
2

12
=
5
20
500
h
h
1
2
2
=

1
= 2000 kg/m
3
]
Q.23
[Sol. Phase change in first reflection shouldchange byt. ]
Q.24
[Sol. E R
(

+ +
CR
Q
CR
Q
dt
dQ

C
Q
= 0
E
C
Q 3
=
dt
RdQ
( ) 3 / RC
Q
3
EC
(

=
dt
dQ
]
Q.26
[Sol.
F
]
Q.27
Sol. W =
2
r
GMm

2
r
1
]
Q.31
[Sol. 1.98 R
S
= 0.02 25 = 0.5 ]
Q.32
[Sol.
2
1
E
E
=
2
1

]
Q.33
[Sol. K
i
= W = k
f
K
i
= 300 eV
w = e(1500) 1.2 = 1800 eV ]
CHEMISTRY
Code-B Page # 1
PART-A
Q.1
[Sol. Due to back - donation, all would have longer CO length than free CO molecule. ]
Q.2
Sol.
O

HCl . conc
Hg Zn




N H /EtO
2 4

LiAlH
4
OH
H

/ KMnO
4
/ A is oxidising agent, it will not reduce cyclohexanone.
Q.3
Sol. BCl C = 0.01 M
B
+
+ H
2
O BOH + H
+
K
h
=
x c
x
K
K
2
b
w

=
c
cx x x
x 01 . 0
x
10
10
2
6
14

x
2
= 10
8
0.01
x
2
= 10
10
; x = 10
5
Q.4
[Sol. AlF
3
is ionic. AlBr
3
and AlI
3
exist as dimer. ]
Q.5
Sol. Carbonyl compounds containing
O
| |
C CH
3

unit will give iodoform test.
Q.6
Sol. X X X
B
C C
B
(g) X
(g)
+ X X
B
C C
B
(g)

A A = A
t tan reac f product f reaction
H H H
AH = [100 + 300] [200] kJ / mole
AH = 400 kJ
AH
reaction
=


product reactant
BE BE
= BE
XX
= 400 kJ
CHEMISTRY
Code-B Page # 2
Q.7
[Sol.
6
7 2
O Si
is Pyrosilicate
O
O
O
O
O
]
Q.8
Sol. Rate of reaction o electrophilicity of C= O group.
Q.9
Sol. K
C
=0.98 at 300 K
K
C
= 1.2 at 400 K
(

A
=
(
(

2 1 C
C
T
1
T
1
R
H
K
K
ln
1
2
(A) With increase in temperature K
C
increases so reaction is endothermic
(B) AG = RT ln K
C
AG < 0 at standard condition
K
C
> 1 so reaction is non spontaneous at 300 K spontaneous at 400 K
(C)
(

A
=
(

120000
100
R
H
98 . 0
2 . 1
ln
AH = 1200 R
(

98 . 0
2 . 1
ln
(D) AG = AH TAS
as AG
=
0
So, AS
=
T
H

A
AS
=
. eq at T
H A
Q.10
[Sol. B
2
H
6
, Fe
2
Cl
6
and FeCl
4

are non-planar
H
H
B B
H
H
H
H

Cl
Fe
Cl
Fe
Cl
Cl
Cl
Cl

Fe
Cl
Cl
Cl
Cl
]
CHEMISTRY
Code-B Page # 3
Q.11
Sol. Cross aldol condensation take place product(s) will be B, C and D [o,|-unsaturated carbonyl
compounds]
Q.12
Sol. x mole x mole
Na
2
C
2
O
4
KHC
2
O
4
. 3H
2
C
2
O
4
with KMnO
4
m
eq
KMnO
4
= m
eq
of salts
0.1 V
1
5 = [x 2 + x 8] 1000
with NaOH
m
eq
NaOH = m
eq
of acid
0.2 V
2
1 = x 7 1000
=
7
4
35
20
2 . 0
1000 x 7
1000
5 . 0
x 10
V
V
2
1
= =

=
Q.13
[Sol. Ligand field strength follows the order Cl

< H
2
O < NH
3
< CN

]
Q.14
Sol. Carboxylic acid + Optically active alcohol

H
Mixture of Diastereomers
( or d/l or racemic mixture )
Q.15
Sol. (A)
10
40 05 . 0
10
40 M
v
w
%

=

=
= 0.2
(B) n
NaOH
= 0.05 mole
66 . 55
18
002 . 1 1000
n
O H
2
=

=
X
NaOH
=
66 . 55 05 . 0
05 . 0
+
(C)
% 2 . 0
v
w
% =
%
02 . 10
2
002 . 1
2 . v / w %
v
w
% =
0
=

=
(D) ppm =
pm 2000 10
1000
40 05 . 0
6
~

CHEMISTRY
Code-B Page # 4
Q.16
[Sol.
F
F
Br
F F
F
]
Q.17
Sol. Acid-base reaction take place
Q.18
Sol. (I)
8
32
M
M
r
r
A
B
B
A
= =
2
r
r
B
A
=
r
A
= 2r
B
(II) H
2(g)
+
2
1
O
2(g)
H
2
O
(g)
o
f
S A
(H
2
O, gas) < 0
as An
g
< 0
(III) 90 ml of HCl (pH = 3)
3
H
10 C

=
+
10 ml of NaOH (pH = 11)
3
OH
10 C

=

60 ml of H
2
O
3
H
10 90 mole m

=
+
3
OH
10 10 mole m

=

3
H
10 80 left mole m

=
+
3
3
H
10
2
1
160
10 80
left C

=
+
pH = log
(

3
10
2
1
= 3 + log 2
pH = 3.3010
Q.19
[Sol. ClO
2
and NO
2
are odd-electron species and O
2
has two unpaired electrons in
*
p 2
x
t and
*
p 2
y
t
molecular
orbitals.]
CHEMISTRY
Code-B Page # 5
Q.20
Sol. Me
O
para
meta
+I
+H
O
O
Me
COH
CNH
2
Q.21
Sol. R = 8.314 JK
1
mole
1
; T = 115.4 K ; M =
mole / kg
1000
32
M
RT 3
U
rms
=
U
avg
=
M
RT 8
t
U
MP
=
M
RT 2
(A) All molecule will have different speed.
(B) U
avg
=
. sec / m 38 . 276
M
RT 8
=
t
(C) U
MP
= 300
. sec / m
3
2
(D) U
rms
=
32
1000 4 . 115 314 . 8 3
M
RT 3
=
PV = nRT
3 1 =
T 08314 . 0
32
10

; T = 115.4 K
U
rms
= 300 m/sec.
Q.22
[Sol. SCl
6
does not exist due to steric crowding.]
Q.23
Sol. PhOMe
partial
double bond

) excess (
HI
PhOH + MeI
Q.24
Sol. At radial node
(r)
= 0
| | 0 e ) 12 8 )( 1 (
2 / 2
= + o o o
o
o 1 =0 , o
2
8o + 12 = 0 , 0 e
2 /
=
o
Hence o = 1,o = 6, 2 and o =
Subtituting the value of o in o =
0
a
r 2
Thus r =
2
a
0
, r = 3a
0
, r = a
0
and r = will have node
Thus there will be No radial node at r = 2a
0
CHEMISTRY
Code-B Page # 6
Q.25
[Sol. Reaction (C) is involved in smelting (Pyrometallurgy)]
Q.26
Sol. CH
3
CH
2
Cl
KCN
CH
3
CH
2
CN
K C N

Ionic bond

This is more
nucleophilic
than N
N C
Q.27
Sol. P
(g)
Q
(g)
+ R
(g)
t = 0 1.5 atm
t =20 1.5 x x x 1.5 + x = 2 atm
x = 0.5 atm
t =40 1.5 x' x' x' 1.5 + x' =
atm
3
7
x' =
6
5
2
3
3
7
=
at t = 20 min
K =
(

=
(

2
3
ln
20
1
x 5 . 1
5 . 1
ln
20
1
at t= 40 min
K =
(

' x 5 . 1
5 . 1
ln
40
1
K =
(

=
(

=
(
(
(

2
3
ln
20
1
4
9
ln
40
1
6
5
5 . 1
5 . 1
ln
40
1
Q.28
[Sol. Ligands are named in alphabetical order. ]
Q.29
Sol. Rate of S
N
1 o stability of carbocation formed
CHEMISTRY
Code-B Page # 7
Q.30
Sol. H
2(g)
+ S
(s)
H
2
S
(g)
K
c
= 8 10
2
0.3 mole 2 mole 0
l 2
x 3 . 0
l 2
x
K
C
=
2
x 3 . 0
2
x

= 8 10
2
x 3 . 0
x

= 8 10
2
x = 0.024 0.08 x
1.08 x = 0.024
x = 0.0222
litre 2 P
S H
2

= 0.0222 0.08 360
atm 319 . 0 P
O H
2
~
Q.31
[Sol. Square planar complex having monodentate ligands does not show optical isomerism due to presence of
plane of symmetry.
H N
3
Br
Pt
Py Cl
H N
3
H N
3
Br Br
Pt Pt
Py
Py Cl
Cl
and
are geometrical isomers.]
Q.32
Sol. (A) CH
3
CH = CH CH
3

O H / Zn
O
2
3


O
| |
H C CH
3

(B) CH
3
CH
2
CH = CH
2

O H / Zn
O
2
3

O
| |
H C CH CH
2 3

+
O
| |
H C H
(C) CH
2
= CH CH = CH
2

O H / Zn
O
2
3


O
| |
H C H 2
+
CHO
|
CHO
(D)
O H / Zn
O
2
3


CHO
|
CHO 3
CHEMISTRY
Code-B Page # 8
Q.33
Sol.
A
100
B
800
50 400
200
100
50
25
50 min 10 min
10 min
10 min
10 min
10 min
t = 50 min
MATHEMATICS
Code-B Page # 1
PART-A
Q.1
[Sol. UsingSinelaw,
C sin
B sin A sin
c = 2 a = 4
b = 5
C A
B
=
c
b a
=
2
5 4
=
2
1
. Ans.]
Q.2
[Sol. Number of ways is 2 4 4 = 32.
2 4 4
]
Q.3
[Sol. Let f(x) = x
2
+ (1 b)x + (b 5)
x = 0
x = |
f(x)
x
x = o
f(0) < 0
b 5 < 0 b < 5
b
Largest integer
= 0004. Ans. ]
Q.4
[Sol.
2
) 1 n ( n +
= 45 n =9 Ans.]
Q.5
[Sol. Given
}
1
0
dx ) x ( f = 4 and
}
2
0
dx ) x ( f = 6
Now
}

2
1
dx ) x ( f =
} }
+

2
1
1
1
dx ) x ( f dx ) x ( f = 8 + 2 = 10. Ans. ]
Q.6
[Sol. When y =
2
5
We have,
3 x 5
2 x 3

+
=
2
5
x = 1;
dx
dy
=
2
) 3 x 5 (
19

g ' (x) =
19
) 3 x 5 (
2

g ' (1) =
19
4
Ans.]
Q.7
[Sol.
dx
dy
=
dx
dv

dv
du

du
dy
= sec
2
u
|
.
|

\
| 1
|
.
|

\
|
+
x v
1
1
2

e x
dx
dy
=
= 1 (1 + 1)
e
1
=
e
2
. Ans.]
MATHEMATICS
Code-B Page # 2
Q.8
[Sol. x eR, tan
1
x e |
.
|

\
| t t
2
,
2
. So cos(tan
1
x) e(0, 1]. Ans.]
Q.9
[Sol. A+ A
T
= O
(

u
u
sin 2 0
0 sin 2
= O
sin u = 0 u = nt, n eI
u = t e (0, 6). Ans.]
Q.10
[Sol. t
r+1
=
14
C
r
( )
r
r 14
2
x
1
x

=
14
C
r
x
28 3r
28 3r = 1 r = 9
Coefficient is =
14
C
9
=
14
C
5
Ans. Ans.]
Q.11
[Sol. | B | =
r c z
q b y
p a x
8

=
r c z
q b y
p a x
8
=
r q p
c b a
z y x
8 = 8 | A| = 16 Ans. ]
Q.12
[Sol.
p
dx
dy
=
1
1
y
x
=
4
3
y
1
=
3
x 4
1
(
x
,
y
)
1
1
P
Y
X
(0,0)
Also x
1
2
+ y
1
2
= 4
9
x 16
x
2
1
2
1
+ = 4
25x
1
2
= 36 x
1
=
5
6
y
1
=
5
8
Ans.]
Q.13
[Sol. We have, f (x) = dt ) 12 t t ( ) 4 t ( e
2
2
x
3
2 t
}
+

f '(x) = 2x
4
x
e

(x
2
4) (x
4
x
2
+ 12)
= 2x
4
x
e

(x 2) (x + 2) (x
4
x
2
+ 12)
0 2 2
+ +
Sign of f '(x)
f(x) + on ( , 2) (0, 2). Ans.]
MATHEMATICS
Code-B Page # 3
Q.14
[Sol. S =
r 1
a

= 20
2
2
r 1
a

= 80 r =
3
2
a =
3
20
=
q
p
(p + q) = 23. Ans.]
Q.15
[Sol.

=

|
.
|

\
|

n
1 r
2
n n
r
1
n
1
Lim
=
}

1
0
2
dx x 1
=
}
t
u u
2
0
2
d cos =
4
t
Ans.]
Q.16
[Sol. Since Lis the tangent tothe hyperbola,
we knowthat its slope is given by
m =
dx
dy
=
2
x
6
at x = 3, that is m =
3
2
.
An Equation for this line is y 2 =
3
2
(x 3).
A
(0,4)
(6,0)
Fromthis equation we get that B=4 and
A=6 which implies that the area is 12. ]
Q.17
[Sol. f '(x) =
3
4
x
3
x
4
f "(x) = 4x
2
4x
3
= 4x
2
(1 x) = 0
x = 1
f "'(x) = 8x 12x
2
f '''(1) = 4 < 0. Ans.]
Q.18
[Sol.
M A
=
4
25
4
1
1 + +
=
2
30
A(1,1,1)
B(2,3,4) C(2,0,3)
\14 \14
M
|
.
|

\
|
2
7
,
2
3
, 0
Ans. ]
Q.19
[Sol. sin x (1 + 2 cos x) > 0
0 2
3
t t 4
3
t 2t
+ +
. Ans. ]
MATHEMATICS
Code-B Page # 4
Q.20
[Sol. f(x)
}
x
0
dt t sin =C(given)
f(x) (1 cos x) = C
put x = t
2(2) = C C = 4
f(x) =
x cos 1
4

|
.
|

\
| t
2
f = 4. Ans. ]
Q.21
[Sol. Slope of OC = tan (u + 45) where tan u =
4
1
=
4
1
1
1
4
1

+
=
3
5
Ans.]
45
u
1/4
B
C
D
O
4
Y
X
Q.22
[Sol.
(A) For f(x) = 3x
2
2, f(2) = f(3)
(B) For f(x) = | x 1|, f '(1) does not exist.
(C) For f(x) =| sgn x|, f(x) is discontinuous at x = 0 e[ 1, 1]
(D) For f(x) =
x
1
x + , |
.
|

\
|
3
1
f =f(3), continuous in
(

3 ,
3
1
and differentiable in
|
.
|

\
|
3 ,
3
1
. Ans.]
Q.23
[Sol. MC = 3 sin 60 =
2
3 3
MC = j

2
3 3
Now MB CB MC = +
C
A
M B
X
Y
60
x
3
2
3
i
i

3
2
,
3 3
2
O
B C j

2
3 3
+ =
i

2
3
( ) j

3 i

2
3
CB = . Ans.]
MATHEMATICS
Code-B Page # 5
Q.24
[Sol. Draw graph of y = p and y = 3x
2
2x
3
y
1
y = p
O
x
Hence, for three roots p e[0, 1]. Ans.
Aliter: Let f(x) = 2x
3
3x
2
+ p
f '(x) = 6x (x 1)
f '(x) = 0
0
1
Now, f (0) f(1) s 0 p (p 1) s 0 p e [0, 1]. Ans.]
Q.25
[Sol. f ( 1

) = f ( 1
+
) p + q = p 1 + 2q q = 1.
Also, f ' ( 1

) = f ' ( 1
+
) p = 3p + 1 p =
2
1
. Ans.]
Q.26
[Sol. f(u) =
u + u
2
cos 2 2 sin 3
1
=
1 2 cos 2 sin 3
1
+ u + u
f (u)|
min
=
1 2
1
+
=
3
1
. Ans.]
Q.27
[Sol. I = dx x sec x tan e e
4
0
2 x tan
2
}
t
Put tan x = t
=
}
1
0
t
dt t e e
2
=
1
0
t
2
e
2
e
(

(
=
] 1 e [
2
e

=
2
e e
2

Ans. ]
Q.28
[Sol.
3
cos
t
=
3
k h
2 2
+
h
2
+ k
2
=
4
9
C (0, 0)
r = 3
A B
P
(h, k)

t
/
3
. Ans. ]
MATHEMATICS
Code-B Page # 6
Q.29
[Sol. We have x cos x ) x ( ' f = ,
|
.
|

\
| t
e
2
5
, 0 x
0
2
t
2
3t
2
5t
+ +
sign of f ' (x)
f (x) has local maximumat
2
t
andlocal minimumat
2
3t
Ans.]
Q.30
[Sol. Clearly, (x, x) eR x eW,
So, Ris reflexive.
Let (x, y) eR then (y, x) eR as x and y have atleast one letter in common.
So Ris also symmetric.
But Ris not transitive
e.g. let x = M I LK
y = L I M E
and z =ENERGY
then (x, y) eR and (y, z) eR but (x, z) eR. Ans.]
Q.31
[Hint: The equation will be satisfied for everypoint lyingonthe x-axis or anypoint lyingon the y-axis.]
Q.32
[Sol. Put log
3
x = a and log
2
y = b
Now a + b = 1 .....(1)
and 2
a
= 2 3
b
.....(2)
On putting b = (1 a) from(1) in (2),
we get
2
a
= 2 3
1 a
6
a
= 6
a = 1 and b = 0
x = 3 and y = 1
Hence, (x
0
3
+ y
0
3
) = (3)
3
+ (1)
3
= 28 Ans.]
Q.33
[Sol. L
1
and L
2
are intersectinglines.
The position vector of their point of intersection is k

6 j

7 i

5 + (For =2 or =1).
Also, angle between L
1
and L
2
=
42 11
70
. Ans.]