13

th
VXY (Date: 04-09-2011) Review Test-2
PAPER-1
Code-A
ANSWER KEY
MATHS
SECTION-2
PART-A
Q.1 D
Q.2 C
Q.3 C
Q.4 B
Q.5 B
Q.6 B
Q.7 D
Q.8 C
Q.9 D
Q.10 A
Q.11 A,B,C,D
Q.12 A,C,D
Q.13 A,C,D
Q.14 A,B,D
PART-C
Q.1 0004
Q.2 0002
Q.3 0039
Q.4 0005
Q.5 0012
Q.6 0003
PHYSICS
SECTION-1
PART-A
Q.1 A
Q.2 A
Q.3 C
Q.4 D
Q.5 B
Q.6 C
Q.7 B
Q.8 A
Q.9 D
Q.10 D
Q.11 A,C,D
Q.12 B,D
Q.13 D
Q.14 A,B,D
PART-C
Q.1 0010
Q.2 0010
Q.3 0002
Q.4 0003
Q.5 0010
Q.6 0005
CHEMISTRY
SECTION-3
PART-A
Q.1 B
Q.2 B
Q.3 B
NOTE :Only for XY-Batch students
Q.4 C
NOTE : Only for V-Batch students
Q.4 A
Q.5 D
Q.6 B
Q.7 D
Q.8 D
Q.9 B
Q.10 A
Q.11 B,C,D
Q.12 B,C
Q.13 A,B
Q.14 A,B
PART-C
Q.1 0500
Q.2 0004
Q.3 0012
Q.4 0163
Q.5 1566
Q.6 2121
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol. W
G
+ W
f
= 0

v=0
Rough
Smooth
1
2
x
2x
u=0
mg sin u 3x mg cos u 2x = 0
3 sin u = 2 cos u
=
2
3
tan u ]
Q.2
[Sol. f = m
B
a B
f
a
= 10 2 = 20 N ]
Q.3
[Sol.
W B BW
v v v

= ; v
BW
= 3 (3) = 6 m/s
Before collision : v
BW
= 6 m/s
After collision, v'
BW
= v
BW
v
w
v'
Bw
v
B
' = v'
Bw
+ v
w
= 6 + 3 = 9 m/s ]
Q.4
[Sol. tan u =
r
t
a
a
=
2
R
R
e
o
= tan
1
|
.
|

\
|
e
o
2
u
r
e
a
t
a
n
]
Q.5
[Sol. | > |
c
sin | > sin |
c
cos o >
n
1
..... (i)
sin u = n sin o
n
sin u
= sin o ..... (ii)
sin u <
1 n
2

u < sin
1

1 n
2

]
Q.6
[Sol. Kinetic energy is conserved
2
2
2
V
M
2
1
MV
2
1
|
.
|

\
|
=
+
2
1
MV'
2
V
2

2
2
' V
4
V
=
' V
2
3
= ]
PHYSICS
Code-A Page # 2
Q.7
[Sol.
C BC B
V V V

+ =
V
B
V
C
V
BC
]
Q.8
[Sol. In absence of air resistance
E
i
= E
f
K
i
+ U
i
= K
f
+U
f
K
f
= K
i
AU
AU = 0
K
f
= K
i
V
f
= V
i
(independent of mass) ]
Q.9
[Sol. (K
system
)
total
= K
CM
+ (K
system
)
about CM
=
2
1
(m
1
+ m
2
) v
c
2
+
2
1
v
rel
2
=
2
1
(4) (0.5)
2
+
2
1

4
3
(2)
2
= 2J
(K
system
)
total
= 2 =
2
1
4 v
c
2
+
2
1
|
.
|

\
|
4
3
(3)
2
v
c
2
=
16
11
]
Q.10
[Sol.
i f
p p p dt F J


= A = } =
AKE = K
f
K
i
=
m 2
p
m 2
p
2
i
2
f

W = K K K s d . F
i f
A = = }

]
Q.11
[Sol.
j

8 i

6 a = i

6 a
t
=

8 a
c
=

8
r
v
2
= v = 4
i

4 v =

2
r
v
= = e
,
o = r a
t
k

3 = o ]
PHYSICS
Code-A Page # 3
Q.12
[Sol. mv
1
Mv = 0
mv
1
= Mv
W
total
= AK =
2
1
mv
1
2
+
2
1
Mv
2
W
total
=
2
1
m
2
m
Mv
|
.
|

\
|
+
2
1
Mv
2
=
2
v
2
1

(

+ M
m
M
2
work done by man on himself =
2
1
mv
1
2
=
2
m
Mv
m
2
1
|
.
|

\
|
=
2
2
v
m
M
2
1
]
Q.14
[Sol. a
B
=
r
v
2
B
=
250
225
=
10
9
= 0.9 m/s
2
A B BA
v v v =

60
v
B
v
A
v
BA
v
BA
=
+ 60 cos v v 2 v v
B A
B A
2 2
v
BA
=
2 / 1 900 225 900 +
= 26 ]
PART-C
Q.1
[Sol. After the mishap, the spaceship moves with an initial velocity v
0
and a deceleration of 1 m/s
2
, while the
satellite moves with a constant speed v
0
. After the mishap, the two vessels will collide at a time t given by
v
0
t = 50 + v
0
t
2
a
t
2
,
or t =
1
100
= 10s ]
Q.2
[Sol. When the maximum speed is achieved, the propulsive force is equal to the resistant force. Let F be this
propulsive force, then
F = aV and FV = 600 W
Eliminating F, we obtain
V
2
=
a
400
= 100 m
2
/s
2
and the maximum speed on level ground with no wind
v = = 10 m/s ]
Q.3
[Sol. The "Scotchlite" sphere is a ball of index of refraction n, whose rear semi-spherical interface is a reflecting
surface. The focal length in the image space, f, for a single refractive interface is given by
f =
1 n
nr

where r is the radius of the sphere. The index of refraction of air is unity. The index of refraction of the
glass is chosen so that the back focal point of the front semi-spherical interface coincides with the apex
of the rear semi-spherical interface i.e.,
f = 2r
Hence n = 2. ]
PHYSICS
Code-A Page # 4
Q.4
[Sol. As shown in figure, the forces acting on the block are the gravitational
force mg, the normal reaction N, the static friction f, and the cenrifugal
force with f =
s
N, P = me
2
r. Thus the conditions for equilibrium are
0
mg
u
x
y
N
P mg sin u = P cos u +
s
N,
N = mg cos u + P sin u
Hence mg sin u = P cos u +
s
mg cos u +
s
P sin u,
giving P =
|
|
.
|

\
|
u + u
u u
sin cos
cos sin
s
s
mg = me
2
r,,
or e
2
=
|
|
.
|

\
|
u + u
u u
sin cos
cos sin
s
s
=
r
g
=
|
|
|
|
.
|

\
|
+

5
3

4
1
5
4
5
4

4
1
5
3

4 . 0
8 . 9
= 10.3
e = 3.2 rad/s ]
Q.5
[Sol.
2
10 5
k
mg 2

=
u
1
f
1
v
1
=
20
1 2
20
1
10
1
v
1 +
=

=
v = 20 cm
d
1
= 20 cm (initial distance of image from mirror)
30
2 3
15
1
10
1
v
1 +
=

=
v = 30 cm
d
2
= 30 cm (final distance of image from mirror)
d
2
d
1
= 10 cm (distance in which the image oscillates) ]
Q.6
[Sol. sin 30 = 1.3 sin u
1
2
1
= 1.3 sin u
1
sin u
1
= sin u
1
=
6 . 2
1
tan u
1
=
h
d
= 0.42 h =
42 . 0
d
= 4.8 = 5 ]
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. Given, L =
|
.
|

\
| +
0
0
x tan
x sin ) 1 a ( ax 2
Lim
3
0 x
=
|
|
.
|

\
|

x tan
x
x
x sin ) 1 a ( ax 2
Lim
3
3
3
0 x
As, L is finite so
3
5 3
0 x
x
........
! 5
x
! 3
x
x ) 1 a ( ax 2
Lim
|
|
.
|

\
|
+ +

=
3
3
0 x
x
x of powers higher containing terms
! 3
x
) 1 a ( x ) 1 a 3 (
Lim
+

must exists.
(3a 1) = 0 a =
3
1
and L =
! 3
) 1 a (
=
6
1
3
1
|
.
|

\
|

=
9
1
.
Hence, (a + L) =
9
1
3
1
+
=
9
1 3+
=
9
4
. Ans.]
Q.2
[Sol. Given, x
2
+ px + p + 2 = 0
2k
k
Now, sum of roots = 3k = p .........(1)
and product of roots = 2k
2
= p + 2 .........(2)
From (1) and (2), we get
2 p
3
p
2
2
+ =
|
.
|

\
|
2p
2
9p 18 = 0 (2p + 3) (p 6) = 0
p =
2
3
, 6.
Hence, integral value of p = 6. Ans.]
Q.3
[Sol. Given,
f(u) =
u +
u +
cos 1 1 1
1 sin 1 1
1 1 1
Applying C
1
C
1
C
3
and C
2
C
2
C
3
, we get
f(u) =
u + u u
u
cos 1 cos cos
1 sin 0
1 0 0
Now, expanding along R
1
, we get
MATHEMATICS
Code-A Page # 2
f(u) = sin u cos u
So, f(u) = 0 u =
2
nt
, n e I.
Clearly, u =
2
t
, t,
2
3t
are possible solutions in interval (0, 2t). Ans.]
Q.4
[Sol. As, f(x) is continuous at x = 5, so f (5
+
) = f(5) = f(5

) ........(1)
Now, f (5

) =
( ) ] x [ x
2
sin Lim
5 x

=
( ) 4 5
2
sin
t
= 1.
Also, f (5
+
) =
( ) ( )
( ) 3 x
8 x 3 x ab
Lim
2
5 x

+

= 3ab
2
From equation (1), we get
3ab
2
= 5(b 1) = 1 b =
5
6
and a =
108
25
. Ans.]
Q.5
[Sol. Given,
P(n) = [
=
|
|
.
|

\
|

n
2 n
2
) 1 n 2 (
4
1
So, P(n) =
( )
[
=


n
2 n
2
2
) 1 n 2 (
4 1 n 2
=
( ) ( )
[
=

+
n
2 n
2
) 1 n 2 (
1 n 2 3 n 2
Now,
[
=
|
.
|

\
|

+
=
n
2 n
1 n 2
1 n 2
) n ( P
[
=
|
.
|

\
|

n
2 n
1 n 2
3 n 2
=
) 1 n 2 ........( 7 5 3
) 1 n 2 ( ) 1 n 2 .....( 9 7 5

+

) 1 n 2 ........( 7 5 3
) 3 n 2 .....( 5 3 1

1 n 2
1

3
) 1 n 2 (
) n ( P

+
=
Hence,
3
1
) n ( P Lim
n
=

Ans.]
Q.6
[Sol.
MB
Given, I = ( )
}
t
t
t + + t +
2
2
3
2 3
dx ) 3 x ( cos ) x (
Put, x + t = t dx = dt, so
I =
}
t
t
+
2
2
2 3
dt ) t cos t ( =

} }
t
t
t
t
+
2
2
function even
2
2
2
function odd
3
dt t cos dt t

=
}
t 2
0
2
dt t cos 2
=
2 4
2
t
=
|
.
|

\
| t
.
MATHEMATICS
Code-A Page # 3
( )
(
(
(
(

t
=
|
.
|

\
|
+ = + =
} }
t t
t
=
=
2
0
2
0
2
t
0 t
2
4 2
t 2 sin
t
2
1
dt t 2 cos 1
2
1
dt t cos , As
Hence, I
10
t
=
2
10 t

t
= 5 Ans.]
Q.7
[Sol. We must have, 1
x 3
4 x
1
2
s

s 1
x 3
4 x
1
2
s

s
x 3
4 x
2

+ 1 > 0 and
x 3
4 x
2

1 s 0
0
x 3
) 1 x )( 4 x (
>
+
and 0
x 3
) 1 x )( 4 x (
s
+
x = 4, 3, 2, 1, 1, 2, 3, 4. Hence, number of integral values is 8. Ans.]
Q.8
[Sol.
MB
Given, f(x) = x | x | and g(x) = sin x
Let G(x) = ( ) ( )

>
<
= =
0 x , x sin
0 x , x sin
x x sin ) x ( f g
2
2
Clearly, G'(0
+
) =G'(0

) = 0 G (x) = gof (x) is differentiable at x = 0 .

Also, G ' (x) =

>
<
0 x , x cos x 2
0 x , x cos x 2
2
2
G ' (x) is continuous at x = 0.
Now, G " (x) =

>
< +
0 x , x sin x 4 x cos 2
0 x , x sin x 4 x cos 2
2 2 2
2 2 2
G "(0

) = 2 and G"(0
+
) = 2 Hence G '' (0
+
) = G ''(0

)
G (x) = gof (x) is not twice differentiable at x = 0.
Hence, S-1 is true, but S-2 is false. Ans.]
Q.9
[Sol.
am
S-1 : Clearly, domain of f = R { 2, 1} Domain of f(x) is not symmetric about origin.
So, f(x) is not an even function.
Obviously S-2 is true.
Hence, S-1 is false, but S-2 is true. Ans.]
[Note :Here f(x) =
|
|
.
|

\
|
+
+

|
|
.
|

\
|

+
8 x
8 x
x
1 x
1 x
x
3
3
2
3
3
2
2 2 f(x) =
2 2
x x
2 2

+ f(x) = f(x) (not possible)
As, domain of f = R { 2, 1} f(x) is not an even function. ]
Q.10
[Sol.
mb
S-1: As, roots of equation 2x
2
+ 7x + 10 = 0 are non-real, so both roots must be common.

) say (
10
c
7
b
2
a
= = =
So, a = 2, b = 7, c = 10
MATHEMATICS
Code-A Page # 4
Hence,
b
c a 2 +
=

+
7
10 4
= 2.
Obviously, S-2 is true and explaining S-1 also. Ans.]
Q.11
[Sol.
vkb
Obviously, f(x) = sin
1
x and f '(x) =
2
x 1
1

f '
|
|
.
|

\
|
2
3
= 2.
Note : sin
1
x > x x e (0, 1) f |
.
|

\
|
3
2
>
3
2
.
Also,
x
x sin
Lim
1
0 x

= 1.
Again, f (x) + |
.
|

\
|

2
x 1 f = sin
1
x + sin
1
|
.
|

\
|

2
x 1 = sin
1
x + cos
1
x =
2
t
Ans.]
Q.12
[Sol. Given, f(x) =
n 2
2 n 2 2
n
x 1
) x ( sin x ) x 2 ( n
Lim
+
+

l
Now,

>
=

< s +
=
1 x for ), x sin(
1 x for ,
2
1 sin 3 n
1 x 0 for ), x 2 ( n
) x ( f
2 2
2
2 2
l
l
=

< <
=

< < +
=

< <
x 1 ), x sin(
1 x ,
2
1 sin 3 n
1 x 1 ), x 2 ( n
1 x ,
2
1 sin 3 n
1 x ), x sin(
2
2
2
l
l
l
Now, verify alternatives.
[Note : f(x) is an even function also.]
Q.13
[Sol
ys
Given, ( ) ( ) ( ) ( ) x cot cosec tan cos sin
1 1 1
=
6
t

|
.
|

\
|
|
.
|

\
|
+
2 1 1
x 1 tan cos sin =
6
t

6
2 x
1
sin
2
1
t
=
|
|
.
|

\
|
+

2 x
2
+ = 2 x
2
= 2 x = 2 .
So, x
1
= 2 and x
2
= 2
Now, verify alternatives. Ans.]
MATHEMATICS
Code-A Page # 5
Q.14
[Sol.
(A) As, f(x) and g(x) are continuous for every x e R and fog (x) is defined,
then obviously ( ) ) x ( g f is also continuous for every x e R.
(B) As, f(x) is continuous on R such that 0 ) x ( f Lim
x
=

and 0 ) x ( f Lim
x
=

, so clearly
f(x) must be bounded .
(C) Let f(x) = cos (tx) 3x + 1
clearly, f(x) is a continuous function in [0, 1].
Also f(0) = 1 0 + 1 = 2 and f(1) = 1 3 + 1 = 3 f(0) f(1) < 0
So, by intermediate value theorem, the equation f(x) = 0 has atleast one root in (0, 1).
Note that f '(x) = t sin (tx) 3 < 0 x e [0, 1] f(x) is strictly decreasing function on [0, 1].
Hence, the equation f(x) = 0 will have exactly one root in (0, 1).
(D) We know that every continuous function in [a, b] is always bounded.
So, there exists some c e [a, b] where f(x) attains its maximum value .
So, by extreme value theorem, f(c) > f(x) x e [a, b]
PART-C
Q.1
[Sol.
mkj
Clearly, f(0
+
) =
x
] x tan[
a Lim
0 x
+
+

= a +
x
0
= a.
and f (0

) =
(

3
0 x x
x tan x
b Lim
=
(
(
(
(
(

|
|
.
|

\
|
+
+

3
3
0 x x
.......
3
x
x x
b Lim = b 1.
As, f (x) is continuous at x = 0, so f(0
+
) = f(0) = f (0

).
So, a = 3 and b 1 = 3 b = 4
Hence,

=
|
.
|

\
|
0 r
r
b
a
=

=
|
.
|

\
|
0 r
r
4
3
= terms ..........
4
3
4
3
1
2

|
.
|

\
|
+ + =
4
3
1
1

= 4. Ans.]
Q.2
Sol. Given, f(x) = (2a + b) cos
1
x + (a + 2b) sin
1
x
= (2a + b) cos
1
x + (a + 2b)
|
.
|

\
|

t

x cos
2
1
= (a b) cos
1
x + (a + 2b)
2
t
.
Clearly, domain of f(x) = [1, 1] and f(x) is a continuous decreasing function on [1, 1].
So, range of f(x) = [ f
min
(x = 1), f
max
(x = 1) ]
Now, f
min
(x = 1) = (a + 2b)
2
t
and f
max
(x = 1) = (a b)t + (a + 2b)
2
t
= 3a
2
t
.
Range of f(x) =
(

t t
+
2
a 3 ,
2
) b 2 a (
MATHEMATICS
Code-A Page # 6
As, Domain of f and range of f are the same set,
So, (a + 2b)
2
t
= 1 ... (1) and 3a
2
t
= 1 .... (2)
On solving (1) and (2) we get
t
=
3
2
a and
t

=
3
4
b
Hence, t(a b) = |
.
|

\
|
t
+
t
t
3
4
3
2
=
2
3
6
3
4
3
2
= = +
Ans.]
Q.3
[Sol.
aj
Given, area (AO
1
O
3
O
5
) = 3 12
4
3
(side)
2
= 3 12
[Note: AO
1
O
2
O
3
is equilateral with length of each side equal 4r]
(O
1
O
3
) = 3 4 .
B
M
A
C
N
30
O
1
O
3
O
5
4r
O
6
O
4
O
2
a
Also, O
1
O
3
= 4r = 3 4 .
r = 3 (radius of circle)
In ABMO
3
,
BM
MO
3
= tan 30

3
1
BM
3
=
BM = 3.
Also, BC = BM + MN + CN
a = 3 + 4 3 + 3 or a = 6 + 4 3
So, area (AABC) =
4
3
a
2
= ( )
2
3 4 6
4
3
+ =
( )
2
3 2 3 3 +
=
( ) 3 12 21 3 +
= 36 + 3 21 = q 21 p + (Given) p = 36, q = 3.
Hence, (p + q) = 39. Ans. ]
Q.4
[Sol.
MB
Given, | x |
2
4 | x | + 3 | k 1| = 0 .........(1)
As above equation (1) have four distinct real roots so both roots of equation (1)
must be positive and distinct.
Now,
(i) D > 0 16 12 + 4 | k 1| > 0 1 + | k 1| > 0, which is true k e R.
(ii) Sum of roots > 0 4 > 0, which is true k e R.
(iii) Product of roots > 0 3 | k 1| > 0 | k 1| < 3 2 < k < 4.
must be satisfied simultaneously.
1 2 3 k e ( 2, 4).
Clearly, possible integral values of k are 1, 0, 1, 2, 3. Ans.]
MATHEMATICS
Code-A Page # 7
Aliter : Graph for f(x) = x
2
4 x + 3.
O
y
x
3 2 1 1 2 3
(0, 3)
(2, 1) (2, 1)
Now, x
2
4 x + 3 = 1 k will have exactly four roots if 1 k < 3 2 < k < 4.
Clearly, possible integral values of k are 1, 0, 1, 2, 3. Ans.]
Q.5
[Sol. Given, f(xy) = f(x) + f(y) + x
2
y
2
(x
2
+ y
2
) x, y e R
+
............(1)
As, f '(x) =
h
) x ( f ) h x ( f
Lim
0 h
+

=
( )
h
x f
x
h
1 x f
Lim
0 h
|
.
|

\
|
|
.
|

\
|
+

=
( ) ( )
h
x f
x
h
1 x
x
h
1 x
x
h
1 f x f
Lim
2
2
2
2
0 h

|
|
.
|

\
|
|
.
|

\
|
+ +
|
.
|

\
|
+ +
|
.
|

\
|
+ +

=
h
h
x
2
x 2
Lim
h
1
x
h
1 f
Lim
0 h 0 h
|
.
|

\
|

+
|
.
|

\
|

|
.
|

\
|
+

........(2)
Put, x = y = 1 in equation (1), we get
f(1) = 2f(1) + 1 2 f(1) = 1.
f ' (x) =
x
2
x 2
x
h
x
) 1 ( f
x
h
1 f
Lim
0 h
+
|
.
|

\
|
|
.
|

\
|
+

(Using equation (1))

f '(x) =
x 2
x
2
x
3
+
f '(x) =
x 2
x
1
+
f(x) = x
2
+ ln + C
Also f(1) = 1 C = 0
Hence, f(x) = x
2
+ ln x.
Clearly,
}
0
1
dx ) x ( f 18 = ( )
}
+
0
1
2
dx x ln x 18 = 18
(
(
(
(

+
} }
0
1
0
1
P . B . I
II
I
2
dx 1 x n dx x

l
( )
(
(

+
|
|
.
|

\
|
=
0
1
0
1
3
x x n x
3
x
18 l
= 18
(

1
3
1
=
|
.
|

\
|

3
2
18 = 12. Ans.]
MATHEMATICS
Code-A Page # 8
Q.6
[Sol.
AT
Given, f (x) =
( ) o + t
1
cos 2
x
2
+ 2 (cos
1
|) x + 2 t cos
1
o
Clearly, graph of f(x) is parabola opening upward.
As, range of f(x) is [0, ), so discriminant = 0
b
2
4ac = 0 4 (cos
1
|)
2

( ) o + t
1
cos 2 4

( ) o t
1
cos 2
= 0
4 (cos
1
|)
2
4 (2t
2
(cos
1
o)
2
) = 0
(cos
1
o)
2
+ (cos
1
|)
2
= 2t
2
f(x)
x-axis
cos
1
o = t = cos
1
| o = | = 1 (Think)
Hence, 1 2 + o| + | o = 0 + 2 + 1 = 3. Ans.]
CHEMISTRY
Code-A Page # 1
PART-A
Q.1
[Sol. H
2
O (l, 1 atm, 373 K) H
2
O (g, 1 atm, 373 K)
the reaction is at equilibrium at given condition, so
AG = 0 AS
Total
= 0
AS
sys
> 0 (Heat is added to the system and phase is changing)
so AS
surr
< 0
q > 0 (Heat is added)
AU > 0 (Heat is added)
AH > 0 (AU > 0 and P
2
V
2
P
1
V
1
> 0) ]
Q.2
[Sol. SiF
4
, XeF
4
, BH
4

All the hybrid orbitals having same percent of s-character so they have same
bond length.
SF
4
Non equivalnt hybridisation due to the presence of different percent of s-character in the hybrid
orbitals, all the bond length of SF
4
are not equivalent.
]
Q.3
[Sol. Strongest acid and strongest base takes reaction maximum in forward direction. ]
NOTE :Only for XY-Batch students
Q.4
[Sol. q = w
AU = q + w
AU = q + q = 2q
nCvmAT= 2 n C
m
AT
or C
m
=
2
C
Vm
or C
m
=
R
2 ) 1 (
R
=

]
CHEMISTRY
Code-A Page # 2
NOTE : Only for V-Batch students
Q.4
[Sol. AH =


P R
) BE ( ) BE (
= (2 350 + 500) (1500)
= 300 kJ mol
1
]
Q.5
[Sol.
]
Q.6
[Sol.
O
| |
Cl C CH CH CH
2 2 3

4C
O
| |
Cl C
|
CH CH CH
3 3

3C
]
Q.7
[Sol. ]
CHEMISTRY
Code-A Page # 3
Q.8
[Sol. For an irreversible cyclic process, AS
surr
= 0 as AS
sys
= 0 for any cyclic process because entropy is
state function.
AS
univ.
= AS
sys
+ AS
surr
> 0 (For Irreversible process)
AS
surr
> 0 ]
Q.9
[Sol. ST.-1 :
ST-2 : dz
2
(Electrodensity present in z-axis as well as x and y axis so nodel plane = 0)]
Q.10
[Sol. In polar aprotic solvent more the charge density more will be the nucleophilicity. ]
Q.12
[Sol. Planar the restricted system
Two different groups should be present on that restricted atoms. ]
Q.13
[Sol. ]
Q.14
[Sol. (A)
O

OH
(Aromatic)
(B)
O

OH
(Aromatic)
CHEMISTRY
Code-A Page # 4
(C)
O

OH
(Anti Aromatic)
(D)
O

OH
(Non Aromatic) ]
PART-C
Q.1
[Sol. AH = AU + AH
g
RT
AH = 43 kJ mol
1
) T T ( C H H
1 2 P
o
T
o
T
1 2
A + A = A
T
1
= 500 K ]
Q.2
[Sol. In a electro rich compound if halogen is act as bridge it is a 3C 4e

bond
;
;
BF
3
and BCl
3
do not dimerised due to the presence of ptpt backboning between B and Halogen
atom.
don't having 3C 4e

bonds ]
CHEMISTRY
Code-A Page # 5
Q.3
[Sol.
]
Q.4
[Sol. 35 + 22 + 63 + 32 + 11 = 163 ]
Q.5
[Sol. In a 2D-sheet silicate
Total number of oxygen atoms are shared in each tetrahedral unit = 3
So, Effective number of oxygen atoms = 15
Number of Si-atoms = 6
Charge = 6 ]
Q.6
[Sol. (a) Compound which shows intermolecular H-bonding has higher solubility than compound has
intramolecular H-bonding.
(b) More the surface area more will be the boiling point.
(c) More EDG on C

, more the stability
(d) More electronegativity more the I ]