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Reservoir Fluid Study

for
Occidental de Colombia
Rondon 1N Well
RFL05097

The analyses, opinions or interpretations in this report are based on


observations and material supplied by the client to whom, and for whose
exclusive and confidential use, this report is made. The interpretations or
opinions expressed represent the best judgement of Core Laboratories
Venezuela, S.A. (all errors and omissions excepted); but Core Laboratories
Venezuela, S.A. and its officers and employees assume no responsibility and
make no warranty or representations as to the productivity, proper operation
or profitability of any oil, gas or any other mineral well formation in
connection with which such report is used or relied upon.

Core Laboratories Venezuela, S.A.


Calle 25 (Carretera Via El Mojan) Km 3 al lado dwe la Coca-Cola
Tel +58 261 7574611, fax +58 261 7578684

Core Laboratories Venezuela, S.A.


Km 3 Via El Mojan. Parcelamiento Buena Vista
Maracaibo, Edo. Zulia-Venezuela
Tel: 58 261 7574611
Fax: 58 261 7578684
Web: http://www.corelab.com

August 1st of 2005


Occidental de Colombia.
Bogota, Colombia.
Attention : Eng. Ciro Pinto Rizzo
Subject:
Well:
File:

Reservoir Fluid Study


Rondon 1N
RFL 05097

Gentlemen:
On May 20th of 2005, two wellhead samples were collected by Core Laboratories
representativesfrom the subject well and were delivered to our fluid laboratory in Maracaibo,
Venezuela for performance of a reservoir fluid study.
Upon arrival at the laboratory, the samples were validated by measuring their bubble point
pressures at laboratory temperature; the selected sample was restored to reservoir
conditions for subsequent PVT testing. Additional tests were required during the course of
the study, preliminary results were provided to the client during the course of the laboratory
study, as well. Final report is presented in the following pages.
It has been a pleasure to perform this study for Occidental de Colombia. Should any
questions arise or if we may be of further service in any way, please do not hesitate to
contact us.
Sincerely,
Core Laboratories Venezuela, S.A

Gustavo Cabeza
Project Manager
Reservoir Fluids Laboratory

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Table of Contents
Section A - Summary of PVT Methods and Data
Summary of PVT methods.......................................................................................................
Summary of PVT data..............................................................................................................

Page
A.1-A.2
A.3

Section B - Summary of Samples Received and Validation Data


Well information........................................................................................................................
Summary of samples received and validation data..................................................................

B.1
B.2

Section C - Compositional Analysis of Bottomhole Reservoir Fluid


Compositional Analysis of Reservoir Fluid to C36+..................................................................

C.1-C.2

Section D - Constant Composition Expansion


Single phase fluid properties at reservoir temperature.............................................................
Constant composition expansion at reservoir temperature......................................................
Graphs of constant composition expansion at reservoir temperature......................................
Constant composition expansion at different temperatures.....................................................

D.1
D.2
D.3
D.4

Section E - Differential Vaporization


Differential vaporization data....................................................................................................
Graphs of differential vaporization............................................................................................
Differential vaporization data adjusted to surface conditions....................................................

E.1
E.2
E.3

Section F - Viscosity of Reservoir Fluid


Reservoir fluid viscosity data at Reservoir Temperature..........................................................

F.1-F.2

Section G - Separation Test of Reservoir Fluid


Atmospheric Flash test at 75 F................................................................................................

G.1

Molecular composition of evolved gas during atmospheric flash at 75 F.................................

G.2

Atmospheric Flash test at 140 F..............................................................................................

G.3
G.4

Molecular composition of evolved gas during atmospheric flash at 140 F...............................


Atmospheric Flash test at 180 F..............................................................................................
Molecular composition of evolved gas during atmospheric flash at 180 F...............................
Atmospheric Flash test at 200 F..............................................................................................
Molecular composition of evolved gas during atmospheric flash at 200 F...............................
Atmospheric Flash test at 220 F..............................................................................................
Molecular composition of evolved gas during atmospheric flash at 220 F...............................

G.5
G.6
G.7
G.8
G.9
G.10

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Table of Contents, continued


Section H - Appendix
Data used in gas compositional calculations............................................................................
Data used in liquid compositional calculations.........................................................................
Crude oil caracterization..........................................................................................................
Crude oil distillation..................................................................................................................

H.1
H.2
H.3
H.4

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Section A - Summary of Analysis Methods and PVT Data

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Summary of Analysis Methods


Sample Validation
The bubble point pressure at ambient temperature and free water content of each wellhead
sample were determined as initial quality checks. From this quality control, the samples showed
good agreement with respect to the measured bubble point pressures and did not contain free
water. Therefore, the samples were deemed valid and were used to continue with testing
Heat Treatment
Each wellhead sample was heated to 200F prior to subsampling for every PVT test to avoid
wax or asphaltene deposition problems
Pressurized Wellhead Fluid Composition
Approximately 30 cc of pressurized fluid was flashed to atmospheric pressure at 120 F and
separated into its respective gas and oil phases. The evolved gas and residual liquid were
analyzed separately, using gas-liquid chromatography and recombined on a weight basis to
produce a C36+ weight percent composition. Calculations to mole% and the plus fractions
properties are described below.
Gas Compositions
Gas compositions were measured using a "one shot" Varian 3800 gas analyzer using method
GPA 2286. The gas chromatograph utilizes 3 columns to clearly identify all the eluted
components from N2, CO2 and C1 through C11+. The chromatograph is calibrated twice per
week using air and synthetic hydrocarbon gas with known compositions. The resultant
calibration data is checked statistically against previous calibrations prior to performing analyses
on unknown samples.
Liquid Composition
Residual/stocktank liquid composition were measured using a Varian 3400 chromatograph. The
gas chromatograph utilizes a cold on-column, "sandwich injection" technique to ensure that a
representative sample is injected and swept onto the column. The sample is run twice; first the
original fluid and then the same spiked with n-tetradecane. This allows the laboratory to take into
account any heavy end (C36+) losses that may have occurred, during the chromatographic run
and make an accurate correction prior to reporting the liquid composition. The data obtained
from the gas chromatograph is in weight percent. Calculations to mole% and the plus fractions
properties are described below.
The chromatograph is checked twice per week as well, using a gravimetric n-paraffin mix
containing a range of pure components from C8 through C36 and a synthetic gas-oil mix
(D2887) with known composition. The resultant calibration data is checked statistically against
previous calibrations prior to performing analyses on unknown samples.

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.
A.1

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Summary of Analysis Methods (Continuation)


Calculation of Mole% Compositions and Plus Fraction Properties
The residue or stocktank liquid whole sample molecular weight and density are measured using
a cryscope unit and a PAAR densimeter respectively.
The mole% data is calculated using GPSA mole weight and density data, where individual
components are identified, from carbon dioxide through decanes. Katz and Firoozabadi data are
used from undecanes through pentatriacontanes. The residue mole weight and density values
are calculated so that the pseudo average mole weight and density are the same as the
measured values. This can lead to anomalous residue mole weights and densities where the
Katz and Firoozabadi values may not be suitable for the isomer groups detected.
Other alternatives are to use an assumed C36+ molecular weight and density value, use a linear
extrapolation technique for components from C10 to C35 to calculate the C36+ properties or to
utilise distillation analysis to produce a C11+, C20+ or C36+ residual oil fraction and physically
measure the molecular weight and density.
Constant Composition Expansion
A portion of the wellhead fluid sample was charged to a high pressure visual cell and thermally
expanded to the reservoir temperature of 225 F. A constant composition expansion was
carried out during which the bubble point pressure and pressure-volume data for the single
phase and two phase fluid were determined. The density of the single phase fluid was also
determined by weighing measured volumes pumped from the cell at 5000 psig. Density data for
other pressures were calculated using the volumetric data.
Differential Vaporization
This was carried out in a high pressure visual cell at reservoir temperature. At several pressure
stages below the observed saturation pressure, the sample was stabilized. The gas evolved
was then pumped out of the cell and its volume, compressibility and composition were
determined. The final stage was carried out at atmospheric pressure when the residual liquid
was pumped out of the cell and its density was determined

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.
A.2

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Summary of Analysis Methods (Continuation)


Viscosity
Live-oil viscosity was measured in a rolling ball viscometer at reservoir temperature. Viscosity
determinations were carried out over a wide range of pressures from above the reservoir
pressure to atmospheric pressure.
The measurements were repeated at each pressure stage until five or more results agreed to
within 0.5% of the ball roll-time. The densities, obtained from the constant composition
expansion and differential vaporization tests, were used in the calculation of viscosities in
centipoise.
Separator Tests
Five atmospheric flash tests at different temperatures each were carried out using a pressurized
test separator cell. A portion of the wellhead sample, at a pressure above saturation pressure,
was pumped into the separator cell and stabilized at ambient pressure and test temperature. Th
gas evolved was pumped out of the cell and the volume and composition were determined. The
final stage was carried out at atmospheric pressure and ambient temperature and the density of
the residual liquid was determined.
Crude Oil Caracterization
A set of atmospheric tests was also performed accordingly with ASTM methodologies and their
results are presented in the Appendex.

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.
A.3

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Summary of PVT Data


Constant Composition Expansion at 225 F
Saturation pressure (bubble-point)

508

Average single phase compressibility


(from 3750 psig to 508 psig)

7.62 X 10-6 psi

Thermal expansion at 5000 psig

psig

1.0761 vol at 225 F / vol at 60F

Differential Vaporization at 225 F


Solution gas-oil ratio at saturation pressure

109 scf/bbl of residual oil at 60F

Relative oil volume at saturation pressure


Density at saturation pressure

1.148 vol/vol of residual oil at 60F


0.7759 g cm-3

Wellhead Fluid Viscosity at 225 F


Viscosity at reservoir pressure

1.622 centipoise at 3750 psig

Viscosity at saturation pressure

1.166 centipoise at 508 psig

Separator Test Data


Pressure
(psig)

Temperature
(F)

Formation Volume
Factor

Total Solution
Gas-oil ratio
(scf/bbl)

508
0

225
75

1.127

103

508
0

225
140

1.132

508
0

225
180

1.140

508
0

225
200

1.147

508
0

225
220

1.155

Stocktank Oil
Density at 60 F
(g cm-3)

Test 1
0.8505

Test 2
108
0.8531

Test 3
116
0.8547

Test 4
121
0.8562

Test 5
128
0.8572

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.
A.4

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Section B - Summary and Validation Data of Samples Received

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Reported Well and Sampling Information


Reservoir and Well Information
Field........................................................................
Well.........................................................................
Reservoir Fluid........................................................

Rondon
Rondon 1N
Black Oil

Formation................................................................
Current Reservoir Pressure ....................................
Reservoir Temperature...........................................

*
3750 psig
225 F

Installation...............................................................
Sand.......................................................................
Perforated Interval .................................................

*
M2 - A
10154' - 10160

Sampling Information
Date sampled..........................................................
Time sampled ........................................................
Type of samples.....................................................
Sampling company..................................................

20-May-05
05:30
Wellhead
Core Laboratories Colombia

Choke.....................................................................
Status of well..........................................................

*
*

Bottomhole pressure...............................................
Bottomhole temperature.........................................

3750
n/a

Wellhead pressure..................................................
Wellhead temperature............................................

305 psig
100 F

Separator pressure ................................................


Separator temperature ...........................................

*
*

Pressure base.........................................................
Temperature base .................................................

14.7 psia
60F

Separator gas rate..................................................


Separator oil rate ...................................................
Water flowrate.........................................................
Gas gravity (Air = 1)................................................
Supercompressibility factor.....................................
H2S.........................................................................
CO2........................................................................
BS&W......................................................................
Oil gravity ................................................................

*
*
n/a
*
*
*
*
*
*

Comments:
* Data not provided

___________________________________________________________________________________________
B.1
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Summary of Samples Received


Wellhead Samples

Laboratory
Bubble point :Pressure
Temp.
(psig)
(F)

Sample
Number

Cylinder
Number

Sampling :Pressure
(psig)

Temp.
(F)

1.1

436251D

305

100

310

1.2

897612C

305

100

305

Water
Cut
(%)

Sample
Volume
(cm3)

76

0.2

890

76

0.2

890

Note:
Sample No.1.1 and 1.2 were selected for compositional and further PVT analyses
One 1000 cc plastic container with crude oil sample was also received to perform crude oil caracterization

___________________________________________________________________________________________
B.2
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Section C - Compositional Analysis of Wellhead Fluid

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Compositional Analysis of Wellhead Sample to C36 plus

H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11
C12
C13
C14
C15
C16
C17
C18
C19
C20
C21
C22
C23
C24
C25
C26
C27
C28
C29
C30
C31
C32
C33
C34
C35
C36+

Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Heptanes
Octanes
Nonanes
Decanes
Undecanes
Dodecanes
Tridecanes
Tetradecanes
Pentadecanes
Hexadecanes
Heptdecanes
Octadecanes
Nonadecanes
Eicosanes
Heneicosanes
Docosanes
Tricosanes
Tetracosanes
Pentacosanes
Hexacosanes
Heptacosanes
Octacosanes
Nonacosanes
Triacontanes
Hentriacontanes
Dotriacontanes
Tritriacontanes
Tetratriacontanes
Pentatriacontanes
Hexatriacontanes plus
Totals :

Mole %
0.00
0.00
0.66
0.20
10.83
2.37
2.35
0.98
1.67
1.12
1.08
2.01
4.11
6.15
5.28
4.76
4.34
4.00
4.03
3.88
3.35
2.76
3.02
2.18
1.85
1.72
1.59
1.48
1.40
1.36
1.36
1.25
1.23
1.18
1.15
1.07
0.97
0.79
0.73
0.87
0.64
8.23
_____
100.00

Weight %
0.00
0.00
0.13
0.03
0.79
0.33
0.47
0.26
0.44
0.37
0.36
0.79
1.74
3.01
2.89
3.04
2.92
2.95
3.23
3.37
3.16
2.80
3.28
2.50
2.23
2.16
2.11
2.06
2.04
2.06
2.14
2.05
2.11
2.09
2.12
2.03
1.91
1.61
1.54
1.88
1.42
27.58
_____
100.00

Note: 0.00 means less than 0.005.

___________________________________________________________________________________________
C.1
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Compositional Analysis of Wellhead Sample to C36 plus

Calculated Residue Properties


C7 plus

Mole%
Molecular Weight (g mol-1)
Density at 60F (g cm-3)

76.73
274
0.8690

C11 plus

Mole%
Molecular Weight (g mol-1)
Density at 60F (g cm-3)

56.43
331
0.8872

C20 plus

Mole%
Molecular Weight (g mol-1)
Density at 60F (g cm-3)

27.02
477
0.9178

C36 plus

Mole %
Molecular Weight (g mol-1)
Density at 60F (g cm-3)

8.23
734
0.9503

Calculated Whole Sample Properties


Average mole weight (g mol-1)
Density at 60F (g cm-3)

219
0.8419

___________________________________________________________________________________________
C.2
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Section D - Constant Composition Expansion (CCE)

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Constant Composition Expansion at 225F


Single-phase Fluid Properties
Saturation pressure (bubble-point pressure)

508 psig

Thermal expansion factor of single phase fluid at 5000 psig


(Vol at 225F)/(Vol at 60F)
Average single phase compressibility
(From 3750 psig to 508 psig)

1.0761 vol / vol

7.62 x 10 -6 psi-1

Density at saturation pressure

0.7759 g cm-3

Mean Single-phase Compressibilities


Pressure Range

Mean
Compressibility
(psi-1) (1)

Initial Pressure
(psig)

Final Pressure
(psig)

5000

3750

6.45

x 10 -6

3750

2500

6.81

x 10 -6

2500

1500

7.40

x 10 -6

1500

508

8.85

x 10 -6

(1) Mean compressibility = (V2-V1) / [(V1+V2)/2] x 1/(P1 - P2)

___________________________________________________________________________________________
D.1
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Constant Composition Expansion at 225F


Pressure
(psig)

Relative
Volume (1)

Density
(g cm-3)

5000
4500
4000
3750
3500
3000
2500
2000
1500
1000
900
800
700
600
508
506
504
502
500
480
464
421
361
302
249
207
166
132
116
101
73

0.9678
0.9709
0.9740
0.9756
0.9772
0.9805
0.9839
0.9875
0.9913
0.9953
0.9962
0.9971
0.9980
0.9990
1.0000
1.0015
1.0029
1.0044
1.0060
1.0221
1.0364
1.0823
1.1713
1.3032
1.4860
1.7063
2.0365
2.4678
2.7554
3.1022
4.0853

0.8017
0.7992
0.7966
0.7953
0.7940
0.7913
0.7886
0.7857
0.7827
0.7795
0.7789
0.7782
0.7774
0.7767
0.7759

Reservoir pressure

Saturation pressure

Instantaneous
Compressibility
(psi-1 x 10-6) (2)

Y-function (3)

6.37
6.48
6.57
6.64
6.77
6.97
7.23
7.61
8.22
8.79
9.07
9.43
9.90
10.51

2.425
2.284
2.145
2.021
1.922
1.826
1.746
1.709
1.673
1.608

(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
(2) Instantaneous compressibility = (V2-V1) / V1 x 1/(P1-P2)
(3) Y-function = (Psat - P ) / ((Pabs)(V/Vsat - 1)).

___________________________________________________________________________________________
D.2
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Graphs of Constant Composition Expansion at 225 F


Relative Volume vs Pressure

1.0000

Relative volume, V/Vsat

0.9950
0.9900
0.9850
0.9800
0.9750
0.9700
0.9650
0

1000

2000

3000

4000

5000

400

500

Pressure, psig

Y Function vs Pressure

4.000
3.500

Y Function

3.000
2.500
2.000
1.500
1.000
0.500
0.000
0

100

200

300
Pressure, psig

___________________________________________________________________________________________
D.3
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Constant Composition Expansions at Different Temperatures


Saturation
Pressures
(psig)

Temperature
(F)

341
402
446
471
500

75
140
180
200
220
225

508

Saturation Pressure vs Temperature

550

Saturation Pressures, psig

500

450

400

350

300
50

100

150

200

250

Temperature, F

___________________________________________________________________________________________
D.4
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Section E - Differential Vaporization (DV)

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Differential Vaporisation at 225F

Pressure
(psig)

Solution
Gas-Oil
Ratio
Rs(1)

Relative
Oil
Volume
Bod(2)

Relative
Total
Volume
Btd(3)

508
400
300
200
100
0

109
91
77
59
39
0

1.148
1.141
1.136
1.129
1.120
1.084

1.148
1.286
1.475
1.906
3.158

At 60F =

Density
(g cm-3)

Deviation
Factor
(Z)

0.7759
0.7774
0.7787
0.7807
0.7828
0.7931

0.954
0.957
0.958
0.967

Gas
Formation
Volume
Factor (4)

Incremental
Gas Gravity
(Air = 1.000)

Saturation Pressure
0.04456
0.875
0.05887
0.859
0.08644
0.875
0.16333
0.966
2.021

1.000

Residual Oil Properties


Density of residual oil

0.8598

API

32.9

g cm-3 at 60F

(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of residual oil at 60F.
(2) Volume of oil at indicated pressure and temperature per volume of residual oil at 60F.
(3) Volume of oil plus liberated gas at indicated pressure and temperature per volume of residual oil at 60F.
(4) Volume of gas at indicated pressure and temperature per volume at 14.70 psia and 60F.

___________________________________________________________________________________________
E.1
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Graphs of Differential Vaporisation


Solution Gas-Oil Ratio v Pressure

120

Gas-Oil Ratio (scf / bbl)

100

80

60

40

20

0
0

100

200

300

400

500

600

Pressure (psig)

Relative Oil Volume v Pressure

1.160

Relative Oil Volume (V/Vr)

1.140
1.120
1.100
1.080
1.060
1.040
1.020
1.000
0

100

200

300

400

500

600

Pressure (psig)

___________________________________________________________________________________________
E.2
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Differential Vaporisation Data Converted to Production Separator Conditions

Pressure
(psig)

Oil
Density
(g cm-3)

5000
4500
4000
3750
3500
3000
2500
2000
1500
1000
900
800
700
600
508
400
300
200
100
0

0.8017
0.7992
0.7966
0.7953
0.7940
0.7913
0.7886
0.7857
0.7827
0.7795
0.7789
0.7782
0.7774
0.7767
0.7759
0.7774
0.7787
0.7807
0.7828
0.7931

Reservoir pressure

Saturation pressure

Solution
Gas/Oil
(scf / bbl)
Rs(1)

Formation
Volume
Factor
Bo(1)

108
90
76
58
39
0

1.096
1.099
1.103
1.104
1.106
1.110
1.114
1.118
1.122
1.127
1.128
1.129
1.130
1.131
1.132
1.125
1.120
1.113
1.105
1.059

Gas Formation
Volume
Factor
Bg(2)

0.04456
0.05887
0.08644
0.16333

Notes:
(1) Differential data corrected to surface separator conditions of :Stage 1

0 psig and 140F

Rs = Rsfb - (Rsdb - Rsd) x (Bofb / Bodb)


Bo = Bod x (Bofb/Bodb)
(2) Volume of gas at indicated pressure and temperature per volume at 14.70 psia and 60F.

___________________________________________________________________________________________
E.3
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Differential Vaporisation Data Converted to Production Separator Conditions

Pressure
(psig)

Oil
Density
(g cm-3)

5000
4500
4000
3750
3500
3000
2500
2000
1500
1000
900
800
700
600
508
400
300
200
100
0

0.8017
0.7992
0.7966
0.7953
0.7940
0.7913
0.7886
0.7857
0.7827
0.7795
0.7789
0.7782
0.7774
0.7767
0.7759
0.7774
0.7787
0.7807
0.7828
0.7931

Reservoir pressure

Saturation pressure

Solution
Gas/Oil
(scf / bbl)
Rs(1)

Formation
Volume
Factor
Bo(1)

116
98
84
66
46
7

1.103
1.107
1.110
1.112
1.114
1.118
1.122
1.126
1.130
1.135
1.136
1.137
1.138
1.139
1.140
1.133
1.128
1.121
1.113
1.067

Gas Formation
Volume
Factor
Bg(2)

0.04456
0.05887
0.08644
0.16333

Notes:
(1) Differential data corrected to surface separator conditions of :Stage 1

0 psig and 180F

Rs = Rsfb - (Rsdb - Rsd) x (Bofb / Bodb)


Bo = Bod x (Bofb/Bodb)
(2) Volume of gas at indicated pressure and temperature per volume at 14.70 psia and 60F.

___________________________________________________________________________________________
E.4
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Differential Vaporisation Data Converted to Production Separator Conditions

Pressure
(psig)

Oil
Density
(g cm-3)

5000
4500
4000
3750
3500
3000
2500
2000
1500
1000
900
800
700
600
508
400
300
200
100
0

0.8017
0.7992
0.7966
0.7953
0.7940
0.7913
0.7886
0.7857
0.7827
0.7795
0.7789
0.7782
0.7774
0.7767
0.7759
0.7774
0.7787
0.7807
0.7828
0.7931

Reservoir pressure

Saturation pressure

Solution
Gas/Oil
(scf / bbl)
Rs(1)

Formation
Volume
Factor
Bo(1)

121
102
88
70
51
12

1.110
1.114
1.117
1.119
1.121
1.125
1.129
1.133
1.137
1.142
1.143
1.144
1.145
1.146
1.147
1.140
1.135
1.128
1.119
1.073

Gas Formation
Volume
Factor
Bg(2)

0.04456
0.05887
0.08644
0.16333

Notes:
(1) Differential data corrected to surface separator conditions of :Stage 1

0 psig and 200F

Rs = Rsfb - (Rsdb - Rsd) x (Bofb / Bodb)


Bo = Bod x (Bofb/Bodb)
(2) Volume of gas at indicated pressure and temperature per volume at 14.70 psia and 60F.

___________________________________________________________________________________________
E.5
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Differential Vaporisation Data Converted to Production Separator Conditions

Pressure
(psig)

Oil
Density
(g cm-3)

5000
4500
4000
3750
3500
3000
2500
2000
1500
1000
900
800
700
600
508
400
300
200
100
0

0.8017
0.7992
0.7966
0.7953
0.7940
0.7913
0.7886
0.7857
0.7827
0.7795
0.7789
0.7782
0.7774
0.7767
0.7759
0.7774
0.7787
0.7807
0.7828
0.7931

Reservoir pressure

Saturation pressure

Solution
Gas/Oil
(scf / bbl)
Rs(1)

Formation
Volume
Factor
Bo(1)

128
109
95
77
57
18

1.118
1.121
1.125
1.127
1.129
1.133
1.136
1.141
1.145
1.150
1.151
1.152
1.153
1.154
1.155
1.148
1.143
1.136
1.127
1.081

Gas Formation
Volume
Factor
Bg(2)

0.04456
0.05887
0.08644
0.16333

Notes:
(1) Differential data corrected to surface separator conditions of :Stage 1

0 psig and 220F

Rs = Rsfb - (Rsdb - Rsd) x (Bofb / Bodb)


Bo = Bod x (Bofb/Bodb)
(2) Volume of gas at indicated pressure and temperature per volume at 14.70 psia and 60F.

___________________________________________________________________________________________
E.6
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Section F - Reservoir Fluid Viscosity Data

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Reservoir Fluid Viscosity Data at 225F


Pressure
(psig)
5000
4500
4000
3750
3500
3000
2500
2000
1500
1000
900
800
700
600
508
400
300
200
100
0

Oil
Viscosity
(cP)

Reservoir pressure

Saturation pressure

Calculated
Gas Viscosity
(cP) (1)

Oil/Gas
Viscosity
Ratio

0.0132
0.0131
0.0129
0.0124

89.1
90.0
93.2
104.7

1.797
1.727
1.657
1.622
1.587
1.517
1.446
1.376
1.306
1.236
1.221
1.207
1.193
1.179
1.166
1.175
1.178
1.201
1.297
1.753

(1) Calculated using the method of Lee, Gonzales and Eakin, JPT, Aug 1966.

___________________________________________________________________________________________
F.1
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Graph of Reservoir Fluid Viscosity Data at 225F

1.900
1.800
1.700

Viscosity (cP)

1.600
1.500
1.400
1.300
1.200
1.100
1.000
0

1000

2000

3000

4000

5000

6000

Pressure (psig)

___________________________________________________________________________________________
F.2
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Section G - Separator Test Data

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Separator Test Data - Test #1

Pressure Temperature
(psig)
(F)

Gas-Oil
Ratio
(1)

508

225

75

102

Gas-Oil
Ratio
Rsfb
(2)

Oil
Density
(g cm-3)

Formation Separation Gas Gravity


Volume
Volume of flashed gas
Factor
Factor
(Air = 1.000)
Bofb (3)
(4)

0.7759
103

0.8445

1.127

Saturation Pressure
1.007

1.105

Residual Oil Properties


Density of residual oil

0.8505

API

34.7

g cm-3 at 60F

Note
*

Evolved gas collected and analysed to Undecanes plus

(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 508 psig and 225F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.

___________________________________________________________________________________________
G.1
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Compositional Analysis of Separator Test Gas to C11+

Test Stage
Pressure Stage, psig
Temperature Stage, F
Component
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6

Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
M-C-Pentane
Benzene
Cyclohexane
C7
Heptanes
M-C-Hexane
Toluene
C8
Octanes
E-Benzene
M/P-Xylene
O-Xylene
C9
Nonanes
C10 Decanes
C11+ Undecanes Plus
Totals :

0
75
Mole %

Weight %

2.94
0.98
53.21
12.82
12.09
3.57
5.14
2.33
3.15
0.67
0.43
0.03
0.49
0.23
0.64
0.05
1.03
0.01
0.04
0.01
0.13
0.01
0.00

4.04
0.86
26.67
12.04
16.66
6.48
9.33
5.25
7.10
1.80
1.13
0.07
1.29
0.72
1.96
0.14
3.68
0.03
0.13
0.03
0.52
0.04
0.00

100.00

100.00

Mole Weight
(g mol-1)
103.3
134.0
_

Density
(g cm-3 at 60F )
0.7370
0.7780
_

Note: 0.00 means less than 0.005.

Calculated Residue Properties


C7+ Heptanes plus
C10+ Decanes plus
C11+ Undecanes plus
Calculated Whole Gas Properties
Gas Gravity
Whole Sample Mole Weight
Gross Calorific Value
Net Calorific Value

1.105
32.01
1790
1638

(Air=1 @ 14.7 psia and 60F)


g mol-1
BTU/scf
BTU/scf

___________________________________________________________________________________________
G.2
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Separator Test Data - Test #2

Pressure Temperature
(psig)
(F)

Gas-Oil
Ratio
(1)

508

225

140

104

Gas-Oil
Ratio
Rsfb
(2)

Oil
Density
(g cm-3)

Formation Separation Gas Gravity


Volume
Volume of flashed gas
Factor
Factor
(Air = 1.000)
Bofb (3)
(4)

0.7759
108

0.8208

1.132

Saturation Pressure
1.039

1.198

Residual Oil Properties


Density of residual oil

0.8531

API

34.2

g cm-3 at 60F

Note
*

Evolved gas collected and analysed to Undecanes plus

(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 508 psig and 225F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.

___________________________________________________________________________________________
G.3
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Compositional Analysis of Separator Test Gas to C11+

Test Stage
Pressure Stage, psig
Temperature Stage, F
Component
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6

Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
M-C-Pentane
Benzene
Cyclohexane
C7
Heptanes
M-C-Hexane
Toluene
C8
Octanes
E-Benzene
M/P-Xylene
O-Xylene
C9
Nonanes
C10 Decanes
C11+ Undecanes Plus
Totals :

0
140
Mole %

Weight %

2.53
0.75
49.60
11.72
11.72
4.07
6.46
3.33
5.06
0.76
0.85
0.05
0.85
0.37
0.58
0.06
1.05
0.01
0.03
0.00
0.14
0.01
0.00

3.21
0.61
22.93
10.16
14.89
6.82
10.82
6.92
10.52
1.89
2.06
0.11
2.06
1.07
1.64
0.16
3.46
0.03
0.09
0.00
0.52
0.04
0.00

100.00

100.00

Mole Weight
(g mol-1)
102.2
141.3
154.0

Density
(g cm-3 at 60F )
0.7350
0.7840
0.7950

Note: 0.00 means less than 0.005.

Calculated Residue Properties


C7+ Heptanes plus
C10+ Decanes plus
C11+ Undecanes plus
Calculated Whole Gas Properties
Gas Gravity
Whole Sample Mole Weight
Gross Calorific Value
Net Calorific Value

1.198
34.70
1954
1791

(Air=1 @ 14.7 psia and 60F)


g mol-1
BTU/scf
BTU/scf

___________________________________________________________________________________________
G.4
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Separator Test Data - Test #3

Pressure Temperature
(psig)
(F)

Gas-Oil
Ratio
(1)

508

225

180

109

Gas-Oil
Ratio
Rsfb
(2)

Oil
Density
(g cm-3)

Formation Separation Gas Gravity


Volume
Volume of flashed gas
Factor
Factor
(Air = 1.000)
Bofb (3)
(4)

0.7759
116

0.8061

1.140

Saturation Pressure
1.060

1.246

Residual Oil Properties


Density of residual oil

0.8547

API

33.9

g cm-3 at 60F

Note
*

Evolved gas collected and analysed to Undecanes plus

(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 508 psig and 225F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.

___________________________________________________________________________________________
G.5
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Compositional Analysis of Separator Test Gas to C11+

Test Stage
Pressure Stage, psig
Temperature Stage, F
Component
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6

Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
M-C-Pentane
Benzene
Cyclohexane
C7
Heptanes
M-C-Hexane
Toluene
C8
Octanes
E-Benzene
M/P-Xylene
O-Xylene
C9
Nonanes
C10 Decanes
C11+ Undecanes Plus
Totals :

0
180
Mole %

Weight %

2.35
1.05
47.20
11.15
11.53
4.58
7.22
4.22
6.12
1.06
0.63
0.04
0.58
0.25
0.64
0.04
1.13
0.01
0.02
0.00
0.15
0.02
0.01

2.87
0.81
20.98
9.29
14.09
7.38
11.63
8.44
12.23
2.53
1.47
0.09
1.35
0.69
1.74
0.10
3.58
0.03
0.06
0.00
0.53
0.07
0.04

100.00

100.00

Mole Weight
(g mol-1)
102.8
140.1
154.0

Density
(g cm-3 at 60F )
0.7350
0.7840
0.7950

Note: 0.00 means less than 0.005.

Calculated Residue Properties


C7+ Heptanes plus
C10+ Decanes plus
C11+ Undecanes plus
Calculated Whole Gas Properties
Gas Gravity
Whole Sample Mole Weight
Gross Calorific Value
Net Calorific Value

1.246
36.09
2024
1855

(Air=1 @ 14.7 psia and 60F)


g mol-1
BTU/scf
BTU/scf

___________________________________________________________________________________________
G.6
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Separator Test Data - Test #4

Pressure Temperature
(psig)
(F)

Gas-Oil
Ratio
(1)

508

225

200

113

Gas-Oil
Ratio
Rsfb
(2)

Oil
Density
(g cm-3)

Formation Separation Gas Gravity


Volume
Volume of flashed gas
Factor
Factor
(Air = 1.000)
Bofb (3)
(4)

0.7759
121

0.7995

1.147

Saturation Pressure
1.071

1.312

Residual Oil Properties


Density of residual oil

0.8562

API

33.6

g cm-3 at 60F

Note
*

Evolved gas collected and analysed to Undecanes plus

(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 508 psig and 225F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.

___________________________________________________________________________________________
G.7
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Compositional Analysis of Separator Test Gas to C11+

Test Stage
Pressure Stage, psig
Temperature Stage, F
Component
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6

Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
M-C-Pentane
Benzene
Cyclohexane
C7
Heptanes
M-C-Hexane
Toluene
C8
Octanes
E-Benzene
M/P-Xylene
O-Xylene
C9
Nonanes
C10 Decanes
C11+ Undecanes Plus
Totals :

0
200
Mole %

Weight %

2.31
0.61
45.00
10.72
11.45
4.63
7.60
4.57
6.92
1.43
0.86
0.05
0.87
0.39
1.03
0.07
1.22
0.02
0.04
0.01
0.17
0.02
0.01

2.68
0.45
19.00
8.48
13.29
7.08
11.62
8.68
13.14
3.24
1.90
0.10
1.93
1.03
2.66
0.17
3.67
0.06
0.11
0.03
0.57
0.07
0.04

100.00

100.00

Mole Weight
(g mol-1)
102.4
140.1
154.0

Density
(g cm-3 at 60F )
0.7350
0.7840
0.7950

Note: 0.00 means less than 0.005.

Calculated Residue Properties


C7+ Heptanes plus
C10+ Decanes plus
C11+ Undecanes plus
Calculated Whole Gas Properties
Gas Gravity
Whole Sample Mole Weight
Gross Calorific Value
Net Calorific Value

1.312
38.00
2143
1966

(Air=1 @ 14.7 psia and 60F)


g mol-1
BTU/scf
BTU/scf

___________________________________________________________________________________________
G.8
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Separator Test Data - Test #5

Pressure Temperature
(psig)
(F)

Gas-Oil
Ratio
(1)

508

225

220

118

Gas-Oil
Ratio
Rsfb
(2)

Oil
Density
(g cm-3)

Formation Separation Gas Gravity


Volume
Volume of flashed gas
Factor
Factor
(Air = 1.000)
Bofb (3)
(4)

0.7759
128

0.7924

1.155

Saturation Pressure
1.082

1.370

Residual Oil Properties


Density of residual oil

0.8572

API

33.4

g cm-3 at 60F

Note
*

Evolved gas collected and analysed to Undecanes plus

(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 508 psig and 225F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.

___________________________________________________________________________________________
G.9
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Compositional Analysis of Separator Test Gas to C11+

Test Stage
Pressure Stage, psig
Temperature Stage, F
Component
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6

Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
M-C-Pentane
Benzene
Cyclohexane
C7
Heptanes
M-C-Hexane
Toluene
C8
Octanes
E-Benzene
M/P-Xylene
O-Xylene
C9
Nonanes
C10 Decanes
C11+ Undecanes Plus
Totals :

0
220
Mole %

Weight %

2.20
0.93
42.40
10.30
11.37
4.73
7.76
5.18
8.07
1.76
1.06
0.06
0.99
0.42
1.05
0.06
1.37
0.01
0.03
0.01
0.19
0.03
0.02

2.44
0.66
17.14
7.80
12.64
6.93
11.36
9.42
14.67
3.82
2.25
0.12
2.10
1.06
2.60
0.14
3.94
0.03
0.08
0.03
0.61
0.10
0.07

100.00

100.00

Mole Weight
(g mol-1)
102.2
141.3
154.0

Density
(g cm-3 at 60F )
0.7350
0.7850
0.7950

Note: 0.00 means less than 0.005.

Calculated Residue Properties


C7+ Heptanes plus
C10+ Decanes plus
C11+ Undecanes plus
Calculated Whole Gas Properties
Gas Gravity
Whole Sample Mole Weight
Gross Calorific Value
Net Calorific Value

1.370
39.69
2233
2050

(Air=1 @ 14.7 psia and 60F)


g mol-1
BTU/scf
BTU/scf

___________________________________________________________________________________________
G.10
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Section H - Appendix

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Data Used in Gas Compositional Calculations

Component

Hydrogen
Oxygen/(Argon)
Nitrogen (Corrected)
Methane
Carbon Dioxide
Ethane
Hydrogen Sulphide
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
22DMC4
23DMC4/CYC5
2MC5
3MC5
Hexanes (nC6)
22DMC5
M-C-Pentane
24DMC5
223TMC4
Benzene

Mole Weight
Density
Component
(g mol-1) (g cm-3 at 60F)
*
**
**
**
**
**
**
**
**
**
*
**
**
*
*
*
*
*
*
*
*
*
*

2.016
31.999
28.013
16.043
44.010
30.070
34.080
44.097
58.123
58.123
72.15
72.150
72.150
86.18
78.16
86.18
86.18
86.18
100.20
84.16
100.20
100.20
78.11

N/A
1.1410
0.8086
0.2997
0.8172
0.3558
0.8006
0.5065
0.5623
0.5834
0.5968
0.6238
0.6305
0.6529
0.7129
0.6572
0.6682
0.6631
0.6814
0.7533
0.6757
0.6947
0.8820

33DMC5
Cyclohexane
2MC6/23DMC5
11DMCYC5/3MC6
t13DMCYC5
c13DMCYC5/3EC5
t12DMCYC5
Heptanes (nC7)
22DMC6
MCYC6
ECYC5
223TMC5/24&25DMC6
ctc124TMCYC5
ctc123TMCYC5
Toluene
Octanes (nC8)
E-Benzene
M/P-Xylene
O-Xylene
Nonanes (nC9)
Decanes
Undecanes
Dodecanes

Mole Weight
Density
(g mol-1) (g cm-3 at 60F)
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
***
***
***

100.20
84.16
100.20
99.20
98.19
99.20
98.19
100.20
114.23
98.19
98.19
114.23
112.21
112.21
92.14
114.23
106.17
106.17
106.17
128.26
134
147
161

0.6954
0.7827
0.6917
0.7253
0.7528
0.7262
0.7554
0.6875
0.6994
0.7740
0.7704
0.7060
0.7511
0.7574
0.8734
0.7063
0.8735
0.8671
0.8840
0.7212
0.778
0.789
0.800

Data Source Refs :


* ASTM Data Series Publication DS 4B (1991) - Physical Constants of Hydrocarbon and Non-Hydrocarbon
Compounds.
** GPA Table of Physical Constants of Paraffin Hydrocarbons and Other Components of Natural Gas,
GPA 2145-96.
*** Journal of Petroleum Technology, Nov 1978, Pages 1649-1655.
Predicting Phase Behaviour of Condensate/Crude Oil Systems Using Methane Interaction Coefficients
- D.L. Katz & A. Firoozabadi.

Note :
The gas mole % compositions were calculated from the measured weight % compositions using the
most detailed analysis results, involving as many of the above components as were identified. The
reported component mole % compositions were then sub-grouped into the generic carbon number
components.

___________________________________________________________________________________________
H.1
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Data Used in Liquid Compositional Calculations

Component

Hydrogen
Hyd. sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Me-cyclo-pentane
Benzene
Cyclo-hexane
Heptanes
Me-cyclo-hexane
Toluene
Octanes
Ethyl-benzene
Meta/Para-xylene
Ortho-xylene
Nonanes
1-2-4-T-M-benzene
Decanes

Mole Weight
Density
Component
(g mol-1) (g cm-3 at 60F)
*
**
**
**
**
**
**
**
**
**
**
**
*
*
*
**
*
*
**
*
*
*
**
*
**

2.016
34.080
44.010
28.013
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
84.16
78.11
84.16
100.204
98.19
92.14
114.231
106.17
106.17
106.17
128.258
120.19
142.285

N/A
0.8006
0.8172
0.8086
0.2997
0.3558
0.5065
0.5623
0.5834
0.6238
0.6305
0.6634
0.7533
0.8820
0.7827
0.6874
0.7740
0.8734
0.7061
0.8735
0.8671
0.8840
0.7212
0.8797
0.7334

Undecanes
Dodecanes
Tridecanes
Tetradecanes
Pentadecanes
Hexadecanes
Heptadecanes
Octadecanes
Nonadecanes
Eicosanes
Heneicosanes
Docosanes
Tricosanes
Tetracosanes
Pentacosanes
Hexacosanes
Heptacosanes
Octacosanes
Nonacosanes
Triacontanes
Hentriacontanes
Dotriacontanes
Tritriacontanes
Tetratriacontanes
Pentatriacontanes

Mole Weight
Density
(g mol-1) (g cm-3 at 60F)
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***

147
161
175
190
206
222
237
251
263
275
291
305
318
331
345
359
374
388
402
416
430
444
458
472
486

0.789
0.800
0.811
0.822
0.832
0.839
0.847
0.852
0.857
0.862
0.867
0.872
0.877
0.881
0.885
0.889
0.893
0.896
0.899
0.902
0.906
0.909
0.912
0.914
0.917

Data Source Refs :


* ASTM Data Series Publication DS 4B (1991) - Physical Constants of Hydrocarbon and Non-Hydrocarbon
Compounds.
** GPA Table of Physical Constants of Paraffin Hydrocarbons and Other Components of Natural Gas
GPA 2145-96.
*** Journal of Petroleum Technology, Nov 1978, Pages 1649-1655.
Predicting Phase Behaviour of Condensate/Crude Oil Systems Using Methane Interaction Coefficients
- D.L. Katz & A. Firoozabadi.

Note :
The residue mole weight and density values ( eg heptanes plus, undecanes plus, eicosanes plus) are
calculated so that the calculated average mole weights and densities correspond with the measured
values. This can lead to anomalous residue mole weights and densities where the Katz and
Firoozabadi values may not be suitable for the isomer groups detected.

___________________________________________________________________________________________
H.2
Core Laboratories Venezuela, S.A.

CORE LABORATORIES
LABORATORY
JOB NUMBER: 250484

CUSTOMER:

CLIENT I.D...:
DATE SAMPLED..........
TIME SAMPLED..............
WORK DESCRIPTION........

Occidental de Colombia

Pozo: Rondon 1 N

TEST DESCRIPTION

TESTS

05/20/05

RESULTS
ATTN: Uriel Sanchez

LABORATORY ID..... 250484-01


DATE RECEIVED..... 06/20/05
TIME RECEIVED...... 13:00
REMARKS.................: Muestreado por: Cliente

FINAL RESULT LIMITES/*DILUTION

UNITS
MEASURE
% v/v
% v/v
% v/v

OF

DATE
TECHN
ASTM D 1796-97 06/23/05 YCH
ASTM D 1796-97 06/23/05 YCH
TEST METHOD

Agua
Sedimento
Agua y Sedimentos
Gravedad API @ 60 oF

1.0
< 0.1
1.0
34.6

0.1
0.1
0.1

Asfaltenos N-Heptano
Parafinas

0.60
11.85

0.05
0.01

% Peso
% Peso

IP 143-96
UOP 46-85

06/23/05 YCH
06/23/05 YCH

Punto de Inflamacion (C. Abierta)


Contenido de Azufre

47
0.17

20
0.01

oF
% Peso

ASTM D 92-01
ASTM D 1552-01
ASTM D 482-00
ASTM D 3230-99
ASTM D 5853-00
SW-846/6010 B
SW-846/6010 B
ASTM D 445-01
ASTM D 445-01
ASTM D 445-01
ASTM D 323-99
ASTM D 240-00

06/23/05
06/27/05
06/27/05
06/27/05
06/23/05
06/28/05
06/28/05
06/27/05
06/27/05
06/27/05
07/25/05
07/21/05

Contenido de Ceniza
Contenido de Sal
Punto de Fluidez
Niquel total (Ni)
Vanadio total (V)
Viscosidad Cinematica a 100 F
Viscosidad Cinematica a 122 F
Viscosidad Cinematica a 210 F
Presion de vapor Reid @ 100 F
Calor de Combustion (Valor Calorfico)

< 0.001
< 1.0
4
5.0
1.0
5.35
4.34
2.28
4.9
19874

0.001
1
-36
0.5
5
0.1
0.1
0.1
0.1
600

% Peso
Lbs./1000 bbls
oC
mg/Kg
mg/Kg
cSt
cSt
cSt
psi
Btu/ lbs

ASTM D 1796-97 06/23/05 YCH


ASTM D 287-00 06/23/05 YCH

YCH
MJ
MJ
MJ
YCH
AM
AM
LO
LO
LO
HR
MJ

Carretera El Mojan, km 3
Maracaibo, Edo. Zulia
(0261) 7574611

_______________________________________________________________________________________________
H.3
Core Laboratories Venezuela, S.A.

CORE LABORATORIES
LABORATORY
JOB NUMBER: 250484

CUSTOMER:

CLIENT I.D...:
DATE SAMPLED..........
TIME SAMPLED..............
WORK DESCRIPTION........
TEST DESCRIPTION

TESTS

RESULTS

Occidental de Colombia

Pozo: Rondon 1 N
05/20/05

ATTN: Uriel Sanchez

LABORATORY ID..... 250484-01


DATE RECEIVED..... 06/20/05
TIME RECEIVED...... 13:00
REMARKS.................: Muestreado por: Cliente

FINAL RESULT LIMITES/*DILUTION

UNITS
MEASURE

OF

TEST METHOD

DATE
TECHN

Destilacin atmosfrica
Punto Inicial de Ebullicion

150

F ASTM D 86-01

5% Destilado

228

10% Destilado

290

15% Destilado

338

20% Destilado

387

25% Destilado

428

30% Destilado

468

35% Destilado

505

40% Destilado

536

45% Destilado

572

50% Destilado

600

55% Destilado

624

60% Destilado

640

65% Destilado

645

70% Destilado

646

75% Destilado

647

80% Destilado

648

85% Destilado

649

90% Destilado

NA

95 % Destilado

NA

Punto Final Ebullicion

650

Porcentaje Destilado

85.0

Porcentaje Total Recuperado

99.5

0.1

Porcentaje de Residuo

14.5

0.1

Porcentaje de Perdidas

0.5

0.1

06/23/05 YCH

Carretera El Mojan, km 3
Maracaibo, Edo. Zulia
(0261) 7574611

_______________________________________________________________________________________________
H.4
Core Laboratories Venezuela, S.A.

Occidental de Colombia
RFL05097
Rondon
1N Well
___________________________________________________________________________________________

Report prepared by

Report approved by

Gustavo Cabeza
Project Manager
Reservoir Fluid Laboratory

David McEvoy
Laboratory Manager
Reservoir Fluid Laboratory

___________________________________________________________________________________________
Core Laboratories Venezuela, S.A.

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