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Rate of reaction = change of quantity in reactant or product per unit time. We usually use water displacement method to collect gas in school laboratory as shown below:
The reaction is fastest at the start when the reactants are at a maximum (steepest gradient) The gradient becomes progressively less as reactants are used up and the reaction slows down. Finally the graph levels out when one of the reactants is used up and the reaction stops. The amount of product depends on the amount of reactants used. The initial rate of reaction is obtained by measuring the gradient at the start of the reaction. A tangent line is drawn to measure rate of reaction at instataneous time
2. Activation Energy
Activation energy is the minimum amount of energy that must be overcome by the colliding
Sodium thiosulphate solution react with dilute sulphuric acid to form a yellow precipitate of sulphur. In this experiment, the time taken for the formation of sulphur to cover the mark 'X' until it disappears from sight can be used to measure rate of reaction.
As the concentration of sulphuric acid is increased, the rate of reaction between sulphuric acid and sodium thiosulphate increases.
When the concentration of the solution of a reactant increases, the number of particles per unit volume of the solution also increases. With more particles per unit volume of the solution of the reactant, the frequency of collision increases. This causes the frequency of effective collision to increase. Hence, the rate of reaction increases.
Catalyst does not change the quantity of the product formed. Catalyst is specific in its action. Only a small amount of catalyst is needed to achieve a big increase in rate of reaction.
How catalyst increase the rate of reaction: When a positive catalyst is used in a chemical reaction, it enables the reaction to occur through an alternative path which requires lower activation energy. As a result, more colliding particles are able to overcome the lower activation energy.
This causes the frequency of effective collision to increase. Hence, the rate of reaction increases. Decomposition of hydrogen peroxide by catalyst of manganese (IV) oxide
Hydrogenation process is addition reaction to convert alkene becomes alkane. It converts unsaturated compound to saturated compound.
Ethene reacts with H2 at 180 C in the presence of nickel or platinum catalyst to produce ethane
In the dehydration of alcohols, a molecule of water is eliminated from each alcohol molecule to produce alkene. There are two methods of dehydration:
a) Ethanol vapour is passed over a heated unglazed porcelain chips, porous pot, pumice stone or alumina (aluminium oxide). b) Ethanol is heated under reflux at 170 C with excess concentrated sulphuric acid.
Alkene can be tested by decolourising brown bromine water or decolourising purple acidified potassium manganate (VII) solution.
Carboxylic acids are organic compounds which form an homologous series with the general formula of CnH2n+1COOH. Carboxylic acids are compounds which contain a -COOH functional group. Carboxylic acids are weak acid which ionize partially in water to produce lower concentration of hydrogen ions compare to strong acid.
Formula
Common Name
Source
IUPAC Name
HCO2H CH3CO2H CH3CH2CO2H CH3(CH2)2CO2H CH3(CH2)3CO2H CH3(CH2)4CO2H CH3(CH2)5CO2H CH3(CH2)6CO2H CH3(CH2)7CO2H CH3(CH2)8CO2H
formic acid acetic acid propionic acid butyric acid valeric acid caproic acid enanthic acid caprylic acid pelargonic acid capric acid
ants (L. formica) vinegar (L. acetum) milk (Gk. protus prion) butter (L. butyrum) valerian root goats (L. caper) vines (Gk. oenanthe) goats (L. caper) pelargonium (an herb) goats (L. caper)
methanoic acid ethanoic acid propanoic acid butanoic acid pentanoic acid hexanoic acid heptanoic acid octanoic acid nonanoic acid decanoic acid
Examples of Esters
+wate r
ethyl methanoate (rum essence) : ethan +methanoic ol acid C2H5O + HCOOH H ethyl methanoate (ester) +wate r + H2O
HCOOC2H5 (ester)
ethyl butanoate (pineapple) : ethan +butanoic ol acid ethyl butanoate (ester) +wate r + H2O
+wate r + H 2O
pentyl butanoate (apricot) : pentan +butanoic ol acid pentyl butanoate (ester) +wate r + H 2O
octyl butanoate (orange) : octano +butanoic l acid octyl butanoate (ester) +wate r + H 2O
methyl ethanoate (solvent) : methan +ethanoic ol acid CH3OH methyl ethanoate (ester) +wate r
ethyl ethanoate (solvent) : ethan +ethanoic ol acid ethyl ethanoate (ester) +wate r + H2O
Redox reactions are chemical reactions involving oxidation and reduction occurring simultaneously. Oxidising agent is the substance that causes oxidation. Reducing agent is the substance that causes reduction.
Oxidation involves loss of electrons and increase in oxidation number. Reduction involves gain of electrons and decrease in oxidation number. Example:
The magnesium's oxidation state has increased from 0 to +2 , it has been oxidised. Magnesium acts as reducing agent. The hydrogen's oxidation state has decreased from +1 to 0 , it has been reduced. The hydrogen ion acts as a oxidising agent. Click on the diagram below to play!
Chemistry Form 5: Chapter 3 - Conversion of Iron (II) to Iron (III) and Iron (III) to Iron (II)
Reduction half equation: Bromine molecules which give bromine water its brown colour gain electrons and are reduced to colourless bromide ions. Br2 + 2 e -------> 2 Br-
Observation: Brown bromine water decolourises. The solution changes colour from pale green (Fe2+) to yellow (Fe3+).
Oxidising agent : Fe2+ ions Reducing agent : zinc Oxidation half equation: Zinc atoms lose their electrons and are oxidized to zinc ions, Zn2+. Zinc powder dissolves in iron (III) chloride. Zn -------> Zn2+ + 2e
Reduction half equation: Fe3+ ions accept electrons and are reduced to Fe 2+. The presence of Fe2+ ions is confirmed by the formation of green precipitate with excess of NaOH solution. Fe3+ + Overall ionic equation: 2 Fe3+ + Zn ---------> 2 Fe2+ + Zn2+ e Fe2+
Observation: Zinc powder dissolves into solution. The solution changes colour from brown (Fe3+) to pale green (Fe2+).
----->
Iron displaces copper from the solution because it is more reactive than copper metal. Iron, being more reactive, loses its electrons readily. The electrons are transferred from the iron atoms to the copper(II) ions in the solution. Copper(II) ions are reduced to copper metal and iron atoms become oxidised to iron (II) ions. Iron acts as reducing agent whereas copper (II) ions act as a oxidising agent. Oxidation reaction: Fe (s) -----> Fe2+ (aq) + 2eReduction reaction: Cu2+ (aq) + 2e- -----> Cu (s) Overall Redox reaction: Fe (s) + Cu2+ (aq) -----> Fe2+ (aq) + Cu (s)
Rusting is a corrosion of iron. For iron to rust, oxygen and water must be present. In the presence of acids and salts, rusting occurs faster because these substances increase the electrical conductivity of water, making water a better electrolyte. Oxygen acts as the oxidizing agent and iron acts as the reducing agent .
The surface of iron at the middle of the water droplet serves as the anode at which oxidation occurs. The iron atoms lose electrons to form iron (II) ions. The electrons flow to the edge of the water droplet where there is plenty of dissolved oxygen. The iron surface there serves as cathode at which reduction occurs. Oxygen gains the electrons and is reduced to hydroxide ions.
The iron (II) ions produced combine with the hydroxide ions to iron (II) hydroxide. The Fe(OH) 2 is then
further oxidized by oxygen to form iron (III) oxide, Fe2O3 known as rust
More electropositive metal undergoes oxidation reaction by releasing electrons and act as a reducing agent. Less electropositive metal undergoes reduction reaction by gaining electrons and act as a oxidising agent. Electrons flow from more electropositive metal to less electropositive metal.
Exothermic Reaction Chemical reaction that gives out heat to the surroundings. Temperature of the surroundings increases. The total energy of reactants is more than total the energy of products. Bond formation releases more energy than is required in the bond breaking.
Endothermic Reaction Chemical reaction that absorbs heat from the surroundings. Temperature of the surroundings decreases. The total energy of reactants is less than the total energy of products. Bond breaking requires more energy than the energy that is released during bond formation
Examples: Combustion of fuel, burning of metal, neutralization, respiration, rusting of iron, reaction of a reactive metal with acid, reaction of alkaline metals with water, Haber process, freezing, condensation, dissolving alkali or concentrated acid in water, dissolving anhydrous salts in water.
Examples: Thermal decomposition of nitrate or carbonate salts, reaction of acid with hydrogen carbonate, photosynthesis, melting, boiling, sublimation, dissolving ammonium or potassium salts in water, heating of hydrated salt.
Soaps are sodium or potassium salts of fatty acids. Soaps are prepared by hydrolyzing fats or oils under alkaline condition. This reaction is called saponification.
The fats or oils are hydrolysed first to form glycerol and fatty acids. The acids then react with an alkali to form the corresponding sodium or potassium salts. The soap formed can be precipitated by adding sodium chloride. This is because sodium chloride lowers the solubility of soap in water. The glycerol and excess sodium hydroxide solution are removed by rinsing the soap formed with water.
Soaps feel slippery and form lather when they are shaken with water.