1

ELITE 2011 I PET/CMP/P(I)/SOLNS BRILLIANT S MOCK ALL-INDIA TESTS (B.MAT) NATIONAL SIT-DOWN PROGRESSIVE EVALUATION TEST 1
FOR STUDENTS OF OUR TWO-YEAR ELITE POSTAL COURSE TOWARDS

IIT-JOINT ENTRANCE EXAMINATION, 2011

PAPER I SOLUTIONS CHEMISTRY MATHEMATICS PHYSICS
PART A : CHEMISTRY SECTION I 1. (D) Radius of nucleus = 1.25 10 = 1.25 10 = 5.0 10
13 1/3

cm

13

641/3 cm

13

cm cm
13 3

Radius of atom = 1 = 1 10 Volume of nucleus Volume of atoms 4 3 4 3

5 10 1 10
39 24

8 3

125 10 1 10
13

= 125 10

15

= 1.25 10
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2. (A) First line in Lyman series of Hydrogen atom is for n2 = 2 to n1 = 1 1 1 = R

H

1 n
2 1

1 n 3
2 2

Z = 1 (for H)

= 109678

1 4

= 82259 cm

3. (C) In OF2 molecule, two bond pair of electrons and two lone pair of electrons are present in oxygen. Hence hybridisation of oxygen in this molecule is sp3.
3 z

4. (C) The d-orbital involved in sp d hybridisation is d 2 . 5. (D) 100 P = V 2 V =

2

40 100

P
3

100 100 40

= 250 cm

V2 = volume of bulb A + volume of bulb B Hence volume of bulb B = 250 100 = 150 cm3 6. (D) r.m.s. velocity = 3RT M
4

r.m.s. velocity for CH r.m.s. velocity for SO 100 = V V = 2 64 = 16 4 = 2

M of SO

2 4

M of CH

at the same temperature

100

= 50 m sec

7. (D) Z2O3 + 3H2 2 Z + 3H2O 1 mole 3 mole If x is the atomic weight of metal, molecular weight of Z2O3 will be (2x + 48) No. of moles of Z2O3 = 0.1596 2x 48 No. of moles of Hydrogen =
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0.006 2

= 0.003
EELP/I PET/CMP/P(I)/Solns

According to the balanced equation, 0.1596 : 0.003 = 1 : 3 2x 48 or 3 0.1596 2x 48 48 = 0.003 48 = 0.1596 0.001

0.1596 2x

= 0.001 or 2x

2x = 159.6 48 = 111.6 x= 111.6 2 = 55.8

Atomic weight of the metal = 55.8 8. (B) In the presence of phenolphthalein indicator, whole of NaOH and half of Na2CO3 are neutralised by HCl. The remaining half of Na2CO3 is neutralised by further addition of HCl using methyl orange indicator. Half of Na2CO3 present in solution = 25 0.2 milliequivalents = 5.0 milliequivalents NaOH + half of Na2CO3 present in solution = 300 0.1 milliequivalents = 30 milliequivalents Amount of NaOH present in solution = 30 5 = 25 milliequivalents = 25 10 = 1.0 g SECTION II 9. (B), (C), (D) P vs V is a curve. But others form linear plots. 10. (A), (B), (C) PH3 has one lone pair and three bond pairs of electrons and P is in sp3 hybrid state. SO 2
3 3

40

ion as well as SO 2
4

ion have tetrahedral shape. XeF4 has four

bond pair and two lone pair of electrons. It is square planar but the Xe atom 3 2 is in sp d hybrid state.
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11. (B), (D) Isotones have same no. of neutrons.

76 32

Ge,

77 33

As and

78 34

Se all have 44 neutrons in their nuclei.

12. (B), (C), (D) 0.1 mole of O2 gas = 0.1 32 = 3.2 g 0.1 mole of SO2 gas = 0.1 64 = 6.4 g 6.02 1022 molecules of SO2 gas =
23

6.02 10 6.02 10

22 23 23

64 = 6.4 g

1.204 10

molecules of O2 gas = =

1.204 10 6.02 10 32 5 = 6.4 g

23

32

SECTION III 13. (B) Molecular weight of the gas = Mx Molecular weight of helium = MHe = 4 According to Grahams law of diffusion Rate of diffusion of gas Rate of diffusion of He 1 = 4 4 M = M
He x

4 1 = 16 M

or Mx = 16 4 = 64 14. (D) Let the volume of gas diffused = V mL Rate of diffusion of gas x = Rate of diffusion of O2 = V 2 m sec m sec
2 2

V 5.65

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Rate of diffusion of gas Rate of diffusion of O V 2 V 5.65 5.65 = 2.825 = 2 2.825 2.825 = x = x 32 x 32
2

M =

32 x

32 =4 2.825 2.825

Molecular weight of the gas = 4 15. (B) Rate of diffusion of H2 gas = 50 20 = 2.5 m minute
2

Rate of diffusion of O2 gas = 40 mL minute t Rate of diffusion of H Rate of diffusion of O 2.5t = 40 t = 32 = 4 2

2 2

M = M

O H

40 4 = 64 minutes 2.5

16. (A) The correct order of strengths of H bonds is H ... F > H ... O > H ... N, since the electronegativity of F is greater than O which is greater than nitrogen atom. 17. (C) Boiling point is proportional to the size of the molecules. Hence the correct order is GeH4 > SiH4 > CH4. 18. (B) BeF2 molecule being symmetrical and linear has zero dipole moment. H2O is bent and has net dipole moment.
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SECTION IV 19. (A) (p), (r); (B) (t); (C) (p), (q); (D) (p), (s) (A) O2 is paramagnetic; Bond order is 2.0 (B) N2 is diamagnetic; Bond order is 3.0 (C) O (D) N
2

is paramagnetic; Bond order is 1.5 is paramagnetic; Bond order is 2.5

20. (A) (s); (B) (q), (s); (C) (r), (t); (D) (p) (A) SF6 d sp hybridisation for sulphur atom.
3 2 (B) XeF4 sp d hybridisation for xenon atom and has square planar shape. 3 (C) CCl4 sp hybridisation for carbon atom and has tetrahedral shape. 2 3

(D) NO

linear and nitrogen atom has sp hybridisation.

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PART B : MATHEMATICS SECTION I 21. (D) Using the numbers in AP, we get 3 log 3b = 3 log 5c 3b = 5c Also a, b, c in GP b2 = ac
2

5 3 Also b = 3 5

c = ac 9 25

a,

c =

a is the largest side A is the largest angle cos A = b

2

2bc

a = 25

81 2 a 625

9 3 a 2 a 5 25

ve

triangle is obtuse angled. x 2x 4y y z 2z 4y = y x 2x 4 2xz x z z 2z 4 2xz x z

22. (D) E =

2xz x z
2

2xz x z [Q x, y, z are in HP]

9xz 2x
2

9xz 2z
2

1 2

9 2 9 2

z x z x

x z x z

1 2

= 1 9 2

which is > 1 + = 10
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since x, y, z are positive

EELP/I PET/CMP/P(I)/Solns

23. (B) rth term = =

r 1 3 5 ... 2r 1 2 1 2 2r 1 1 3 5 2r 1 1 3 5 2r 1 13 1 1 135 1 1 1 3 5 2n 1 1 1 1 1 1 3 5 ... 2r 1

= 1 2 1 2

T =
1

T =
2

13

........................... T =
n

1 2

1 3 5 2n

Sn = T1 + T2 + ... + Tn = 1 2
n

1 1 2

1 1 3 5 2n 1 0 = 1 2 ... (1) ... (2) 1

Lt S =
n

24. (B) 1 < 2 < 3 < 4 sin 1 = sin 2 = sin 3 = sin 4 = (positive) we can choose 2, 3, 4 as follows 2 = 1 E = 4 sin
1

3 = 2 + 1 3 sin 2
1

4 = 3 1 2 sin
1

2
1

2 2 sin

2
1

sin

3 2

= 4 sin

2
1

3 cos

2
1

cos

= 2

sin

2
1

cos

2
EELP/I PET/CMP/P(I)/Solns

= 2 1

sin = 2 1

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25. (D) 2 + kx + sin

(x 2x + 2) + cos
1

(x 2x + 2) = 0
1

2 2 + kx + sin

((x 1)2 + 1) + cos

((x 1)2 + 1) = 0

2+k+ ( Q sin
1

= 0
2

((x 1) + 1) etc. is valid only when x = 1) 2 2

k=

26. (C) rth term t r = sin

r r r r r r

r 1

= sin

r 1 1 r y
2

1 1 1 1 1 r

r r

= sin

1 r

1 y 1

r x
2

= sin

where x = = sin
r 1

1 r

y =

1 r 1

x sin
1

y
1

t = sin

1 r

sin
1

1 r 1 2 1

t = sin
1

1 1 2

sin

t = sin
2

sin

1 3

t
n

= sin

1 n

sin

1 n 1
EELP/I PET/CMP/P(I)/Solns

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Adding Sn = sin

1 sin

1 n 1
1

As n the above = sin = 27. (A) 2

1 sin 0 = 2

1 2

BD DC

area of ABD area of ADC 1 AB AD sin 2 1 AD AC sin 2 = 2 AB AC = 2 AC AB ... (1)

Hence

sin sin sin

Similarly

sin

... (2)

The product gives the result = 4 28. (A) The equation is cos sin x 4 5x 4 sin x sin x 4 cos x 2 cos
2 2

sin

cos x = 0

cos x = 2

Since both the terms of LHS are 1 the above is valid if sin 5x 4 = 1 and cos x = 1, simultaneously

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5x 4 x= 2 4n

= 2n 8n 5 1 5 2

and x = 2m and x = 2m 1 = 5m

= 2m 4n

This will be true if n = 1, 6, 11, .... 14, 9, 4, .... All these will be exhausted if we take n = 5k + 1. x = = 2 4 5k 2 5 1 5 20k 5 1

= 2 (4k + 1) = 8k + 2 Finally k can be replaced by n x = 8n + 2 SECTION II 29. (B), (D) Given equation is sin x + 2 cos a cos x = 2 LHS lies between
2 2 2 2

4cos a 1 2

1 and
2

4cos a 1

4cos a

4cos a

4 cos a + 1 4 4 cos a 3 cos2 a 3 4 3 4 1 4 ... (B) is correct ... (D) is correct

1 sin2 a sin a sin2 a 1 4

2

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30. (B), (C)

Case I: Let ADC = 45 then by (m n) formula 2 cot 45 = 1 cot B 1 cot 30 2 = cot B 3 cot B = 2 + 3 = cot 15 B = 15 Case II: Let ADB = 45 then ADC = 135 2 cot 135 = cot B 3 2 = cot B 3 cot B = 2 + 3 B = 105 31. (A), (B), (C) sin2 x sin2 y = 3 2 3 2 (Qxy= 2 1 3 )

sin (x + y) sin (x y) = sin (x + y) sin 3 = 3 2

sin (x + y) = 1 (x + y) = (4n + 1) x + y = 2n + 1 2 ,nI

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Put n = 0

x+y= xy=

1 2 1 3 5 2 1 3 solving (x, y) = 17 13 , 12 12 ... (B) solving (x, y) = 5 12 12 , 1 .... (A)

Put n = 1

x+y= xy=

n=1 n= 1 2

gives (C) gives (D)

but n is an integer. Hence D is not valid. 32. (A), (B)

3 We can take the 4 terms as a , a , ar, ar 3 r r

Product a4 = 9 a2 = 3; a = 3 Also a = 1 3 r ar a2r2 = 1 ar = 1 r= There are 4 cases a Sum to infinity = 1 r

3 2

1 3 1 r
2 2

a = r 1

a = 3 taking a and r as r = 33 1 1 3 = 9 3 2 = 27 2

3,

1 3

or

3,

1 3

Similarly S = 27 in the other cases. 2

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SECTION III 33. (C) tn = Sn Sn 1 = a 3n a (a 3n 1 a) =a3

n1

2 = 2a 3

n1 2

The sequence is 2a, 2a 3 2a 3 .... It is a GP with common ratio 3 34. (A) tk = Sk Sk 1 = a 4k a (a 4k 1 a) =a4
k1

= 3a 4
k 1

k1

1 t
k

1 3a
1

1 4
2

Hence

1 t
k

1 3a

1 1 1

1 4 =

1 4 4 9a 1k k 12

...

1 3a 2

1 4 k

35. (D) tk = k k = = 1 t
k

1 k 12 k k 1 4 4

1 12 k k

1 3

k k

1 1 k k 1 2
EELP/I PET/CMP/P(I)/Solns

Let it be uk = 4

1 1

u1 = 4 1
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u2 = 4

1 2

1 3

un = 4 1 n 1 n 1 n 1 1

Adding Sn = 4 1

Sum to = 4 [1 0] = 4 36. (A) B1 + B2 = given expression is sin C sin B

1 1 1

sin C sin sin C

1

B
2

sin C

sin B c
1

=
2 2 2

c b

Now a = b + c 2 bc cos A c2 2 bc cos A + (b2 a2) = 0 The two roots are c1 and c2 c1 + c2 = 2b cos A expression = 2b cos A b = 2 cos A

37. (B) Required sum of the areas = 1 2 ab sin C

1

sin C

As per Qn. 36

c1 + c2 = 2b cos A sin C1 + sin C2 = 2 sin B cos A

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sum of the areas = =

1 2

ab 2 sin B cos A b cos A

2

a sin B b
2

= sin A b cos A = 1 2 b sin 2A 2

38. (C) a2 = b2 + c2 2bc cos A

2

7 2

= 16

2 4 c = 0

1 2

2 c 4c + 16

49 4

c2 4c +

15 4

= 0

Roots are c1 and c2 c1 + c2 = 4 c1 c2 = 15 4

2 (c1 c2) = 16 4

15 4

= 16 15 c1 c2 = 1 SECTION IV 39. (A) (q); (B) (r); (C) (s); (D) (p) (A) tk = tan
1

k 1

k k
2

1 k
1

2 2

k k

1 1

1 k

= tan

(k + k + 1) tan
1

(k k + 1)

t1 = tan t2 = tan tn = tan

3 tan

5 tan
2

3
1

(n + n + 1) tan

(n n + 1)
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Sn = tan Lt S
n cos x
2

(n + n + 1) tan = 2 4 = 4

(B) 81

81 81
cos
2

= 30
x
2

cos y + 81 = 30 where y = 81 y

y2 30 y + 81 = 0 y = 27 or y = 3 3
4 cos x
2 2

= 3

4 cos x

= 3

4 cos2 x = 3 cos x = 3 2
2 cos x =

1 4 1 2

cos x = A pair of solutions is Sum = 2 c b c b a 6 and 3

(C) Given equation is a b c (b + c)2 a2 = 3 bc b2 + c2 a2 = bc

2 2 2 b + c a = 2 bc

= 3

1 2

cos A = A= 3

1 2

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(D) E = sin

6 x 6

cos 4

= 2 sin

Maximum E is attained when x 6 4 = 2 12

x=

40. (A) (q); (B) (p); (C) (s); (D) (r) (A) LHS

k = 1 j = 1

2j k k 2
2

k = 1

k 1 n n 2 2n n
2

k = 1

= = = = = A= 1 3

n n 1 n n 6 1 n n 3
3 1 n 3

1 2n 6 1 1 3n n
2

1 2 2n

1 3 n 3

2 n 3 C= 2 3

B=1

3A + 3C = 1 + 2 = 3 3A + 3C + B = 4
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(B) Let A and R be the first term and common ratio of the GP AR AR AR 1 2 3 2
p1 q1 r1

= 64 = 27 = 36
3 q

... (1) ... (2) ... (3) 64 27 36 27 4 3 4 3

R3r 3q = Rp q 3r 3q = p q 3r p = 2q 3r q (C) cot B = p = 2 c

2

cos B sin B a
2

= b
2

a b 2c asin B c
2

a
2

b
2

4 b c
2

cot C = cot B

4 cot C = b

and cot A = 2a
2

4 2a 3a
2

cot A (D) The equation is 1 + sin x sin (sin x) sin

= 1

x 2 x 2 =

= 0

1 x = 1 2

sin x = 1 and sin2

which is not possible. Hence no solution.

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PART C : PHYSICS SECTION I 41. (A) r = ct bt 2

2

Velocity v = v v = c
2

dr dt

= c bt c

bt bt
2

v = c c

bbt

2 bct

2 2 2 2 v = c + b t + 2 bct, since b and c are collinear

= (c + bt)2 v = c + bt Aliter: Since c and b are constant and collinear we can write the given equation as r = ct + b t 2
2

Differentiating with respect to t v = dr dt = c bt

v = c + bt 42. (B) v = 2s Squaring we get v = 2s

2 2

Differentiating with respect to t we get 2v i.e., a = 2s a s = 2 dv dt dv dt = 2 2s = 2s ds dt

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43. (C) U =

A x x
2

[B] = [x2] = L2 (since x is distance) A = U x

2

x M L T L
1 2 2 2 1 2 2

= M1 L7/2 T

1 7/2 [A] [B] = M L T

L2

=M L

11/2

44. (B) Circumference = 2.40 cm But being a number has unlimited significant figures. Therefore = 22 = 3.14159 given 7 circumference = 3.141 2.40 cm = 7.5384 = 7.54 cm 45. (D) Because the particle has zero displacement at t = 0, the slope at t = 0, is zero. Between 4 and 6s, the displacement versus time curve is a parabola pointing up. Between 2 and 4s the displacement versus time curve is a straight line. At t = 8 sec, v = 0. Hence the slope at t = 8 sec is zero. 46. (A) Distance travelled by the particle projected vertically up, in one second is y = ut 1 2 gt
2

= 10 1 y=5m

1 2

10 1 1

Let the particle projected at an angle have a velocity of projection u. The horizontal component of velocity is evidently u cos . Horizontal distance
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covered in one second is u cos 1 = 1 m (the distance of separation between the two particles). The equation of trajectory for the projectile is given by y = x tan gx
2 2 2

2u cos

In our case y = 5 m u cos = 1 m/s x=1m 5 = 1 tan 5 = tan 5 tan = 10 = tan

1

10 1 1 2 1 1

(10)

47. (C) Since speed is constant for both the particles let us assume that A collides with B after travelling a distance x along the circumference of the circle. Then x v
A

2 R v
B

x (vA + vB) = 2 RvA x= 2 R v v

A A B

= = t= x v
A

2 5 0.7 2.2 21.99 2.2 = 9.996

9.996 0.7

= 14.3 s 48. (C) Since the blocks have the same acceleration they can be considered together as a single system. Then the tension in the spring becomes an internal force. Therefore, net external force on the system is F = F1 F2 = (72 32)N = 40 N
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Total mass = (7 + 3) kg = 10 kg acceleration of the system = 40 N 10 kg = 4 m s

2

Let us now consider the 3 kg block. Force on the 3 kg block is

72 T = 3 4 T = 60 N Stiffness of the spring K = 1000 N/m = 10 N/cm Extension = T K = 60 N = 6 cm 10 N cm SECTION II 49. (A), (D) When the speed of the man is x, we have v
m

= x i
r

Let v = a i Then v
rm rm

b j for the rain

r

= v

(by definition) xi i bj ... (2) ... (1)

= ai = a

bj x

But v rm = b j (given) ax=0 a=x In the second case v v

rm r

= 3 2 cos 45 i v
m

3 2 sin 45 j 2x i i bj
EELP/I PET/CMP/P(I)/Solns

= ai = a

bj 2x

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3 2 cos 45 i a 2x = 3 b=3 Since a = x x 2x = 3 x=3 v

m

3 2 sin 45 j = a

2x

bj

3i
m

Speed is v

3 i = 3 km hr

Speed of rain is b = 3 km/hr Vector diagram

(Before doubling the speed) 50. (C), (D)

(After doubling the speed)

Force = Fg newton ( Q 1 kg f = g newton) But F = ma (by Newtons II Law) ma = Fg Also v = at ( Q u = 0) = Fgt m from 1 ... (1)

Now v2 = 2ax ( Q u = 0) x = v = v m using (1) 2a 2Fg Also x = 1 2 at =

2 2 Fg 1 t 2 m 2 2

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51. (A), (D) F.B.D for the mass m1 is

T1 = m1 g where T1 is the tension.

F.B.D for the movable pulley

T1 = 2T2 (since the pulley is at rest) If we consider the masses m2 and m3 as the system, we have, net force is (m2 m3)g assuming m2 > m3 Total mass is (m2 + m3) acceleration of the system is For the mass m2 we have m2g T2 = m2a T2 = m2g m2 m
2 2

2 2

m g
3

m m

2 2 3 2

m m

3 3

g
2 2 3

= g

m m
2

m m

m m
2

m
2 3 3

T =
2

2m m m
2

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52. (A), (B), (D)

For the particle at O, ao = 8 cm s

2 2

For the particle at O, ao = 4 cm s OO = 36 cm

With respect to the particle starting from O, the particle starting from O has u = (70 40) cm s a = ( 4 8) cm s Now s = ut + 1 2 at
2 1

36 = 30t
2 2

12 2 t 2

t 5t + 6 = 0 t 3t 2t + 6 = 0 (t 2) (t 3) = 0

t = 2 sec and t = 3 sec Hence the particles meet twice, at time 2 sec and 3 sec
2 x(2) = 40 2 + 4 2 = 96 cm

x(3) = 40 3 + 4 32 = 156 cm Aliter Using equation x(t) = x(0) + vx(0)t + 1 ax t 2 For the particle starting from O x (t) = 0 + 40 t + 1 2 8t
2

For the particle starting from O x(t) = 36 + 70 t

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1 2

4t

EELP/I PET/CMP/P(I)/Solns

27

If they meet x(t) = x(t) 0 + 40t + 4t = 36 + 70 t 2t i.e., 6t 30t + 36 = 0 t2 5t + 6 = 0 t = 2s or 3s

2 2 2

x(2) = 40 2 + 4 22 = 96 cm x(3) = 40 3 + 4 3 = 156 cm SECTION III 53. (A) m = 10

2 2

kg, motion is along positive x-axis K , K = 102 Nm2 (given) 2x

2

F x =

At t = 0, x = 1.0 m and v = 0 (given) F x = dv dt K 2x i.e., m dv dx dv dx

2

= dx dt

K 2x
2

K 2x K 2x
x 2 2

Here

dx dt

is

ve

i.e., m
v

v =

or m

K vdv = 2x
0 1 2 x

dx

i.e., mv 2 i.e., mv 2

=
2

K 2x K 2
1

1 x

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or v =

K m K m

1 x 1 x

v =

When x = 0.5 v = K m 1 0.5 1 = 1 m s

Since retardation is along + ve x-axis and velocity is decreasing along positive x-axis we have v = 1 m/s 54. (C) We have v = i.e., x 1 x x 1 x dx dt = 1 x dt x Q K m = 1 m s

dx =

0.25

dx =

dt

Put x = sin2 dx = 2 sin cos d

2 sin
2

d =

2 cos 2 = 1 2 sin

2 sin2 = 1 cos 2

cos 2 d =
6

sin 2 2
2

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i.e., 6

6 2 3 3

1 2

sin 1 2

3 3 2 t

2 = t

1 2

sin =

3 4

= 3 4

t=

55. (C) Time taken to go from x = 1 m to x = 0. This is

0.5

x 1 x

dx =

dt
t

i.e.,

cos 2 d =

dt (by virtue of solution above)

4 4 4

sin 2 2 1 sin 2 2 1 2 2 1 = 2 4 = t 1 2
2

= 2 t

t 1 sin = 2

t =

average acceleration =

v t

2 2

v t

1 4 1 2

0 0

4 2

m s

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56. (B) Suppose the string moves from the position A to A and the block from C to C in a small time interval t. In the Figure, AP represents the perpendicular drawn from A on line AB. When the displacement is small, AB = PB. Now AB + BC = AB + PB.

When the displacement is small, AB = PB. Therefore AB + BC = AB + BC (as length of string remains constant) AP + PB + BC = AB + BC i.e., AP = BC BC = CC or AA cos = CC or AA cos t = CC t

CC t AA t

speed of the block speed of the ring

speed of the block = v cos 57. (A) If the initial acceleration of the ring be a , then the acceleration of the block will be acos . Suppose T is the tension in the string at this instant. Force acting on the block are

Mg T = Ma cos
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... (1)
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Forces acting on the ring are

Taking component along the rod, we get T cos = ma or T = ma cos ... (2)

Substituting for T in (1), we get Mg ma cos

2

= Ma cos

a=

Mg cos m M cos
2

2m 9.8 cos 30 m 2m cos 30 3 2 3 4 a cos 6.8 cos 30 6.8 2 3 = 7.8 N = 6.8 m s

2

2 9.8 = 1 2

58. (D) From equation (1), we get T = 1 = =

SECTION IV 59. (A) (p), (q); (B) (r); (C) (r); (D) (q), (s) 60. (A) (r); (B) (q); (C) (s), (t); (D) (p)

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