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API Recommended Practice 57


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5.2 Process Unit PFDs


Simplified process flow diagrams for several process units commonly found in many refineries are shown in
this section. The PFDs are highlighted to show some of the areas within the unit where many of the primary
damage mechanisms can be found. The reader should be advised that this is not intended to be an all
inclusive list of the damage mechanisms but should serve as a starting point for some of the major
considerations.
The process flow diagrams included in this section are listed below. A key to the Damage Mechanisms
The numbering system for damage mechanisms used on the PFDs is shown in Table 5-4.
5.2.1

Crude Unit / Vacuum: See Figure 5-65.

5.2.2

Delayed Coker: See Figure 5-66.

5.2.3

Fluid Catalytic Cracking: See Figure 5-67.

5.2.4

FCC Light Ends Recovery: See Figure 5-68.

5.2.5

Catalytic Reforming CCR: See Figure 5-69.

5.2.6

Catalytic Reforming Fixed Bed: See Figure 5-70.

5.2.7

Hydroprocessing Units Hydrotreating, Hydrocracking: See Figure 5-71.

5.2.8

Sulfuric Acid Alkylation: See Figure 5-72.

5.2.9

HF Alkylation: See Figure 5-73.

5.2.10 Amine Treating: See Figure 5-74.


5.2.11 Sulfur Recovery: See Figure 5-75.
5.2.12 Sour Water Stripper: See Figure 5-76.
5.2.13 Isomerization: See Figure 5-77.
5.2.14 Hydrogen Reforming: See Figure 5-78
5.2.15 Visbreaker: See Figure 5-79.
5.2.16 Caustic Treating: See Figure 5-80.

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Table 5-4 Key to Damage Mechanisms


DM#

Damage Mechanism

DM#

Damage Mechanism

Sulfidation

34

Softening (Spheroidization)

Wet H2S Damage (Blistering/HIC/SOHIC/SSC)

35

Reheat Cracking

Creep / Stress Rupture

36

Sulfuric Acid Corrosion

High temp H2/H2S Corrosion

37

Hydrofluoric Acid Corrosion

Polythionic Acid Cracking

38

Flue Gas Dew Point Corrosion

Naphthenic Acid Corrosion

39

Dissimilar Metal Weld (DMW) Cracking

Ammonium Bisulfide Corrosion

40

Hydrogen Stress Cracking in HF

Ammonium Chloride Corrosion

41

Dealloying (Dezincification/ Denickelification)

HCl Corrosion

42

CO2 Corrosion

10

High Temperature Hydrogen Attack

43

Corrosion Fatigue

11

Oxidation

44

Fuel Ash Corrosion

12

Thermal Fatigue

45

Amine Corrosion

13

Sour Water Corrosion (acidic)

46

Corrosion Under Insulation (CUI)

14

Refractory Degradation

47

Atmospheric Corrosion

15

Graphitization

48

Ammonia Stress Corrosion Cracking

16

Temper Embrittlement

49

Cooling Water Corrosion

17

Decarburization

50

Boiler Water / Condensate Corrosion

18

Caustic Cracking

51

Microbiologically Induced Corrosion (MIC)

19

Caustic Corrosion

52

Liquid Metal Embrittlement

20

Erosion / Erosion-Corrosion

53

Galvanic Corrosion

21

Carbonate SCC

54

Mechanical Fatigue

22

Amine Cracking

55

Nitriding

23

Chloride Stress Corrosion Cracking

56

Vibration-Induced Fatigue

24

Carburization

57

Titanium Hydriding

25

Hydrogen Embrittlement

58

Soil Corrosion

26

Steam Blanketing

59

Metal Dusting

27

Thermal Shock

60

Strain Aging

28

Cavitation

61

Sulfate Stress Corrosion Cracking

29

Graphitic Corrosion (see Dealloying)

62

Phosphoric Acid Corrosion

30

Short term Overheating Stress Rupture

63

Phenol (carbolic acid) Corrosion

31

Brittle Fracture

64

Ethanol Stress Corrosion Cracking

32

Sigma Phase/ Chi Embrittlement

65

Oxygen-enhanced Ignition and Combustion


Organic Acid Corrosion Of Distillation Tower
Overhead Systems

33

885 F (475 C) Embrittlement

66

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API Recommended Practice 571
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Figure 5-65 Crude Unit / Vacuum

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Figure 5-66 Delayed Coker

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Figure 5-67 Fluid Catalytic Cracking

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Figure 5-68 FCC Light Ends Recovery

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Figure 5-69 Catalytic Reforming CCR

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Figure 5-70 Catalytic Reforming Fixed Bed

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Figure 5-71 Hydroprocessing - Hydrotreating, Hydrocracking

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Figure 5-72 - Sulfuric Acid Alkylation

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Figure 5-73 HF Alkylation

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Figure 5-74 Amine Treating

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Figure 5-75 Sulfur Recovery

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Figure 5-76 Sour Water Stripper

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Figure 5-77 Isomerization

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Figure 5-78 Hydrogen Reforming

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Figure 5-79 Visbreaker

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Figure 5-80 Caustic Treating

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