MH-CET

CHEMISTRY

TEST-1 MARKS :50

1. In a face centred cubic lattice the number of nearest neighbours for a given lattice point is A)6 B)4 C)8 D)12 2. CH3 CHO -- NH2OH---> A -- Na in C2H5OH ---> B Idenftify the product B A)Ethanamine B)Propanamine C)Ethanol D )Propan-1-ol 3. Dichloromethane is used A)To decaffeinate tea & coffee B)As a dry cleaning agent C)For refrigeration D)In air conditioning 4. Acetone and acetaldehyde are differentiated by A)HNO2 B)I2 C)NaOH D)Ag(NH3)2 5. Suffix-O is added to the name of a ligand when the ligand is A)Positively charged B)Neutral C)Negatively charged D)All of the abo ve 6. An exothermic reaction is one which A)Takes place only on heating B)Is accompanied by a flame C)Is accompanied by absorption of heat D)Is accompanied by evolution of heat 7. In H2- O2 fuel cell the reaction occurring at cathode is A)2H2 + O2 -----> 2H2O(l) B)H+ + OH- -----> H2O C)O2 + 2H2O +4e - -----> 4OH- D)H+ + e- ----->1/2 H2 8. Which of the following unit cells has the highest symmetry? A)Hexagonal B)Orthorhombic C)Cubic D)Monoclinic 9. The mass of gold in an 18 carat gold ring of 4 g is : A)4g B) 3g C) 2g D)1g 10. In the preparation of alky1 amines by action NH3, excessive use of NH3 A)Suppresses the formation of other amines B)Increases the formation of oth er am,ines C)Does not afftect the reaction D)None of these 11. The E cell is given by the reaction A)E anode E cathode B) E cathode- E anode C) Eo cathode + Eo anode D) E anode +E cathode 12. In a lead accumulator, the cathode and anode, respectiverly are A)Pb-plates and PbO2 plates B) Pb-plates and Pb-plates impregnated with PbO 2 C) PbO2plates and Pb-plates D) Pb-plates impregnated with PbO2plates and Pbplates 13. Homolytic fission is A)A permanent polarization of a single covalent bond B)A temporary shift of pi bond electrons C)A symmetrical breaking of a covalent bond D)An unsymmetrical brea king of a covalent bond 14. It is possible to obtain oxygen from air by fractional distillation becaus e: A)Oxygen is in different group of the periodic table from nitrogen B)Oxygen h as higher b.p. than nitrogen C)Oxygen has a lower density than nitrogen D)Oxygen ha s a lower density than nitrogen 15. An example of nucleophilic substitution reaction is A)Wurtz reaction B) Williamsons synthesis C)Grignards D)Clemmensens reaction 16. Accordingly to the equation, C6H6(1) +15/2 O2 (g) ----->6 CO2(g)+3H2O(l); H= -3264.4 kJ mol-l A)163.22 kJ B)332.64 kJ C)3.264 kJ

D)326.4 kJ 17 .If half-life of a substance is 5 yrs, then the total amount of sub stance left after 15 years, when initial amount is 64 grams is : A)16 grams B) 2 grams C) 32 grams D) 8 grams 18.In the reaction 2A=B A2B the rate of consumption of reactant A is A)Half of the consumption rate of B B)Equal to the consumption rate of B C)Twice to the consumption rate B D)Equal to the rate of formation of A2B 19.Who is responsible for synthesis in proteins in human being ? A)RNA B)Amino acid C)Nitric acids D)Ammo n ia 20.Pepsin enzyme hydrolyses; A)Proteins tro amino acids B)Fats to fatty acids C)Glucose to ethyl alcoh ol D)Polysaccharies to monosaccharies 21.The IUPAC name of Ni (CO)4 s; A)Tetracarbonyl nickelate (0) B) Tetracarbonyl nickelate (II) C) Tetracarbonyl nickel(0) D) Tetracarbonyl nickel(II) 22.(CH3)3CONa on treating with CH3Br will give A)(CH 3)3COCCH33 B)CH3OCH3 C)CH3CH2O CH2CH3 D)CH 33COCH3 23.The equation showing the effect of temperature change on heat of reaction i s called ; A)Arrhenius eqn B)Kirchoffs eqn C)Ostwalds eqn D)none of t hese 24.CuSO4 dissolves in NH3 due to the formation of A)Cu(OH)2 B)Cu(NH3)4SO4 C)Cu(NH3)4(OH)2 D)CuO 25. A double triangular void surrounded by three spheres above and threed sphere s below is calledA: A)Triangular void B)Tetrahedral void C)Octahedral void D)Trigon al bipyramidal void 26. Aspirin can be obtained by the acetylation of A)Benzene B)Benzoic acid C)Phenol D)Salicylic acid 27. Osmotic pressure is measured by A)Berkeley Hartley method B)Ostwalds method C)Habers method D)Sol vays method 28. An alkyl hydrogen sulphate is obtained when an alkene is passed through A)Hot conc. H2 SO 4 B) Hot dil. H2 SO 4 C) Cold conc.H2 SO 4 D)Cold d il. H2 SO 4 29. The oxidation number of Fe in Fe3O4 is A) +2 B) +3 C) 8/3 D) 2/3 30. The most useful classification for medic ianal chemists is, the classificati on based on: A)Pharmacological effects B)Chemical structure C)Molecule targets D)Bi ochemical processes 31. The transition element, which exhibits maximum oxidation state, has the elec tronic configuration A) 3d4 4s2 B) 3d8 4s2 C) 3d3 4s2 D) 3d5 4s1 32. Which of the following exhibits highest solubility in water? A) NH 3 B) PH 3 C) ASH 3 D) SbH 3 33. An isomer of ethanol is A) Methanol B) Diethyl ether C) Acetone D) Dimethyl ether 34. The unit and value of rate constant and tghat of rate of reaction arte same for A) First order B) Zero order C) Second order D) Third order 35. Soft drinks and baby feeding bottles are generally made up of A)Polystyrene B) polyamide C) Polyurethane D) Polyurea 36. The molal elevation constant(ebullioscopic constant ) is the ratio of the e levation of boiling point to

A)Molarity B) Molality C) Mole fraction D) Mole fraction of solv ent 37. Which of the following animal fibre? A)Silk B) Linen C) Terylene D) Jute 38. Atoms in a P4 molecule of white phosphorus are arranged regularly in the fol lowing way: A) At the corners of a cube B) At the corners of an octahedro n C) At the corners of a tetrahedron D)At the centre and corners of a tetrahe dron 39. Sulphide ores are generally concentrated by: A) Froth flotation B) Roasting C) Gravity D) Reduction by carbon 40. Anisole undergoes bromination to produce major product A) p-bromoanisole B) o-bromoanisole C) m-bromoanisole D) 50% ortho & meta bromoanisole 41. Iodoethane gives rise to ethanol, when it is boiled with A)Alcoholic KOH B)Aqueous KOH C) Ethanolic KOH D) Ammonical KOH 42. In the preparation of sulphuric acid, V2O5 is used in the reaction, which is : A)S+O 2 SO 2 B)2 SO 2+O 2 2SO 3 C) SO 3 + H 2 O H 2SO 4 D) None of these 43. The formula of the ferrocence is: A)[(C2H5)2Fe] B)[Fe(CN)6]3- C)[Fe(CN)6]2- D)[Fe(CO)5] 44. Which of the following does not give Cannizzaros reaction? A)CCI 3 CHO B)HCHO C)C 6 H 5 CHO D)CH 3 CHO 45. Thermally isolated gaseous system can exchange energy with surroundings. Mo de of transferences of E can be A)Heat B) Work C) Radiation D) Entropy 46. What weight of sodium carbonate is required for preparing 250 ml of N/10 sol ution? A) 1.325 g B) 0.1325 g C) 1.06 g D) 2.12 g 47. Which of the following is an exam ple of molecular solid? A) ZnS B) MgO C) ice D) Diamond. 48. Magnetic separation is used for increasing concentration of the following: A) Horn silver B) Calcite C) Haematite D) Magn esite 49. The molecular formula C 6H 14O 6 is of A)Glucose B) Fructose C) Sucrose D) Sorbital 50. Which of the following is not a nitro-derivative? A) C 6 H 5 NO 2 B) HO- ph-NO 2 C)CH 3 NO2 D) CH3CH2-ON=O