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Rock-forming minerals.
The
tine
original of
tiiis
book
is in
restrictions in
text.
http://www.archive.org/details/cu31924004063529
ROCK-FORMING MINERALS
FRANK EUTLEY,
F.G.S.,
WITH
126
ILLUSTRATIONS.
Eonbon
THOMAS MURBT,
3,
E.G.
1S88. 21/
PBEFACE
Students on the Continent
giving instruction in the
are. well supplied witli text-books
is
otherwise, and
those
who wish
for
badly, unless they can attend lectures and devote their time
to a course of systematic
work
in the laboratory.
Even then
there
is
a constant
demand
for a
book
to
them
to
forming minerals.
Tet, although
many
that
of the works
useful,
this
now
want
much
is
seems
still
to
remain unsatisfied.
Whether
time being,
this
is
book
will
in any
way meet
it,
a question,
are,
to
a great
upon these
or
upon
collateral
branches of science.
iii
"
iv
Preface.
ing works
De
....
.
. .
884.
1885.
Rosenbusch, H.,
" Mikroskopische
Bd.
i
Physiographie/'
1885.
.
. .
1884.
To the writings
of
Profs.
Zirkel,
Naumann and
A. von Lasaulx.
also
are
information
have
far
been given,
its
as
they would
beyond
present limits.
The
bibliography in
American
Mr.
P. R.
"
"
With
M-rata.
PAGE
I
and y," read " y, j3 and a." 34, line iX from bottom, for " a, 35 ,, 11 ,, for " Chalunes," read " Chaulnes." ,, 40 3 after "that" insert "on meeting the film of ,, ,,
57
57,
58, 58,
58
82,
92
92 92
93,
106,
balsam. 6 and 7 from bottom, for "normal to these common tangent planes or circular sections of the elhpsoid read " following these surfaces of the cones." " last line for " Ox Ox," read " The directions Oxi" and for " external read "internal." top line for " Of these " read "Here." line 3 from top, for " ex-" read "in-." for "internal" read " external." ,, ,, " optic," insert "traces of the " 6 ,, bottom, before ,, 11 ,, for "thickening," read "thinning;" and for ,, ,, " greater,' read " less." for "thickening," read "thinning." ,, 7 ,, ,, for " greater," read " less." 6 ,, lines 6, 20, and 24 from top, for " thickening," read " thinning." line 6 from bottom, for " on the basal plane" read " on a face of the cube." 10 top, before " magnetite," insert "a moderate amount of." bottom, after "Oj2," add ' 4- 2H2O." Id 16 ,, top, before "absence, " inserc "usual." ,, bottom, for "(100)" read "(110)." 9 ,,
,,
.')
165, foot-note, for "Yarbuch," read " Jahrbuch.' 167, line 16 from bottom, erase "hence." for "of," read "between"; 195 20 ,,
and for "axis," read " axes." 208 4 top, for " c c," read " P P." 208, Pig. 105, for " C C," read "P P," insert c beside central dot on the line joining b b', and erase " 001." Nt te. In this figure the plane of projection is at right angles to the
vertical axis c. 208, Pig. 106, for " c C," read " c c." In this figure the plane of plane of projection is on s s' in Pig. Note 105 i.e., not quite parallel to the clinopinacoid, 010, which in Pig. 105 is parallel to P P. 218, line 6 from bottom, erase "not particularly"; for "but," read " and " and for " so," read " also strong." 219, Pig. 115, for "a," read " c" ; and for " c," read "a." 2S3, line 9 from top, for " acute," read " obtuse." 281, Pig. 124, for "Toi " read " loT."
" Indices, o
1 -8876,
1-8940, 7
2-0093,
ROCK-FORMING MINERALS.
PART
I.
I.
have to be employed.
We
may, in the
first
what
is
absolutely
with the means employed in the prosecution of the somewhat more advanced class of research ; but the elaborate and costly
instruments
now used
beyond the
An
ments and of the methods of using them will be found in Groth's " Physikalische Krystallographie " (2nd edition), in Kosenbusch's " Mikroskopische Physiographie der petrographisch wichtigen Mineralien
" (2nd
edition),
For the successful examination of a rock, an acquaintance with various branches of science
chemistry,
is
necessary, namely,
physics
(especially
optics),
mineralogy,
and
geology.
Geologyj indeed,
may be regarded
as the
without
it,
we can
and
it is this
often,
however, only a
under
thera-
Mode
of occurrence
is,
2
fore,
Rock-Forming Minerals.
a matter of immense importance in
all
petrological
first
The general mode of occurrence of rocks will be found described in any good text-book of geology, and it is therefore needless to encumber these pages with an account of the principles, or of the more detailed explanations, relating to
this
be-
map
map
of large scale, cut into small pieces for the sake of portability
With
this,
be able
' '
to
We
but
little
indispensable to the
successful
prosecution of this
for informa-
branch of research.
tion
Those, however,
who wish
"Reactions
1886,
Bofickjr's
"Elemente einer neuen chemisch-mikroskopischen Mineralund Gesteins-analyse" (Prag, 1877), Fouque and Levy's " Mineralogie^Micrographique " (Paris, 1879), etc.
be possessed
this purpose,
to study petrology.
For
referred to the
text-
Rock-Forming Mmerals.
From
the foregoing observations,
it
3
be seen tbat the
will
The pocket-lens.
of rock,
eyes,
When
all
and
it
may
here
in a
manner
this,
calcu-
lated to give
it
To do
tips of
hold the
specimen
in the left
Rest the
one or more
gained.
If the
specimen be too
left
hand.
is
When
it
Should
to manidiffi-
.pulate a knife
This
lens,
held
but
it is
The hands
are thus
left free.
The other
end
is
is
then bent to
about tworthirds of a
bead.
There
is
Rock-Forming Minerals.
any muscular
effort
whatever ; and
it
specific gravity
of a rock^ or of
in the ordinary
way by means of a suitable balance ; but larger masses may be employed when Mohr's apparatus is used, a considerable advantage when rocks composed of more than one kind of mineral are being examined. The latter consists
of a burette
with
its
usual
support.
end
diameter
placed,
and across
its
mouth
is
is
piece of india-rubber
of
The specimen, having been accurately weighed in air, immersed in the water, which rises in the cylinder.
operator next applies his
now
The
mouth
the upper end of the burette, the lower end being adjusted
so as to be well below the level of the water in the larger
vessel,
men
below the
He
up to the needle-
point)
stone,
is is
restored.
now
in
The amount of water displaced by the the burette, and can be ascertained by means
If then
of the graduation.
we
Rock-Forming Minerals.
burettej
we get
may be due
Walker's balance
another instrument well suited for this purpose, and capable of giving rapid and satisfactory results. Jolly's spring balance,
although
less portable,
is
may
also
about 8 grammes
To
thread for
its
ments.
Where
greater precision
is
required,
is
the
older
employed, will be
but
it
is
air
within
The
of roughly pulverized
rocks
may
also
be determined by
means
of a solution of
known
Sonstadt's solution.
Maximum
3'196 (Goldschmidfc).
in this solution.
Klein's Solution.
Bofo-tungstate
Maximum
sp. gr.
of
Cadmium.
3"28.
by
* The author
is
the
'6
Rock-Forming Minerals.
The
salt,
the solution.
Maximum
This solution discolours
diluted with Benzol.
sp. gr.
^ 3'34.
to light,
when exposed
and must be
It can
when cooling
upon the
water-bath.
Eohrhacli's Solution.
Maximum
water that
to
its
use
is
very restricted.
in the solution.
is
at times
em-
whose specific gravities range from 2 "4 to 5. The mixture is fused in a small tube placed in a sand-bath
perfect
heavier particles sink to the bottom of the tube while the less
The
test-tube,
plunged
and the
to
which
nitric acid is
The minerals thus separated, when washed, are ready analysis. Fused Boro-tungstate of Cadmium similarly
3'6.
when
Sonstadt's,
first
For the
7
generally found
effected by means of other apparatus, especially tbat devised by Harada, and manufactured by Kramer, of Freiburg in Breslau.
may be
end of which
is
closed
is
prolonged into a tube, a small glass stop-cock shutting off the bulbous from the tubular portion of the
apparatus.
f\
r'""'""r
The stop-cock being closed and the stopper removed from the upper orifice, the solution (Klein's
or Sonstadt's)
is
\ /
^gjl
now poured
^^^^
\ /
by the
stippling at
a;
A small conical
that the
end of the
is
stop-cock
cautiously opened.
Some drops
now
end of the
water
(z
is
The stop-cock
is
little
a thin layer
Fig.
1)
on the solution.
The apparatus
is
when
passes into the test-glass, while the water rises into the tube
as far as the closed stop-cook.
"Mi-
i.,
may be
still
more
Rock-Forming
Mine7'als.
p. 216).
In practice
clip
The value
for example,
very evident.
If,
some pulverized
diorite
In
this
particular mineral
may
be isolated
gravities.
This
may
easily be done from the tables given at the end of this work.
Fusibility.
The
fusibility of
a rock
is,
of course, depen-
dent upon
its
minerals of which
is
composed.
All experiments
made
upon the
fusibility of
at
all
coarsely
kind of selective
fusibility,
an expression,
dependent
if
one may
use such
is
phenomena being
upon
the different
when
dark-brown
frothy glass.
a white
Flame
Reactions.
value in
Rock-Forming Minerals.
The method adopted by Szabo
mining the
dififerent
is
by means of the extent and intensity of colour communicated respectively by the alkalis
felspars
K and Na.
is
employed
(fe)
chimney of sheet-iron
Fig. 2.
which
ing
is
supported by a
little
(c)
of
The remainder of the apparatus consists of an upright rod (d) fixed to a heavy foot, and having a small arm or wire projecting at right angles from the rod and capable of being easily raised or lowered by a sliding motion. Upon this arm a little piece of glass tubing (<i) is slid, being drawn out at one extremity to a point, in
which a very thin piece of platinum wire
loop to support the assay.
is
taken up
be previously
be about the
The felspar fragment should The assay is then brought the splinter resting on the
be gradually heated
It should thus
lo
it
should then be rapidly transferred for a few seconds to the hottest part of the flame, about the apex of the blue
inner conej
It
when the felspar fuses and adheres to the wire. should now be withdrawn, and the arm supporting the
The
this
will
be seen to communicate
;
and
flame
may be
;
dis-
being
this,
and extent
until
The
16%.
first
the third, 2 to
4%
the fourth, 4 to
8%
and the
at the
fifth,
8 to
end of one
minute.
also
chimney
flame,
now
introduced a
little
above the
previous
trial.
is previously coated with a little pure and finelypowdered gypsum, and the operation conducted for two minutes. The maximum yellow coloration may here be reached, and it
may extend
The
and
side
trials for
potassium
are-
by
through,
first
Rock-Forming Minerals.
aniline blue in a cell 4 centimetres thick.
II
this
By
means the
first
is
abolished.
In the
trial
for potassium, in the outer envelope of the flame, there are three
In the second
;
trial,
there
and in the
third,
when
gypsum
the
is
of sulphates,
In
two
first
be rendered more
(Fig. 3).
3id Trial.
Na
indicated
by
K is
present.
the letter a.
The
12
Rock-Forming Minerals.
The following table, which is an abbreviated version of that given by Dr. Szab6j* shows how the results may be recorded.
Rock-Forming Minerals.
tlie
13
of comparatively
For a certain limited class of work, a binocular arrangement may be desirable ; but, as a rule, the Extremely large monocular form is the more convenieiit.
microscopes present but few advantages to compensate for
Fig. 4.
this is
be made.
unjiecessary.
it
may
is
14
to
This will
foot
A=the
and B = the tube. In the difEerenfc patterns of microscope, the parts connecting the tube with the foot vary considerably. In those in which
the instrument
position, the
is
by means of trunnions, t.t, or by a simple joint. C = The eye-piece. This is usually of the kind known as The two plano-convex negative,, or as Huyghens' eye-piece.
either
lenses,
of which
(a) is
field-glass,
have
slots
(fe)
their convex
(c)
of the eye-
two
These should
Two
may be cut
in
the tube well above the level of the spider- lines, either through
the upper right and lower
left,
wedge
there
this,
is
in such a
manner that
its
In Nachet's microscope
although advantageous,
G = The
which
upper
easily rotated.
At the lower
divisions,
howneed only mark eight equidistant points, one of which must accurately coincide with the principal section (i.e. the
These eight points enable the observer to place the principal section of the analyser either at right angles to, parallel to, or at an angle of 45 to the
shorter diameter) of the Nicol.
a divided disc.
The
When the eye-piece analyser is not in use, a perforated brass cap is placed over the eye-piece, to prevent reflection from the surface of the eyeprincipal section of the polarizer P.
Rock-Forming Minerals.
glass
15
effect the latter
and to cut
off
extraneous
light.
To
more completely, the cap of the eye-piece is sometimes provided with a cup-shaped opening but the same purpose
object
;
is
better answered
by
fitting
five
The The A
No. 1, being the one generally employed, and having the lowest magnifying power, B, or No. 2, and C,
or No. 3, etc., give higher amplifications
;
entails
a slight loss of definition and, with the deeper eye-pieces, a very considerable loss of light.
only two or three objectives the
The
spider-lines should
be
A, or No.
it
can
in
The A,
or No.
1,
eye-piece
is,
= a tubular
tion plate, the Klein's quartz platCj or the lens for enlarging
interference figures.
is
The
the microscope.
There
are,
care-
rule,
not generally
desiderata
being
of
flatness
The following
selections will
be found
useful.
They are
Rock-Forming Minerals.
rule, necessary.
D = The
Stage.
moving a slide about by hand. One thing necessary in a microscope intended for mineralogical and petrological work is, that the stage should rotate, and that there should be some means of bringing the axis
of rotation into coincidence with the axis of vision.
For a
but permanently,
this case
efifected
by the maker
is,
of the instru-
ment; and in
tring
paratively
any
is
little
employed,
small consequence.
will,
Most
students,
provided
it
will
then be found
that,
owing to unavoidably
slight differences in
the manufacture, scarcely two can ever be. found which will
require a slight themselves or of the stage, in order to make the rotation of the latter concentric with the axis of vision.
shift either of
not,
This concentricity
either
by having
a centring arrangement for the stage or a centring arrangement for the objective. The latter, although the less satisfactory, is the cheaper,
and
apparatus
known
screwed
Rock-Forming Minerals.
to the lower
17
is
tapped at
its
process is effected
Whether nose-piece or stage be arranged for centring, the by means of two screws terminating in small milled heads, which, when tamed, give a backward or
one another.
Let
a,
Fia. 6.
of the field.
will
ib
but,
less
Assume
that
it
the line tw, one of the directions in which the stage can be
Now, when the object is at so as to move the stage in the direction of the arrow towards t until the object has moved through half the distance ac, the spot indicated by the small Then, without again touching the centring cross marked A. screws, move the slide on which the object is mounted, by
moved by the centring screw
the point
c,
x.
os,
means
centre of the
1 1 I'i'
in
Again
and we
C
will
iS
In this case the milled head y must be turned so as to move the stage in the direction of the arrow towards r until the
object has
distance ea).
moved from the point c to the point i {i.e. half the Once more adjust the slide on the stage so that
lies at
of the field
is
rotated.
round with
it,
in
differ
in
may
be divided
may be employed;
but -for
ordinary work
will
to adopt the
The edge
coarsely milled
or
it
small projecting
knobs or cogs on which the finger readily catches. Mechanical traversing arrangements for the object-carrier are rather an encumbrance than an advantage. The most
generally useful contrivances are spring clips, d, Fig. 4, beneath
which the
screws
is,
by
accident,
and the
cen-
To
19
a small pivot
h,
and not participating in its rotation, is upon which turns an arm with a tubular fitting,
made
of the
a disc similar
to that at the base of the analyser, also bearing eight equidistant lines, while four slight holes are drilled corresponding
A tubular
little
collar,
carrying
an index,
the disc
fits
outside the
first
depressions
when
rotated,
and
acts as a stop.
The
principal section
of the polarising Nicol must accurately coincide with the line joining one pair of these depressions
when
the stop
is
clicked.
prevent
it
far.
By
this
arrangement the
polariser can
The tube surrounding the prism should be long enough slide some distance up the aperture in the stage.
Two
Fig. 7.
7,
x,
mounted
in
upper end (at and the plane surface of the upper lens should, when the polariser is pushed up, be on a level with the surface of the stage, so that it almost touches the glass slide on which the
of this tube
fig. 4)
preparation
is
mounted.
when
the inter-
When
b^
20
Rock-Forming Minerals.
fifcting
should be sub-
Seen
but they
may
in-
When
images
forated by a pin-hole,
is
H,
Fig. 5,
is
and from
I,
up the
and
adjustment
is
not needed.
In
a micro-
way
them
will,
gradually explained.
petrological microscopes
this small treatise.
now in use would be out of place in Good instruments, suitable for the purby Swift, Watson, Beck,
pose,
are
made
in this country
Among
made on
the
Continent,
Seibert.
may be mentioned
latter, if
The
difierent thread.
Rock-Forinmg Minerals.
The
case
;
21
and the
fittings in it
When
glue only
is
used, the
may
sustain severe
damis
The handle
will
or
it
more than a short distance, unless the instrument be a very light one. For artificial illumination any small paraffin lamp will serve. The usual microscope lamps, supplied by the opticians, answer perfectly well for all ordinary purposes. For examining objects by reflected light, a bull'scarried for
eye condenser
is
necessary.
can easily be
packed.
TKin
with a
sections.
If
we put
cloth,
its
we
shall
information regarding
its
structure,
and
little
or
none concerning
its
origin.
road-metal, therefore, as
altogether encouraging.
The
simpler, but
is
used to this
kind of work
the otter
some
worked by a
necessary.
treadle, others
Good
sections
thin chips.
22
Rock-Forming Minerals.
hammer, and ground emery and water.
irregular chips is
of grinding
it is
down
and
desirable to
employ a machine
little
grinding
Such a machine may to fit be made on the pattern of an ordinary lapidary's wheel. The them for microscopic examination.
Fig,
8.
is
shown
in plan in Fig. 8,
where
by means
a very
knob
The edge
e,
of this disc
much
which
and about on a
wooden
by a nut which
tightened up by
means of a spanner. The edge of this disc is charged with diamond dust and oil, the paste being carefully applied to an inch or two of the edge at a time, and then pressed into the soft
iron with a burnisher or a smooth piece of agate.
iron pivot,
plate, h,
i,
On
a round
holes pass two pieces of iron rod, which are riveted to anothe?
Rock-Foi'ming M'inerals.
strip of stout iron plate.
23
Eacli rod
is
which, after
it
a nut
is
screwed.
javsrs
The
is
placed be-
tween the
firmly.
A string,
is
next
fixed
the end of the string, so as to draw the clamped stone against the edge of the slitting disc.
a
little
edge of the
Soap
is
Into
keeping
now
in readiness
large
wooden
of stout cardboard
After the
slice
necessary to grind
Two
emery
its
emery
mixed with water. It is important to keep these two no grain of coarse emery may reach the slab on which the fine emery is used. If a chip be taken in hand, a flat surface must first be ground
used,
slabs well apart, so that
on
it
It
to clear
from
all
coarse
must then be thoroughly washed, emery mud, and the flat surface smooth as possible upon the second
perfectly
24
Rock-Forming Minerals.
it
on a piece of plate
glass,
is
As
soon as
it
becomes
emery
when washed and placed under the microscope, to be make it. Often, by not daring
section thin enough, a worthless slide is prosection
cared
vanishes.
tnean,
Between these evils lies the happy, diaphanous which insures a really good section.
lamp or a Bunsen's burner to put beneath it, a watch-glass standing in a pill-box lid, and containing a few drops of turpentine, one or two small camel's-hair brushes, an
a spirit
ofi"
so as to afford a flat
end
to
push with, a
terminating in two
forceps.
pieces of cork,
and a
little
pair of
lighted,
When
sufficiently
is
heated
cemented, the
plate,
glass slab
is slid
and
hand.
With his right he takes the blunt-ended pushing bar, which he places against the edge of the section, and slides it
the glass slab into the
awhile,
off
it
turpentine bath.
25
cautiously over the hot plate or over the lamp, care being
He
with them,
A glass
slip is
now placed on the hot plate, which when it has been warmed, it should
it.
on to the middle of
The
section
is
then
lifted care-
and it is brought over the and allowed gradually to rest on it. When slightly warmed, the cushion of balsam spreads out beneath it, and another drop of balsam is allowed to run
side of
it
which
section.
A thin
covering-glass,
warmed near
when the
allowed gradually to
subside
section is
warmed.
all
It should next
be pressed
be
left
to dry gradually.
When
it
a crumb of
may be
opticians.
The
sections
should
lie flat
but
if
horizontally.
Methods of Examination.
scope.
There
26
(i.)
la
light
which would pass through the well or aperture in the stagCj is shut off by a diaphragm ; or an opaque plate, either
white or black,
paration.
may
is
Light
of the object
artificial
by means
When
or in conjunction
is
valuable
and descriptions
of this, the
Lieberkuhn,
etc., will
Sub"
stage Illumination),
from
the mirror, and passes through the aperture in the stage and
By
this
may
at times par-
In some instances,
as
when
is
power
stage.
may be
of which that
Of such condensers there are many different patterns, shown in Fig. 6 is one of the simplest, as by
it
will
be found that
is
greatly improved
lens.
when the
condensing
With the
polarizer only.
is
This arrangement
Rock-Forming Minerals.
a mineral has to be determiaed.
tion of the
h.
27
An
explana-
phenomena
will
shorter diameters
With
at right angles.
The
Nicols
latter is the
generally have to
is
work
how
When
is
brightly
illuminated.
mains dark.
Each
its
Nicol'is
mounted
in a piece of cork
cylin-
be turned within
it
is
they
To do this, two stout needles or pins may be employed, and may be driven through a piece of wood at a suitable
that
distance apart, so
can be
of the
these
The operator must, however, remember very soft, and that an accidental
that
slip of
one
of the needles
may
to
seriously injure,
if
Another way
is
down
safe
is
again into
its fitting
there
is
means
28
its
and
the A, or No.
its
eye-piece, with
is
its
on which a few
mounted,
is
and
Now
turn the stage of the microscope until the longest axis of the
crystal coincides with,
spider-lines.
or
is
exactly parallel
to,
it
one of the
slowly round.
There
will
maximum
darkness; and
if,
exactly
be in
its
proper position.
But
we have assumed that this was not so. Such being the case, we should find that at none of the points at which the field attained its maximum darkness did the crystal of mesotype
become absolutely dark.
less illuminated rod.
We should see it still as a more or We must then turn the cork containing
when
restored to
its
the polarizer in
stopped
maximum
darkness,
slightly,
to do which may be necessary to turn the polarizer the crystal disappears completely in the gloom. The
it
its fitting
is
a very tedious
We
may now
its
namely, with
We have next to
we now
attend to the
analyser.
Kthe
polarizer be clicked at 0,
29 The
principal
of the polarizer.
is
analyser
it,
badly adjusted.
But we have assumed that the When, therefore, we look through the field is not at its maximum darkness and the analyser, we shall see through how many
;
maximum
darkness supervenes.
Again we have
the cork and
analyser
is set
at 90
is
0,
mesotype crystal
all
and the
The
reason
why a mesotype,
will
employed
2.
Books are
more or
and to
it will
and that it consists merely of a vibratory motion, communicated to one particle of ether, and transmitted from that particle to the next, so that from one disturbance a chain of
-^
FiQ. 9.
disturbances ensue.
30
travels,
a succession of waves.
Thus, in Fig. 9,
is
travelling,
moment
It will be seen
wave
e,
line
in
and on either
sides of
c,
all
it if it
be a ray of
ordinary light.
In the
figure, a,
d,
and
e are
nodal points,
many
{i.e.,
was generated)
c,
starting-
d,
and
e.
has
The point 6 was also the starting-point now reached h'. The distance h to V
it is
ihe
full
extent
the swing of
upon that
The way
particles, after
In
this
the
wave
is
ever
to the
9,
wave
travels.
In Fig.
a d a
c is half
wave-length, or ^
Xj
The wave-lengths
the longest waves and the least velocity, while the violet have the shortest waves and the greatest velocity, or rapidity of
vibration, on either side of the line in which the ether particles
originally rested.
in the
performance of
an entire vibration
any given
be in
Rock-Forming Minerals.
diflferent or like jsAaseSj as
31
it
the case
may
be; and
will
be seen
that a wave-length
is
opposite phases.
The amplitude
it
of a vibration is
independent
may
same
the
colour.
may be
may
The
velocity is dependent
upon the
elasticity of the
medium medium
any displacing
light passes;
force.
The
comes
less in
which the
and as in
is
all crystals,
except those of
all directions,
not equal in
them
When
with equal
vi-
they
differ in
phase
by
of half
wave
Fia. 10.
line c i;
and
if
we assume
fact
in a
different
32
manner, as
Rock-Forming Minerals.
in Fig. 11,
particles x
and
"^
Fl8. 11.
Another result of this principle of interference is, that when two luminous waves of equal length, but dififering in amplitude or intensity, travel in the same direction and vibrate in
the same plane and in the same direction, a the amplitude of which will be equal to the
wave
will result
sum
of the ampli-
This
is
indicated
FiQ. 12.
in
Fig. 13.
Fig. 13.
Bejlection.
This
consists in the
it
light
The angle
is,
of
on the
There
reflecting
however,
total
Owing
crystals.
^1>
be found
text-books of mine-
ralogy.
By
figures
and variously arranged markings or lightmay often be discerned, the disposition of the markings
face.
Fi3. 14.
Refraction.
If a ray of
it
of a
medium
of a density difierent
previously pursued
and
if
34
Rock-Forming Minerals.
The angle
of
and the refracted ray. The two following laws govern simple
sines of these
refraction,
i.
The
an-'
termed the
index, of
denoted by the letter n. ii. The incident and the refracted rays always lie in the same plane, which is perpendicular to the limiting surface between the two media. The value of n may be procured by dividing the sine' of the incident by that of the refracted ray. In optically uniaxial
crystals there
there are
three
be noted, namely, a maximum, a mean, and a minimum, respectively denoted by the letters
different refractive indices to
In Fig. 14 the sinea of the angles of maximum, /3, and 7. minimum, and mean -refraction in Olivine are diagrammatically represented side by side for comparison.* The relation of the
a,
refractive
indices
to
the
axes of optical
elasticity,
:
and
to
Axes
of Elasticity
Refractive Indices
Velocities
=a =a max. ^ \
max.
min.
mean.
mean.
^b =^ mean. ^ \
min.
max. =: y
min.
=^
The determination
may be
* a is the refractive index for rays propagated at right angles to a and vibrating jiarallel to a. j3 for those propagated at right angles to b and vibrating jiarailel to b. y for those propagated at right angles to t and vibrating parallel to c. The direction of greatest velocity corresponds with the index of least refraction and vice versa, or the velocities are
inversely proportional to the refractive indices.
35
when the incident and emergent rays make equal angles with the faces of the prism. Then
sin \
(a+d)
sin \ a
'
Another method of determining the index of refraction caasists in accurately focussing under the microscope an object,
such as a delicately engraved line on a glass plate, and noting,
by means of the
of the micro-
when
the line
in focus.
fiat
plate of
now be
procured,, either
by cleavage or by grinding and polishing. This plate is then laid upon the glass plate so as to cover the engraved line, and the microscope must be racked back in order to accurately
re-focus the line through the plate of the mineral.
This being
done, the distance between the original and the present read-
{i.e.,
r)
must be
The thickness,
accurately measured,
formula
t
=,i.
This
is
commonly known
far
as the
and dates as
back as 1767.
The
and descriptions
of^ its
con-
and use
be
will
should
noted
that
the
borders
of transparent
:
by a
The
36
irregu-
Double
Iceland
spar,
the
most
transparent
variety of calcite,
means of studying this property. It cleaves easily into rhombohedral forms ; and if we place a moderately thick cleavage rhombohedron with one of its faces flat upon a piece of paper
on which a small ink-spot has been made, we
images
If,
shall see
two
of the spot,
we employ' a
piece of
card through which a small pin-hole has been made, and hold
the spar before the eye with the perforated card behind
shall see that the light
it,
we
is
light,
on
split into
two
is
If in either experiment
it flat
we turn the spar slowly round, keeping dotted paper or the perforated card, we
image
which
travels
is
against the
(Fig. 15).
rhombohedron of Iceland spar, and gr?nd away the poles, we shall form two triangular faces, of which a a and b b (Fig. 1 6) represent the traces. Having
similar cleavage
w take a
37
them
flat
On
looking
straight
down upon
in a direction
normal to the
now be
we look obliquely, the two images will again become visible. The direction in which the single
seen
;
but
if
is
seen, is that in
It is a.dirpxtion of
and
termed the
crystals
which
known
as uniaxial crystals.
is
which
in
be negative uniaxial
for
shall
instance,
Fig. 15
we
and
;
e,
we
have a diait
gram of a
In
all
to,
graphic axis.
The
which
infinite
number
deof a
is
seen
38
uniaxial crystal
axis, is not
Rock-Forming Minerals.
is
also seen in
is
moved about
upon the stage of the polariscope. The indices of refraction for o and e differ in different minerals. For the same mineral the separation of the two images depends, of course, upon the thickness of the plate employed. Thus, two cleavage rhombohedra of calcite, of
equal thickness, placed one above the other in a similar position, will give twice as great a separation of the
images as
either of
singly.
Polarization op Light.
is
When
a ray of light
it is
compelled to perform
(This
its
is
vibrations
said to be polarized.
also
termed
its
it
vibrations in
all
Fig. 17.
travels.
If such a ray
{i i,
p, certain
be noted
if
When
the tourmaline
is
held with
its
principal axis in
PPP
(which
is
* The angle at which complete polarization of the reflected ray takes is 58 for glass. This is termed the polarizing angle for glass. For substances with higher or lower refractive indices than glass, this angle is proportionately higher or lower. At the polarizing angle, the refracted and reflected rays form a right angle.
place
39
no light
will
and in
be
In the
when
to
means
of
may be
are,
th,at
The prism
is
then sliced in
(Fig. 18,
A); and
the cut faces, after having been polished, are cemented to-
A ray of light,
i',
on entering the
into an ordinary
and an extraordinary
vibrates in a plane
;
s/\.
-'(----^s
principal section.
\/
extraordinary ray.
(n
= l"536)
Of these the
Fig. 18
^passes
any
same
refractive
* 0,
has
= l'654), and
undergoes
the direction o
of the prism
s s, indicating
Fig. 18, A.
A transverse
B
;
section
shown
in Fig. ^8,
its
shorter diameter,
Fig. 18
is
however.
40
Rock-Forming Minerals.
shced,
medium.
By
these
and also iu the nature of the .cementing means the length of the prism is coneither as a polarizer or as an analyser
siderably diminished.
ordinary ray
is
abolished
by
one set of
to
namely, those
parallel
the
the
When
transmitted
when they
27).
darkened.
Wh}j darkness
The
light
which
is
principal section
and, consequently,
when
due
to
any
in-
terference
number
of half
therefore, not
owing
to interference, is
proved
when the
for,
parallel,
transmitted.
The
enters
when
it
undergoes
total reflection.
Polarized Light.
When, between
crossed Nicols,
we
insert 9
Rock-Forming Minerals.
41
Light
ever,
If,
how-
we
of the Nicols,
between crossed
we
more or
If,
If
it
and smooth
adhering films,
it will
If,
instead
we
cut the
wedge, colours
of the wedge.
colours.
will
have now to consider the cause of these They depend upon the retardation of certain rays of light. A polarized ray which enters the plate of the crystal under examination, is split into an ordinary and an
extraordinary ray, both of
We
one
somewhat
different length of
somewhat
an axis of greater or
axial crystals, or to
least elasticity
The index
of refraction of
the mineral and also the thickness of the plate have a very
material influence on the retardation of one or other, or in
different degrees
them
more or
in
less different
is
The direction
to
an optic axis
So
no interference
On
is
again
split into
two
rays,
42
but these
differ in
certain
wave
wave
For instance, in a tolerably thick plate we may get extinction The red rays haye longer of the red rays by interference.
wave-lengths than those of other colours, and the residual
colours will then be transmitted.
On. the other hand,
when
When
the
at
an angle of 45
we have
is
rotated on
the stage, they become less brilliant, until they merge into
darkness, and at this point an axis of elasticity,
of
i.e.,
a direction
maximum
* The strength of
ness, but
tlie
of different
may
exist
seen in polarized light. With weak double refraction, the colours will be those low down in Newton's scale; with strong double refraction, the colours will be those of higher orders. (See Newton's Colour Scale,
p. 95.)
43
The
difference of phase
by referring
plate P,
to fig. 19,
where
% k,
i'
Ic
into
two
rays.
k' V,
so that,
The ray k has a longer path when they emerge from the plate,
I' ;
the waves of
h'
V being a
brought
into the
The
by
crystals
when they
are viewed in polarized light, often afford important information regarding their structure.,
Pseudomorphs,
this
for instance,
may be
frequently recognised
by
means.
Thus we may
find
it
to be
made
different positions
lie,
or, in
more or
less mosaic-like
appearance.
may
often be ascer-
by means
of
sections
crystals
exhibit
in plane
polarized
light.
banded with
numerous coloured
bars,
4.
in
Polarized
infinite
44
Rock-Forming Minerals.
The
and
it
is
therefore needless to
to
them
here.
It
remind
the beginner that the crystallographic axes are usually symbolized by letters
;
frontfc,
and-back axis
is
denoted by
and the
vertical axis
by
set vertically.
it,
In
all directions
around
and
at right angles to
assumed
to
be so placed
macrodiagonal with
6.
is
assumed
it is
to'
so that
In the In
axis
triclinic
Axes of Optical
is
In
tion or polarization,
and
but,
different velocities.
In the case of
from
less
and
less, until, in
45
into
velocities
one
ray.
parallel
from a doubly-refracting
crystal in
of elasticity,
we
shall find, if
we
tion at right angles to the faces of the plate, that only a single
is visible,
The
vibrations of the
two
an axis of
elasticity,
emerge with a
difference of phase
and in
this respect
an axis
an optic
axis.
which
is also
is
an axis of optical
elasticity.
elasticities,
elasticity
mean, and
least, respectively
symbolized by the
italic
;
letters
a, 6, c.
c,
letters a, i,
for,
although a
i with h,
case. &
may sometimes be
t
and
with
c,
yet this
= a, c = b.
The axes
of optical elasticity are also directions of
maximum
crystal transmits
always
lie
at
46
two rays whicli travel together along such an axis are polarized In determining the optical at right angles to one another.
properties of a crystal,
it
is
most important
to ascertain the
known
crystallographic edges
which
lie parallel to
The methods employed to effect this object are various. The most simple, perhaps, is that described on page 28, as affording a convenient means of accurately crossing the principal sections of the Nicol's prisms.
field
of the
it
edges (and
must
be an edge which
axis) is coincident
is
known
to be parallel to a crystallographic
eye-piece.
Due
and exactly
parallel
and analyser.
The observer
the crystal
is
will
now
see one of
two things
either that
is
it
more
or
less illuminated.-
maximum
extinction of light,
If,
i.e.,
no
The
divided
which
is
it
mum
darkness
attained
by the
crystal.
There may at
;
first
be some
exact position
make an
three degrees.
By
repeated
trials,
47
Where great accuracy is needed, mean of many careful observations. quartz, commonly known as " Klein's plate," is
result.
It is inserted in a slot
and
in consequence of
field
becomes
uutil
The
analyser
should
next be
turned
now being
field.
parallel with
be seen whether
If
it
should then
tint as
be turned
the
field.
same
The reading
of degrees
number
through which
the
will
known
crystallographic edge,
i.e.,
with a
known
crystallo-
graphic axis.
The foregoing
are,
The
The
On
will
now be
seen, traversed
by
elasticity
with
the
known edge
if
there be any
more or
is
less distorted,
and the
In
properly restored.
method there
is
also a tolerably
48
Rock-Forming Minerals.
This
two
it
to the
hand.
alternately,
and are
carefully
their
of the
known edge
parallel to
one of the
if
an axis
which
should
lie
lines, will
A reading
is
formity of tint
and the known edge, or its corresponding crystallographic axis. Beginning with those biaxial crystals which possess the
lowest grade of symmetry,
we
find that
In
maximum
extinction,
In
one axis of
axis,
elasticity
is
and that
we may
tersecting
a,t
may be
axes.
Rock-Forming Minerals.
1%
the
49
elasticity coincide
It is
(See p. 28.)
crystals,
Although uniaxial
tion
when
The reason of
this
is,
an optic axis
for light of
two
different
colours.
section is
since,
Even when monochromatic light is employed, the also illuminated when rotated between crossed Nicols,
to internal conical refraction (p. 58)
owing
around the
become separated
into an infi-
number
polarized in
Among
In both
of
we
find that
maximum
remain dark between crossed Nicols during a complete revolution of the stage.
they
may be
cut,
transmit no light
all positions,
have been strained by pressure, or are in an abnormal condition of tension, in which cases they exhibit more or less
double refraction ; and what
is
50
Rock-Forming Minerals.
no double
refraction,
Good examples
of tension
vitreous lava,
with, in
same
in all directions.
widely
diflFerent
been found
at
which they
The
be anall
not uniform in
directions.
Among
extinction, already
classes
(a)
alluded to,
may be
of
maximum
;
and
aniso-
manner
Monoclinic System.
sections parallel
Parallel extinc-
tions in
j)lanes.
sections
to
Rock-Forming Minerals.
RJiombic System.
51
parallel
Parallel
extincfciors
in sections
Parallel extinctions
Extinction in
all
to this axis.
5.
Wave
Scefaces.
Crystals.
Luminous
wave-sur-*
In a crystal belonging to
a luminous point
is
therefore,
we conceive
of
arrest,
infinite
in
film, or
luminous wave-
The wave-surfaces in systems other than the cubic are not spheres j and we shall find that they are not so, because the
molecular structure of the crystals belonging to these systems,
as denoted
directions.
by
and
this difference
may be
no such
triclinic systems.
we
we should
52
had
in
Rock-Forming Minerals.
travelled with different velocities for the ordinary
and
for
the direction of the optic axis the two rays had journeyed
In
least velocity.
As
if
and
its
wave-
surface is
consequently a
sphere
and,
we
join up the
we should
be an oblate
ellipsoid of
a, a,
major axis of
lie at
minimum velocity,
section of
{e.g.,
for the ordinary ray is also a sphere, while that for the extrais
it
and touching
optic axis.
In
Rock-Forming Minerals.
velocity in tlie direction of the optic axis,
in a direction at riglit angles to
it.
53
its least
and
velocity
is
given,
By drawing
lines radiating
by
their lengths
between the central point and the points where they are cut
by the
ellipses,
nary ray, while as radii of the circles they denote the uniform
velocity of the ordinary ray in each case.
Wave
These, like
is
the wave-
depend
on
propagated within
viz.,
maximum
light
is
a,
mean
fi,
and minimum
a
c.
In
biaxial crystals
maximum
minimum
in another,
and a mean
in a biaxial crystal,
we
first
elasticity 3
and
axis
6,
luminous
a
of elasticity
split
two
rays, polarized
at right
angles
to
one
another,
least elasticity.
The
mean
54
velocity,
Rock-Foi'-ming Minerals.
and we accordingly mark
to represent this
off
points,
mean
.
The
vibrations
have a minimum
velocity,
a,
and we consequently
on each side of the
mark
origin,
off
two more
least or
minimum
velocity.
We next
Along the
direction of the
former
latter
off
we have we have
We
accordingly mark
axis
\,
upon the
in one case
proportional to the
velocity.
maximum,
minimum,
For directions lying between the axes a and \, but in the same plane, we get a series of different velocities, and we
measure
off distances proportional to those
is
which luminous
to elapse
assumed
If
we now
join
up
all
of these points,
we
shall get
ellipse, as
Fig. 22.
We next
elasticity i
and
t lie.
the*
55
in the direction
will vibrate in
a,
of the axis
t,
and
Upon
axis 6
the axis
therefore,
we
greatest
and mean
upon the
velocities.
we again
mark
to
off distances
the
On
joining up
Fia. 23.
we procure an ellipse lying within a circle. we take the plane in which the axes a and c
Fig. 23.
lie,
Finally,
and by adopt-
/^
we
arrive at a circle
The two lines 00, o'o, intersected by an ellipse (Fig. 24). which join the four points in which the circle cuts the ellipse, and which intersect in the centre of the figure, are in which the velocities are equal, and along these
there
is
directions
directions
These may be
56
termed the two
p. 58),*
Rock-Forming Minerals.
<ypiic axes,
axes a and
and they always lie in the plane which contains the By combining the three sections, namely i.
elasticity a
and
and
b,
t, t,
and
structed.
it
i a
and
may be
con-
be found that
at
all
The
line
tially
upon the
circular
and
elliptical
figured. t
It will
crystal consists of
two intersecting
the points o o
o'
o'.
Any
o'
is
common
and the
o'o'
ellipse,
so
that rays passing in the directions o o or * The student must not imagine that ai-e merely two fixed lines within the crystal. They may be represented by two lines but an infithese optic axes
;
a a-
.Ida
p'e" / c-a
nite
number
of lines
parallel to
them
Here o o,o o, represent the optic axes, and the dotted lines B and c the bisectrices but the lines marked o' o" o'" are also the optic axes, and a', a", a'"; t', t", etc., are also the bisectrices. The
;
+ Plaster models of the wave-surfaces of uniaxial and biaxial crystals are prepared by Dr. L. Brill, of Darmstadt.
Rock-Forming Minerals.
travel with the
57
same
velocity.
vatures of the surfaces of the sphere and the ellipse, the plane
a
Fio. 26.
are not
(Fig. 26)
The tangent
however,
common
x,,
to both, so that, if
from the
which
o o
and
o'o'
we
or, in
whose
apices are at O,
will
emerge as a cylinder
tangent-plane
common
Ox Ox
.58
refraction.
i i,
and
is
of ex-
correctly-speaking,
is
6.
Bisectrices.
The
maximum
extinction.
The angles formed by the crossing axes are alternately acute and obtuse ; and the
is
bisected
of elas-
which
is
known
is
bisected
and
bisectrix, or
When
bisectrix is used, it
The acute
is
crystal
be
When
of greatest,
the
obtuse bisectrix
alische Krystallographie,"
* For a detailed account of conical refraction, see Groth's " PhysikRosenbusoh's " Mikroskopisohe 2nd ed.
;
Physiographie," vol.
Optics," etc.
i.,
pp. 94
et seq.,
2nd
ed.
t In biaxial crystals the axis of least elasticity is sometimes called the positive bisectiix, and that of greatest elasticity, the negative Msectrix. When the positive bisectrix is the acute bisectrix, the double refraction
of the crystal is positive,
is
is
negative.
Rock-Forming Minerals.
59
la tbe trielinic system, there is no necessary relation between the bisectrices and the crystallographic axes. In the monoclinic system a bisectrix is sometimes parallel
to the orthodiagonal.
p.
80
et seq.)
Optic Normal.
The
axis of
mean
elasticity in
a biaxial
known
as the optic
normal.
The angle
at
different minerals,
and sometimes,
;
to a considerable extent, in
therefore a matter
The method
elasticity,
of
has already been described on p. 46, et seq. The means of distinguishing which is the axis of greatest, and which that of least elasticity, i.e., which is the acute, and
bisectrix, will
tongs.
is
coiled
round
discs
so that
the
To use the
instru-
6o
Rock-Forming Minerals.
the section is inserted between the tourmalines, and the arms of the tongs are allowed to close. The instrument should be held close to the eye.
A
much
is,
however,
efficient
work
and an
which the writer has recently planned for class-demonstration, and for the use of students, is now manufactured by Messrs. Watson, Bros., of Pall Mall. The
general construction of the instrument
is
shown
in Fig. 27,
Pig. 27.
joint, 6,
r,
wooden
foot,
e,
c.
Upon
this
the stage m, and the arm of the tube d. by a rack and pinion, g ; but the tube e merely slides by moving the fitting at/ At the lower end of tube d is a system of plano-convex the
of the tube
arm
The
latter is adjusted
downwards towards
e is
a similar
surfaces
directed upwards
Rock-Forming Minerals.
towards the stage.
6r
metal plate, with
The
latter is simply a
which
works
The upper
clips, o,
plate, or
carrier, is
e is
a Nicol's prism,
i,
the analyser.
d,.
of the tube
is
a lens of
The cap of the analyser turns on the end latter, and a little below the analyser, low curvature, and just below this, at g, the tube
In the
is slotted,
or a quartz-wedge.
More
ments
all
the requireChevalier,
made by Fuess,
;
In lieu
to serve
may be made
on p. 19.
Interference-figures [Uniaxial).
If,
when the
polariscope
is
light,
we
we
shall
is
when
rings *
by a dark
cross, the
arms of the
NN,
;
* The colours in each ring have a regular succession, as in Newconsequently each ring is a succession of concentric coloured rings, which merge one into the other, the same colour
ton's rings
extending completely round the ring in any given zone. Hence these rings are termed isoohromatio (like-coloured) curves. These, in the interference-figures of uniaxial crystals, are circles if the sections be
cut perfectly at right angles to the optic axis.
62
This
is
The arms
of
and the rings become narrower, and occur closer together the further they lie from the centre. Each ring shows the
colours of the solar spectrum.
On
;
no change
is
when
now appear
in the rings.
Fig.
28
is
Fig. 28.
interference-figure
Under
by a dark
is
cross, as
shaded gradu-
away on the
sides of the
arms.
This
may be
taken
are,
There
Of the
latter,
crystallizing
system
rhombohedral).
Crystals of arti-
63
Circular Polarization
is
power
that
it
manner
rotation
in
The amount of
The
to
result of this
is,
the
optic
axis,
crystal-plate
field
illuminated in
exhibits a uniform
the crystalit is
is
of uniform thickness.
Fia. 29.
by a dark
cross,
most
ring.
The
c.
spread of colour
64
Rock-Forming Minerals.
The dextro-
with
its
The
ex-
which
will
In
when
the analyser
is
direction as that in
The rings
In the case
In
and instead
of a dusky
one
is
seen, traversed
cross.
Fio. 30.
When
handed
is
placed over a
left-
or
vice
versd,
peculiar
interference-figilre,
known
is
as
" Airy's
spirals," is produced.
These
spirals
may
left-
Rock-Forming Minerals.
especially in amethyst.
65
sections.
The distance between the rings depends, however, not merely upon the thickness of the plate, but also upon
together.
two
In
calcite, for
is
very strong,, a
{Biaxial).
The
interference-figures of
some
Fig. 31.
to those of uniaxial
crystals.
This, however,
is
only seen
when
axes
is
by
The
in convergent light,
to
66
Rock-Forming Minerals.
system of concentric circular rings
will
be
visible
and
tbese will
be traversed by
a single straight
of rings
clinic),
section
is
Such a system
In sections of biaxial
crystals,
coalesce.
colours,
reprecase,
In
either
when
tion
is
parallel
bar (Fig.
When
the section
is
N'
i I
II I
-N'
shown
in Fig. 32,
where
N,
is
said to
be
in the
normal position>-.
67
now, the-Nicols
still
NN, N'N'
the two
The portion
is
it
fringed with colour, the colour on one side of the bar differing
There
is
When
the section
is
ference
figure
shown
in Fig. 33,
it is
said to
be in the
diagonal position.
light,
of plano-convex lenses
In the direction
is
there
68
and varying,
axis,
rays
nary rays.
In positive uniaxial
rays
radially,
and
the
extraordinary
In either
rays,
more or
if
less retarded
on
plane,
the
white light be
Each
matic zones.
With
they succeed one another from the centre towards the margin,"
so an increased difference of phase occurs.
split into
by uneven numbers of half-wave lengths, become reduced to the same plane of vibration (i.e., they have to vibrate
parallel to the principal section of the analyser),
amount
to
Rock-Forming Minerals,
69
uneven numbers of half-wave lengths, while the interspaces between the rings result from rays which differ in phase by even numbers of half-wave lengths.
In Fig. 34, an endeavour
is
made
to
show the
relation of
the rings under the respective conditions of monochromatic and of ordinary white light. Only half of the interferenceiigare
is
represented.
The
lines
NN,
crossed Nicols.
The
left
In the
results
left
quadrant the
first
to a difference of
the second dark ring to a difference of f\, and the third dark
ring to ^\.
The
num-
no interference takes
place.
c, c, c,
to the
matic
i>
>
light.
Here,
again,
the
in
phase
are
when the
analyser,
f l^j or uneven numbers vibrations are reduced to the same plane by the
interference,
accompanied by colour,
this
results.
It
diagram expresses
70
Rock-Forming Minerals.
if
seen
when red
light is
somewhat
bands
different positions
c, c, c,
In the case of biaxial crystals -it has already been stated that
when a
section is taken
interference-figure
consists
or
approximately
section
is
made
at right angles to
two
systems of rings are developed, and these rings are not circular.
On
it
will
be remembered that
1 1
to the plane
constitute a
we should have
its axis
a circular section,
an
elliptical section.
We
may, in
difference
obliquely,
fact, realize to some extent the nature of this by cutting through an ordinary drawing pencil and comparing this cut surface with the circular end
of the pencil.
there
are,
however,
vast
number which
follow
optic axes,
and
it is
As
the crystal
is
then
We
Rock-Forming Minerals.
71
right angles to one another about each of the optic axes ; but
way
produced
differs
If to any
number
Fig. 35,
we draw
radii
Fig. 35.
lines, as f' a,
jp' b,
c, etc.,
which
will vibrate,
while the
g, etc.
On
be abolished by
the other
set,
when reduced
possess differences of
give
when white
mono-
WW,
in the direction
N N.
On
72
Dispersion.
Rock-Forming Minerals.
It
colours
If,
is
as an example,
we
take a section,
made
at right angles to
we
or polar rings, are fringed with red, while the outer sides
will
The
letters
and
violet.
is
Fig. 36.
position.
The coloured
clear, light
shading
is
also used
Fig. 37
shows
section into
fringes
The inner
This
is
and
an example of what
is
known
as rhombic dispersion.
All crystals of the rhombic system do not, however, show the same colours in the same situations, although the relative
distribution of the colours, both in the normal
and diagonal
Rock-Forming Minerals,
positionSj is always similar.
73
this particular
For instance, in
is
Fig. 37.
light, a condition
we meet with
expressed by
/j
> w.
will, in
the normal
and blue on
illustrate
model to
complete.
lines
The
line
c is
74
Rock-Forming Minerals.
The former
is
is also
and
it
coincides with, or
vf
parallel to,
one of the
fu
1d
Vv
vfi
p
FiQ. 38.
is
The
dotted lines p
p,
p, are
marked v v, v v, are the optic axes for blue light. The card itself upon which the lines are drawn, represents the opticaxial plane, and the needle i the axis of mean elasticity, which is also the optic normal, and is likewise coincident with or
parallel to another of the crystallographic axes.
-
According to
would be taken
as the
but
it is
If
we examine a
we have p<v
first
in red,
and then
in blue light,
we
much
closer together
relatively
light.
75
The thick
circles
and curves denote the rings and hyperbolse and curves indicate the rings and
Fio. 39.
What we
different
j
see
is,
however, quite
for
white light
We
in blue
light,
we
see in the
p<v,
by the
is less
than that of
hyperbolae are fringed with blue towards the inside, and with
it
is
therefore
is
always symmetrical
76
Rock-Forming Minerals.
j
is
common
for
rhombic system
The mineral which shows this peculiarity the most marked manner is Brookite, the rhombic form
titanic acid.
in
of
is still
common
bisectrix.
we have
p<.v, as in barytas.
in sections of cerussite
met
and
crossed.
this case is
Inclined Dispersion.
The interference-figure in
Fio. 40.
by shading,
rings are not always of the same size and shape, also that the
broa,der bar of the dark cross
is
same
size.
is
also to
Rock-Forming Minerals.
11
be noted, the red, in the case here figured, fringing the right
sides of both rings, while their left sides are fringed with blue.
On
lies at
45 to
indicated in Fig. 41
is
seen.
The convex
FiG. 41.
bola,
same
and the concave side of the other being fringed with the colour. Selenite and diopside aflford good examples of
In some crystals of adularia
(a variety
inclined dispersion.
may
also
be observed ; but
the phenomenon
just mentioned.
is
lie
in
Horizontal Vispergion.
In
angles to the orthodiagonal, so that the obtuse bisectrix coincides with, or is parallel to, the latter.
78
Rock-Forming Minerals.
interference-figures under
Fig. 42.
that the narrower dark bar, lying in the plane of the optic
axes, is fringed, where
it
blue on the one side of the bar, and with red on the other, the
Fio. 43.
maximum
sides of that ring, while the upper inside edges of both rings
Rock-Forming Minerals.
are fringed with the same colour,
e.g.,
79
but with a
differ-
somewhat
similar
dispersion.
Grossed Dispersion.
If from
examined
in
interference-figure
is
in the
Fia. 44.
not the
shall
case
in the
two rings we
being fringed with blue above in the right ring, and blue
below in the
left,
the
maximum
distributed
much
gure of a crystal
in
i.e.,
as
8o
Rock-Forming Minerals.
is
on one side of
different kinds of
and
from con-
show the
axes of
positions
elasticity,
and the
For the
latter,<
they
Fio. 45.
Fig. 46.
Upon
are
and
axes of elasticity, in the second and third cases, axes of elasticity only.
is
represented in a some-
what
Rock-Forminor Minerals.
the tliick vertical line
crystallographic axis,
diagonal.
8i
is assumed to be parallel to the vertical and the thick ohlique line to the clino-
Fia. 47.
is
drawn
as
if
it
were a
which
is
supposed
clinic crystal.
On
Sj
two continuous
marked p p, are shown. These are the They intersect and pass through the
centres of the
figure I.
first
v.
They
intersect in the
They same
point as the optic axes for red light, and pass through the
centres of the
first
82
We have then
The
lines a v a
/o
and
for red
light respectively.
They are also axes of greatest elasticity for those colours. The lines tv tp are also respectively the obtuse bisectrices for blue and for red light, and they are the axes of least elasticity for those colours. The optic normal, or
axis of
mean
elasticity, passes
optic axes
intersect,
and
it
lies at
right angles
to the plane S.
To avoid
it
confusion,
is,
however, omitted
in the drawing.
Prom
this figure
will
for
red, blue,
and indeed
make
all
is
also
in
this plane
that
the
interference-figures
are
displaced.
Here,
is
it
will
and
which are
and blue
respectively
symmetral plane somewhat below that The optic-axial planes in both cases are parallel to one another, and lie at right angles to the plane of symmetry. The acute bisectrix for red, a p, and that for blue, a v, lie in the plane of symmetry, and, of course, intersect at the same angle as the corresponding optic-axial planes. The obtuse bisectrix
t
Rock-Forining Minerals.
83
common
and
is
to the plane of
symmetry.
The
lines
Again,
is
the
symmetral plane
bisectrix
The obtuse bisectrix, for red, c p, and that for blue, r v, lie in the plane of symmetry ; but they make slight angles with one another, and consequently the optic axes, for red, p, and for blue, u, which lie in planes
for all colours.
common
angle with the plane of the optic axes for blue light.
therefore liken the acute bisectrix a to a pivot,
We
may
become more or
less
turned
a.
47),
slightly crossed
;
by the
by dotted lines the areas of the inner rings for blue being denoted by vertical shading. The optic normals for red, p,
fi
and
symmetral plane.
Inclined, horizontal,
In
we meet
with
In
a condition which usually occurs in microscopic preparations of rocks, and in cleavage -plates of minerals in which the
cleavage planes
sectrices, it is
make an angle with one or other of the bicommon to see, in convergent polarized light.
84
Rock-Forming Minerals.
In very thin
sections,
looking at an interference-figure at
all
the impression of a
that
is
The following examples may serve these obscure markings have their meaning :*
In the case
when
of the polariscope,
it is
of the interference-figure
before us.
lies just
and
the interference-figure
is
drawn through
lie
at 45 to the
Fia. 48.
Fio. 49.
In
this instance
two
of a
of the arms a
a'
r.
and part
coloured ring,
In
reality,
are never sharply defined at their edges, and in very thin sections they appear merely as blurred,
shadowy bars
while in
such cases the rings are usually so wide that they do not come
into the field.
is
* For a more complete series of figures, the student should consult the plates in Fouqiii? and Levy's "Mineralogie micrographique," or
that in Hussak's " Anleitiing
zum Bestimmen
der Gesteinbildenden
Mineralien."
Rock-Forming Minerals.
85
optic axis lies further out of tbe field tlian in tbe preceding
marked
1.
round in tbe
march slowly across the field from left to right, still retaining and consecutively occupying tbe positions
shown by tbe dotted lines 2&, 3c, until it leaves the field. If the rotation be continued in tbe same direction, tbe point in which tbe arms of tbe cross intersect will gradually reach the
By
field,
arm
of tbe cross
but this
lies in
is
a horizontal position,
continued, tbe hori-
field,
occupying successively
etc.,
edge of
and
is lost
to view.
We
of uniaxial crystals,
when
it
disappears,
enters in a
86
to that pursued
Rock-Forming Minerals.
by the former
bar, until
it
too disappears
from view.
This phenomenon often helps to decide whether a partial
interference-figure should be referred to a uniaxial crystal or
not.
'Partial
Interference-figures of Biaxial
Crystals.
In
those
cases in which one of the optic axes lies within the field of
is
then visible
is easily
on rotation,
it
and
the brush
may
also be seen
cases in which the centre of the field lies between one of the optic axes
and the
This condition
is
shown
in
In
Fig. 51.
Fig. 52.
Fig. 53.
axes
lie
outside the
field, as
by the
thick,
of
Rock-Forming Minerals.
87
which sweeps obliquely as a dark brush across the right of the field. In Pig. 53, a further rotation has thrown the hyperbola
completely out of the
tions,
fields
In
Fig. 54.
Fig. 55.
Fig. 56.
we have corresponding
all
positions of the
crossed Nicols;
but in
microscope.
i.e.,
In Fig. 54,
In
the section
Fig. 55, a rotation of 25 to 30 has caused such a change, that only portions of the hyperbolic brushes are visible on the
right and
left
margins of the
field,
In Fig. 56,
the section
hyperbolae
lie
outside
the
field,
owing
to
Portions
The ex-
may be observed
in different positions
when
88
Rock-Forming Minerals.
askew
light.
to
a bisectrix,
are
Optic-Axial Angles.
For
this
purpose
Each of the
bisectrix;
optic axes
makes an
This
is
which
is
Each
ray, however,
when
it
emerges from
57,
air,
(in
as
shown
in the figure).
similar angle, E, is
also formed on
the other side of the bisectrix by the other optic axis, and
these two angles constitute the angle 2E, which
is
termed
'J'his
is
2V.
89
from that of
In the same
is
the obtuse by the symbol Va, the half of the obtuse real angle
way the
denoted by
The real angle of the optic axes may be directly measured by employing a cylinder, so cut from the crystal that its axis is parallel to the optic normal, or axis of mean elasticity, &; or
a sphere cut from the crystal
may be
refraction
on emergence.
The
to
at right
consists
The
polariscope
and the
where
it
crystal plate is
crosses a first
is
it
is
afterwards
is
brought into
The angle
is
The
immersed
in a little parallel-
oil,
which has a
air.
re-
By
is
reduced, so
from
'
90
li
Rock-Forming Minerals.
E = the
air,
{Ha = the apparent semi-acute angle in oil. Ho = the apparent semi-obtuse angle in oil, Va = the real semi-acute angle, Vo = the real semi-obtuse angle, n = the refractive index of the oil,
/3
=the mean
Then
sin
E= n sin Ha ;
sin
Va = -^
sin
Ha ;
sin
Vo = -^
sin Ho.
When
mean
it is
acute apparent angle, the true angle of the optic axes and the
refractive index of the crystal can
be determined, since
sin Vo
= cos
tan
,
Va.
Hence
-rr
sin sin
it is
E
Va
always desimilar in
monochromatic
light.
Arrangements
For
the
upon
this
branch
of
investigation
Mica
is
is
biaxial
the axis of
The
planes of cleavage in the micas are almost precisely at right angles to the acute bisectrix
axis of least elasticity,
elasticity, lie in a
;
bisectrix, or
axis of
mean
Rock-Forming Minerals.
If
91
of wide optic-
upon
sucli a mica-platej
axial angle,
viewed
preferably one
we
place
being set parallel to that of the other, the rings of the interference-figure will appear to be narrower
and
If,
now, a third
By
the superposition
marked
two systems
more
closely together.
On removing
we
make
to
the rings of
its
interference-
is
make
and more
closely packed.
be noted
phenomena indicative of thickening were produced when the mica plates were arranged with their axes of minithat the
mum
If
elasticity parallel.
we take a
we
the
i.e.,
is
r.
If,
now, we
and
such a
we
longer
black, but
92
and we
If,
appear somewhat
larger.
we
take a
are
wedge
end
and
insert this
to
the optic-axial
plane of the
we
shall see, as
we
expand and
lemniscata,
travel
field
towards one
another, until, one pair after another, they unite and form
which
margin
of the field.
it
seems to
expand.
is
the axis of
elasticity
The axes
of greatest
and mean
therefore
lie
the former being parallel and the latter at right angles to the
optic-axial plane.
The
efiect
quartz
wedge
wedge was
Had
the
wedge been
inserted in a
been
parallel to
an axis of
less elasticity,
i.e.,
the axis of
Now we know
;
mean mean
elasticity is
never a bisectrix
Rock-Forming Minerals.
93
Again,
if
we take a
and
place
tion,
it
in convergent polarized light, in the diagonal posishall notice that the effect of thickening is
is
we
produced
inserted with
its
principal axis in a
Clearly, then,
is
but as
it
is
normal
of
is
mean
elasticity.
mean
axis
remaining axis of
must be the axis of least elasticity ; and the elasticity, which lies at right angles to the
By
sides
ibs
known
elasticity,
we can determine
duced when
inserted
but
is
if
the apparent
The
sign,
may
likewise be recognised
by focussing the
crystal in
the field of the microscope, between crossed Nicols, turning the stage so that a known crystallographic edge lies at 45 to the principal sections of the Nicols, and then inserting the
quartz wedge below the analyser in the same direction,
the bars of colour which cross the
when
wedge
edce
will appear to
94
Rock-Forming Minerals.
In the former
;
case,
the rise
in colour
shows that
it is
negative.
in colour
" may be
further
number of coloured
bars, shading
one into
wedge recurring
Rock-Forming Minerals.
95
96
If
tlie
Rock-Forming Minerals.
crystal C, Fig. 58, can
be arranged as in the
figure,
overlap
faulted.
it,
2nd order will be faulted into or towards the region occupied by those of the 1st order, as shown in the case of the positive
crystal C, Fig. 58
;
but
if it
be an axis of greater
elasticity in
is
of
In
this
method of
is
used, and the condensing lenses above the polarizer are re-
moved.
The microscope
is,
In convergent
light, in the
may be
made
to serve the
same end, by
tilting
it,
The
may
also
by focussing
it
in the microscope,
in, or
97
at right angles to, the direction of one of the axes of elasticity in the plate of the mineral.
The position
be diagonal and,
managed by
first
45.
The condensers
are then
polarizer,
when
the Klein's
centre,
and then
is
the bisectrix
but
if
the colours
recede from
the centre, and then advance inwards from the margin of the
field,
the bisectrix
is
negative.
crystal, the
employ a mica
This, usually
either inserted
little
known
as a quarter-undulation plate,
may be
below
it is
In a Norremberg's polariscope
slot
should be
when
a uniaxial crystal
placed in the
its
field of the
instrument, the
optic-axial plane at 45 to
phenomena indicated in Figs. 59 and 60 will be observed. In cases similar to that shown in Fig. 59, the cross separates
two hyperbolae, which are resolved into two dark spots spots lie in the ; and these
which the optic-axial plane
of the
into
direction in
inserted.
mica plate
is
98
Rock-Forming Minerals.
easily
ready means
recognising
the
Fig. 59.
Fig. 60.
plate is
margin
of the field, as
shown
in Fig. 60.
The quarter-undulation
.plate
may
also
be used
may, however, be
mode
of pro-
The polariscope is arranged for convergent light, the Nicols being crossed. The crystal-plate is then turned until the interference-figure lies in the normal position. The micacedure.
plate
is
its optic-axial
plane at 45 to the
Fig. 61.
it
passes obliquely
If the crystal
be negative, the
99
larger than those in the lower left and upper right quadrants
line.
its
in-
Fig. 62.
perhaps, preferable to
it
is
they
is
very small,
as
approximate more or
appearances of
less
closely
j
to uniaxial
crystals,
and
in
positive
crystals,
quarter-undulation
Figs. 59 and 60.
"
lOO
Pleocheoism.
when viewed
in different direc-
amount of
which
colour.
There
are,
artificially.
The phenomenon
is
due
Some
crystals
exhibit
different colours
or tiats in three
different directions.
Such
be
trichroic.
Trichroism
If,
is
alias Cordierite,
which
that
we
shall see,
on looking
greyish-blue
the mineral
icoids it will
will
appear yellow
pinait
look indigo-blue.
If the crystal
be cut so that
tints will
be
seen.
Other minerals exhibit only two colours when viewed in The different directions, and these are said to be dichroic.
optically uniaxial crystals,
colour, exhibit
of the
dichroism.
optic
Such
crystals, if
which
axis.
seen in
all
its axis is
may,
if
viewed in the
it
displays a clear
Rock-Forming Minerals.
green colour.
green,
is
101
mixed
tint,
resulting
The
by transmitted
light.
of least
that axis, one set of vibrations lying in the plane of the axis
of greatest elasticity,
a,
mean
elasticity, \,
and
while
t,
rays
travelling along
Ij
and
as
indicated
by the small
The
faceaxis-
therefore determined
by the
depends
is
upon the axis-colours for a and c, while the face-colour C compounded of the axis-colours for a and 6.
102
The
one direction
may be
separated
and seen simultaneously by means of an instrument termed a dichroscope. They may also be separated, but cannot be seen
siniultaneously,
by means
In
this
may be
placed on
the polarizer
is
turned.
The beam
elasticity,
and the
colour.
crystal
will
then
and the
crystal
will
show a corresponding
axis
By
two colours
in rapid succession.
however, the crystal be too small to permit the employof an ordinary Haidinger's dichroscope, and the observer
ment
so
by placing the
serting a
diaphragm with a very small aperture in the the eye-piece, removing the polarizer, and placing a
will
double-
analyser.
Two
it
now be
seen, one
turned.
The former
is
the
latter that
formed by the
side
by
side.
which two
glass
prisms,
e,
e,
103
"is
The
latter
mounted
in
W'l a!
'
|-M 'J4
,.J!ljmLJ
Fig. 64.
At one end
is
B,
is
by a diaphragm
slides into the
made,
On
by
To
is
and through
it
to
glass.
FiQ. 65.
ordinary image,
0,
former
lie
in a plane at right
The directions of vibration in e and 0, Fig. 65, are denoted by the small double-headed arrows. Having ascertained the directions of vibration in the two images, we are in a position to investigate the pleochroism of
104
a crystal.
If,
we examine
a crystal of
common
greenish hornblende,
we may
mean
elasticity brownish-green,,
and those
The strength
instance
of the absorption
may
also
be greater or
less
we
travelling in the
show the weakest absorption. The absorption-scheme for this hornblende therefore, t>b>a.
elasticity, a,
crystal
is,
Among
uniaxial crystals
it is
it is
the more
is
Thus
in tourmaline
it is
the absorption
> e,
ray which
-Pleochroism
to
be localized
in a
Such
pleochroic
spots
some
crystals of lolite,
Pleochroism
may
also
be
artificially
some other minerals by heating thin sections ness, for a minute or two, upon platinum foil.
it
them
to red-
to
show pleochroism.
it
their
The author is indebted to Mr. H. A. Miers and Mr. Grenville A. J. Cole for valuable assistance in the revision of several pages in Part I. Dr. F. H. Hatch and Mr. J. J. H. Teall have also kindly revised several
pages in Part
II.
lO;
PART
Haying rendered
II.
some extent^
must next learn the leading characters -whicli distinguish the more common rock-forming minerals from one another; and
here, before
his eyes.
to use
be in his
The number
rocks,
is
commonly
constitute
comparatively small
may
The minerals
which they
are
classified
ci-ystallize.
as a rule, described.
CUBIC SYSTEM.
Wative Iron.
Fe
{\-are).
The presence
of native iron- in
MM.
section of the rock with a solution of sulphate of copper, the surface of the iron
In
tine,
and
is
Pyrites.
Fe So.
io6
is
often altered
quite opaque
is
and consequently,
may be mistaken
ever,
for
both of
frequently associated.
It
may, how-
then presents
colour,
its
characteristic metallic
lustre
more or
less
deep scoring of
by the emery or other abrading material used in grindMinute quantities" of gold in a rock are,
is
foil
and
A piece
filtrate
of.
bromine water,*
magnetite.
hedron.
Fes
O^.
is
Such
on a face
octahedron, as in spinel.
Octahedra of magnetite
also very
also article
* Orookea' " Select Methods of Chemical Analysis," 2nd edition. by P. Holland, " Ohemical News," vol. Ivi., p. 271.
107
crystals.
Fig. 66.
The mineral
also
By
it
always opaque.
By
reflected light
and appears
;
black,
and may
and
polarity
may
not unfrequently
be recognised by the
its
exerts
The
pre-
sence of magnetite in
may
also
be ascertained by
when
will
it
chromite,
is
du-omite.
present.
Fe Or^
0^ (wAew
'i^ure)
Mg and Al
generally
and patches. In very thin sections chromite is translucent, and shows a brown or reddish-brown colour when seen by
io8
transmitted light
irregular
Rock-Fortning Minerals.
;
mineral.
The
by irregular
cracksj
By
and
especially in Serpentines.
lipinel,
Mg
to
AlaOj.,
crystallizes
monly twinned on a
differs,-
owing
to
When
spinels occur in
and alumina.
Hercynite,
By
transmitted light
it
Alj
O4,,
chromium
In these
spinel, is occasionally
Rock-Forming Minerals.
lucent,
109
and
of a deep
brown or coffee
colour,
drops of glue whicli appear to have been irregularly smeared over tte
slide.
Crarnet Crroup.
which
R
is
may be
dite,
Ca,
Mg,
it is
Fe, or
Fcg,
Mn, while
is
R is
Alg,
except in Andra-
where
and in Oawarowite
Crj.
The habit
The
generally dodecahedral, as
sections,
octagonal, or square
when well-formed
but
it is
extremely
common
occur in
rounded,
The
crystals
perfectly isotropic,
complete
much
The
careful investigation.
peculiar structure of
some
sidered
by
four groups.
is
the
and these
pyramids,
a,nd
i.e.,
of forms
one basal plane. The basal plane of each hemimorphic pyramid corresponds with one of the faces of the rhombic
dodecahedron, while the pyramids
of the
all
pyramids
no
Rock-Forming Minerals.
marked
II., III.,
I.
If a
made
rhombic dodecahedron,
will
be seen, in plane-polarized
Fia. 68.
light, to
be composed of four narrow marginal areas bordering a central rhomb, in which, by convergent light, a biaxial inter-
ference-figure
axial plane
(i.e.,
may be
is parallel
rhomb
rhomb
face, as
indicated in
Fig. 69.
If,
again, a section be
it
made
as at B, Fig. 68,
wiU be seen
Rock-Forming Minerals.
)reak
Ill
up
maximum
field
ixtinction
.be
Fm.
69.
Fio. 70.
Fia. 71.
where
maximum
shown
)y tbe
arms
two opposite
faces,
and following
)olarized light,
shows
and
by the
Pig. 72.
i description of the less common types of doubly-refracting 'arnets will be found in the last edition of Eosenbusch's
'
Mikroskopische Physiographie."
Garnets frequently exhibit a zoned structure, which in thin
lections is
spnes
sometimes denoted by differences in colour, the probably difi'ering in chemical composition, through
112
yarious grades of isomorplious substitution; or at others lie zones will be seen, in parallel polarized light, to be alternately
isotropic
and
anisotropic.
So
or in
The
Grossular usually
It is at times rich
and
fluid lacunae
are often
colourless
It
Common
may be
or various shades
and yellowish-red.
Occasionally
frequently has a zoned structure, and often passes by alteration into chlorite
double-refraction.
and hornblende.
Fluid lacunae
it
exhibits
and other
inclosures are
common.
when viewed
by transmitted
-
light.
Spessartlne,
or
manganese
it is
hone-stones, of which
an important constituent,
it
occurs
observed.
Pyrope,
or
magnesia-alumina
garnet,
usually
containing
some chromium and protoxide of iron, occurs chiefly in serpentines and rocks rich in" olivine, always in rounded or angular grains. Crystals of pyrope are not known. In thin
sections,
by transmitted
light,
it
The
grains of
Rock-Forming Minerals.
ii
is
an alteration pro-
and has been named Kelyphite by Schrauf j but its precise constitution is not yet known. Becke has described
iuct,
similar
picotite,
alteration-products or
as
consisting of
mixture of
The
a
lieuclte,
Kg Al^
Si^ Ojj,
was
originally
regarded as
Gr.
vom Eath
described
it
as crystallizing
The anomalous optical properties which leucite crystals jommonly exhibit were first recognised and discussed by
Brewster, and of late years they have
much
research.
;he cubic
and
rhombic and
its
nonoclinic systems.
efraction to
Some
double
Crystals of leucite
In
show twin lamellation (frequently parallel to faces of a rhombic dodecahedron, unless of very small limensions, when they appear isotropic), and display more or
ess double refraction.
ihese lamellee
'aces
To
by
of the crystal,
work.
The
be attributed to
them
nd subsequently those
The double
erceptible in
show that
at a temperature
and
is
im-
very
-thin,
quartz plate cut parallel to the optic axis, and of such thickess as to
show the
teinte sensible,
be employed.
14
Rock-Forming Minerals.
common
in leucite crystals
;
augite, are
frequently
By
colourless.
in
moderately thick
a finely fibrous
structure,
which
is
attributed
by
several
of the
analcime into a
ulti-
mixture of felspar and mica, of which the felspar may mately pass into kaolin.
Leucite
is
districts in
which
States,
in
where
It
it is
a few other
is
States.
Analcime,
Na^ Alg
Si4 Oj^,
occurs
is
in
icosi-tetrahedra,
filling
It
The
refractive
index
is
fraction is
is
common in this
mineral
now
By
strongly
On
efi'ect,
Rock-Forming Minerals.
a brought about by
fa.
tliis
lalcime
is
constant constituent of
also very
common
in basalts.
It is likewise
met with
in the
CBolite- Syenites
Soilalite.
it
2(N'a3 AI3
upon a
+Na CI.
is
th the octahedron.
:e
The
spinel,
some
The cleavage
of sodalite
it is
is
rallel to faces
seldom
formed
in cavities.
By
The mineral
ly
is
and when
has always
sen in the
The index of
;ht
Inclusions of other
etc.,
nerals,
dalite,
are
met with
in
which
also,
at
times,
contains
gas-bubbles, glass
closures,
and
fluid lacunae.
a syenitic character.
Haiiyne (Nosean).
2 (Na^ AI3 Sig Og)
+ Na^
+ Ca SO^.
Rock-Forming Minerals.
tlie first may be taken as that of the Nosean type, while the Haiiyne type may be represented by
+n Naj SO4
i2(Ca AJ2
Sig Og)
+in Ca SO^
Both minerals are soluble in hydrochloric acid, with gelatinization. The solution on drying gives microscopic monoclinic
crystals of selenite (Fig. 73),
when
Fig. 73.
owing
The
conducted too
Haiiyne
it
is is
usually of a
bright
sometimes
reddish or
Nosean
is
usually
grey,
sometimes
colours
of
bluish-grey, greenish, or
blackish-brown.
The
these
minerals,
they are
sul-
Heated in
clear
Nosean
in
thin
sections appear
and
but
colourless, except
Between
;
occasionally
observed.
Rock-Forming Minerals.
117
inclusions,
large
in definite
numbers of microliths. These are generally arranged ways (Fig. 74), sometimes forming zones. Within
Fio. 74.
and other
the
striae,
formed
in-
by the
and other
cube and of the rhombic-dodecahedron show two sets of strise, crossing at right angles to one anMinute scales of specular iron are also at times other. present in these crystals, and, as pointed out by Eosenbusch, frequently lie in the planes of dodecahedral cleavage, and
parallel to faces of the
The
is
alteration
sulphur,
natrolite,
and by a gain of water, the result being usually Calcite is likeor occasionally some other zeolite.
wise formed
now and then from the alteration of hatiyne, and limonite is sometimes found pseudomorphous after both haiiyne and nosean.
These minerals occur very plentifully in many phonolites.
1 1
leucitophyrs, etc.
may be looked
for in
Perowskite, Ca Ti O3, is another cubic mineral sometimes met with in rocks containing nepheline or leucite. The common forms are the octahedron and cube, or combinations of them.
The
crystals,
which
are of
by transmitted
light
form
aggregates.
They
purely microscopic
The larger
show none.
spinel,
crystals
which
is
smaller crystals
To
distinguish this
etc.,
chromite,
recourse
must be had
to chemical analysis.
Fluorspar,
Ca never occurs
F^,
met with
Sections
.of
The
mineral,
when
in thin sections,
The colour is due to the presence of some hydrocarbon compound, and may be disusually appears colourless or violet.
charged by heating.
cosmic
salt,
When
The
it
becomes corroded;
serves to distinguish
refractive index
Rock-Forming Minerals.
HEXAGONAL SYSTEM.
From
those
tlie
foregoing descriptions
it
will
many
We know
that
accompanied by contraction
In
the former instance,
in
tension
the crystal,
crystallization
strain
which surrounds
opposing forces
;
It
and,
when
expansion or contrac-
The
results of contraction
and
is
wholly
the
and
repulsions which
upon
it,
and
by the
{i.e.,
resistance
the repulsions
may be
com-
able to offer.
In such a
pression
irregular;
may be
which frequently
I20
Rock-Forming Minerals.
crystal,
surround a rock-forming
at a given time.
would more or
crystal
may
undergo irregular changes in its molecular spacing sufficient to produce an appreciable change in its angles, so that a cubic
crystal
may
as
The
optic
axis
coincides with,
it
or is
may
In
is
negative
in the
Crystals
sections,
both of hexa-
when the
preparation
is
On moving
the
interference-figure
If
we examine such a
for
section
we
to
of
twinning or
of
strain
account
these abnormal
phenomena.
CrrapMte,
in slates
0,
shales,
is chiefly
met
and
and occasionally
and
gneiss.
It
but
and often as
dusty
matter.
The
crystals
Rock-Forming Minerals.
sections parallel to
tlie
base,
in directions
Graphite
light,
is
opaque ;
it
planes of cleavage or
will soil
it,
as if with
should, however, be
remembered
and manganese oxides also soil paper ; but a of the powder scraped from the rockj and submitted to
Hematite,
Fe^
Og,
is
met
known
In the
latter, it
occurs in rhombohedra
usually
much
and
forming six-sided
rhombohedra appearing
from
their brilliant
Such
crystals,
me-
lustre,
are
known
as
specular
iron,
or iron-glance.
When
They
When
appears merely as a pigment, forming more or less transCrystals of iron-glance, too thick to be termed micaceous,
lustre
by reflected light, they exhibit a metallic and appear black or greyish-black, but show a somewhat reddish tint, or, where scratched, a bright red earthy,
are opaque, and,
reddle-like streak.
122
Rock-Forming Minerals.
Hematite
is
common
constituent of
many
rockSj
and
fre-
iron,
which often
becomes converted
especially in the
into
sesquioxide,
vicinity of joint-planes.
may
be procured
by
Carnallite,
which owes
its
Ilmenite,
Fe TiOg, occurs
may
fre-
and have a
metallic lustre.
bear the same kind of relation to the larger crystals that micaceous hema;tite, or iron-mica, does to iron-glance or
specular
iron.
These
The mineral
also
it
The de-
composition-product, which
termed leucoxene,
is
a granular
substance which
though
strong
double-refraction.
By
In a
Rock-Forming Minerals.
crystal, see,
therefoi-e,
123
by
and the latter of unaltered ilmenite. Sometimes the decomposed areas appear irregular ; and, when
entire crystal
is
the
yellowish-white
The
distinguish ilmenite.
now regarded
The brownish
been found by Cathrein to result from a mechanical admixture of rutile (sagenite), the latter mineral originally occurring
in the ilmenite.
many
Calcite,
Ca CO3,occurs
the
rhombohedron |R
artificially
or
tt
(0112).
A similar structure
shown by Reusch's
may
well-
be
produced in
calcite, as
known
now very
In most instances
colourless
;
and
but
it is
124
is
The Owing
and negative;
does
to
be recognised
by removing the
may
These minerals
also
show
cleav-
though very
no means of distinguishing them from one another. In limestones of oolitic character, the small spherical
line aggregates
crystal-
show a
radial
and exhibit a dark cross when viewed between crossed Nicols in parallel polarized light. Fluid lacunae and enclosures of other minerals, usually also carbonates, are comstructure,
mon
in calcite.
calcite is
an
and as a cement
origin or not,
is
in breccias
and
;
tuffs,
whether of pyroclastic
also
very frequent
and
it is
common occupants of the cavities which are so plentiful in many lavas, the amygdaloids, when not chalcedonic or zeolitic,
being generally calcareous.
as
In
all
it
must be
sili-
attributed
more or
decomposition of
and
it
is
Pseudomorphs of
Rock-Forming Minerals.
those rich in lime, are often met with
;
125
thgse, together
and
In other
of
we have examples
as
sembles
calcite closely in
some
it
respects.
As
a rock constituent
crystalline
or
tt
(1011).
The importance
means
emphasized by Eenard as a
from
calcite.
Even
in
we do not
find that
developed rhombohedra.
common
as strongly
On
dilute
feebly
would dissolve
rapidly,
effervescence.
Another
often
seen in the
former.
An
very
common and
very variable]
show considerable
Apatite,
3 Caj Pg Og + Ca
it
is
a mineral of frequent
In micro-
126
Rock-Forming Minerals.
hexagonal outlines and, between crossed Nicols, appear perfectly dark during a complete rotation.
Sections parallel to
that
axis
is
to
or other of the
Nicols.
The prisms
As
is
a rule,
The double
refraction
negative
^and weak.
The absorption
The coloured
e,
varieties are
an unequal absorption
in small crystals.
for o
and
which
is
perceptible even
The
interference-figures afforded
by
basal
very irregular.
To detect apatite chemically in a rock, it is often necessary upon a tolerably large sample, as the crystals have a tendency to mass themselves together in certain spots. The usual molybdate of ammonium reaction, which gives a yellow crystalline precipitate, is the most satisfactory, while dilute sulphuric acid, added to another portion of the solution,
to operate
will yield microscopic crystals of selenite.
may be decomposed
in the laboratory,
to weathering.
common
in crystals of
This mineral
is
Uuartz,
Si Oo,
is
The
Rock-Forming Minerals.
well-developed combinations of the prism
and R
or^
more
ment of the
latter often
The faces, and rounded forms are very common. show signs of corrosion, which, when far advanced,
magma
frequently
con-
met
It
what
is
known
as
micropegmatitic
structure.
is,
however,
common to
show
little
or
no indication of
Qaartz,
when
free
may
under the microscope, to be due to the inclusion of numerous These are usually of quite microscopic dimenfluid lacunse.
sions, the
movement
128
which
is
Rock-Forming Minerals.
latter
assumes the gaseous condition when the section heated to between 31 and 32 C. In Pig. 75 a, such a fluid lacuna is shown, w representing
the water, x the liquid carbonic dioxide, and y a bubble of carbonic dioxide gas. When heated to the critical point, the
appearance shown in Pig. 75 h will be visible for a second or two. This apparent ebullition is due to the vaporization of
the liquid carbonic dioxide, which, when complete, gives rise to one large gas bubble, as shown at y, Pig. 75 c.
In Pig. 75
a, it will
adheres to the water-surface, in preference to the wall of the cavity. The shading in the figures denotes the surrounding
quartz.
Minute
met
with in the
The
light, to
be 1'5441
and 1-5532
ordinary ray.
The double
refraction is
also give, in
In
now showing
the intersection of
The
optical sign
may
also
be recognised even
in the ex-
In
sections of crystalline
schists,
the
quartz
frequently
show
when examined
in polarto
ized light.
In such rocks
it is
also
by no means uncommon
ranged in more or
may be
seen to follow
129
of consecutive
number
orientation.
This
phenomenon may,
as
At times
of
these parallel,
sati;ie
or approximately
may be
traced in the
direction.
crystals, indicative of
stresses in
differs
differs
its
specific
gravity,
is
2"65.
habit and
systems, but
The cleavage
refraction.
somewhat resemble
one crystal
sections,
or
The larger
in a peculiar
been found
to
to depolarize
the base in
It
viewed in
on cooling to
its
anisotropic condition.
The conclusion
is,
130
Rock-Forming Minerals.
abnormal tension, generated during their high passage from the temperature at which the tridymitein a condition of
by those rocks on
cooling.
Tridymite
is essentially
Mont D'or
in the Auvergne, of
It has also
been observed
in
Chalcedony,
SiOg, has a
silica.
regarded as a mixture
of
Chalcedony
is
of
common
basalts, etc.
In such rocks
it
also
appears
micro-
frequently,
normal
constituent
It also
of
their
felsitio
ground-mass, or base.
less
more
or
examined
a
in parallel
polarized light,
is
show a dark
cross, and,
;
when a quartz-wedge
fall
in colour being
wedge
passes.*
Rosenbusch appears
as, possibly,
to regard chalspecies,, of
a distinct
is
doubtful.
Nepbeline,
SNagO,
occurs
in clear
Rock-Forming Minerals.
hexagonal prism
(0001),
00
131
or (lOlO)
occasionally modified
pyramid.
In this species
is also
plutonic rocks.
The
latter
The
and
to the
elseolite
more often
;
to
be seen in sections of
undergone.
elseolite is
The
refractive
and they become more marked which the crystals have index both in nepheline and
;
and sections
of these
minerals, consequently,
show
little
or no irregularity of surface.
The
dark, in parallel
polarized
Nicols.
light,
In convergent polarized
;
dark cross
is
to
be
axial interference-figure
visible,
but
it
generally appears
is
more
or less deformed.
The double
and
refraction
negative.
common
in nepheline
elseolite,
Nepheline and el^olite are easily decomposed, and consequently they are often only represented by pseudomorphs.
zeolites,
which
latter
unaltered.
tephrites
tes-
132
Rock-Forming Minerals.
2CaCo3+3H20.
more or
less
When
;
sections
containing cancrinite
are
heated, Cohen has found that the mineral becomes turbid and
opaque
and
means of
heated in
distinaeids,
When
its
In
unaltered condition
due to
Tourmaline. 311^
The
The composition
present.
greatly in colour,
indigo-blue,
while
is
rubellite
variety, schorl,
The
crystals are
tt
00
E,
(1010) and R,
(1011) being
common
;
forms.
Basal sections
The
by
is
cracks.
By
transmitted
j
violet tint
often to be seen.
The
coloured varieties.
greatest absorption.
as pointed out
by Eosenbusch,
we
meet,
among
rock-
differences.
many
Schists,
Syenites,
becoming
Rock-Forming Minerals.
'
133
la such cases the schorl frequsntly appears to have segregated in small nests and irregular aggregates of crystals. Chlorite Cfroup. In this group are included Ripidolite^
Clinoclore and Pennine.
all
The
crystals
due
to the
of different orders.
The
and the
Although well-formed
crystals
can
hardly be considered
in irregularly-bounded
met with
The
irregu-
boundaries
may perhaps be
commonly
attributed to the
crystals very
exhibit
more or
less
irregular flexure
this
of such thin,
bent, platy
In
owing
to separation of the
and the
little,
divergent,
may
definite
is
then
134
may
In thin sections and cleavage plates the minerals of the chlorite group nearly always appear green by transmitted
light, the colour
The double
in the
refraction
ranging from pale to deep shades of green. is very feeble, and its sign varies even
or
cleavage-plates and scales,
light,
same mineral.
sections,
Basal
when
ex-
amined
feeble
in parallel polarized
appear either
perfectly
owing
double
refraction.
In convergent
clinochlore
thick cleavage
plates
of
show a good
is visible,
polar rings.
which,
opticre-
on rotation of the
up
into hyperbolae.
The
cross
in convergent light.
lie
The
seldom
clearly
The members
Itis
is
of
this mineral
from Zermatt
= greenish-blue
viz.
and
= orangeas
yellow.
greenish-blue,
light, separates
same
on
Rock-Forming Minerals.
The
but
clilorites
^35
may be regarded as isomorpbons mixtures of 3(Mg,Fe)0, 2Si03 + 2H20 and 2(Mg,Fe)0, (A.l3,Fe3)03, SiOs! + 2 H3O in
the proportions of 3
:
2 to 1
2.
Heated on platinum foil, the chlorites part with water and become opaque, frequently changing their colour to reddish brown or black.
These- minerals decompose in acids.
They
may be
most common
other times,
it
TETEAGOWAL SYSTEM.
What
ters of
Rutile.
TiOo.
first
prism of the
order, 00
00 (100), the
pyramid of the
first
order,
(111)
and
00 (101).
The
face, or
K>^
Fig. 76.
face,
00
(301), a repetition of
giving
136
Rock-Forming Minerals.
on the plane (301) show kite-shaped eections, Fig. 77. The crystals of rutile met with in rocks are usually of exceedingly
small
formed.
Larger
crystals
Fig. 77.
oo (101),
intersect at right
The
known
as sagenite (from
a net).
may
some-
iron, as in
clearly
The double refraction of rutile is positive and very strong, and the surfaces of sections consequently show their irregularities very strongly
under the microscope.
tions
Minute
to
when
of moderate
thickness
is
impossible
mena.
Rosenbusoh
made out
ray.
in sections of
medium
Rock-Forming Minerals.
In convergent light, owing to twinning,
tlie
137
interference-
rutile is
well-marked and
renders
it
or Sonstadt's solutions
from most of the other rock constituents. In syenites, amphibolites, gneiss, and various
schists rutile is of frequent occurrence.
like crystals so
crystalline
were
found to be crystals of
form,
rutile.
Anatase.
It differs
Ti O^.
from
Common
or (111),
generally
occurs as an alteration-product.
rutile in
having a lower
The habit
of
The pyramid
com-
The
basal.
The
= 2'554, e = 2"493, is
nearly
The doable
refraction is negative.
show a system
latter,
ism
is
By
different
colours in the
same
crystal.
Anatase
rocks, also
is
met with in granites, diorites, and other eruptive in gneiss and in many sedimentary rocks of various
for the study of this mineral is the
geological ages.
good rock
well-known
138
Rock-Formtng Minerals.
in hydrochloric acid
in
zircons, tourmalines,
and other
minerals.
Tinstone.
the forms
SnOg.
Poo
Crystals are
(101), 00
(111),
is
of
Twinning
tinstone
parallel to 00
00
(100),
and
is,
as a rule, invisible
in microscopic crystals.
by Rosenbuch,
rutile.
The double
and strong.
By
yellow,
brown, or reddish-brown.
By
The
satisfactory,
and frequently resemble those of biaxial crystals. Tinstone occurs chiefly in gneiss and granite, especially near
slates.
It
is also
a frequent
Zircon.
ZrOg SiOo.
(100), the
The
crystals are
commonly combina2nd
order, 00
P 00
pyramid of the
(HI) and
faces
P3
(311).
The prism
The cleavage
parallel
toooP
* " Memoirs of the Geological Survey," " The Iron Ores of Great I., 1856, p. 95, where an analysis of Cleveland Ore by Mr. A. Dick will be found, with an account of the anatase, which amounted
Britain," Part
sample analysed. the f Tor further details concerning the mode of occurrence and microscopic characters of tin-bearing rooks, the student may consult " Cornish Tinstones and Tin Capels," by J. H. Collins a series of papers originally published in the Mineralogical Magazine.
to about 0*03 per cent, of the
:
Rock-Forming Minerals.
seen in basal sections of the larger crystals
the prism of the
;
139
that parallel to
2nd order
;
is
is
The double
refraction is positive
by broad, dark
crystals
The microscopic
and
in the
larger crystals
not at
all
perceptible.
common
in crystals
of zircon
and
fluid, gas,
also frequently
seen in them.
may be washed
is 1
When
crystals of
Zircon
granites,
syenites,
and in such cases the enveloping mineral sometimes shows a distinctly pleochroic border around the included zircon.
Microscopic crystals of zircon occur plentifully in the Lower
first
"On
May, 1887,
140
Rock-Forming Minerals.
Scapolite essentially consists of silicates of alumina, lime, and soda, often with some NaOl; but it is of very variable
composition.
As
a rock constituent,
it
generally appears in
definite
irregularly-shaped grains,
crystalline forms. It
is
navian gabbros.
crystalline schists,
It is chiefly
met with
in gneisses
and other
and in the limestones associated with them. In the latter the mineral is usually well crystallized, the crystals
being combinations of the prisms of the 1st and 2nd orders with pyramidal terminations ; but these last faces are not generally well developed.
is,
The cleavage
parallel to 00
00 (100)
as a rule,
well-defined,
particularly
in slightly
altered
crystals.
The double-refraction
by ordinary transmitted
is
on the surfaces
perceptible.
of sections,
when mounted
In convergent
show a sharply-defined
and
dichroite.
is
Meionite, which
Somma, Vesuvius. Idocrase is a lime-alumina silicate of variable composition, and containing a small percentage of combined water and usually some iron, mostly as sesquioxide. The crystals are
fully in the limestone blocks of
met with
in them.
The cleavage
is ill- defined.
colourless,
Rock-Forming Minerals.
yellowish, greenish, or rose-red
141
light.
by transmitted
More
The
feeble,
refractive index
strong
The double
refraction
is
In perfectly colourless
uncommon
which some cases are found to vary in their optical sign, some being positive and others negative. The double refraction of
Idocrase
is,
In convergent light
interference-figure,
show a peculiar
In
The
pleochroism
is
weak.
stones.
Melilite, 12CaO, 2AI3O3, QSiOa often with alkalies (3 or 4 per cent.) or magnesia partly replacing the lime, and some
sesquioxide of iron replacing part of the alumina.
The basal
rule, poorly
planes are
crystals of melilite
form of irregularly-bounded
By
of
or brownish.
The more
Capo
is
The
refractive
index
weak.
quently low
down
142
Rock-Forming Minerals.
to the colourless, or feebly-coloured character of the
Owing
A curious
structure
is
is
and arrangement.
are seen
In sections
parallel
striae
cracks,
From
these, lateral
The pegs do not pass quite halfway across a band of unstriated or unpegged crystal is
This has been termed peg-structure
by
Stelzner.
Melilite
is
believed to be a zeolitic
or peg-like
fine, fibrous
(i.e.,
fibres occasionally
An
alteration
been observed.
The mineral
BHOMBIC SYSTEM.
In
this system, as already
elasticities to
be recognised;
mean, and
least;
and
the
three axes
of elasticity
One
all
of these axes
colours,
the
common
Rock-Forming
Minei'als.
143
and
be the axis of
but
if it
be that of greatest
The
axis of
mean
angles to the plane in which the optic axes and their bisectrices are situated,
and
it
is
normal.
been
be
show no interference-figure
in convergent light
under
such circumstances we
elasticity.
know
mean
inter-
On
the section
is
show an
ference-figure,
we know
that
it
we have
is
to determine
lies at
when the
section
is
in the
normal position.
elasticity, it is
evident
that the narrow bar of the cross corresponds with the axis of
greatest elasticity
if
correspond
it is
in
with
the
three
crystallographic axes,
respectively parallel
result
also
to
those
edges
coids, or to
The
interference-figures of
144
to
Rock-Forming Minerals.
lines
two
this
and bronzite.
R = Mg
known
short-
as amblystegite.
The
crystals of the
prismatic habit.
and
intersect at
cleavage's,
commonly traversed by
much more distinct cleavage parallel to the brachypinacoid, Occasionally very imperfect cleavages parallel 00 Poo (010).
to the taacropinacoid are also to be detected.
In
sections
lie
The
by irregular cracks
the vertical axis.
by transmitted
which
The
varieties.
The double
refraction in enstatite
and bronzite
all
is is
but in
cases
ifc
145
higher than red of the 1st order, while those of enstatite and
bronzite,
do not
rise
The
c=>t,
vertical axis is
a,
&
= 6,
The
ferriferous varieties
Owing
must be measured
for the
elasticity,
the dis-
p>v
more
ferriferous varieties,
and
p<u
for
The pleochroism,
ferous bronzites
is
also,
less ferri-
more marked
Sec-
changes
(" Schillerization
"
of Judd),
common
The pleochroism
Owing
and
age
enstatite
(ooPoo),
show no
light.
definite
interference -figure
convergent
polarized
norite, gabbro,
They
in
alteration of
In Figs. 78 and 79 the mutual relations of the crystallographic axes, the optic axes, the axes of
elasticity,
and the
L
146
tite
projectionj
78
representing
enstatite,
and Pig.
hypersthene.
In these figures a = a
fusion,
=6
and
= tj
being omitted.
I.
Pigs. 78,
and
79, I.
show the
and hypersthene
respectively.
^
"i
Rock-Forming Minerals.
tion
147
by
0,
Fig. 78,
I.
in this figure
The
are indicated
on the macropinacoidal
greatest elasticity,
a, is
Here the
axis of
x
a
6 C
= = =
a b
C
II
148
toxide of iron.
Rock-Formwg Minerals.
It is essentially
an altered condition
is
of en-
statite or bronzite in
small.
is
Hence
it
must be regarded
pseudomorph.
The form
that of enstatite
irregular plates
and bronzite, but it also frequently occurs in with a more or less fibrous structure. The
cleavages characteristic of enstatite and bronzite are also present in bastite, that parallel to the brachypinacoid being even
and the
commonly
a metallic
and show a
fibrous
granular bodies,
many
the
The
are parallel
and
and
to
If
such
lie
at 45 to the principal
it will
be seen, on inserting a
'[i.e.,
if
wedge], the red of the 1st order in the latter being seen, where it overlies the bastite, to be faulted into the region of
the
If
we
an interference-
macropinacoids and a
shall
is
the acute
bisectrix
or
rather,
we
see
the
dark-crossed
bars
of the interference-figure,
we can thus
and
The
Rock-Forming Minerals.
149
of the
fibres,
is
shows that
them
an axis of
less elasticity
but
in this case
a is
The acute
bisectrix
consequently normal to the planes of cleavage. The angle of the optic axes in bastite varies from 20 to nearly 90
is
p^v.
too feeble to be detected in any but thick
is
The
and
the brachydiagonal
Fig. 80, the
numbers
II.,
and
150
On comparing
see that,
owing
the optic-axial
convergent
light, in
is
When we
know why
this
we can
and
since, in
some
ing rocks
may have
temperature, and
other causes,
conjunction with
may
chemical constitutions of
family, but
members
may
also
how
individually or conjointly
concerned in effecting the change in the position of the opticaxial plane in bastite, has yet to be explained.
From
in rocks
its
is
of
common
in serpentines.
Rock-Forming Minerals,
Rltombic Amphibole Crroup.
Of
SiOe.
tliis
151
:
eedrlte,Mg, Ala
and horn-
AnthophylUte, (Mg,
Both
being
blendic schists.
faces
oo
is
The
prism (110)
The
to
crystals never
coid, 00
Poo
by the thicker
strokes,
z,
in
xP
(110).
parallel
to the brachy-
pinacoid,
P 00
(010),
may
likewise be
detected, as a rule;
but this
The
crystals also
Fia. 81.
frequently
show a tendency
(001),
By
152
Rock-Forming Minerals.
and sometimes
of a
reddish-brown colour.
The double
and, as
it
refraction
may be
either
and
is
The
directions
of
maximum
ex-
rhombic
crystals, parallel
and at
or to
the edges
faces.
The
macropinacoids
owing
to
it
is
necessary, in
many
cases, to
oil,
make
the observation in
oil,
the
apparent angle in
sometimes as
much
47.
The dispersion
t
being stronger in
tions parallel to
some examples of gedrite to The pleochroism also varies, the deeper-coloured specimens. For vibravaries.
the colours
greenish to
c<;a = 6.
common
in
Lamellar inter-
common.
gent
light,
by a
M indicates monoclinic
bic amphibole.
amphibole, and R,
lamellae of
rhom-
Rock-Forming Minerals.
153-
microscope.
(bisectrices) seen in
represented,
figures in
cated
by the dotted
lines
N N,
N' N',
If the
Fig. 82.
would separate into hyperbolae. Fig. 82a, while the dark bar
in the middle disc
nally across the field and out of view, leaving only the rings
visible. Pig. 826.
chiefly
hornblendio gneiss.
They
also occur
serpentines which
Olivine.
(Mg, Fe)
SiO^^.
SiOg.
The proportion
of iron to
mag-
becomes Fcj
stituting the
in combi-
nation are the prism 00 P, the macro- and brachy- pinacoids, con-
rectangular
P 00
and
00
P 00,
154
00
Rock-Forming Minerals.
the
P2 and
doma
planes
P oo, P oo
and 2P
oo.
Basal planes
of the crystals
The angles
the
by
the action of
the surrounding
magma
rounding pro-
been carried so
far that a
rounded grain or
crystal-face can
be
detected.
common
occur,
in certain rocks ; and in the glassy basalt of the Sandwich Islands exceedingly beautiful crystallites of olivine
many
of
of
them
some
The
and which
closely
x250
Fig. 83.
Cleavage
P oo
(010),
and
also
be seen in
Traces of
oo
macropinacoid
P oo
(100),
oo
(110)
may
also be occasionally
detected.
The
by
irregular
fissures,
often strongly-defined.
The highly
Rock-Forming Minerals.
155
while, occasionally,
are
red or
reddish-brown.
Owing
rough aspect.
The double refraction is ezceedingly strong, and is positive and the colours seen in polarized light are also strong, being usually of the 2nd or 3rd order. The optic-axial plane lies parallel to the basal planes and
;
is
is
c,
which also
a,
and
consequently 6 = 3 and
parallel to the
as
shown
in Fig. 84.
Sectiona
light, give
macropinacoid
will, in
convergent
X
5-^
I
/9A
6.a
a=c
\.
Fig. 84.
The
optic-axial angle
is
The
dispersion
weak, p <
v.
The
pleo-
chroism
is feeble,
even in
fayalite, in
156
Rock-Forming Minerals.
If sections of
in iron,
colour,
is
and become more or less pleochroic. One of the most common changes to which olivine is its conversion into serpentine. The process begins
fissures,
at the
more pronounced.
The
incipient
change
marked by the
crystals.
place,
or limonite.
As
the alteration
serpentine
of chrysotile
or fibrous
now
show
Fig. 8&.
is
is
the result.
In
olivine
can
still
like structure.
With some
in
serpentines
practice this may often be detected which have resulted from the alteration of
Eeplacement of
olivine
by other
Rock-Forming Minerals.
minerals
is
157
In olivines rich in
in such cases
it
which frequently
crystalline
Eemarkable
schists,
changes
also
occur
in
certain
amphibole group,
Cases have
which
chlorite
olivine
crystals
have been
converted into an
aggregate of
small
amphibole crystals,
and magnetite.
Topaz.
5 Alg Si O5 + AI3 Si
the prisms
00
P;iq.
The
combinations of
00
(110),
brachydomes 2 P
basal planes
(021),
oP
The cleavage w (Fig. 86), which is parallel to the base, is and well-shown. Microscopic sections of topaz are transparent and always colourless. The double refraction is
perfect
positive,
brilliant
light,
although
in thin
are rather
first
weak
order.
The
axis c
and
The
ranging from
is
70 to 120,
Even
weak
in thin sections
imperceptible.
158
figure in
Rock-Forming Minerals.
which the dispersion
is
seen to be
p>v; and
the
Inclusions of
common
in
met with
Rock-Forming Minerals.
of dichroite are often twinned
aragonite.
159
same manner
and
-as
much
in the
When
II.
;
In
but in
also
may
II
i6o
Rock-Forming Minerals,
when the
vibrations are parallel to the
Basal sections do not show this phenomenon. vertical axis. The pleochroisin of dichroite sometimes becomes more distinct when the mineral is heated but this, in thin sections, occa;
Finite, chlorphyllite,
and
owe
Some
of these
and
limonite.
^oisite,
Hg
occurs
either in individual
usually 00
(110), with
00 (010),
Terminations are
ooP2 (120); qoP4 rare, and when present they of P (lll)j and 2 P oo (021).
and the showu
which
it
Rock-Forming Minerals.
transverse fission parallel to the basal planes, which
is
r6r
some-
what
irregular.
Some
varieties (Thulite,
tain manganese.
The
The refractive index is high, and" consequently upon the surfaces of sections appear strongly
plane sometimes
lies parallel to
defined.
The
others
opfcic-axial
the brachy-
pinacoid,
as
shown diagrammatically
in
Pig. 88,
while at
it is
In either
Fig. 89.
is
is parallel to,
In the
first
instance,
is
parallel to (010),
a = C, h = \,
it is
The
l62
Rock-Forming Minerals.
air.
almost 0 to 100 in
coid
(]
Sections parallel to
tlie
macropina-
give an interference-figure in convergent lignt wtich exhibits very strong dispersion. This, in cases like that
00)
shown
in
Fig. 89
p>v.
displays peculiarities in twinning,
of
Zoisite
sometimes
which the student will find .a description in Rosenbusch's " Mikroskopische Physiographie " (2nd ed., vol. i., p. 421).
Lamellar twinning
is
also to
be seen in
this mineral.
It is
met with
chiefly,
how-
ever, in amphibolites
schists, also in
eclogite.
phyrite,
known
as porjido-rosso-antico.
of included quartz
together
with
carbonaceous
matter,
kyanite, tourmaline,
mica and
The microscopic
for the
crystals,
however,
are,
most
part,
much more
crystals
ai'e
free from
impurities.
The
commonly
oo
P
oo
(100), (010),
with
Fia. 90.
brachypinacoids
oo
P (001). Macroand basal planes domes P 00 (101) are often present, but
they are usually very small, and are by no means of conA platy structure parallel to the base is stant occurrence.
sometimes seen.
planes f Poo
(032),
fPf
(232),
occurrence even
in microscopic crystals.
Rock-Forming Minerals.
parallel to (010)
indistinct,
163
and
perceptible.
is
The
colour
by transmitted
light
reddish-brown, or
yellowish-brown.
and the surfaces of sections show their irregularities distinctly. The double refraction is positive and strong, and
the colours seen in polarized light are vivid.
00
The Poo
optic- axial
plane
lies
parallel to
the macropinacoid
also
(100),
c,
and the
vertical
axis
c,
axis
of
least
is,
elasticity
is
The
optical
scheme
therefore, a = 6, &
= a,
is
=c
but
(as
shown
in Fig. 90).
The dispersion
chiefly in
feeble
is
and p>v.
schists,
The pleochroism
is
distinctly perceptible,
rather^ feeble.
Staurolite occurs
the
crystalline
especially in
mica-schist
and
gneiss.
The
crystals
are
sometimes so
imperfectly
Andalusite.
Al^ O3
SiO^-.
The
com(001),
planes.
it is
little is
more
rarely,
crystals,
to a
Some
is
parent,
The
is
refractive
index
The double
refraction
negative
in
and weak, and the colours seen in polarized light are low
the
first order,
as giving an important
means
of
distinguishing
lies
andalusite
from
sillimannite.
in the brachya,
which
164
graphic axis
c,
Rock-Forming Minerals.
is
the
acute bisectrix;
consequently a = t,
and 5 = 6, as shown in Fig. 91. In Fig. 91, III., the optic axes are repeated, in order that their emergence on the basal plane may be shown, since it is the basal section which is normal to the acute bisectrix a,
and, in this section, the interference-figure will be seen in
convergent light.
The
optic axes
Fig. 91.
also
on the macropinacoidal
;
section,
to
bisectrix c is normal
polar rings
angle,
is
greater
by
The
optic axial
2y = 83
to 85. of andalusite
is
The pleochroism
for
most
In thin
sections,
Crystals of andalusite often contain carbonaceous matter and inclusions of other minerals, particularly mica, as well
as fluid lacunae.
Rock-Forming Minerals.
ChiastoUte
is
165
and some of the less crystalline schists. The peculiar markings to which the mineral owes its name, though originally regarded as slaty material, are now considered
also
met with
in mica-chist, gneiss,
by Rosenbusch
to
W.
Miiller,
as the
surrounding rock.
of the larger
crystals, especially in
specimens, which frequently present no crystalline form, occurring as elongated fusiform bodies, somewhat resembling
transversely.
Fig. 92.
good example from the slate occurring close to the Dartmoor granite near Okehampton, in Devon, is shown in The small crystals usually Fig. 92 (magnified 250 linear).
* "
Neuea Tarbucb,"
1888, vol.
i.,
pt. 2, p. 175.
66
Rock-Forming Minerals.
andalusite ; indeed, apart occur in forms similar to those of from the symmetrically-disposed. inclusionSj chiastolite diflfers
Andalusite These minerals pass, by alteration, into kaolin. into fibrous and scaly aggregates changed of. also becomes
muscovite or
sericite.
jgiUimannite,
thin
AI3 O3 Si O^, occurs chiefly in extremely and needle-like prisms, often appearing of excessively
The most
common form
angle of 111.
Pinacoids
is
(110), with an
are
occasionally
developed
to
but
the crystals,
show them.
Fine
striation,
The cleavage
is parallel
also trans-
wide
intervals.
is
Sillimannite
colourless
when viewed by
is
ordinary trans-
mitted light.
The double-refraction
= c.
= 3when
a prism of
sil-
light,
its
is
inserted, also
the blue of the second order, for instance, appearing in the lower region of the first order, or close to the thin edge of the quartz-wedge.
In andalusite, which is optically negative, the effect would be reversed, so that we have, here, a means of distinguishing
Rock-Forming Minerals.
this
167
of the latter
light,
sections
showing
an
interference-figure
in
convergent
the
and
Pleochroism
Sillimannite
is
is
and other
Fibrolite
crystalline schists.
common product
By
alteration,
IVatrolite (Mesotype). Na^ Al^ Sig Oio + SHjO. The crystals are commonly combinations of 00 P (110) and P (111) ;
frequently,
with brachypinacoids,
it
00
P 00
(010).
In
thin
sections of rocks
which
show a dark
and
maximum
which
is
also the
The
in the
is
brachydiagonal section
positive,
and a = a,
is
fe
= b,
= c.
The apparent
is
optic-axial
angle in air
cleavage
crystals.
is
p<v.
The
prismatic,
but not
perceptible
in
microscopic
Natrolite
is
essentially
decomposition
product
after
etc.,
and
An
interesting study,
by M. Laoroix, of the
association of silliman-
from Ceylon, will be found in the " Bulletin de la Societe S'ran5aise de Mineralogie " t. xi. p. 150, the A section tangential two minerals having crystallized simultaneously. to the obtuse angle formed by the prismatic cleavages of the andalusite shows three orientations of the included sillimannite with reference to c parallel to c, c at 90 to c, and c at 45 to c. The the andalusite, viz. same author also mentions a similar association in specimens derived from Morlaix in Brittany.
nite with andalusite, in a specimen
:
68
to be
Rock-Forming Minerals.
met with
in volcanic
is
Talc,
in scales, which,
seen edgewise in rock-sections, bear a resemblance to fibres or in thin plates with rounded or hexagonal boundaries, the
latter resulting
(001), with oo
(110),
and
00
Poo
The
The cleavage
of talc
is
normal or oblique
By
transmitted light
it
appears colourless.
is
The index
of
refraction is low.
The
double-refraction
negative, very
high.
The
optic-axial plane
is
and
is parallel to,
crystallographic axis;
axial angle
is
hence, a=ij, h t,
= a.
The
optic-
rather small.
Even
convergent
light, only
The
The
flesh-coloured
blowpipe-reaction,
when
talc is
from muscovite.
Talc
and other
magnesian
silicates,
but
it is
Rock-Forming Minerals.
ia eruptive rocks.
It;
169
is
chiefly
notably in talc-schist.
Anbydrite,
Ca SO*, The
P
crystals
are
and
the
basal
planes.
Generally,
however,
anhydrite
occurs
lamellae
Twin
By
The
lies
is
double-refraction
The
optic-axial
plane
in
the
is parallel
to the brachydiagonal a.
plates, parallel
Cleavage
to
The apparent
2E = 7r 10'to7r20'.
Anhydrite very commonly becomes altered into gypsum by taking np water. Aragenite, Ca CO3, sometimes occurs as an alterationproduct in certain eruptive rocks. Under these circumstances, it is chiefly met with in crystalline aggregates, which
In
by ordinary
is
transit
also
shows no pleochroism.
very strong.
section,
The double
refraction
negative and
The
6
Hence, a = li,
= c, c = a.
In convergent
show an interference-figure, and, in large crystals, sometimes The optic-axial angle 2V=]8 for two, owing to twinning.
sodium
light.
170
MONOCLINIC SYSTEM.
The
only.
crystals of this system are symmetrical to
one plane
Cleavages
may
to this plane of
symmetry ; but
be equally perfect.
Cleavage
may
and
to the
orthodomes.
direction
Each of these cleavages takes place in a single onlyj and they are consequently termed moTwtomous.
Monoclinic crystals
may
also present
make
We
may
Pinacoidal
ooPod = 010
co
ooPoo = 100
oo
OP = 00L
Orthodomous P
= iol
2 P
= 201.
00
P = 110 and
110.
The pinacoidal planes of cleavage cut one another in such a manner that those parallel to 010 and 100 intersect at right angles on the basal pinacoids; while those parallel, 010 and 001, intersect at right angles on the orthopinacoids, or on The cleavage-planes parallel sections parallel to those faces. to 100 and 001 intersect upon the clinopinacoids at an angle
corresponding with the inclination of 001 to 100, this angle
intersect
to,
upon
the
basal
less
but somewhat
;
while
Rock-Forming Minerals.
angle of intersection will be precisely that of the prism.
171
The
of which
(p.
mono6,
or axis of symmetry,
lie
in the symmetral
If the axis of
mean
elasticity 6
= 6,
axes and their bisectrices will be situated, and also be dispersed, in the plane of symmetry.
sion
and the optic axes would be have a symmetric position, as shown in Fig. 45, p. 80.
inclined,
If,
would be
on the other hand, either the acute or the obtuse bisecwith the orthodiagonal, the optic axes will then
trix coincide
lie
46, p. 80,
and
47,.p. 81,
when,
if the
dis-
would be said
to
The
sections
first
work.
The minerals of
bounded
In
this,
this
and aggregates
of,
of crystals
and grains.
crystals
and grains of
172
be understood that
common occurrence
.
ooPoo (100)
(111)
-P
is
and OP
(001). 1
Twinning
00
.
(HI)
it is,
In such,
numerous twin-lamellse are frequently visible, runningwhich is also the plane of 010 has twinning. Fine striation parallel to the edge 001
parallel to the plane of composition,
:
pyroxene in the
Whin
1
Sill
of
Tyne Head,
two
74
in which,
owing ta
00, the
sets of striae
meet chevron.t
and 75
= the angle
/3)
Twinit
generally
many
The two types of twinning just mentioned are occasionally seen in the same crystal; the latter type is especially frequent in diallage and diopside. A less common type of twinning is on a face of the hemiorthotwin-lamellation parallel to
(001).
OP
dome-Poo
(101).
is
A
but
zoned structure
this is not
often
met with
an^
'
by the help
173
The zones
differ slightly in
chemical com-
position,
owing to isomorphous
substitution.
A peculiar struc-
is now and then seen in augite crystals, which is known as " the hour-glass structure.'^ Such crystals show four fields in
ture
colours.
The
is
direction of
maximum
nate fields
somewhat
This structure
subsequent
Fig. 94.
The cleavage
consequently
87
6'.
is
parallel to the
oblique-rhombic prism
F (110),
the
that at which
The cleavage-planes
axis,
therefore
in
another
vertical
their
show parallel fissures which are parallel to the vertical axis and to edges formed by faces of the prism with one another, and with the ortho- and clino- pinacoids. These cleavages are,
however, seldom so well defined as in hornblende.
crystals
In those
which
174
there
is
Rock-Forming Minerals.
generally a very distinct basal fission, which must
By
pyroxenes
may appear
tint,
brownish
The
diflferent
by Rosenbusch, even
same rock,
may be
detected in pyroxenes
And
he
and
alkalies,
and those
-of
poor in
alkalies,
An
when
examination
an
show how
The green
crystals,
artificially
heated,
In
all
high,
and strong.
The optic-axial plane is situated in the plane of symmetry. The inclination of the bisectrices to the vertical axis is very
variable, as also is the optic-axial angle
elasticity, i.e.,
;
cliiio-
The oblique
mum at
This
mum
Rock-Forming Minerals,
and
this
is
175
attributed to
now
it is
and alumina,
c
:
as in diallage
extinction-angle augites
it
For instance,
if
bisectrix,
if
normal to an optic
may show
to a bisectrix.
show
Pleochroism
is,
as
a rule, barely
yellow, or brown.
There
are,
however,
many
exceptions, as ia
etc.,
where a and
yellowish,
and for \
violet.
The
violet
and reddish-brown
colours
weak pleochroism
rally serves,
is
The
possible.
176
Pyroxene Group may be expressed by the general formula H" Si O2, in which K = Mg, Ca, Pe, or Mn. Alg and Fcj are
also frequently present
;
Kg
or Nag.
They commonly contain 5 to 15 per cent, of ferrous oxide. The crystals are long-prismatic in habit j and, in addition- to the usual prismatic and pinacoidal cleavages parallel to the vertical axis, they are generally traversed by strongly-defined
cracks, which cross the crystals at right angles to the vertical
axis.
of a ser-
This
is
and commonly
like
results in the
which
still
another,
In con-
and
and
this serves to
plane
lies at
the cleavage"
axial plane
is
due
to excessive
by basal cleavage-
planes.
etc.,
and
The granular
Diallage.
in altered
Rock-Forming Minerals.
seen.
177
As
a rule, diallage
it is
far less
Occasionally
parallel to the
met with
Tschermak
as 15
much
from the orthopinacoid (100). Diallage commonly shows a fibrous or rod-like structure.
is is
The colour
refraction
least
elasticity
vertical axis.
The
show one
I'hombic pyroxenes.
lamellae of
It is
These
when
light,
of sufficient
they show a
It
dark
cross,
must be remembered, however, that these are included crystals, and not cleavage plates. Diallage becomes altered into serpentine, frequently with some admixture of
is
This change
found to be con-
178
Rock-Forming Minerals.
varies considerably in chemical composition,
Augite
Si Oj with
times,
but
Al^^
Mg
Mg Fe^
is
there
molecule
Nag Fe^
Si4 Ojg.
and in
which show no
The well-formed
.
(110)
00
? 00
(010)
00
00 (100)
P (Hi)
are
-P
(111)
00 .(lOl)
and OP
(001).
Twin
crystals
common, and the twinning is upon a plane parallel to the Sections parallel to this face do orthopinacoid 00 P 00 (100). not therefore show the twinning, but in those parallel to the
clinopinacoid (010) and the prism (110)
it is
distinctly seen.
layers,
which
more or
less in composition
through isomorphous
crystals.
substitution, is frequently
cleavage
is parallel
to 00
The
(100)
but the
at
others very
When
planes,
is
about
can, thereto
be detected at a glance.
orthopinacoid
is
the
much
less
strongly
it
in
this cleavage
alteration
may undergo.
Rock-Forming Minerals,
that
diallage
is
179
augite.
by
or violet.
When
The double
refraction is positive
and sections
do the same.
The
relative posi-
Fio. 95.
shown
in Fig. 95,
the
common
in augite.
i8o
Rock-Forming Minerals.
zonal
structure is present, the optical characters
When
usually vary to
some extent
seen
is
the same for both mineralSj and they also have the vertical
axis in
common.
chlorite, epidote, greenearth,
and
it also,
being
termed Uralite.
crystal remains;
Augite
is
andesites, etc.
and
crystals,
Omphacite
eclogite.
is
inter-
common
vertical axis
differ in
Minute
as inclusions
in
omphacite.
Acmite
is
The
crystals,
when
perfectly
seldom seen in rock-sections, where the faces developed are P (110) and the orthopinaooid, oo P oo (100).
Clinopinacoids,
if
present, are
quite
subordinate,
but they
Rock-Forming Minerals.
are nearly always absent.
i8i
The
Sometimes the
The
The
P.
principal cleavage
prism
oo
By
reflected light
the crystals
appear
The double
lies in
refraction
is
very strong.
The
optic-axial plane
of the double
The character
it
is
regarded as
negative.
The
a,
trix, lies in
by the
vertical
and the
of
maximum
make an angle
is
8 to 10.
The pleochroism
is
very strong,
to yellow.
= dark-brown
to greenish-brown, b
= clear-brown
a>b>C,
= greenish-yellow.
The absorption
axis,
a lying nearly
This
Aegirine, which
is
closely related
somewhat from acmite in the pleochroism. a = chestnut The axis-colours brown, 6 = olive-green, i = grass-green.
here given for acmite and aegirine are, however, not invariably
met
often showing
different colours.
By
blackish-lrown.
l82
Although
forming
such as
Spodumene,
Lij
87;
Alg
Si^ Oi^,
occurs
as
an accessory
The
cleav-
to oo
an angle of
clino-
and there
is
pinacoid.
In optical characters
spodumene
resembles diopside.
By
alteration
peculiar changes
first
is
called yS
spodumene, which
In
Sij Og.
/S
spodumene
In sections of
spodumene cut
Fia. 96.
parallel
to
the latter
is
seen to be
due to
The alteration of spodumene into /Q spodumene results from an exchange of sodium for half of the lithium present in the
unaltered mineral.
Rock-Forming Minerals.
The next phase of
183
spodumene
in
other
/8
spodumene,
albite, the
is
and
In this a
when
the two
into
distinct
layers
of
crystals of micro-
Connecticut and Massachusetts, where crystals of spoduoccasionally been found measuring nearly four feet
mene have
and two
^^ollastonite,
seen.
The
axis
P (001) ; 00 P oo- (100) The forms chiefly developed are iP 00 (102) and -Poo (101). The basal planes dominate, from which circumstance the mineral is also known as table-spar. Twinning on the orthopinacoid is common, the basal planes then making an angle of
1
There
is
and a
less distinct
one
The cleavage-planes
in these
By
The
acute bisectrix
/3.
vergent polarized
light.
pleochroism..
184
It is chiefly
this
group the
crystals,
common, show,
of the
This
is
especially
common
and
microliths,
by side
may
offer
a rude approxi-
Among
common
forms
P
00
about 124
00
(010), the
pyramid
Qo
(111)
(001).
The clinodomes ?
(Oil) are also faces of very frequent occurrence; but the ortho-
uncommon, and,
consequently, sections of
more
This
is,
In the more
all
common
of the crystal and the two basal planes to the other, a phenojnenon very usual in cl-ystals of basaltic hornblende. Such
185
of delicate
no re-entering angles.
of the twin.
number
between the
seen in amphibole.
is
which
is
to the vertical
In
all
lie
in
iiO
will
110 and
As
to the
ing
to
In glaucophane, however,
Acti-
the colour
nolite
is
always green
basaltic hornblende
brown
or reddishis
almost
green to
The colour, however, may be changed from red or brown by heating, the ferrous oxide in the
ferric
oxide.
It
is
thus
that
the
when
the rock
is artificially
colour.
The refractive index of the monoclinic amphiboles is high. The double refraction is strong, and usually, but not invariably, negative.
it
is
notably positive.
86
The
symmetry.
The
The
lies
in the acute
the vertical axis, and makes with the latter an angle which
0 to 27 or more.
No
tween the chemical composition and the angle been satisfactorily made out.
has yet
The measurement
age-plates parallel to oo
(110)
is
necessarily
much
smaller
S 00
(010).
But an approximation
may
measured in a cleavage-plate
parallel to oo P.
Sections taken in the orthodiagonal zone give interferencefigures, entire or partial, in convergent polarized light.
If
if
normal
to the bisectrix,
normal to an optic
more or
Cleavage-plates parallel to
of rings lying near the
ooP
(110)
show a
single system
margin of the
field
of the polariscope
or microscope.
heated to redness
on platinum
foil.
The absorption
than for
a.
mono-
amphibole.
Amphiboles containing
little
or
no alumina.
a colourless variety of
Tremolite,
is
187
(110), usually
much
or never
split
by irregular transverse cracks. show any terminal faces, but either end abruptly or
into fibres.
up
Ordinary asbestus
is
is,
in fact, a variety of
essentially
and completely
The cleavage
larger
crystals
is
well defined
is
and
The double
refraction
strong.
Tremolite occurs in beds of limestone and dolomite, associated with crystalline schists.
In serpeatines
it
usually
Tremolite
it-
talc.
Actinolite
it.
Apart from
is
but
little
difference
and
tremolite.
actinolite usually
form divergent or
The crystals, in addition the prismatic cleavage, sometimes show one parallel to the
Like those of tremolite they never exhibit any
clinopinacoid.
in
dimensions,
some
noticeable.
The
it
is
quite distinct,
and yellowish-green
or
]>ij
and
6.
The absorption
is ]>l)l>a,
= a.
crystalline
schists, asso-
88
Rock-Forming Minerals.
and
it is
the
It is also a
common
met with
The emerald-green
variety
known
which
as smaragdite
it
is
in the saussurite-gabbros, in
frequently appears in
is
probably to be regarded as a
paramorph
It
is
not certain whether the so-called smaragdite in the o rock known as eclogite should be referred to actinolite or to
common
hornblende.
is,
The ^aie of China and the Pacific Islands ferred by Damour to smaragdite; but most
nephrite
is
in part, re-
of the jade or
tremolite or actinolite.
Hornblende.
position
of
other varieties,
formulae.
to express precisely
by means
of
Ca Mg3 Sii
Oi3
CaPe3Si4,Oi2
Common
by transmitted
brown
or
brownish red.
Fig. 97 shows the relation of the optic axes and axes of
elasticity
and
prismatic cleavages.
The
extinction angle c
c,
as measured in cleavage-plates of
common green hornblende parallel to the prism oo P (110), is 13 or more. In common brown hornblende it ranges from
13 to 0.
The pleochroism
is
very
distinct; frequently a
= yellow,
= brownish-green, c = bluish-
Rock-Forming Minerals.
green; in the brown, a = yellowish or greenish, i and
different
tints
189
t
of
brown.
The
pleochroism
is
generally
Fig. 97.
Common
gneiss, amphibolites,
and various
crystalline schists.
In some of these rocks the hornblende occasionally appears in a condition known as reedy hornblende " schiljige hornhlend."
Eosenbusch regards
this as
it
an altered or uralitized
to be
more
closely allied
common
hornblende.
Eosen-
some
in-
be developed by the splitting up of a crystal of ordinary hornblende through the partial conversion of the
crystal into chlorite along the cleavage-planes.
go
Rock-Forming Minerals.
occurs in well-formed
oo
(110),
oo5oo
(010),
(ill),
and
(001).
At
them.
magma which
surrounded
is
in these crystals
strongly
by transmitted light even very thin sections appear of a deep brown or reddish-brown. Occasionally they show zonal growths of alternating green and brown colours. The pleochroism is
reflected light they look black;
marked.
By
= dark-brown. The
c
:
abc
c>ii>a.
The oblique
nil.
extinction angle
is
and
sometimes
alteration products
after
common horn-
blende.
very easy
fusibility.
is
Crlaucophane,
NagAl^Si^Ojg,
clinic amphibole, and until quite recently has only been found
and prevalent constituent of certain Japanese rocks, which have been described by Kot6 under the name of glaucophane The crystals are prismatic in habit and in cleavage, schist.
the angle of the latter being the same as that in
common
hornblende.
There
is
met with
to 6.
in actinolite.
or
ultramarine-blue,
c = sky-blue = violet a =
; ;
yellowish-green or colourless.
The mineral
is
Rock-Forming Minerals.
omphacite, epidote, etc.
191
it is
fre-
Arfvedsonite,
of Scandinavia
Na2Fe3Si40j2, occurs
in the zircon-syenites
and Greenland.
It resembles
common
horn-
blende in appearance.
light
flakes transmit
Krokydolite, a blue
asbestiform
The well-known krokydolite catseye imported from Griqualand results, as shown by Renard and Klement,* from the
infiltration of silica
among
brown
or
golden-yellow colour of
mica
The micas
are characterized
Cfroup.
P
of
(001),
parallel
by the approximation
by the extensive development and by the perfect cleavage to this plane, by their lustre, and their crystals to hexagonal and
mica we have a six-sided table or film, of which four of the sides are boundaries due to faces of the oblique-rhombic
prism
00
P P
(110),
00? 00
(010), as
(ill),
shown
and
of
in Pigs. 100
and 101.
Faces of the
pyramid
-J P
(112),
-2 P
is
(221),
and
00
Poo
Twinning
by no means unOf
these, one
most prevalent
00
is
rhombic prism
(001).
By
this
method of twinning
where the
shown
in Pig. 98,
upper half
is
192
Rock-Forming Minerals.
Rock-Forming Minerals.
seen in these sections.
193
may be
observed.
The cleavage
plates of mica
may be
by the
elasticity of the
mica
plates,
i.e.,
we
be dex-
The
star
which
:
lies in
the plane
symmetry, or
lie
parallel to the
edge 001
others
edges 001
110 and
001
angles of 60".
If.
The
we examine a mica
we
In
mica
lies-
either
symmetry.
other words, the line joining the two systems of rings in the
* Cometimes better results may be procured by employing a blunt-ended punch and.
a small hammer.
cally
ss. Fig. 99, and driven by an adjustable watch-spring w, has been successfully used by Lattermana for producing percussion-figures in veryminute scales of mica.
on a
little
^i
77"
194
Rock-Forming Minerals.
be found to be either parallel to that the plane of symmetry, as in Fig.
it,
which
lies in
as in Fig. 100.
An
important means
is
Pia. 100.
tain species of
that,
in this
may
orders
the
first
the guide-line.
By pressing
may
be produced, the rays of which lie in directions at right angles llO, as indicated to the edges 001 010, 001 110, and 001
:
by the dotted
or so
lines in Figs.
pressure-figures.
They
perfect as
the percussion-figures.
The rays
of the
applied.
The following
is
list
of the
principal
micas, classified
according to the direction of the optic-axial plane with reference to the plane of symmetry.
* For the purpose of demonstration it is best to employ a mica in wHcti the angle of the optic axis is considerable, such as musoovite.
Rock-Forming Minerals.
1st Ohder.
r95
2nd OaDEK.
^
/
(Muscovite
< Lepidolite
(.
p >v.
Mg fPhlogopite 3 g.lZinnvraldite
IBiotite
\
I
p<v.
p->v.
Paragonite >
'
Anomite
Meroxene Lepidomelane Ip
pq
Rubellane
Anomite ?
The refractive index of the micas is comparatively low. The double refraction is always negative and very strong, and
the colours in polarized light brilliant.
As shown
in the
lies
sometimes parallel
of symmetry.
at
others
at
the plane
The angle
0
in
some of the
biotites to about 80
musco-
vites.
The acute
elasticity, is
bisectrix,
which
is
also
the
axis
of greatest
which
it
makes with
it
appreciable ; and
it is
seldom that
this angle c
a exceeds 9.
In consequence of
this, cleavage-plates of
is
still less,
become
so nearly circular
scarcely possible
distinguish
interference-figures
of truly
uniaxial crystals.
Owing
first
to
the clinodiagonalj
196
obtuse bisectrix
We
first
order,
a z, & = b,
that
= a,
in
a.
Ii,
&
c,
= a,
or
met with
In consequence of
this, all
sections of mica
to
maximum
may be
measured, but
The resemblance
biotites
of
close.
The
approximate
more
hexagonal system.
appear
In the
in
isotropic
parallel
polarized light
between
would
micas,
do.
As
more marked.
In
all
to, are
more
The absorp-
may be
quite well
in calcite.
is
very strong.
an axis of
elasticity.
197
iris-
Sections of
brown
colours, while
some
varieties, as rubellane,
show dark
The following
principal micas,
is
Biotite.
mixtures of
commencing with those of small axial angle. The micas of the biotite series are isomorphous K3 Alg Sig Og (or the muscovite-molecule) with
,
Mg2
Si
O4,
two molecules
replaced by
1 to 2": 1.
is
more or
less
manganous
Haughtonite
is
Twelve analyses of
of from 14 to over
1
this species,
9 per cent, of
Under the name biotite are included known as meroxene, lepidomelane, and
belong to Tschermak's second order,
coincides with, or
is parallel
i.e.,
"They
all
to the plane of
symmetry,
also to
c
:
The angle
is
The
optic-axial angle
is
is
frequently so
small that
uniaxial character.
tites in
Tschermak
56
and Rosenbusch
occasionally
higher, Lattermann having found 2E = 72 30' in the a mica-andesite from Repistye, near Schemnitz.
The pleochroism
of biotite
is
igS
parallel to 6
Rock-Formmg
and
t,
Minerals.
basal cleavage
whicli both in a plane parallel to the; being almost totally absorbedj as in the case
lie
;
The
lation
relative absorption of i
and
a.
varies.
The general
re-
may be
stated as
^b>
is
become more or
mixed with
less
These
Pseudomorphs of limonite
of the mica-porphyrites.
common
in
some
The decomposition
micas are of
rocks,
schists.
tite
is
wedgThese
common
kersantite, in
which bioBiotite
is
localities.
is
In convergent
light, thin-
by coloured fringes which faintly indicate /3<:u. Aiiomite is a brown or reddish-brown variety of biotite, which generally differs from the other members of the series in the position of the optic-axial plane; but, although some anomite belongs to the first order of micas, it seems by no means certain, according to Eosenbusch, that there are not
anomites of the second order, in which the optic-axial plane
lies
at
right
The
disis
order
Rock-Forming Minerals.
p>v, while
of most
in those
199
it is
p<y,
is
The
latter
common
occurrence in rocks.
The pleochroism
the
same as
in biotite.
buckel 2 E=40.
c<li.
The dispersion is always a<c and 6 with Anomite occurs in basalts, andesites, porphyrites, etc. Pblogopite. In chemical composition phlogopite is similar
to
biotite,
Kg AI3
Si^ Og,
first
;
with
Mg^
Si O4,
molecule by the
so that, chemi-
and
By
The pleochroism
and the
2
is feeble.
The absorption
is
is
c>6>a.
In the
is slight,
seldom exceeding 20. The dispersion is p<v. The phlogopites of certain localities, especially some of the American ones, show a very distinct six-rayed luminous star
when
a candle-flame
is
of the mineral.
due to
platy or flattened
thinness, or of
of specular iron,
often of extreme
excessively minute
directions
crystals of tourmaline
60.
grouped in three
which cross at
By
It is
chiefly
met with
beds of
200
Rock-Forming Minerals.
K2 AI3
Sij Og,
molecules
Mg2 Si 0^ in isomorphous admixture with the Sijo Hg 0^^, and Sijo Og Flg^ in varying proportions.
greyish-white to dark-brown.
It is a
By
less, pinkish, or
mica of
symmetry.
The angle
angles
ranging from
is
very small,
a becomes considerably
all
The
the other
The pleochroism
almost
so, 6
is
and
brownish-grey.
The absorption
is
t>b>a.
Zinnwaldite
may be
The presence
pipe-flame.
districts.
of lithium in zinnwaldite
it
may
easily
be
re-
chiefly in
KgH^ AlgSieOj^,occurs
and
scales, the
either in
boundaries
By
The
colour
is
never sufiBciently
deep to give
sorption
is,
rise to
The ab-
to those planes a
visible
marked
difference
in
the illumination
is is
201
Such
sections also
The double
refraction
is
The
vergent light
show
brilliantly-coloured rings
and a wide
optic
of the
axes
The angle
made by
is
Thin laminee
and
elastic,
The
very talc-like
in certain
met with
it
protogine-gneiss,
etc.,
to which
imparts a silky
lustre
on the planes of
foliation.
Sericite occurs in
In optical characters
sericite
resembles muscovite.
of
The
means of distinguishing
Damourite
Brittany,
kyanite.
Lepidolite,
is
it
from
talc.
and
occasionally
forming
pseudormorphs
Og PljJ,
after
Sig
O5J
(SijQ
appears
vibrating
Nicol,
shows
the
rays
No
pleochroism
is
perceptible.
The angle
is
202
basal plane.
Rock-Forming Minerals.
The
optic-axial angle ranges
from 50
to 70
In
but this
is
by
lithium
muscovite.
Para^ojw'ie (Soda Mica),
NagH^, Alg
Sig O24,
occurs
chiefly
in
certain
crystalline schists,
It
and in some
cases constitutes
paragonite schist.
minute colourless
scales,
perties as muscovite,
is
only to be
distinguished chemically.
Ottrelite.
The
precise chemical
composition
uncertain,
owing
its inclusions.
grey,
or leek-green,
gates or fasciculi.
Very rarely six-sided tabulaT cyrstals are met with which give angles of, as nearly as possible, 120. These crystals must be
regarded as combinations of
(001),
(111)
and 00 J
c (010).
The
when
present, have a
resinous lustre.
met with in the micas, is almost invariably seen in sections. The cleavage is basal, but is far less perfect than that of mica. The cleavage-plates are very brittle, and are only translucent
Twinning upon the basal plane,
similar to that
when extremely
thin.
Rock-Forming Minerals.
either imperfect or obscure,
203
By transmitted
is
The refractive index is rather high. The double-refraction weak and positive ; and sections, even when not very thin,
first
maximum
extinction
lie parallel
If this
it
will
will
be
ft.
The oblique
extinction angle
is
found to vary
is
found to
lie
the surfaces
of basal sections
or
cleavage-plates.
In these basal
sections, a single
system of
field,
rings
may sometimes be
The
it
the
outside of each ring being bordered with red, and the inside
with blue.
dispersion
is
then p>v.
But, as a rule, no
from which
plane
may be
inferred
that
there
is
considerable
optic-axial
optic axes.
to,
The
The pleoohroism
is
Ii=indigo, or plum-colour
=yellowish-green.
may
which
it
7.
Owing
twin-lamellation,
and
its
The
by the constant
in-
clusion
of tourmaline, rutile,
quartz,
carbonaceous matter.
204
etc.,
chlorite,
and usually a
little
felspar.
Ottrelite
schist is
head
to smaller dimensions.
as
ottrelite, or chloritoid
its varieties,
their apophyses,
arkose,
Adularia,
chlorite
a transparent variety,
is
met with
is
in
the gneiss,
sanidine,
or glassy felspar,
essentially
volcanic rocks.
The chemical composition of these felspars is represented Orthoclase occurs in porby the formula Kg Alg Sig Oj^.
phyritic
In crystalline-
generally in a less
less
conforming more or
to
of the
crystals
by which
it is
surrounded,
etc.,
orthoclase fre-
quently
irregular
exhibits
no
form,
occurring
in
The 00? 00
crystals
(010), 00
usually
show
(110),
(ill).
Poo
(iOl),
2? 00
(021),
Rock-Forming Minerals.
2
205
Poo
(201),
and
OP
(001).
common.
is
The angle
basal plane
hemiorthodome (lOl)
37'; (110) to (010)
129 40';
36',
=99
=119
and
The
development of the
less tabular,
them more or
while in others, the extension of the basal planes and clinopinacoids in the direction of the clinodiagonal axis
causes
in
them
to
is
well
shown
Orthoclase
are
frequently twinned.
The most
common kind
in
00
of twinning is that
known
is parallel to
the orthopinacoid
Poo
partially
may be
distinguished as
and
left-
the right or
of the observer.
Pig. 102.
which
PP
is
00
the
206
Another type
Carlsbad,
is
parallel to the
clinodome 2
oo (021),
and
it is
of composition.
The twinning
axis
is,
of course,
normal to the
twinning plane.
In this type, the basal plane pertaining to one half of the twin is brought to a position at right angles
to
is
the basal plane of the other half. The Baveno type only met with in those crystals of orthoclase which have
section through such a crystal, parallel to the orthopina-
Fia. 103.
Fig. 103
is
in-
It will also
third and
less
is
common
type of twinning,
is
occasionally
met with
in the felspars
parallel
to the
base, the
P
oo
(001).
The two
parallel to
is
(001),
and to
f oo
(010).
Of
rather the
better
and
easier.
They
intersect at right
angles.
Rock-Forming Minerals.
Sections
light.
207
of orthoclase
The
The double
refraction
is
The
order.
The
an angle of from 3 to
7,
Owing
makes
Orthoclase, in
by
orthose non-deforme, or
normal orthoclase.
is
horizontal,
The
is
about 21.
rapidly, attaining
90
when the
as
The
are
parallel,
may be
section in
convergent polarized
This,
or
basal
polarized light
show simultaneous extinction when parallel is employed, the basal and clinopinacoidal
extinction.
of
maximum
00? 00
maximum
208
Rock-Forming Minerals.
Such
sections, if
and
6'
an
% made by
the optic-
Rock-Formtng Minerals.
to the cliaopinacoid, so, in such
209
the angle c;
li,
in'
make
together
an angle of about
is
shown
in Fig. 106j
where cc = the
k = the
acute
:
= the
In other sections in the same zone (100 010), the angle formed by the directions of extinction b and Ii'
'
being at
first
more considerable
in-
clination to
Under
similar
conditions,
by the
basal
cleavage planes in the two halves of the twin also increases from 127 46' to 180. The plane of composition always
halves the cleavage planes and extinction angle symmetrically in sections in the zone (100': 010).
The zone
In the
first
(001
010),
zone of P
00
individual
we then
two directions of
cleavage.
In
this
zone (001
made
by the
the orthopinacoid
show
2IO
Rock-Forming Minerals.
by
is
The
the boundaries of such a section, which, owing to the prevalent habit of the Baveno crystals, is approximately square.
A section of
this kind,
when examined
in convergent polar-
one half of the twin having the optic-axial plane parallel to one of the edges of the section, while that in the other half
has
its
that of the
and such
crystals
Sometimes,
however, orthoclase crystals are met with in which the opticaxial plane lies in the plane of
(ortJiose
are chiefly
Such
show an
inclined
dispersion, which
always p<^v.
is
The acute
bisectrix, as in the
a,
normal orthoclase,
the axis of
greatest elasticity,
the clinodiagonal.
and it makes an angle of about 5 with The axis of least elasticity, t, which is also
makes an angle
The angle
and sometimes.
Rock-Forming Minerals.
too small to be measurable, 2
64,
211
limit of 2
B=40
to 0.
The
V=
V=69.
Crystals of abnormal
at a
their formation.
1^
212
Rock-Forming Minerals.
lies
it
somewhat analogous
common
The
to
substitution of
Pleochroism
The
shown
and 109.
Intergrowths of
occurrence.
triclinic felspar
The
owing to the
is
common
orthoclase.
Adularia represents a
Epidote.
which
Under this
more or
silicates,
name
in
differ
less
chemical
composition.
as a
According to
mixture of two
Tschermak, epidote
may be regarded
namely
Sig Ogg (or Zoisite silicate) Sig Ojg (or
Epidote
silicate).
rhombic system)
is
dimorphous.
Rock-Forming Minerals.
proportions, the ferrous oxide attaining 17 per cent, in
instances.
213
some
Those
varieties
The more
ferric
ferriferous varieties
alumina
is
often replaced
by
minute, rod-like crystals, which, like the larger crystals, have a long prismatic habit by extension in the direction of the
orthodiagonal axis
b.
in rocks, and
P oo
00 (101), all of
which faces
lie
in the
by
faces of prisms or
A section
001
100
Fia. 110.
r
sections of crystals in
as
is
Sections
orthodiagonal
or b axis would
cut, or
crystallographic edge.
The cleavage
214
basal plane,
Rock-Forming Minerals.
less perfect parallel to the ortliopinacoid.
The
two directions
Epidote, as
is
either
(especially yellowish-
The
slices
refractive
index
is
double refraction
on the surfaces
of
consequently appear
well
The
and
especially so in
a range of colour
by few other
is
equalled
zircon,
and is only surpassed in sections of rutile, anatase, and the rhombohedral carbonates. In the well-known
light.
The
metry.
The acute
(negative) bisectrix,
a,
or axis of greatest
elasticity, lies
and the vertical axis, and makes an angle with the latter of about 2 to 3, as shown in Fig. Ill, In convergent light, all
sections
Rock-Forming Minerals.
figures^ or the dai-k
215
bars,
the
of
maximum
;
cleavage
and there
therefore,
risk
of mistaking such
In sections in the zone (100:010) the extinction angles range from 0 in sections parallel to (100) to about 28 in
those parallel to (010)
;
angles
is
met with
in sections in the
occurring in
Pleochroism,
although
excessively strong
in
the
dark-
much
less
marked
in their rock-
forming
representatives,
being
generally
a= colourless
c
or
pale yellowish-green, b
= colourless
or yellowish-green,
siskin-green or yellowish-brown.
The absorption
is
c>b>a, Knappenwand it
6>c>-a; and in the Japanese crystals of piedmontite or manganese epidote described by Kot6, the absorption is a>-c>Ii,
where
Twinning, although
a= deep reddish-violet, c = brownish, red, b = light violet.* common enough in the larger crystals
frequently seen in the epidote occurring in rocks.
is less
The
* Piedmontite occurs in the mica schists of the lie de Groix, ofE the south coast of Brittany ("Bull. Soc. Fran, de Min." t. xi. p. 148); and it has recently been met with in one or two British localities. This
species must, therefore,
now
be included
among
well-recognised rock-
forming minerals.
2i6
twinning plane
tlie
Rock-Forming Minerals.
is
and
it
is
also
lie
plane of composition.
it is
position product.
schists
often
met with
in
metamorphosed
a rock-
limestones.
are present in
etc.,
decom-
Orthlte (AUanite)
chemical composition
its
may be regarded
as that of an epidote
may
likewise be present.
it
In form,
Sec-
resembles epidote.
light, are of
by transmitted
colour.
a reddishstates
brown
or greenish-brown
Eosenbusch
that
The
epidote.
optic-axial plane is
the
plane of symmetry, as in
Cross,
it
bisectrices
made an angle
clinodiagonal.
They record
it
its
and
andesites,
diorites,
is
met
allied to
and gneissic
etc.,
Rock-Forming Minerals.
Sphene
(Titanite). Ca 0, Si
217
)
%,
per cent.
a normalj but subordinate, constituent of eruptive rocks,
As
sphene
usually
small, crystals,
these, the
(123),
their forms.
Of
most common
(001)
consists of a combination of f
Fia. 112.
2 (123) and 00
(110).
and 113,
I.
show the
Fig. 113.
(100),
and in both
II.
and 118,
Here, to
facilitate
2i8
Rock-Forming Minerals.
In Fig.
2
P:cP = 133
52',
while |
= 186
Sections showing twinning on a plane parallel to the orthopinacoid, as in Fig. 1.14, are. very characteristic of sphene.
Fig. 114.
is also
common.
The cleavage
it is
parallel to
(110), but,
owing
2 (123),
by the
latter faces.
brown
colours
reddish- brown, and, in the latter case, they are not very
translucent.
Dark
borders,
and the
irregularity in a
is
positive
and
is so, as
shown
by the The
lines
when[,the form ^
oo (102)
is
is
seen to be normal to that face, while the obtuse bisectrix, or c, makes an angle of 39 17' with the
Rock-Forming Minerals,
vertical crystallograpMc axis
c,
219
:
010).
The acute
There
is
but
Fig. 115.
diflferent
is
coloured
considerable,
as
may be
and afterwards a blue, glass beneath the stage of the instrument. According to Des Cloizeaux, the apparent angle for
red light 2 E/) = 56 in one instance, while for blue 2
Bu = 34.
These
are,
In convergent polarized
bisectrix
The -pleochroism
is
Sphene, when
rocks,
it
crystallized out
must be regarded as one of the first minerals which from the magma. It is found in granites,
plentifully in gneiss
and
crystalline
220
schists.
Rock-Fortmng Minerals.
Sphene sometimes becomes altered into
rutile,'
at
Crypslun,
CaS04+2H20,
is chiefly,if not
exclusively,
met
When
filling
small
(satinspar, in
part).
Gypsum,
is
intensely-red
gypsum
is
ferric oxide.
The
double-refraction is
crystals
and
remarkably strong.
By examining
lie in
the symmetral
plane ; and the interference-figure, in convergent light, shows inclined dispersion. The angle of the optic axes is 2 V. 61*
24' at the ordinary temperature.
in the
angle
/3.
pinacoid.
is
an-
a normal
P 00
(101).
The
arms of which
intersect at
about 60.
TRICLINIC SYSTEM.
Triclinic
crystals, as
;
already mentioned,
are symmetrical
and no form in
221
The crystals
of cleavage.
elasticity
No relation exists between any of the axes of and the crystallographic axes; but occasionally an
monoclinic system.
are usually seen to
lie
The
directions of
maximum
extinction
and to cleavage-planes.
when
The
distribution of
unsymmetrical.
at right angles to
when not
an optic
nicrocline.
orfchoclase.
Chemical
Although microcline
crystals
and brachypinacoidal cleavages make an angle which only differs from 90 by less than a quarter of a degree ; and there is an equally close approximation in the angle formed by the corresponding faces in crystals of these two minerals. Crystals of microcline occur in cavities and fissures in certain granitic rocks, and very closely resemble those of orthoclase in
external form
ciate
so
any difference in
this respect.
These microcline
crystals,
however,
clase,
structure,
due
is
to the
The
as
twinning
upon two
known
22 2
Rock-Fovming Minerals.
when viewed
diflBculty in
so
will
have
little
recognising
it
again.
In addition to
lamellse
this lamella-
tion, microcline
albite,
and
also of orthoclase.
lie
The twin
which follow
010) in
lie
parallel to the
edge (001
100).
On
and
to the brachypinacoid oo
:
P eo
j
(010),
parallel to the
edge (001
while
run
parallel
edge (100:010),
and
by
their intersection,
all
an angle which
In
some
lens.
be seen upon the basal plane without employing even a pocket These larger crystals appear also to twin on a larger
upon the Carlsbad type, quite independently of the Baveno and Carlsbad types of, what one may Jierm, microscale
scopic twinning.
In addition to the basal- and brachy- pinacoidal cleavages, which so closely approximate to the corresponding cleavages
in orthoclase that practically no distinction need be
made
between them,
there
is
cline, parallel to oo
Rock-Forming Minerals.
light.
223
The
makes with
(010) an angle of 82
The obtuse
The
Ha = 88 to 90
:
the position of the bisectrices in a cleavage plate parallel to the basal plane, the acute edge (001
010), from
by the
is
line
EE
figure.
The acute
bisectrix
the
C-.
-*
~-C
/iS'M iSsm,
a
Fig. 116.
t!.
Fig. 118.
obtuse,
c.
B.
In Fig. 117 a
assumed
on a plane p^allel to
being inverted.
this case,
Assuming the
section to
stand as
it
would be
left
in order to
224
get
Rock-Forming Minerals.
maximum
while to cause
The two
directions of extinction in
As
number
of minute
90.
The twin
lamellas
them
and these
edge
(001:100) or (OP: ooPoo). The relation of the lamellee twinned on the albite a,nd pericline types is indicated in Figs.
3
the right of them, these lines denoting the traces of the macropinacoid 100, and the brachypinacoid 010.
When
two such
the directions of
maximum
to,
by the
Rock-Forming Minerals.
225
to
mineral
may be
albite
recognised by
or straight, extinction.
The
and
5 in basal sections.
In sections of microcline
the edge (001
the
010) or (0
If,
there-
lie
parallel to the
maximum
ex-
The
is
seen in sections
clino-diagonal axis,
an angle of
5.
field.
The
alterations
which
common denomination
According
of plagioclase,
members
of the
226
The molecular
Rock-Forming Minerals.
relations,
shown
where
Ab
An
Andesine
Labradorite
Bytownite
Anorthite
in
Si
16J
which
Ab = Na, AL
Abg Anj Abi Ahq Abg Ahi Abg Anj Ab^ Ang Abs Apg Abj Anj Abj Ad 3 Abj Ang Abj Aug Abj Ang Abo '^"i and anorthite => Oa^ Al^ Si^ O^
but they differ from them in the fact that the angle made
several degrees
by their basal and brachy pinacoids deviates from a right angle, in some cases over 4.
angle 001
:
In albite the
94 10'.
010 = 93
36',
while in anorthite
it is
In
25'.
The other
= (110)
and
2,P,oo
=(201),
all
Fia. 120.
is
that of a rhombohedron.
The
crystals
are very
commonly
Twinning
is
so
common
it
Rock-Forming Minerals.
is
227
the exception to find an untwinned crystal. A simple twin composed of only two halves or individuals, as in Fig. 121,
twinning being
usually
many
composed
of a great
number
of parallel
twin-lamellae.
It is
now
twin-lamellation
felspars, a
may be
developed
artificially in
untwinned
Fig. 121.
a normal
to the brachypinacoid 00
P 00
(010).
entering angle of 172 48', while their macrodomes ,P^oo (101) also form a re-entering angle of 172 42', Fig. 12 L A basal
section of such a crystal
may be
maximum
and (100
would
In the most
common
228
Rock-Forming Minerals.
010).
lOLSSi
Fio. 122.
edges
colours.
These
are
not
always
continuous
The
pres-
sures to which these crystals have sometimes been subjected, and the consequent flexure which they occasionally display, seem to have a marked influence upon the distribution and
The pericline type of twinning, first explained by G. vom Rath (Neues Jahrbuch, 187<6, p. 689), and so named from pericline,
a variety of albite,
is far less
common
in plagioclastic
of composition or contact
is
Rock-Forming Minerals.
the angle whicli
it
!29
cx3
oo
F and
oo
oo
on
'P and
oo
lie
in the
manner
and approximately
at the angles
shown
in Fig. 123.
Here, in
Albite
...
13 to 22
Oligoolase
...
...
Andesine
...
Labradorite
...
...
2 to 9
Anorthite
Fig. 123.
...
18
(OP:
00
Poo)
= (001
:010).
is
13
to 22 to this edge.
In oligoclase
only
4,
the lamellae
(001:010).
clination
in-
of the edge
(001
anorthite
18.
albite
met with
in
the same
crystal^ the
two
sets of lamellee
upon the
to the
pericline type is
shown by the
230
Rock-Forming Minerals.
010 in the
different species
shown.
ning
exist, a simple
only to be seen in
is
The
may be
realized
side
by
macrodomes
also
of the other.
The
met with, at times, in conjunction with the Baveno type. The cleavages, of the plagioclas'tic felspars are respectively parallel to the basal- and brachy- pinacoids, the basal cleavage being the more perfect. Other subordinate cleavages may be
developed, but their existence
scopic sections.
is
Apart from the flame-reactions, first successfully employed by Szabo for the determination of the different species of felspar (p. 9), a similar end may be attained by measuring
their angles of
maximum
(001
010) or (0
00
Such
P 00. These extinctions have been carefully investigated by Max Schuster and by other competent observers and although
;
it is
with precision,
mean
of a great
number
must be regarded
it
may be taken
(001
is
010)
is
the line
drawn
parallel to
Rock-Forming Minerals.
another dotted line also parallel to
angle of
231
EB.
In measuring the
maximum
line
the edge
EB,
or the
boundary
(albite type)
parallel to
Fis. 124.-
B B,
is
it
maximum
extinction is attained.
is
010).
The extinction-angles of the principal felspars are diagrammatically shown in Figs. 125 and 126. In both of these
figures the dotted line
BE
010), or
is
represented by
BE
in Pig. 124..
Ex-
in
232
Rock-Forming Minerals.
emerges from the section more or less c) The optic-axial angle varies somewhat from 90. In albite and oligoclase the dispersion is p < u, while in labradorite and anorthite it is p > v.
Fig. 125.
when examined
normal and a
remote from
The
field,
emerge from
233
The
inclined
Basal sections
The dispersion
in oligoclase
Sections of labra-
dorite
and bytownite
Tig. 126.
(010), and also in those parallel to (001 ), show a system of rings and an hyperbola, due to the oblique emergence of an optic
and there
is
feeble inclined
is
of axial rings
faces (010)
By
and
234
At
times these
fel-
spars are altered into micas, sucli as muscovite, or, in the case
In the
common
also
occurrence.
common among
clastic felspars.
Kyanite,
AljOsSiOg,
^is
chiefly
etc.
are
00
usually combinations
(110)
j
Poo
(100), oo
combination.
The angle
(100)
=145
13'.
Twinning
is
normal
By
when
The
colour, however,
Sometimes the
presence of carbonaceous
matter.
The
The
(010).
to the macro:
pinacoid, and
is
The optic-axial angle is genei-ally very large 2V The dispersion is weak, p>v.
In sections
82 to 83.
it is
7 to 8.
Rock-Forming Minerals.
The pleochroism
coloured crystals.
is
235
less
homogeneous
when
Among
Seriientine,
light,
H^ Mgj
diflferent
Sij
Og+aq.,
which,
by transmitted
Various struc-
appears of
by serpentine, which have received the names " mesh-structure," " lattice-structure," etc. The structural differences are apparently dependent upon the nature of
the mineral which, by
serpentine.
its alteration,
The conversion of
(p.
156).
from
their
decomposition
differs
generally in structure from that which has been derived from the alteration of olivine, the mesh-structure usually characterizing the latter, while the former mostly exhibits the latticestructure.
irregular
traversed,
The character of the mesh-stracture is due to the fissures by which crystals of olivine are usually
and along which the serpentinous matter
is
first
lattice-
The ultimate
The
wide,
and the
bisectrix, a,
Consequently
t,
is
236
it is
found
to be negative again,
is
small.
Delessite, a hydrous
sometimes occurs pseudomorphous after amphibole and pyroxene. It is also met with in the cavities of vesicular rocks
It
successive
fibrous
growths.
The double refraction is weak. The directions of extinction are suggestive of a rhombic The axis of least elasticity lies parallel to the length mineral. Delessite shows more or less pleochroism. of the fibres.
Crlauconite, which occurs plentifully in
many
mentary
origin,
and possibly
in
some
others,
is,
name
It is essentially a
hydrous
silicate
and potash, but the composition is very variable, alumina being usually present and occasionally a very Between crossed Nicols it shows small amount of soda.
of protoxide of iron
feeble double refraction or, in
some
often found to
tests.
Glauconite
is
A variety occurring in
the Minnesota
reagent.
J
is,
Crreenearith, or Celadonite,
is
It is of a
deep
olive- or
237
turns, according to
ed.), first yellow,
Naumann
("
10th
to Klaproth
decomposed, leaving a pulverulent residue of silica. According and Von Kobell (Dana's " System of Mineralogy,"
5th ed.),
it
is
Green-
also
found
Kaolinite,
AI3
O3, 2 SiO^, 2
H3O,
is
common product
of
The mineral crystallizes usually in when of moderate dimenshow double refraction and optical characters generally
sist
The ordinary earthy kaolin, when levigated, is seen to conof very small and irregularly-bounded scales. The mineral is optically negative ; and, according to Rosena, is
normal or approxi-
Rock-Forming Minerals.
239
240
Rock-Forming Minerals.
Tetragonal System.
Rock-Forming Minerals.
241
MoNocLiNio System.
242
Rock-Forming Minerals.
Rock-Forming Minerals.
Teteagonal System.
243
o o
;?;
EH ra
to
1^
Hi
EH
"
"
Rock-Forming Minerals.
247
BIBLIOGRAPHY.
The following works may be consulted with advantage by
the student
:
Lehrbuch der Mineralogie " Berlin and Leipzig, 1886 Batjekman, H., " Text-book of Systematic Mineralogy " London, 1881 1884 " Text-book of Descriptive Mineralogy ,, Beale, L. S., " How to Work with the Microscope," 1880 5th ed London, 1831 Beewstbu, D., " Treatise on Optics 1852 Brook & Miller, " Minerology " Dana, J. D., " System of Mineralogy," 5th ed. London and New York, 1871
.
Appendices L,
II.,
and
III. to "
.
System
. .
of
New York, 1882 Mineralogy," 5th ed. Dana, E. S., " Text-book of Mineralogy," 3rd ed. Dattbreb, a., " Etudes Synthetiques de Geologic ExParis, 1879 perimentale "
.
De Lapparent,
Des
"...
.
1884
1862
Cloizeatjx, A., "Manuel de Mineralogie" FouQTJE & Levy, " Mineralogie Micrographique
''
Glazebkook, E. T., " Physical Optics " Leipzig, Geoth, p., " Physikalisohe KrystaUographie " HussAK, B., "Anleitung zum Bestimmen der gesteinbildenden Mineralien " Paris, Jannettaz, E., " Les Eoches " Heidelberg, Kalkowsky, E., " Elemente der Lithologie " Klement, C. & Ebnard, A., " Reactions Microchimi. . .
. .
1883 1885
1885 1884
1886
Brussels, 1886
. .
Bonn, 1875
1875
1877
LoMMEL,
E., "
The Nature
of Light,
with a General
.
Naumann,
London, Account of Physical Optics " Leipzig, Elemente der Mineralogie," 10th ed. EosENBTJSCH, H., " Mikroskopische Physiographie der Petrographisch wichtigen MineStuttgart, ralien," 2nd ed " Mikroskopische Physiographie der Stuttgart, massigen Gesteine," 2nd ed. London, Spottisttoode, W., " Polarization of Light "
C. F., "
.
1885
1887
1874
248
Teall,
Rock-Forming Minerals.
. . . .
J. J. H.," British Petrography " TscHERMAK, G., "Lehrbuch der Mineralogie" Vogelsang, H., " Die Krystalliten "
....
. .
. .
Ziukel,
F., "
Mikroskopische Beschafienheit der MineLeipzig, 1873 ralien und Gesteine " "Microscopical Petrography," U.S. Geol. Washington, 1876 Exploration of 40th Parallel.
treatises
Numerous
scientific
to
Mineralogy and
literature
more Amongfsuch
may be mentioned
the ''American
Gfologique du Nord," " Mineralogical Magazine," " Mineralogische u. Petrographische Mittheilungen," " Neues Jahrbuch
fiir
Mineralogie,"
etc.,
d.
Naturforscher,"
d.
Deutschen Akademie
Annalen,"
" Quarterly
and
Proceedings
u.
of
the
Royal
Society,"
" Tschermak's
Mineralogische
" Zeitschrift
States Geological
d.
Survey" (Annual Reports and Bulletins), Deutschen Geologischen Gessellschaft," " Zeit-
The publications
of other
it is
list
The bibliography
appended
to
Mr.
Teall's
INDEX
s.
= synonym.
{Felspar
i;.
= variety.
{v.
Abnormal
Orthoclase
Bastite
Group), 210.
Baveno Type
Berfcrand's Stauroscope Bye-piece, Biotite {Mica G^-oup), 197. [48. Bisectrices, 56, 58. Boro-tungstate of Cadmium Solution, 5.
Acute
Bisectrix, 58.
64
Albite, 226. Type of Twinning, 222. AUanite (s. OHhite), 216. Almandine (Garnet Group), 112.
Breon's Mixture, 6. Brezina's Calcite-plate, 48. Brogger's Apparatus, 7. Bronzite {Rhombic Pyroxene Group), 144. Bull's-eye Condenser, 26. Bytownite (Plagioclastic Felspar Group), 226.
Calcite
(s.
Calcspar), 123.
Amphigene
(.
Leucite), 113.
Andesine
{Plagioclastic
Felspar
Group), 226-229.
Anhydrite, 169. Anisotropic Bodies, 50. Anomite {Mica Group), 198. Anorthite {Plagioclastic Felspar Group), 225.
Anthopliyllite (_Bhomhio bole Group), 151. Apatite, 125.
Amphi-
Aragonite, 169. Arfvedsonite {Monoclinic Amphibole Group), 191. Asbestus, 187. Asterism, 199. Pyroxene {Monoclinic Augite Grovf), 178. Axes, Crystallographic, 48. of Optical Elasticity, 44. Deter
250
Crystallograpliio Axes, 43. Cubic System, 50, 105. Cutting Sections, 22. Oyanite (s. Kyanite), 234.
Index.
Graphite (s. Plumbago), 120. Greenearth, 236.
Oymatolite, 183.
Gypsum,
220.
Pyroxene
Haidinger's Dichroscope, 102. Harada's Apparatus, 7. Hardnesses, Table of, 239. Haughtonite, 197. Haiiyne (s. HaOynite), 115. Hematite, 121. Hercynite (Spinel Group), 108.
Hexagonal System,
119.
Dichroscope, 102. Diopside see Malacolite, 176. Directions of Extinction, 48. Dispersion, Crossed, 79-83. Horizontal, 77-82.
Reedy, 189. Hour-glass Structure, 173. Hypersthene (Bihombie Pyroxene Group), 144.
,
Rhombic,
72.
Idocrase, 140. Ilmenite, 122. Inclined Dispersion, 76-80. Extinctions, 50. Index of Refraction, 34. Indicolite (v. Tourmaline), 132. Interference, 31.
-figures, 61.
Pyroxene
Partial, 83. Theory of Formation, 67-70. -figures, in thick and thin Sections, 66, 91. Iron-glance (v. Hematite), 121. -mica 121. Native, 105. -pyrites (s. Pyrites), 106.
65.
Spacing
of,
Isotropic bodies, 50. Jade, 188. Jefireysite (v. Phlogopite), 199. Kaolinite, 237. Kelyphite, 113. Klein's Plate, 47, 96. Solution, 5.
(v. Arfvedsonite), 191. Cyanite), 234. Labradorite (Plagioclastia Felspar Growp), 226. Lattice-structure (Gitterstructwr),
Garnet,
Common,
112.
Krokydolite
(s.
Group, 109.
Gedrite (v. AnthophyUite), 151. Glassy Felspar (g. Scmidine), 212. Glauconite, 236. Glaucophane (v. Hornblende), 190. Gold, 106.
Kyanite
Lepidolite
(v.
Muscovite), 201.
Index.
Lepidomelane (. Biotite), 195. Leucite (8. Amphigene), 113. Leucoxene, 122. Light, Propagation of, 29.
Velocity of, 31. Lithia-mica (s. Lepidolite), 200, 201. Lithionite 200.
251
Luminous Waves,
29.
Objectives, 15. Oblique Extinctions, 50. Obtuse Bisectrix, 68. Ootahedrite (s. Anatase), 137. Oculars, 15. Oligoclase (Plagioclastie Felspar Group), 226. Olivine (s. Peridot), 153.
Wave-surfaces, 51. Magnesian Micas, 197. Magnetite (s. Magnetia Iron), 106. Malacolite (MonocKnie Pyroxene
Group), 176.
Omphacite
(v.
Augite), 180.
Optic Axes, 37, 61, 55. Secondary, 66, 68. Axial Angle, Measurement
of, 88.
Manebach Type of Twinning, 206. Manganese Epidote (s. Piedmon213-215. Martite, 107. Maximum Extinction, 45. Measurement of Optic
iiie),
Plane, 58.
59.
Normal,
Optical Constants, Table of, 242. Sign, Determination of, 90. Orders of Colours, 95.
-
axial
Ordinary Bay,
36.
167.
Orthite (s. Allanite), 216. Orthoclase, Abnormal (Felspar Group), 210. Normal (Felspair Group), 207.
Ottrelite, 202.
Andradite,
Garnet
Group), 112.
Melilite, 141.
Meroxene
(.
Biotite), 197.
Methylene-iodide Solution, 6. Micaceous Iron (v. Hematite), 121. Mica Group, 191. Microcline (Felspar Group), 221. Microscope, Construction of, 12. Mohr's Sp. Gr. Apparatus, 4. Monoclinic Amplubole Group, 184. Felspar 204.
Pyroxene System, 170. Mounting Thin Sections, 25. Muscovite (Mica Group), 200. Native Iron, 105.
,,
171.
Perowskite, 118. Phase of Vibration, 31. Phlogopite (Mica Group), 199. Picotite (Spinel Group), 108. Piedmontite (Epidote Group), 213,
Natrolite, 167.
93, 98.
Crossing
69.
of, 27.
Normal, Optic,
216. Pistacite (v. Epidote), 212. Plagioclastie Felspar Group, 225. Pleochroism, 100. Pleonaste (Spinel Group), 108. Plumbago (s. Graphite), 120. Pocket-lens, 3. Polariscope, 60. Polarization, Circular, 63. of Light, 38.
(Felspar
Polarizer, 40.
16.
Plane
of, 38.
Nosean
(s.
Nosite), 115.
252
Index.
Sonstadt's Solution, 5. Specific Gravities, Table of, 239.
Positive Uniaxial Crystals, 37, 98. (. Muscovite), 200. Preparation of Sections, 21. Pressure - figures {Vruchfigwen),
Potash-Mica
Gravity,
4.
194.
Pyrites
(s.
Iron-Pyrites), 105.
Specular Iron (v. Hematite), 121. Spessartine {Garnet Group), 112. Sphene, 217.
Spinel, 108.
Pyrope (Garnet Group), 112. Pyroxene Group, Monoclinic, 171. Bhombic, 144.
Quarter-undulation Plate, 97. Quartz, 126.
Plate, 47.
Spodumene,
Staurolite
(s.
Wedge,
92, 96.
Stauroscope-Ocular, 48. Stauroscopic Examination, 47. Straight Extinctions, 50. Strength of Double Refraction,
42.
Refraction, Refractive
33.
Conical, 57.
242.
Kyanite), 234.
151.
of, 21.
Pyroxene Group,
144.
Inter-
growths of, 153. System, 142. Rings and Brushes, 61. in Monochromatic Light, 62.
Ripidolite {Chlorite Gi'oup), 133.
Thoulet's Solution, 5. Tinstone, 138. Titaniferous Iron (. IlmervUe), 122. Titanite (s. Sphene), 217. Topaz, 157.
Tourmaline, 132. Tongs, 59. Transmitted Light, 26. Tremolite {Monoclinic Amphibole
Group), 186. Triclinic Felspars, 225. System, 220. Tridymite, 129. Turgite, 122. Uniaxial Crystals, 37. Uralite, 180. Vermiculite {v. Phlogopite), 199. Vesuvian (g. Idocrase), 140.
Tourmaline), 132.
Rutile, 135.
Sagenite (. Rutile), 136. Sanidine (v. Orthoclase), 212. Satinspar {v. Aragonite), 169.
(v. Gypsum), 220. Scapolite, 140. Scmlfige Homhlend, 189. Schillerspar (g. Bastite), 147. Schorl (v. Tourmaline), 132.
Vibration, Amplitude
of, 30.
"Wave-lengths, 30.
58.
-lines, 30.
Section-cutting, 21. Selenite (v. Gypsum), 220. Serpentine, 235. Sign, Determination of Optical, 90. Sillimannite, 166.
Slitting-disc, 22. Smaragdite, 188. Sodalite, 115.
-surfaces, 51. of Quartz, 92-96. Wernerite (g. Scapolite), 140. Wollastonite (. Table-spar), 183. Zinnwaldite {v. Phlogopite), 200. Zircon, 138. Zoisite, 160.
Wedge, Use
'^MM^j&A yi(
'W^
m-'.. iu'
''