Beruflich Dokumente
Kultur Dokumente
4%
(1999 )
1/3
GNP
Non-Pipe
Constr/Instal
Pipe
Mfr
Prev. Damgd Pipe
Malfunction
Stress Corrosion Cracking
Vandalism
0.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
COST OF CORROSION
$5.0 bil.
8.4 MPa
10 MPa
12 MPa
374.1
314.4
296.5
228.8
External Coating
44.1
44.1
44.1
42.0
Internal Coating
21.2
21.3
21.2
21.2
Weight Coating
67.2
63.7
57.8
54.0
Cathodic Protection
20.7
20.5
20.5
20.2
Pipe Laying
80.7
78.1
80.8
80.8
Dredging& Backfill
17.7
17.1
16.8
16.1
8.4
8.4
8.4
8.4
634.1
567.6
546.1
471.5
Total
10 15% of total direct construction cost for corrosion protection (coating + CP)
(Cited from Feasibility Study Report for Irkutsk PNG pipeline)
Chemical/microbiological corrosion
/
Electrical corrosion
10
(corrosivity)
vs.
3
P/S
Disbonded area
Sulfate
P0
P0
P0
0
-2.0
0
-1.8
-1.6
-1.4
-1.2
-1.0
20
40
60
80
100
0
0
10
120
P/S (V/CSE)
10
10
SRB
pH
10
2-
10
Resistivity
P0
P0
P0
1
1
0
4
pH
10
0
3
10
10
10
10
10
10
10
0
1
10
10
10
Resistivity (Ohm.cm)
10
Soil Resistivity
Wenner 4-Pin Resistivity Measurement
I
.
= R A/L (
(
cm)
)
4-pin method
Soil box
Soil pin
.
.
a/2
5,000 ohm.cm
1.E+06
1.E+05
1.E+04
corrosive
1.E+03
1.E+02
0
10
20
30
40
50
60
70
Distance (km)
80
90
100
110
120
130
B
A, B
?
19
A.
B.
C.
.
.
.
.
D.
20
h1
h2
h3
S
h4
h5
1
R
1
R1
1
R2
1
Rn
21
4m
1.
2.
3.
2m, 4m
(R2, R4)
R2-4
1
R4
R2
1
R2
4
2 4
1
R2
R2 R 4
R2 R 4
400
2-4
22
R2 R 4
R2 R 4
Pin
2m
R2 = 6.3
Pin
4m
R4 = 1.3
2m
2= 2 2006.3=7,917
cm
2m
4= 2 2006.3=3,267
cm
Test data
a (cm)
R (Ohms)
200
400
Barnes Analysis
Avg.
1/R
(1/R)
Layer R
6.3
7,917
0.16
6.3
7,917
1.3
3,267
0.77
0.61
1.64
2,061
23
Layer
Test data
Barnes Analysis
a (cm)
R (Ohms)
1/R
(1/R)
Layer R
150
1.1
0.91
1.1
1,040
300
0.89
1.1
0.19
5.3
4,995
450
0.46
2.2
1.1
0.91
858
600
0.14
7.1
4.9
0.20
190
750
0.083
12
4.9
0.20
190
900
0.076
13
1.0
1.0
94
Ref.) T.H. Lewis, Jr., Deep Anode Systems, NACE (2000) p.7-11
24
Layer
SO42-
APS + PPi
Enters cell
2e-
SO32- + AMP
H+
S2O52-
Metabisulfite
2eOutside cell
S2-
2e-
S2O32Thiosulfate
2e-
S2O42-
Dithionite
S3O62-
Trithionate
Anaerobic bacteria
Neutral environments
Reducing sulfate to corrosive sulfides
27
Pi
Resistivity
10
10
10
10
10
10
SRB (cells/g-soil)
10
10
10
10
10
SRB (cells/g-soil)
10
10
10
10
10
10
10
10
10
10
10
Clay content
10
10
10
10
10
10
10
Redox potential
10
10
10
10
10
20
30
40
50
10
60
0.0
0.2
0.4
Eh (V/NHE)
( cm)
-0.2
10
10
10
10
Anaerobic,
Neutral,
High clayey,
Low resistivity,
High water content
10
10
10
APB (cells/g-soil)
SRB (cells/g-soil)
10
10
10
10
10
10
10
10
10
APB
Water content
10
10
20
30
40
50
10
10
10
10
10
10
10
SRB (cells/g-soil)
10
10
0.6
0.8
-0.4
25 m
SRB-active
Biocide added
APB-active
Fe
Ecorr (mV/SCE)
S
Fe
Al
-0.6
-0.8
20 m
Fe
Si
0
2
10
20 m
2.0
-1.0
0.4
0.36mm/y
0.3
D
0.2
m
0.1
2.0
1.5
0.0
0
1.5
Energy (keV)
50
100
Time (Day)
1.0
Fe
150
200
Fe
1.0
Fe
0.5
P
Si
0.5
Fe
C
Si
Al
Fe
2
Energy (keV)
Energy (keV)
0.0
0
Fe
0.0
10
10
2.0
1.5
1.0
0.5
Fe
C
Fe
Si
Al
Fe
0.0
0
Energy (keV)
SRB
10
CP
SRB-active soil
Ref.) K. Kasahara, et al.,
Corrosion, 55(1) (1999) 74
2H 2O
2e
2 OH
31
CP vs. MIC
3
P0
0
-2.0
-1.8
-1.6
-1.4
-1.2
P/S (V/CSE)
-1.0
Pt & Reference
~15cm depth
Ref1
Ref2 Pt
Pipe
3. Ref 2 vs. Pt
33
Potential
mV vs. Cu/CuSO4
P/S
-1430 (-1200)
In Crevice
-610 (-500)
Pt Electrode
-480
Redox
*1. At pH 7
34
ANSI/AWWA
< 700
700 - 1000
1000 - 1200
1200 - 1500
1500 - 2000
> 2000
10
8
5
2
1
0
pH
0-2
2-4
4 - 6.5
6.5 - 7.5
7.5 - 8.5
> 8.5
> 100
50 - 100
0 - 50
<0
(polyethylene
encasement)
10
5
3
0
0**
0
3
(mV)
0
3.5
4
5
(sulfide)
positive
trace
negative
(moisture)
(drainage)
,
,
DIN 50929
,
3.5
2
0
,
2
1
0
35
CORROSIVITY MAP (
36
P=ktn
P:
t:
k, n:
Power law
P=kt
t, (Time/year)
.
.
37
LogPc
0.700
0.203Log( Cl ) 0.050E h
Clay
0.014pH Log( )
2.5
R=0.942
2.0
P0
0.500Pc t 0.372
P0, obs
1.5
1.0
Chemical factors
Biochemical (microbial) factors
CP effects
0.5
0.0
0.0
0.5
1.0
1.5
2.0
2.5
P0, cal
38
INTERFERENCE
(interference)
(stray current;
(
(
,
)
( :
,
AC
(anodic interference)
(anodic interference)
(cathodic interference)
crossing
Rectifier
power up
corrosion !!
Rectifier
-1
-2
-3
0
50
100
Distance, m
150
STS 304L
:1
:
DC
1.2V/CSE
(combined interference)
(combined interference)
49
25km,
10km,
: ~3km
100
10
90
80
70
60
50
40
30
20
10
10
feeding current ( )
Il'''/I (%)
7000A
leak current
vs.
.
(
/
(BS EN 50162: 2004)
(KS C IEC 62128-2)
(
(2005) p.83
10
10
9
8
7
6
5
10V
1
19
18
17
16
15
14
1
13
12
11
+5V
5
10
6
7
7
6
10
15
19
4
3
2
1
-5V
18
17
16
13 11
12
14
I-BEAM (
I-beam
I-beam
(
1
[A]
[A]
[A]
[A]
15.5 19.0
7.2
4.7
0.04
3.2
79%
15.5 18.9
9.9
4.2
4.7
100%
15.5 18.5
0.9
12.9
75%
15.5 16.8
8.0
48%
15.5 14.6
0%
[V]
1
2
[A]
/
-
/
: 19A
: 0.82
14.6A (23%
1.06 (30%
40
30
20
10
-800
-600
-400
-200
Potential, mV/CSE
200
Rail spike
: 2-3
1.2m
61
(-)
Is
Potential
Controlled
Rectifier
Is
structure
buried reference
electrode
)
instant off
7.5A
-1.0
12.5A
-1.5
E (V Vs. CSE)
-0.5
-2.0
-2.5
-3.0
-3.5
-4.0
32
30
28
26
24
T/B No.
22
20
18
T3-14
)
)
R3-5
C3-8
R3-4
T3-15
T3-12
T3-11
C3-4
R3-3
R4-4
R4-3
R4-5
R4-2
R4-6
R4-7
T3-10
R3-2
R4-8
R4-1
R3-1 C3-2
T3-8
T3-7
T3-6
C3-7 T3-5
T4-9
T3-2
T3-3
C3-9
T3-4
C3-6
66
CP
Corrosion Protection
TB
: Mg, Al
:
,
Mg
+
-
long pipelines,
gas and oil transmission lines,
ships,
chemical processing equipments, etc.
Eapp
Cu
Fe
Corrosion current
EFe<ECu
(a) before protection
Cu
Fe
Corrosion current
Eapp>ECu-EFe
(b) after protection
CURRENT
ANODE
CURRENT
CURRENT
ANODE
2.0
1.5
1.0
Galvanic
0.5
0
10
20
30
40
50
60
70
80
90
100
CP
73
CP
74
Effect of CP
76
: -850mV vs Cu/CuSO4
: -5,000mV
P/S
Pipe to Soil
(
: Sat. Cu/CuSO4
Ag/AgCl
T/B
300m - 500m
Electrochemical
Reaction
Electrochemical
Reaction
Rct
Resistance
of Solution
Rct
Rsol
Anode
Double-layer
Capacitance
: Rsol
78
Double-layer
Capacitance
Cathode
Potential (-mV)
(+)
80
ON Potential
IR
100 mV
Polarization
100 mV Depolarization
81
P/S
82
Potential (-mV)
(+)
ON Potential
IR
100 mV
Polarization
100 mV Depolarization
Time
(polarization shift)
100mV
100mV
86
(polarization shift)
87
Test Point
-500
-600
-700
-800
CP criteria
-900
TB 3
15.4mA
-1000
-1100
TB 4
14.7mA
TB 1
26.8mA
-1200
TB 9
25.2mA
TB 7
TB 6
19.2mA 34.3mA
TB 2
55mA
-1300
TB 8
0 mA
TB 5
11.4mA
-1400
-1500
0
Test points
TP
TP
Distance (km)
10
!!!
Test Point
Aboveground
Storage Tank
Grade
Test / Access
Station
Reference Cell
Monitoring
Tube
Rim
25'
On -1411 -698
Off -902 -664
Potentials (mV)
Center
55'
Rim
-404
-402
-601
-578
-1455
-911
120o
Ls
3-4m
15
10
5
-5
Defect
-10
-15
-20
-25
0
Measure Point
Solution
DCVG *1
CIPS*2
ILI*3
Internal Expert
Consulting Service
(2003)
1MPa
15
10
HCA
7
(ECDA)
(pressure testing)
, e.g., In-line inspection (MFL-ILI)
ECDA
PRE-ASSESSMENT
INDIRECT EXAM.
POST ASSESSMENT
DIRECT EXAM.
Risk Assessment
(region)
CIPS/DCVG/
SEVERE
MODERATE
MINOR
IMMEDIATE
SCHEDULED
MONITORING
/
/
1.
Pipe locator
AC
30m
ECDA
Pre-assessment
,TB,
:CIPS,DCVG,
)
,PCM
1.
Active/passive corrosion
04-4
04-3
04-2
04-1
03-4
03-3
03-2
03-1
02-4
02-3
02-2
02-1
01-4
01-3
01-2
01-1
00-4
00-3
00-2
00-1
99-4
99-3
99-2
99-1
98-4
98-3
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
1.
-2,500 --2,000
-1,000 --500
-500 -0
1.
ECDA 1
ECDA 2
ECDA 3
ECDA 4
ECDA 5
CIPS
CIPS/DCVG
PCM
CIPS/DCVG
River
Sandy-Loam
Sandy
Sandy
Loam
Medium
Well Drained
Well Drained
Poor Drainage
No History
Low
Med. Resist.
High
No History
Some Problems
Many Problems
1
CIPS(
2
2)
DCVG
(ASP)
,
/
CIS
DCVG
(
<50m,
CIS
>50m,
DCVG
CIS
PCM
CIS
DCVG
CIS
DCVG
CIS
DCVG
CIS
DCVG
CIS
PCM
Steel casing
DCVG
encasement
CIS
DCVG
CIS
DCVG
1.
2.
30m
3. 1, 2
, 40-50m
SCM
DCVG
.
CIS
DCVG
1.
2.
3.
30m
DCVG
4)(
5)( 6)
(
GSD 2124
(
6)
CIS
SCM
4)
NACE RP0502
OO
UNITS
CpIS (ICCP)
1-3m
mV (CSE)
DCVG
12m
%IR
Cathodic/anodic
- 1.2-3m
-
Resistivity
(Wenner 4-pin
method or soil
box)
PCM
1/3
, 2/3
18 45 m,
35 m
% IR
cathodic/anodic
(dip)
- %IR
cm
(50m)
20m
CIPS
(mA)
2.
TB,
TB
2.
(mVCSE)
(m)
600m-1Km
13
(TB)
M01
-498
-511
-503
M02
864
M03
1386
126
180
-59
-5
22
88
M04
2028
230
70
150
M05
2970
540
100
320
M06
3186
168
-227
-24
M07
3732
920
560
740
M08
4494
-84
-432
-285
M09
4908
148
-299
-97
M10
5748
-181
-598
-412
M11
5976
-219
-705
-432
M12
6762
-235
-535
-427
M13
7488
-207
-483
-361
TP
TP
2.
Wenner
~200m
2.
(CIPS)
120o
Ls
CIPS
CIPS
CIPS
(25 ft to 5 ft)
5 ft interval
25 ft interval
2.
DCVG
2.
Mg
115
DCVG - %iR
5 ft interval
25 ft interval
%IR
(NACE RP0502-2002)
.
.
.
117
1995
-2002
DCVG
DCVG-GPS System
120
CIPS/DCVG
GPS Antenna
Measure cable
PDA
Push switch
Bluetooth communication
receiver
(receiver
Case I.
Case II.
Case III.
Case IV.
short
Case V
Case VI
PCM
OO
transmitter
,
, 4Hz, 1A
)
transmitter
loss
Receiver
PCM
2.
(static or dynamic)
))
(STA 29+37.91)
0
STA 73
80V 9A
-300
E, mV
-600
-900
-1200
-1500
-15
-10
-5
10
15
Distance, m
: ~0.2A (
9A
2.2%)
Carrier pipe
128
casing
-500
-1,000
-1,500
-2,000
-2,500
-3,000
0
20
40
60
80
No drilling
100
120
Drilling
140
160
180
200
0
-200
-400
-600
-800
-1000
CIPS
-1200
-1400
-1600
-1800
-2000
250
%IR
300
600
900
1200
1500
1800
2100
2400
2700
3000
3300
3600
600
900
1200
1500
1800
2100
2400
2700
3000
3300
3600
600
900
1200
1500
1800
2100
2400
2700
3000
3300
3600
3300
3600
200
150
%IR
100
50
0
100000
300
PCM300
10000
1000
100
10
1
2500
2A
2A
2A
2000
1500
PCM
1000
500
0
0
300
600
900
1200
1500
1800
2100
2400
2700
3000
TB2
TB23
-2
T2 TB TB 5-1
TB23
TB2
24 25
-1
6 TB2TB2
7 8
Pipe locator/SCM
TB2
3
TB3
5
TB3
TB3 4
TB33
2
TB3
TB3
TB20 1
9
T1
CP History
Insulation Survey
Rectifier/Test
Point/Insulation Flange
Soil Corrosivity
Resistivity/Water
Content/MIC etc.
0
D2-9
D2-8
-500
-0.75V
-0.85V
P ote n tial ( VC SE )
-1000
CIPS/DCVG/PCM
-1500
-2000
23
-2500
23-1
T1
T2
23-2
26
25
25-1
Mitigation Action
Documentation
Steel Casing
DC/AC Interference, etc.
30
27 28
24
31
32
33 34
29
-3000
0
500
1000
1500
2000
2500
3000
3500
4000
4500
DIRECT EXAMINATION
(urgency of excavation)
(Immediate action required)
(Schedule for action required)
(Suitable for monitoring)
feedback
(
1
:
DCVG +
cm)
2
1
CIPS
1 good coating)
DCVG*
Severe
Moderate
Minor
NI
< 3,000
I*
S*
S*
M*
3,000 7,000
I*
S*
M*
M*
7,000 20,000
I*
S*
M*
NI*
> 20,000
S*
M*
M*
NI*
I*
S*
M*
NI
Severe
Moderate
Minor
NI
NI
NI
1
+ CIPS
* I: Immediate (
), S: Scheduled (
), M: Monitoring (
(
(minor)
2 poor coating)
(moderate)
CIPS
> 10,000
cm
(severe)
< -0.65V
5,000 10,000
Off
cm
> -0.65V
< 5,000
CIPS
I
II
III
IV
V
cm
pH
(monitoring)
Disbonded area
(scheduled)
Mechanical Damage
Coating disbondment
(
STN
(immediate)
pH
(mV)
cm)
:10,362cm2
1
-604
6,513
:56cm2
: 12
:25 ~ 70cm2
2
7~9
-735
2,098
: 12
,7
:10,362cm2
3
-562
2,538
:1,602cm2
:5.4 ~ 6.1cm2
,
8~9
-701
1,360
:7.6cm2~47cm2
Types
Potential (mV/CSE)
Pipe-to-Soil Potential
-1430 to -1200
-610 to -550
OFF
pH
2H 2O 2e
H2
pH
2OH
1)
, OH-
pH
2)
pH
(
)
pH
3)
pH
pH
pH>10~11
,
.
vs. pH
pH
.
.
pH< 8
4.
ECDA
Maximum pit depth/burial time
0.4 mm/y*1
0.3 mm/y at least 40mV CP
*1. Upper 80% confidence level of maximum pitting rates for long term (up to 17y) underground corrosion tests of
bare pipe coupons without CP in a variety of soils including native and non-native backfill.
RL
t
0.85SM
GR
FOR:
PFAIL
SM
PYIELD
PMAOP
PYIELD
) = 10 mil/yr.
RL
) = 0.330
1/2
0.330
0 .85 (. 6 )
.010
ECDA
16 .8 yr
!!!
ECDA
DCVG
.
DCVG
, ECDA
.
.
DCVG
ECDA
.
ECDA
,
feedback
DCVG
Pearson
EM
AC Attenuation
Coating holidays
1,2
1,2
1,2
Stray currents
1,2
1,2
1,2
1,2
1,2
1,2
1,2
Shorted casing
1,2
Uncased crossing
1,2
1,2
Cased piping
Wetlands (limited)
1,2
1,2
*1:
*2:
*3:
<600mm2),
147
ECDA + ILI
(
ILI
(GRI-02/0087)
33% ILI
40
75%
25%
ILI
ECDA
ILI
(
(2002)
unpiggable
. (25% + (42%))
ECDA+ILI (KOGAS
ILI
/
(Defect Assessment)
Geometry pig
MFL pig
(CIPS)
/
( )
(ECDA)
ILI-MFL
.
(threshold value)
.
Wireless
Networks
GPS
GIS
Satellite
Communication
TB 1
Rectifier
Remote
Control
Rectifier
TB 2
Remote
Monitoring
Data Logger
Reference
Electrode
Anode
155
Current
Rectifier
Remote
Monitoring
Data Logger
Remote
Control
Rectifier
Reference
Electrode
Anode
SMPS type
SCR type
(on/off)
GPS
10 msec
Installed
Being installed now (2009)
Future
Remote Monitoring
70
Manual Maintenance
Relative Cost
60
50
40
30
20
Assumption:
- Lifespan: 15 y
- One rectifier + Two TB in 2km region
10
10
15
20
25
30
10
10
9
8
7
6
5
10V
1
10
OO
(-),
= -2.5VCSE
(+)
)
6
OO
OO
4
OO
OO
vs.
2
4 P/S
3 P/S
2 P/S
35+25=60(A)
16
CIPS
logger)
(data
(#13, #26,
#28, #30)
(
R19 on/off,
25
(on/off
27mV)
)
R15 on/off,
R18 on/off,
R17 on/off,
20mV
17
(on/off
-74mV)
13
21
(on/off
(on/off
192mV)
-1756mV)
(
30
13
14
15
18
16
17
19
20
21
22
23
24
25
26
28
(m
)
-1000
6
864
2028
2364
2970
3186
3504
3732
4380
4908
5748
6762
7488
7650
8650
M1
M2
M4
M5
M6
D2
M7
M9
M10
M12
M13
End
R1
R2
R3
R4
R5
R7
R8
R9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-200
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
R11 R12
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
R13-1
R13-2
R13-3
R14
R15
R17
R18
R19
R20
R21
R22
R23
R24
R25
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
192
36
28
69
29
31
0
0
0
0
0
0
0
0
0
0
0
0
0
50
0
-74
-23
-22
0
0
0
0
0
0
0
0
0
0
24
36
43
100
94
208
-1756
258
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
49
27
43
0
0
0
0
0
0
0
0
0
0
0
26
43
29
0
0
76
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
28
30
45
43
0
0
0
0
0
0
0
0
0
ILI
IT
( )
(ECDA,
Communication is important.
Communication of agreed reasons for failures may not always
reach the designer. (ASM Metals Handbook, Vol. 13A)
Site personnel: 77%
Designers: 55%
Materials suppliers: 37%
Contractors: 11%