BoTO h.

CitiI(ConStruction Maha

ng) BoTech`CivilVater ResourcOs E ginee Ternl End Exanlination Detember,2007

91mont)/

105(B}:CHEMISTRY ET
Timc:3 hours Max:mum Mar s:7

Nore=

Alswer grr thc qucstions.Usc o/calculatOr is

a1lowed

1.

mpt any threc 6f the fon6wing: Att (a) .(1)

3 5=15

What dO ,Ou understand by HciSOnberg's ? uncertainty principl

(li) What is thO wavelength of a phOton emitted

during a transition fr9m nh.bl=4 to,inJt=? s 105 cm 1) c in the H atom.(R=10697

(b) What are the electroniC COnfigurations a d bOnd

Ord9rS 9f He2,BC2 an4 N2?

(c) Calculate the packing fraCtiOi of a simp10 cubic i lattiCe 5

_ 5

(d) Explain hydr6gen bonding givinC speCifiC exampleS.

E-105(B) P. 0:

2 ttempt any thre9 0f the fOHOwing: (a)

3 5=15

State third l,W Of therrnOdynamics and find the

entropy Of a substanec at 20 K if the mOlar heait capacity 6f the substance at 15 K is K 007 1.= 5
(b)

(1) A sattp19 0f 350 g Of wat 1 0 0 5 Ct o 5 01 C . T h e

r is heated fro s p e c i f i c h e a t o f w

is 4 184 Jg 1 C) 1 Calculate thc heat cha,ge. . (11) Defihe``Ehtropy

)

(1) At 27 C,a reaction has H +10 kJ mOl 1

1.wh =+30 JK Llo and S tth vab

What do y6u indarotand by autO atal,si ?
5

of G?

(li)
(d)

Derive rate cqatiOn for first Order r actiOn`

Attempt an (a) Dofine:

rec of the fO110wing:

3515 5

{1) NOrmality (li)M61arity (111)Molality (ivl Mole fractiOn (b) Explain a lDanicn cen in which the reaction l : l

zn Cu l)tttk9'place. ) l l)+CYa)'
ET-105(B)

(C) The equilibrium cOnstant for the reaction i )+ 2 C 1 2 2 g O + 2 1 C l + N i a )

108x1017 at 298 Ke the What vahe of the standard c l Elen H potenti r f th4is reaCtion? =80314 .Kttl ( Ol 1) . L :
)What are buffer sdu cquatiOne 1 1 ons?D ve HendersOn's 5

4Atte pt any: 90f the fo110wing:

5 Ib

3 ) bl : 7 ,allLll]:::: illFT .111 ti

WntC IUPAC hattes Of the f6HOwing: (b) 5'

(1) PtCl:l
(li) ICo(en):I C13 : :

(lil)K21Cu9141
H o)4CI (iVI Cr l Cl l

.
.
i

(VI IPt(NH3)2(N 2)21

(c)Wh l do y9u inder t and by`Hard"ater'?LiSt different methods used tO makc hard water sott aAd
eXplain any 9n of theme r5

-105(B) E

P. .0

5.

Attempt any threc of the fo1lowing: (a) Write the structures of

5=15 3 5

(1) 3-mettyl-2-butanOne (li) 2,3-dirnethyl hexane l

2-propanol (lli) 2-rnethyl (lv1 1,2-dirnethyl cyclopentene

{v1

3-chlorobutanoic acid 5

rials move grea,y mat (b) Explalh ho"soap helps to r lub19 in Watere not 3 thOugh they ar

(c,

n tt bp ye knOcknC?wntO What

the

tackle this problem.

6Lcdar (d)What is the centrJ dOCma of bi910gy?

E-105(B)

3,000