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Baloxy Thai Integral Co., Ltd.

Total Hygiene Solutions
Food Hygiene Division


Date Printed: 12/Mar/2010 1.

Identification of Product and Company

Identification of the substance and preparation Product Name: Product Use:

EvoCip 30-A
Acid Cleaner


Baloxy Thai Integral Co., Ltd. 1 / 13 Moo 4, T. Lumlukka, A. Lumlukka, Pathumthani Thailand 12150 Tel: +66-2987-0015 / +66-2987-1380 / Fax: +66-2549-5232


Composition / Information on Ingredients

Ingredient Name
Phosphoric Acid Nitric Acid

7664-38-2 7697-37-2

231-633-2 231-714-2

20-35 10-30

C: R34 O: R8, R35

See section 15 for a full text of R phrases that declared above. Occupational exposure limit (s), if available, are listed in section 8


Hazards Identification
Classification: Human Health Hazards: C: R35 Causes severe burns.


First Aid Measures

After Eye Contact: In case of eye contact, immediately rinse eyes thoroughly with plenty of water. Remove any contact lenses and continue rinsing for at least 15 minutes. Get immediate medical attention. After Skin Contact: In case of skin contact, immediately flush exposed area with plenty of water for at least 15 minutes. Remove any contaminated clothing and wash thoroughly with soap and water. Get immediate medical attention if irritation persists. After Inhalation: Remove to fresh air. If irritation persists or there is any trouble breathing, get immediate medical attention. After Ingestion: DO NOT induce vomiting. Drink plenty of water for dilution and call a physician immediately. Never give anything by mouth to an unconscious person. Specific Treatments: Not available. Treat symptomatically and supportively.


Fire-Fighting Measures
Auto-Ignition Temperature: Flash Point (C): Flammable Limits Upper: Lower: Products of Combustion: Not available > 100 Not available Not available Decomposition products may include the following materials; carbon oxides (CO, CO2), nitrogen oxides (NO, NO2), phosphorous (PO, PO2). Extinguishing Media: Use water spray, foam, dry chemical or carbon dioxide, as suitable for surrounding fire. Special Protective Equipment : For Fire-Fighters Wear self-contained breathing apparatus and protective equipment and clothing appropriate for fighting a typical chemical fire.


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Accidental Release Measures

Personal Precautions: Large spill and leak, immediately contact safety personnel. Keep unnecessary personnel away. Use suitable protective equipment. Environmental Precautions: Avoid dispersal of spilled material and runoff and contact with soils, waterways, drains and sewers. Cleaning Up Methods: Small spills, rinse with plenty of running water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal.


Handling and Storage

Handling: Wear personal protective equipment when handle product. Do not get in eyes, on skin, or on clothing. Do not breathe vapor or mist. After handling, always wash hand and protective equipment thoroughly with soap and water. Storage: Keep container tightly closed. Keep container in a dry, cool and well ventilated area and away from incompatible materials. Do not store above 40C.


Exposure Controls / Personal Protection

Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the air borne concentrations of vapours or aerosols below their respective occupational exposure limits. Ensure that safety shower and eye bath are close to workstation location. Personal Protection Respiratory Protection: A respirator is not needed under normal and intended conditions of product use. Wear appropriate respirator when ventilation is inadequate and occupational exposure limits are exceeded. Eye Protection: Wear safety glasses. Use chemical splash goggles. For continue or severe exposure, wear a face shield over the goggles when handling. Skin Protection: Wear safety apron, suitable protective footwear, rubber gloves or other protective equipment as necessary to prevent skin contact. Hand Protection: Use chemical resistant impervious gloves.

Exposure Controls Ingredient Name: Phosphoric Acid: Occupational exposure limits EU OEL (Europe, 6/2000) STEL: 2 mg/m3, 15 minutes / Form: All forms TWA: 1 mg/m3, 8 hours / Form: All forms Nitric Acid: ACGIH TLV (United States, 9/2004) STEL: 10 mg/m3, 15 minutes / Form: All forms STEL: 4 ppm, 15 minutes / Form: All forms TWA: 5.2 mg/m3, 8 hours / Form: All forms TWA: 2 ppm, 8 hours / Form: All forms


Physical and Chemical Properties

Appearance Physical State: Color: Odour: Clear liquid Colorless Pungent


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Properties pH (1.0%): Boiling Point: Melting Point: Flash Point: Flammability (solid, gas): Explosive Properties: Explosion Limits: Oxidizing Properties: Vapour Pressure: Relative Density (g/cm3: 25C): Solubility: Octanol / Water Partition Coefficient: Viscosity: Vapour Density: Evaporation Rate: 1.1-1.9 > 100C Not available > 100C Not applicable Not applicable Not applicable Not available Not applicable 1.230-1.245 Easily soluble in cold and hot water Not applicable Not available Not available Not applicable

10. Stability and Reactivity

Stability: Materials to Avoid: Stable under normal conditions of handling and storage. Extremely reactive or incompatible with alkaline and chlorinated solvents. Reactive with organic materials and metals. Non reactive with acid. Do not mix with bleach or other chlorinated detergents, will cause chlorine gas.

11. Toxicological Information

Toxicity Data Phosphoric Acid: Nitric Acid: Oral Rat: LD50 Oral Rat: LD50 1530 mg/kg > 90 mg/kg

Potential Acute Health Effects Eye Contact: Skin Contact: Inhalation: Ingestion: Severely corrosive to eyes. Severely corrosive to skins. Severely corrosive to respiration system. Cause severely burns.

12. Ecological Information

Products of Degradation: Degradation products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2), phosphates. Persistence and Degradability: Environmental Precautions: No information If acid or alkaline products are discharged into waste water, installations care must be taken that the discharged waste water has a pH in a range of pH 6-10. As pH variations could cause disorders in waste water channels a biological sewage treatment plants. Do not dispersal of spilled materials and run off as well as contact with soils, waterways, drains and sewers.


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13. Disposal Considerations

Methods of Disposal: Disposal of this product, solutions and any by-products at all time should comply with the requirements of environmental protection and waste disposal legislation as well as for containers must be completely rinsed before disposal with any regional local authority requirements.

14. Transport Information International Transport Regulations

Regulatory Information ADR / RID Class AND Class IMDG Class UN 2031 UN 2031 UN 2031 UN Number Proper Shipping Name Nitric Acid Mixture Nitric Acid Mixture Nitric Acid Mixture 8 8 8 II II II 8 8 8 Class Packing Group Label

Do not ship by air

15. Regulatory Information

Hazard Symbol: C Corrosion

Corrosion Contains: Risk Phrases: Phosphoric and Nitric acid mixtures R8 R35 R37 R38 R41 Safety Phrases: S2 S26 Contact with combustible material may cause fire. Causes severe burns. Irritating to respiratory system. Irritating to skins. Risk of serious damage to eyes. Keep out of the reach of children In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Type of Product: Type 3 Hazardous substance ACT B.E. 2535

16. Other Information

Version: Date of Issue: Date of Previous Issue: Prepared By: 1 12 March 2010 12 March 2010 Technical Division