Chemistry 161 Exam II

Student Name (Print): ______________________________ Student Signature: ____________________________________ Recitation Section Number:

March 23, 2010

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Recitation Instructor: __________________ The exam booklet has 25 questions for credit and one additional question to check the color of your exam booklet. Please answer all 26 questions on the OpScan sheet. There is no penalty for guessing. Answer each question with the best choice from those provided. At the end of the 80-minute exam period, please hand in only this top sheet and your OpScan form. Please be sure to sign your name above your printed name on the Opscan form. If you finish early, please do not disturb your fellow students. A proctor will check your picture ID, OpScan form, signature and calculator during the exam, and collect the cover page of your exam and the seat pass. The use of calculators with permanent memories (graphing calculators), cell phones, pagers, PDAs or other electronic devices other than a basic scientific calculator is expressly forbidden. The last page of the booklet contains a periodic table along with other useful data. The use of any other notes or information on this test will be considered a violation of the Academic Honesty provisions of the student code. Exam scores will be posted as soon as possible.

ON THE OpScan FORM (Use a #2 pencil or darker) 1. SIGN your name across the top of the form. 2. Code the following information (blacken circles) Your Name (LAST NAME FIRST) Your RU ID [Start under Box A and continue to Box I] 3. Your RECITATION SECTION NUMBER in K & L [Sections 01-08, code a 0 under box K] 4. Your EXAM FORM NUMBER under box P RP= Robert Porcja, LP= Louis Petrone, BL= Bryan Langowski Periods: 6 = 5:50 -6:45, 8 = 8:45-9:40

Sec 01 02 06 07 08 11 12 13 14 15 16

Per. T6 T6 Th6 Th6 Th6 T8 T8 Th8 Th8 Th8 T6

Instr RP LP LP RP BL LP RP LP RP BL BL

Your EXAM FORM is:

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BEFORE STARTING THE EXAM PUT YOUR FORM # IN COLUMN P AND YOUR SECTION # IN COLUMN K AND L ON THE SCANTRON. ALSO DARKEN THE CIRCLES PLEASE.
1. A gas bulb is connected to an open end manometer. The pressure in the bulb is 0.355 Torr more than atmospheric pressure. If the manometer is filled with mineral oil (density = 0.888 g/cm3), what will be the difference in height between the two sides of the manometer? Density of mercury is 13.6 g/cm3. A. B. C. D. E. 0.184 mm 5.44 mm 4.83 mm 0.315 mm 0.355 mm

2.

What is the concentration of an oxalic acid (H2C2O4) solution if 10.00 mL of that solution required 21.08 mL of 0.0988M KMnO4(aq) in order to reach the equivalence point? 5H2C2O4(aq) + 2MnO4-(aq) + 6H+(aq) 10CO2(g) + 2Mn2+(aq) + 8H2O(l) A. B. C. D. E. 0.0833 M 0.208 M 0.521 M 5.21 M 0.833 M

3.

What is the oxidation state of V in V2O74-? A. B. C. D. E. 5 6 7 2 4

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4.

Which of the following solutions will produce a precipitate when mixed? A. B. C. D. E. AgNO3(aq) and LiClO4(aq) HCl(aq) and NH3(aq) Hg2(NO3)2(aq) and NaCH3COO(aq) Ba(NO3)2(aq) and K2SO4(aq) NaCl(aq) and KI(aq)

5.

A gas mixture, has a total pressure of 300. Torr and consists of equal masses of Ne and Ar. What is the partial pressure of Ar, in Torr? A. B. C. D. E. 75 Torr 101 Torr 155 Torr 202 Torr 175 Torr

6.

Hydrogen peroxide, H2O2, was decomposed to water and oxygen gas and 75.3 mL of the oxygen gas was collected over water at 25 oC and 742 Torr. What mass of the oxygen gas was collected? (Vapor pressure of water = 24 Torr at 25 oC) A. B. C. D. E. 0.00291 g 0.0931 g 0.0962 g 0.0993 g 0.062 g

7.

A system delivers 1275 J of heat while the surroundings perform 855 J of work on the system. Calculate U in J. A. B. C. D. E. -2130 J -420 J 420 J 2130 J -1275 J

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8.

Consider the reaction: CH4(g) + 2 O2(g) CO2(g) + 2 H2O()

H = - 890.3 kJ

What volume of CH4(g) at 25C and 755 Torr will produce 88600 kJ of heat when reacted with excess oxygen? A. B. C. D. E. 2.45 1.57 2.46 1.55 5.60 x 103 L x 103 L x 101 L x 101 L x 102 L

9.

A block of iron with mass of 250. g is initially at 33.0 C. After absorbing 5.65 kJ of heat, what is the final temperature? (Specific heat of iron: 0.449 J/(gC)) A. B. C. D. E. 83.3 C 23.1 C 50.3 C 10.1 C 43.1 C

10.

In a Styrofoam cup calorimeter, what is the final temperature when 100. g of iron at 100. C is added to 100. g of water at 20. C? (Specific heat of iron: 0.449 J/gC; specific heat of water: 4.18 J/g0C) A. B. C. D. E. 50 C 60 C 28 C 72 C 40 C

11.

A 0.167 g sample of Mg(s) is burned in a bomb calorimeter which has a heat capacity of 3081 J/C. In this process, the temperature of the calorimeter increased by 1.34 C. Calculate the heat given off by burning Mg(s) under these conditions (in kJ/mol). A. B. C. D. E. 601 kJ/mol 24.7 kJ/mol 1.02 kJ/mol 933 kJ/mol 9.33 kJ/mol

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12.

Consider the process in which a pressure cooker three fourths full of liquid water is heated. Which statement is incorrect? A. B. C. D. E. Water vapor will be formed. Water will boil at a temperature greater than 100 C. The pressure will increase. The temperature will increase. More work will be done with the pressure cooker than with an open pot containing the same amount of water.

13.

In a certain process, the internal energy of a system increases 40.7 J and the quantity of work the system does on the surroundings is 78.9 J. Which one of the choices is correct? A. B. C. D. E. q = - 38.2 J q = + 119.6 J q = + 38.2 J q = - 119.6 J q = + 59.8 J

14.

What is the mass of 2.88x104 L of N2 (g) at STP? A. B. C. D. E. 3.60x104 g 4.63 x104 g 8.06x104 g 6.28x103 g 1.29x103 g

15.

The products in the net ionic equation for the reaction of BaS(aq) with CuSO4(aq) are: A. B. C. D. E. Ba2+(aq), SO42 (aq) , Cu2+(aq), and S2 (aq) Ba2+(aq), SO42 (aq) , and CuS(s) BaSO4(s) and CuS(s) BaSO4(s), Cu2+ (aq), and SO42 (aq) BaS(s), SO42 (aq) and CuS(s)
-

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16.

A gas starts out in an expandable 5.00 L cylinder at 20.0 C and 1.50 atm. If the Kelvin temperature doubles and the pressure decreases to one fourth of its original value, the volume has changed to A. B. C. D. E. 2.50 L 10.0 L 30.0 L 40.0 L a volume greater than 50.0 L

17.

The root mean square speed of CH4 at 160 K is 5.0x102 m/s. At what temperature will the root mean square speed of C2H6 be the same? A. B C. D. E. 160 K 155 K 123 K 155 K 301 K

18.

Consider the reaction: 6 FeCl2 + K2Cr2O7 + 14 H+ 6 Fe3+ + 2 Cr3+ + 7 H2O + 2 K+ + 12 Cl

-

What is the mass percent of FeCl2 in a 2.000 g sample of impure FeCl2 if the impure sample was titrated with 25.72 mL of 0.1006 M K2Cr2O7 to the endpoint? (Molar mass of FeCl2: 126.7 g/mol) A. B. C. D. E. 19. 99.82 % 98.35 % 97.25 % 93.29 % 90.00 %

A container holds 1.00 mol O2, and the pressure in the container is 2.00 atm. A student adds 60.0 g of gas Y to the container. The total pressure (of O2 and gas Y) is 3.00 atm. What is the molar mass of gas Y? (V and T constant) A. B. C. D. E. 180 g/mol 90.0 g/mol 120 g/mol 160 g/mol 141 g/mol

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20.

Which one of the following salts will not produce a gas upon treatment with acid? A. B. C. D. E. Na2SO4 K2SO3 NaHS Cs2S LiHCO3

21.

The temperature of a 15-g sample of lead metal increases from 22C to 37C upon the addition of 29.0 J of heat. The specific heat capacity of the lead is: A. B. C. D. E. 7.8 J/gC 1.9 J/gC 29 J/gC 0.13 J/gC -29 J/gC

22.

The H for the solution process when solid sodium hydroxide dissolves in water is 44.4 kJ/mol. When a 13.9 g sample of NaOH dissolves in 250.0 g of water in a coffee-cup calorimeter, the temperature increases from 23.0C to ________C. Assume that the solution has the same specific heat as liquid water: 4.18 J/gC. A. B. C. D. E. 35.2C 24.0C 37.8C 37.0C 40.2C

23.

Which one of the following underlined atoms can only be oxidized? A. B. C. D. E. H2S N2 S2Cl2 NO ClO2

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24.

Which one of the following conditions would always result in an increase in the internal energy of a system? A. B. C. D. E. The system loses heat and does work on the surroundings. The system gains heat and does work on the surroundings. The system loses heat and has work done on it by the surroundings. The system gains heat and has work done on it by the surroundings. The temperature of the system remains constant.

25.

Which one of the following reactions is not a redox reaction? A. B. C. D. E. 2SO2 + O2 2SO3 2NaOH Na2O + H2O S2Cl2 2S + Cl2 2N2O 2N2 + O2 2AgCl 2Ag + Cl2

26.

What is the color of your exam? A. B. C. D. White Green Pink Blue

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CHEM 161 EXAM II DATA AND FORMULAS K = 273.15 + C 1 atm = 760 mmHg = 760 Torr

SPRING 2010

1 mol = 6.022 1023 objects

R = 0.0821 L.atm/mol.K = 8.31 J/mol.K

1 L =1000 cm3

% yield =

actual yield x 100 % theoretical yield P = hdg r2/r1 = d = m/V

q = m x s x T
u rms = 3RT/.M.

PV = nRT

M 1 /M 2 (T constant)

1 L.atm = 101.3 J
U = q + w

PV P1V1 = 2 2 n1T1 n2T2

k =

3 R T 2 NA

1W = 1J.s 1

U = qv H = qp

w = -PV

H = U +PV

STP = 1.0 atm and 0C

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