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In an acid-base neutralization, an acid and a base react to form water and salt. In order for the reaction to carry out, there must be the transfer of protons between acids and bases. Proton acceptors and proton donors are the basis for these reactions, and are also referred to as conjugate bases and acids.
React with metals Have a low pH When phenolphthalein (a common indicator) is added to an acidic solution during a titration, the solution stays clear.
Arrhenius Acid: An Arrhenius acid produces hydronium ions [H3O ] when it dissociates in water. + Bronsted-Lowry Acid: Proton donor; donates hydrogen ions [H ] to the base.
What makes an acid strong or weak? A strong acid is one that can dissociate easily to form hydrogen ions. A weak acid is one that can not dissociate as easily, therefore cannot form hydrogen ions as readily. Example of a strong acid in solution
Examples of Weak Acids: Acetic acid (HC2H3O2), hydrofluoric acid(HF), Nitrous Acid (HNO2) Examples of Strong Acids: Hydrochloric Acid (HCl), Sulfuric Acid (H2SO4), Nitric Acid (HNO3)
Bases
Is an electrolyte Has a high pH level When phenolphtalein is added to a basic solution during a titration, the solution turns pink. Arrhenius Base: An Arrhenius Base produces hydroxide ions [OH ] when it dissociates in water. + Bronsted-Lowry Base: Proton acceptor; accepts hydrogen ions [H ] from the acid.
What makes a base strong or weak? Like a strong acid, a strong base dissociates easily to form not hydronium, but hydroxide ions. A weak base cannot dissociate as easily, therefore cannot form hydroxide ions as readily.
Examples of Weak Bases: Ammonia (NH3), Phosphate Ion (PO4 ), Water (H2O) Examples of Strong Bases: Sodium Hydroxide (NaOH), Potassium Hydroxide (KOH), Calcium Oxide (CaO)
3-
Acid/Base Reactions
NH3(g)+H2O(l)NH+4(aq)+OH(aq We say that NH4+ is the conjugate acid to the base NH3, because NH3 gained a hydrogen ion to form NH4+, the conjugate acid. Theconjugate base of an acid is formed when the acid donates a proton. In the equation, OH- is the conjugate base to the acid H2O, because H2O donates a hydrogen ion to form OH-, the conjugate base. Note: The stronger the acid or base, the weaker the conjugate. The weaker the acid or base, the stronger the conjugate.
1. 2.
HNO3 Is an acid because it donates a proton to water and its conjugate base is NO3 .An easy way to identify the conjugate base is that it differs from the acid by one proton. H2O is a base because it accepts a proton from HNO3 and its conjugate acid is H3O . Again to identify the conjugate acid (or any conjugate pair) is that it differs from the base by one proton. The following table is an example of conjugate acid and base pairs in a given equation:
+
Equation
Acid
Base
HClO2
H2O
ClO2-
H3O+
H2O HCl
OClH2PO4-
OHCl-
HOCl H3PO4
Practice Problems
Identify the acid, base, conjugate acid and conjugate base for the following reaction: 1. 2. 3. 4. 5.