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UJIAN BULANAN TINGKATAN 5 APRIL 2007

CHEMISTRY 1 hour 15 minutes

DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO Information for candidates : 1. This question paper consists of two section, Section A and Section B 2. Section A - objective questions Section B structured questions 3. Answer all the question and write your answers in the spaces provided 4. Do not remove this page. Attach with your answers. FOR EXAMINER USED ONLY SECTION MARKS A 1 2 B 3 TOTAL

_______________________________________________________________________ This question paper consists 11 printed pages

SECTION A 1 Which of the following is an organic compound ? A B C D 2 Calcium carbonate Potassium cyanide Methane Sodium hydrogen carbonate

When a mixture of an organic substances and copper(II) oxide is heated strongly as shown in figure below , a gas is evolved at X

Which of the following is gas X A B C D 3 Hydrogen Oxygen Methane Carbon dioxide

Which of the following is true of hydrocarbon ? A B C D The combustion of hydrocarbon in excess air produces carbon monoxide, carbon dioxide, carbon and water Hydrocarbons of low molecular mass are soluble in water whereas hydrocarbons of high molecular mass are insoluble in water The bigger the size of molecules of hydrocarbon, the lower the melting point. The melting point and boiling point of hydrocarbons are directly proportional to the number of carbon atoms in its molecule.

Ethane and ethene is classified as a hydrocarbon because both A B C D contains only carbon and hydrogen are a liquid at room temperature are insoluble in water but soluble in organic solvent contains two carbon atom

When a mixture of methane and bromine is exposed to strong sunlight, a reaction occurs. Which of the following is correct about this reaction ? A The major product is ethane B A substitution reaction takes place 2

C Hydrogen chloride is liberated D An addition reaction takes place Which of the following is an unsaturated hydrocarbon ?

What is the main product when chlorine reacts with methane ? A B C D Chloromethane and hydrogen Tetrachloromethane and hydrogen chloride Dichloromethane and hydrogen Dichloromethane and Tetracloromethane

Alkane A B C D are always gases are more reactive than alkenes are water-soluble contains single covalent bonds only

Which of these is a saturated molecule ? A B C D C4H6 C6H6 C8H18 C3H6

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Which of these molecules is an alkene ? A B C D C6H14 C8H18 C10H22 C22H44

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When ethene combines with steam to form ethanol, this is an example of A B an addition reaction a neutralization reaction 3

C D 12

a displacement reaction a substitution reaction

Which of these is an incorrect structural formula of a hydrocarbon ?

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The melting point and the boiling point of alkanes are comparatively low Which of the following explains the above statement A B C D Alkanes are hydrocarbons Atoms in an alkane molecule are bonded by weak covalent bonds Alkanes are molecular compound Alkane molecules are held to one another by weak attraction forces

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Which of the following is true of both ethane and butane ? A B C D Burn in limited oxygen to produce carbon monoxide, carbon and water Decolourise acidified potassium manganate(VII) solution Are represented by the general formula CnH2n Shows addition reaction with halogens

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Heptene and octene are members of the alkene homologous series. Base on this, it can be expected that both alkenes I II III IV A B C D can be represented by the general formula CnH2n have similar chemical properties have a similar functional group have similar physical properties I and IV only II and III only I, II and III only I, II, III and IV

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Propene undergoes an addition reaction with bromine to form a single product, X. Which of the following is the correct structural formula of X ?

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Which of the following is a saturated hydrocarbon A B C D Alkane Alkene Alcohol Carboxylic acid

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The structural formulae of two organic molecules are shown below

Both molecules A have the same molecular formula B decolourize bromine water in the dark C polymerize to form polypropene D burn completely in oxygen to produce carbon dioxide and water

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The result of tests on compound X are shown Test Add bromine water Add acidified Potassium Manganate(VII) solution What is compound X Result Turns colourless Turn colourless

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Propene is an unsaturated hydrocarbon. Its structure is shown below

What is produced when propene reacts with water at 300oC and 60 atm using H3PO4 as a catalyst ?

ANSWER FOR SECTION A 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = A= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = B= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= = C= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D= =D=

SECTION B 1. . The apparatus shown in the diagram was used to study the combustion of a liquid hydrocarbon, Hexane, C6H14

Gases from the burning hydrocarbon were drawn through the apparatus for several minutes. (a) A clear , colourless liquid appeared at X. (i) Name this liquid. ..................................... (ii) Describe a test to prove the identity of this liquid (b)(i) What would you observed at Y as the experiment was carried out ? (ii) Name the gas that produce at Y. ... (c) Write a balanced chemical equation for the complete combustion of hexane .. 8

(d)

When the experiment was completed, a black deposit was noted at Z (i) Name the black deposit .. (ii) Explain how the black deposit was form .. ..

(e)

Name the homologous series for hexane . ..

The structure of four hydrocarbon molecules P, Q, R and S are as follows:

(a) State the meaning of hydrocarbon .... (b) Which of these molecules (i) are saturated hydrocarbon ? 9

... (ii) would decolorise bromine water ? (iii) is called propene ? ... (iv) undergoes addition reactions ? .. (c) Hydrocarbon P reacts with chlorine in sunlight(uv) to produce a mixute of products. One product of the reaction is chloromethane, CH3Cl. (i) Write the balanced chemical equation for the reaction. (ii) What type of reaction is taking place ? ... (iii) Other products formed include dichloromethane, CH2Cl2 and trichloromethane, CHCl3. Write down the name and formula of the last product. Name : ... Formula : 3 The melting point and boiling points of the several members of the alkene series are shown in table below Compound Ethene Propene But-1-ene Pent-1-ene Hex-1-ene Hept-1-ene Molecular formula C2H4 C3H6 C4H8 C5H10 C6H12 C7H14 Melting point(oC) -168 -185 -174 -138 -98 -83 Boiling point(oC) -104 -49 -6 30 64 53

(a) What is the physical state of the alkenes below at room conditions ? (i) (ii) Propene Hept-1-ene : ... : ... 10

(b) What is the relationship between the boiling points and the relative molecular mass of alkene members ? .. .. (c) (i) Give the general formula of the alkene homologous series. .. (ii) Write the molecular formula of the alkene member with 10 carbon atoms in its molecule. .. (d) Draw the structural formula of Hex-1-ene

(e) Write a chemical equation to represent the reaction between ethene and bromine water. ........ (f) Hexene, C6H12 and Hexane, C6H14 are both hydrocarbon with the same number of carbon atom. (i) Compare the sootiness of flame during the combustion of both hydrocarbon. (ii) Explain your answer in (f)(i)

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