CLASS TEST - 3

Q.1 What is true about the following equilibrium ?

CHEMISTRY

IIT-JEE

P. JOY
+ H3C C K

(A) (B) (C) (D) Q.2

H
+ H3C H

It will be almost completely It will be almost completely The equilibrium constant is The equilibrium constant is

shifted to the left. shifted to the right. very close to one. zero.

What is the ranking of the equilibrium constants for the following reactions ?

(A)

(B) (A) A > B > 1 Q.3 (B) 1 > A > B (C) A > 1 > B Q.8 (D) B > 1 > A

Give one of the major products of the reaction between acetic acid (CH 3CO 2H, pKa ~ 4.5) and formic acid (HCO2H, pKa ~ 3.5) (A) (B) (C) (D)

Q.4

Which of the following structures are correct?

Identify each species in the following equilibrium according to the code : SA = stronger acid; SB = stronger base; WA = weaker acid; WB = weaker base The pK a of (CH 3) 2 NH is 36; the pKa of CH 3OH is 15.2. + (CH3)2NK l CH3OH 1 2 1 2 1 2 (A) W A WB (B) WB WA (C) S A SB (D) SB SA (E) W A WA The correct mechanism of reaction between formaldehyde and boron trifluoride given by-

(A)

(B)

(C)

(D)

Q.9

Q.5

For the following two acid base reactions, which is true ? CH3CH3 + CH 3NH I CH3CH2 + CH3NH2 pKa = 35 pKa = 50 + H2O HF + HO II F pKa = 15.7 pKa = 3.2 (A) I is favored to the right, II is favored to the left (B) I is favored to the left, II is favored to the right (C) I is favored to the right, II is favored to the right (D) I is favored to the left, II is favored to the left From the following reactions HC CH + LiNH2 NH3 + HC CLi H2O + CH CLi HC CH + LiOH predict which of the following orders regarding the acid strength is correct. (A) HC CH > H2O > NH3 (B) HC CH > NH3 > H2O (C) H2O > HC CH > NH3 (D) H2O > NH3 > HC CH Referring to the following equilibrium (R = alkyl group) RCH 2CH2 + RCCH RCH2CH3 + RCC: (A) K < 1; the equilibrium would lie to the left. (B) K > 1; the equilibrium would lie to the right. (C) K = 1; equal amounts of all species would be present (D) Not enough information is given; the structure of R must be known.
..

:O :
(A)

O + H B F3 H C

C H

B F 3H

:O :
(B)

B F3

C H H

B F3 H

C H B F3

Q.6

:O :
(C)

C H H

B F3 H

C H

Q.7

:O :
(D)

O + H B F3 H C
B F

C H

H
3

Q.10

Which of the following produces a significant amount of acetylide ion on reaction with acetylene ? (A) Conjugate base of CH3OH (pK a = 16) (B) Conjugate base of H2 (pKa = 35) (C) Conjugate base of H2O (pKa = 16) (D) Both (a) and (c)

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CHEMISTRY IIT JEE (CLASS TEST - 3) A N S W E R K E Y
Name : .......................................................................................................... 1 2 3 4 A B C D 5 6 7 8 A B C D 9 10

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Roll No. : .................................. A B C D