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MID-YEAR EXAMINATION (CHAPTER 1 TO CHAPTER 3)

This question paper consists of 50 questions. Answer all the questions. Each question is followed by four options A, B, C and D. Choose the correct answer for every question. A

4541/1 KIMIA KERTAS 1 1 jam 15 minit

Question 1 and Question 2 are based on Diagram 1. 1 Diagram 1 shows the volume of hydrogen gas in a reaction when a piece of granulated zinc is added into hydrochloric acid.

slower as the reaction progresses because A the amount of hydrogen gas is increasing. B the temperature is increased. C the mass of the magnesium ribbon is decreasing. D the solution becomes saturated with magnesium sulphate. 6 Which of the following mixtures will result in the lowest reaction rate? A 20 cm3 of 1 mol dm3 hydrochloric acid and 2 g of marble chips. B 20 cm3 of 0.2 mol dm3 hydrochloric acid and 4 g of marble chips. C 20 cm3 of 0.2 mol dm3 hydrochloric acid and 4 g of marble powder. D 20 cm3 of 2 mol dm3 hydrochloric acid and 2 g of marble powder. 7 Diagram 2 shows the set-up of the apparatus for the reaction between sodium thiosulphate solution and dilute sulphuric acid to form a precipitate.

Diagram 1

What is the average rate of overall reaction? A 0.18 cm3 s1 C 0.32 cm3 s1 3 1 B 0.16 cm s D 0.13 cm3 s1 2 What is the average rate of reaction between 60 and 90 second? A 0.133 cm3 s1 C 0.533 cm3 s1 B 0.167 cm3 s1 D 0.267 cm3 s1 3 Which of the following can be used to determine the rate of reaction? I The change of the pH. II The change of the temperature. III The change of electrical conductivity. IV The mass change of reaction mixture. A I and II only B II and III only C I, II and III only D I, II, III and IV 4 Which of the following statements is correct about the rate of reaction? A It is usually increased when the concentration of one of the reactants in increased. B The rate of reaction is constant if the reaction is carried out at a very high temperature. C The rate of reaction doubles when the amount of catalyst is doubled. D It will be very rapid if the activation energy is high. 5 The reaction between sulphuric acid and magnesium ribbon becomes
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Diagram 2

The time, t, taken for the reaction to complete is recorded. Which of the following graphs shows the relationship between the concentration of sodium thiosulphate solution against ? 8 Table 1 shows the reacting conditions of two sets of experiments. I 0.5 g of calcium carbonate is added in 50 cm3 of 1.0 mol dm3 hydrochloric acid.

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MID-YEAR EXAMINATION (CHAPTER 1 TO CHAPTER 3)

4541/1 This question paper consists of 50 questions. Answer all the questions. Each question is followed by four options KIMIA A, B, C and D. Choose the correct answer for every question. KERTAS 1 1 jam 15 minit 9 Which of the following reasons are Which of the parts labelled A, B, C II 0.5 g of calcium carbonate is 3 3 correct about the uses of catalysts in and D, shows the activation energy added in 50 cm of 2.0 mol dm industry? for the reaction? hydrochloric acid. I Increase the rate of products 13 The rate of decomposition of formation. Table 1 hydrogen peroxide can be increased II Lower cost of manufacturing in a Which of the following shows the by adding manganese(IV) oxide. shorter time. volume of carbon dioxide collected This is because III To produce a better quality of against time for both experiments is A manganese(IV) oxide has a larger product. correct? surface area. IV Save energy and time. A B manganese(IV) oxide can A I and II only increase the concentration of B I and IV only hydrogen peroxide in the C I, II and III only reaction. D I, II and IV only C manganese(IV) oxide can reduce the activation energy of the 10 Which of the following reaction. interpretations are correct about the D manganese(IV) oxide can collision theory of chemical increase the kinetic energy of reaction? hydrogen peroxide particles. I The rate depends on the B frequency of effective collision. II The rate depends on the mass of the reactant molecules. III The rate depends on the magnitude of activation energy. IVThe rate depends on kinetic energy of the colliding particles. A I and II only B II and IV only C I, III and IV only D II, III and IV only 11 When the particle size of a fixed mass of solid reactant is smaller, the rate of reaction increases because smaller pieces of solid reactant A have a larger total surface area exposed for collision. B have a high kinetic energy. C have smaller total surface area exposed for collision. D have a low activation energy. 12 Diagram 3 shows an energy profile diagram for a reaction represented by the following equation: L+MN+O 14 How does the increase of pressure in a chemical reaction raise the rate of reaction? I There is increase in the molecules per unit volume of gas. II Increase the frequency of effective collisions. III Increase the total number of particles in the gas. IV Increase the total surface area for collision. A I and II only C II and IV only B I and III only D III and IV only 15 Which of the following match of industrial process and catalysts are incorrect? Industrial process A Haber process B Contact process C Margarine production D Ostwald process Catalyst Iron powder Vanadium (V) oxide Aluminium oxide Platinum

16 Which of the following is an inorganic compound? A Ethanol C Carbon dioxide B Petroleum D Fat 17 A non-hydrocarbon is an organic compound that contains A carbon and hydrogen only.
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Diagram 3
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MID-YEAR EXAMINATION (CHAPTER 1 TO CHAPTER 3)

4541/1 This question paper consists of 50 questions. Answer all the questions. Each question is followed by four options KIMIA A, B, C and D. Choose the correct answer for every question. KERTAS 1 1 jam 15 minit B carbon, hydrogen, oxygen and 23 Diagram 5 shows the structure of nitrogen. compound X and compound Y. 25 Calculate the volume of carbon C carbon only. dioxide gas produced when 4.0 g of D hydrogen only. butene is completely burned in air. [Relative atomic mass: H, 1; C, 12; 1 18 Below shows a molecular formula mole of gas occupies a volume of 24 that can be found in a compound X. dm3 at room temperature and Compound X pressure] CH3(CH2)4CH3 A 6.0 dm3 C 6.9 dm3 Which of the following is compound B 3.5 dm3 D 5.5 dm3 X? A Fat C Alcohol 26 The following shows the structural B Starch D Petroleum formula of butene. Compound Y CH3 CH = CH CH3 Diagram 5 19 Diagram 4 shows the structural Which of the following is the isomer formula of an organic compound. Which of the following difference of butene? on these compounds is correct? A Compound X A Insoluble in organic solvents B Nonconductors of electricity C It is in solid form D Less sooty flame Compound Y Soluble in organic solvents
Conductors of electricity

Diagram 4

What is the IUPAC name of the organic compound? A Pentane B 2, 4-dimethylpentane C 2-ethyl-4-methylpentane D 3, 5-dimethylbutane 20 What are the products formed when butane burns in insufficient supply of air? A Butane and water B Carbon monoxide and water C Carbon and hydrogen D Carbon monoxide and methane 21 Complete combustion of 1 mole of a hydrocarbon Y produces 8 moles of water. Alkane Y is A hexane B pentane C heptane D propane 22 The following chemical equation shows the reaction between hexane and oxygen. 2C6H14 + 19O2 12CO2 + 14H2O What is the minimum weight of oxygen required for the complete combustion of 1 mole of hexane? A 304 g B 152 g C 204 g D 608 g
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It is in liquid form D More sooty flame

24 Below shows the equation of the reaction between pentene and bromine gas.

27 C4H10 has how many isomer? A 2 C 4 B 5 D 8

What is the structural formula of Q? A

28 Which of the following represents the structural formula of an alcohol? A

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MID-YEAR EXAMINATION (CHAPTER 1 TO CHAPTER 3)

This question paper consists of 50 questions. Answer all the questions. Each question is followed by four options A, B, C and D. Choose the correct answer for every question. D Ethyl ethanoate 33 Latex from rubber trees will coagulate with a faster rate when mixed with A ammonia solution B ammonium chloride C ethanoic acid D water 34 Which of the following metal compound is the strongest reducing agent? A Zn C Ag B Pb D Sn 35 Chlorine shows different oxidation number in different compounds. Which of the following shows the oxidation number of NaClO, HClO 4 and Cl2O? NaClO A B C D 1 +1 +2 0 HClO4 0 +7 1 +6 Cl2O +1 +1 2 +4 B The colour of chlorine water changes to dark blue. C Electrons flow from electrode Y to X through the connecting wire. D Chlorine water acts as a reducing agent. 38 Element P is a strong oxidising agent. Which of the following most likely to be the electron arrangement of P atom? A 2.8.1 B 2.8.8 C 2.8.6 D 2.8.7 39 Diagram 7 shows the rusting process of iron.

4541/1 KIMIA KERTAS 1 1 jam 15 minit

29 The following word equation shows a chemical reaction.

Which of the following is Y? A Yeast B Oil C Glucose D Sulphuric acid 30 What is the functional group of a carboxylic acids? A Hydroxyl group B Carbon-carbon double bond C Carboxyl group D Carboxylate group 31 What is the structural formula of the organic compound formed when ethanoic acid reacts with propanol? A

Diagram 7

36 The following is an ionic equation for a reaction. Zn (s) + 2H+ (aq) Zn2+ (aq) + H2 (g) Which of the following statements is true about the reaction? A Zn is the oxidising agent. B Oxidation number of hydrogen changes from +2 to 0. C Hydrogen ion is oxidised. D Zn is oxidised. 37 Diagram 6 shows an experiment to observe the transfer of electrons.

Which of the following equations occurs at the anode and cathode? Anode A Fe (s) Fe2+ (aq) + 2e Cathode Fe (s) Fe3+ (aq) + 3e

B 4OH (aq) Fe (s) 2H2O (l) + O2 (g) Fe2+ (aq) + 2e C Fe2+ (aq) Fe3+ (aq) + e D Fe (s) Fe2+ (aq) + 2e Fe (s) Fe3+ (aq) + 3e 4OH (aq) 2H2O (l) + O2 (g) + 4e

32 The following chemical equation shows the formation of an organic compound.

40 Diagram 8 shows three iron nails which are wrapped with metals L, M and N and then are placed in potassium hexacyanoferrate(III) solution.

Diagram 6

What is the name of the compound Z? A Ethyl propanoate B Propyl ethanoate C Propyl propanoate
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Which of the following statements if true? A The colour of the potassium bromide solution changes from colourless to orange.

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MID-YEAR EXAMINATION (CHAPTER 1 TO CHAPTER 3)

This question paper consists of 50 questions. Answer all the questions. Each question is followed by four options A, B, C and D. Choose the correct answer for every question.
Diagram 8 Q change change

4541/1 KIMIA KERTAS 1 1 jam 15 minit

After 2 days, the results are shown in the table below. Pair of metals Iron + L Iron + M Iron + N Intensity of dark blue colouration None Low High

Copper is No change Zinc is displaced displaced

Arrange the metals in descending order of reactivity. A O, P, Q B O, Q, P C Q, P, O D P, O, Q 45 A mixture of magnesium powder, copper oxide and calcium oxide is heated in a crucible until no more reaction occurs. After heating, the mixture contains A calcium oxide, magnesium powder and copper oxide. B calcium, magnesium oxide and copper oxide. C calcium oxide, magnesium oxide and copper. D calcium oxide, magnesium oxide and copper oxide. 46 Which of the following can be used to extract zinc from zinc nitrate in laboratory? I Calcium III Carbon II Tin IV Hydrogen A I and II only C II and III only B I and III only D III and IV only 47 Diagram 9 shows the set-up for a simple chemical cell.

Diagram 10

Arrange metals L, M and N in increasing order of reactivity. A N, M, L B L, M, N C M, L, N D M, N, L 41 Which of the following metals can act as the sacrificial metal to protect iron from rusting? A Copper B Lead C Magnesium D Silver 42 Which of the following metal oxides can be reduced to the metal using iron? A Magnesium oxide B Copper oxide C Aluminium oxide D Zinc oxide 43 Below shows a portion of the reactivity series of metals. ... , Al, Y, Zn, ... What is element Y? A Copper B Carbon C Hydrogen D Calcium 44 The table below shows the results of displacement reactions.
Solution CuSO4 MgSO4 (aq) ZnSO4 (aq) (aq) Metal O P Copper is Magnesium Zinc is displaced is displaced displaced No No change No

Which of the following equations occurs at the negative electrode and positive electrode? Positive electrode Negative electrode

A Cu2+ (aq) + 2e Zn (s) Cu (s) Zn2+ (aq) + 2e B Zn2+ (aq) + 2e Cu (s) Zn (s) Cu2+ (aq) + 2e Cu2+ (aq) + 2e C Zn (s) 2+ Zn (aq) + 2e Cu (s) D ZnSO4 (aq) CuSO4 (aq) Zn2+ (aq) + Cu2+ (aq) + SO42 2 SO4 (aq) (aq) 49 The table below shows the information of voltage obtained from three simple cells. Pair of metals L and M N and M O and M Voltage (V) 4.50 1.00 0.40 Positive terminal L N M

Diagram 9

What modification can be made so that a lower voltage is obtained? A Change the voltmeter. B Reduce the distance between aluminium and iron plates. C Replace the aluminium plate with carbon. D Replace the sodium chloride with copper sulphate. 48 Diagram 10 shows the set-up of the Daniell cell.

What is the voltage of the cell in which L and O are used as electrodes? A 2.5 V B 3.5 V C 5.0 V D 4.9 V 50 During electrolysis of copper(II) sulphate solution, the reactions occurring at the anode are A 2H+ + 2e H2 B Cu2+ + 2e Cu C 4OH O2 + 2H2O + 4e D O2 O2 + 2e

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MID-YEAR EXAMINATION (CHAPTER 1 TO CHAPTER 3)

This question paper consists of 50 questions. Answer all the questions. Each question is followed by four options A, B, C and D. Choose the correct answer for every question. SECTION A [60 marks] Answer all the question in this section

4541/1 KIMIA KERTAS 1 1 jam 15 minit 4541/2 KIMIA

KERTAS 2
2 jam 30 minit 1 A student sets up an experiment to investigate the rate of reaction of calcium carbonate with excess hydrochloric acid. The student uses a measuring cylinder to collect and measure the total volume of gas produced every 30 seconds. The results are shown in Table 1. Time (s) 0 30 60 90 120 150 180
Table 1
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[1 mark] 2 A conical flask containing 50 cm3 of 0.1 mol dm3 sodium thiosulphate solution is added with 5 cm 3 of 1 mol dm3 sulphuric acid. The conical flask is placed on top of a piece of white paper with an X mark, as shown in Diagram 1. The time required for the X mark to disappear from sight is recorded. Five experiments are carried out with five different temperatures.

Volume (cm3) 0 20 35 44 47 48 48

(a) Draw the set-up of the apparatus for the experiment.

Diagram 1

Table 2 shows the result obtained. Experiment Temperature (C) Time (s) 1 (s1) Time [2 marks] (b) (i) State the gas that released in the experiment.
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1 20 31

2 30 10

3 40 7

4 50 5

5 60 4

Table 2

[1 mark] (ii) Calculate the average rate of liberation of gas in cm3 s1.
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(a) (i) Write the chemical equation for the reaction between sodium thiosulphate solution and sulphuric acid.
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[1 mark] (ii) Complete the Table 2.

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[2 marks] (iii) Write a balanced equation for the reaction.

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[2 marks] (b) Use the data in the Table 2 to plot a graph of: (i) temperature (C) against time (s).
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[1 mark] (c) (i) Give two methods to increase the rate of reaction without changing the quantity of gas released in the experiment.
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[2 marks] 1 (ii) temperature (C) against Time .

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[2 marks] (ii) The rate of reaction decreases as the reaction proceeds. Briefly explain the reason.

[2 marks]
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MID-YEAR EXAMINATION (CHAPTER 1 TO CHAPTER 3)

4541/1 This question paper consists of 50 questions. Answer all the questions. Each question is followed by four options KIMIA A, B, C and D. Choose the correct answer for every question. KERTAS 1 1 jam 15 minit (c) (i) Referring to the graph in (b) (ii), state the (d) Write the chemical equation for process Z. relationship between the temperature and the rate _______________________________________________________ of reaction. [1 mark] ___________________________________________________ [1 mark] (ii) Use the collision theory to explain how the temperature affects the rate of reaction.
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[2 mark] (iii) What is meant by rate of reaction?

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(e) Give one use of ester. ____________________________________________ _ [1 mark]

[1 mark] 3 Diagram 2 shows the flow chart of a series of reactions.

4 Diagram 3 shows the structural formulae of two compound P and Q.

Diagram 3 Diagram 2

(a) Write the molecular formula of compound P and compound Q.

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(a) Write the molecular formula for: (i) propanol.

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[2 marks] (b) Name compound P and compound Q according to IUPAC nomenclature.

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(ii) propanoic acid.

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[2 marks] (b) (i) Name the process Y and process Z.

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[2 marks] (c) Draw the structural formulae of two isomers of compound P.

[2 marks] (ii) Identify catalyst M.

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[1 mark] (iii) Identify compound X.

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[1 mark] (c) Draw the structural formulae and name the ester.

[2 marks] (d) Compound Q can be converted into compound P. (i) Draw a labelled diagram for the apparatus used to carry out this conversion.

[2 marks] (ii) Name this reaction.

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MID-YEAR EXAMINATION (CHAPTER 1 TO CHAPTER 3)

This question paper consists of 50 questions. Answer all the questions. Each question is followed by four options A, B, C and D. Choose the correct answer for every question.
________________________________________________________

4541/1 KIMIA KERTAS 1 1 jam 15 minit

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[1 mark] (iii) Give two reagents that used to convert compound Q into compound P.
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[1 mark] (f) Write the ionic equation for the reaction that occurred in negative terminal and positive terminal.
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[2 marks] 5 Diagram 4 shows an experiment conducted to study redox reaction. 6

[2 marks] Diagram 5 shows the set-up of the apparatus for an experiment.

Diagram 4

(a) (i) Give an example of solution Y.

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[1 mark] (ii) What is the function of solution Y?

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Diagram 5

(a) State the observation for the reaction: (i) in test tube I.
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[1 mark] (b) (i) Which rod is the anode?

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(ii) in test tube II.

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[1 mark] (ii) Explain your answer given in (b) (i).

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[2 marks] (b) Referring to the reaction in test tube I, (i) name the reducing agent.
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[1 mark] (iii) State one observation in the anode.

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[1 mark] (ii) briefly explain your answer.

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[1 mark] (c) State the change of oxidation number of zinc in the experiment.
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[2 marks] (iii) write an overall ionic equation for the reaction in test tube I.
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[1 mark] (d) State the flow of electrons.

________________________________________________________

[1 mark] (c) Clarify the answer given in (a) (ii).

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[1 mark] (e) What will happen to the reading of the galvanometer if rod zinc is replaced by copper and zinc sulphate solution is replaced by copper sulphate?

[1 mark] (d) What is the meaning of a displacement reaction?

________________________________________________________

[2 marks]

SECTION B [20 marks] Answer only one question from this section. 7 (a) Define rate of reaction and activation energy. [2 marks]
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(b) By using the collision theory, explain why potatoes that are cut into smaller pieces take shorter time to
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MID-YEAR EXAMINATION (CHAPTER 1 TO CHAPTER 3)

4541/1 This question paper consists of 50 questions. Answer all the questions. Each question is followed by four options KIMIA A, B, C and D. Choose the correct answer for every question. KERTAS 1 1 jam 15 minit cook compared to potatoes that are cut into bigger 8 (a) Diagram 6 shows the apparatus set-up to determine pieces. the position of carbon in the reactivity series of [3 marks] metals. Table 4 shows the results of the experiment. (c) A student conducted three experiments to investigate the factors influencing the rate of reaction. Table 3 shows the results of the experiment. Experiment Mass of Mg Concentration of H2SO4 A B 5.0 g of Mg powder 5.0 g granulated Mg 5.0 g of granulated Mg 2 mol dm3 2 mol dm3 Temperature 30 C 30 C Metal oxide Zinc oxide 1 mol dm3 30 C Aluminium oxide
Table 3

Diagram 6

Observation The mixture glows brightly. A grey solid is formed. No visible change.
Table 4

(i) Write the chemical equation of the reaction between magnesium and sulphuric acid. Calculate the maximum volume of hydrogen gas produced. [Relative atomic mass of Mg, 24; H, 1; Cl, 35; O, 16; Molar gas volume = 24 dm3 mol1 at room conditions] [4 marks] (ii) Sketch the graphs for the volume of hydrogen gas against time for Experiment A, B and C on the same axes. [3 marks] (iii) Compare the rates of reaction between Experiment A and Experiment B and between Experiment B and Experiment C. By referring to the collision theory, explain why there are differences in the rates of reaction in these three experiments. [8 marks]

(i) Arrange carbon, zinc and ascending order of reactivity.

aluminium

in

[1 mark] (ii) Write the chemical equation of the reaction between zinc oxide and carbon. [1 mark] (b) Define oxidation and reduction in terms of gain and loss of hydrogen. (c) Explain on how rusting can occur. [8 marks] (d) Briefly explain the following methods of rusting prevention. (i) Sacrificial protection of magnesium on iron. [3 marks] (ii) Plating iron with chromium. [3 marks]

SECTION C [20 marks] Answer only one question from this section. 9 [Relative atomic mass: H, 1; C, 12; O, 16] [6 marks] (ii) Referring to the Diagram 7, name P and S. [2 marks] (b) (i) Describe one chemical test to differentiate between R and Q. [3 marks]

Diagram 7

R in Diagram 7 has a relative molecular mass of 28. Its composition according to mass is 85.7% of carbon and 14.3% of hydrogen. (a) (i) Determine the molecular formula of P and draw its structural formula.
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MID-YEAR EXAMINATION (CHAPTER 1 TO CHAPTER 3)

4541/1 This question paper consists of 50 questions. Answer all the questions. Each question is followed by four options KIMIA A, B, C and D. Choose the correct answer for every question. KERTAS 1 1 jam 15 minit (ii) State three physical properties of Q and S [7 marks] respectively. (c) Latex coagulates when dilute ethanoic acid is added. [6 marks] Explain the coagulation process of latex. (c) Write the chemical equation to show how S is formed. [6 marks] [3 marks] (d) (i) Draw and label the vulcanised rubber. 10 (a) What are the differences between unvulcanised rubber [1 marks] and vulcanised rubber? (ii) State one use of unvulcanised rubber. [5 marks] [1 mark] (b) Describe an experiment of producing vulcanised rubber in the laboratory.

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