Beruflich Dokumente
Kultur Dokumente
IInstructions
The final examination will be weighted as follows Modules 13 Modules 46 The format of the examination will be as follows: Part A: Fill-in-the-Blanks Part B: Multiple Choice Part C: Short Answer Total Marks Include units with all answers as required. Useful Information You will need the following in order to complete this examination:
n n n n
writing utensils and eraser or correction fluid some scrap paper a ruler a scientific calculator
You will have a maximum of 2.5 hours to complete your final exam.
Grade 11 Chemistry
13. Polar and charged substances dissolve well in ____________________ solvents because of the electrostatic attraction between opposite charges. Polar 14. Adding a solute to a solvent lowers the ____________________ pressure of the solvent. Vapour Organic Chemistry (8 marks) 15. Inorganic compounds do NOT tend to contain ____________________. Carbon 16. Decaying animals and vegetation is a major source of ____________________ compounds. Hydrocarbon 17. When carbon atoms are bonded together in a tetrahedral lattice arrangement, ____________________ is created. Diamond 18. Any alkane with one or more alkyl groups is automatically a ____________________ alkane. Branched-chain 19. Ethene, a simple alkene, can be transformed back into ethane by adding ____________________. Hydrogen 20. All hydrocarbons that do not possess rings are called ____________________ compounds. Aliphatic 21. The functional group that identifies a compound as an alcohol is called the ____________________ group. Hydroxyl 22. The process of forming an ester from a reaction between an organic acid and an ____________________ is called esterification. Alcohol
Grade 11 Chemistry
5. Convert 35.0 L of nitrogen gas to moles of nitrogen gas at STP. a) 1.56 moles b) 0.640 moles c) 7.84 moles d) 22.4 moles 6. Which of the following quantities is conserved in every chemical reaction? a) Molecules b) Mass c) Formula units d) Moles Solutions (20 marks) 7. Which of the following is LESS soluble in hot water than in cold water? a) CO2 b) NaCl c) NaNO3 d) KBr 8. What can be done to crystallize a supersaturated solution? a) Heat the solution. b) It will crystallize if you leave it alone. c) Add a crystal of the solute or scratch the glass. d) Expose the solution to ultraviolet light. 9. In a concentrated solution, there is a) No solvent. b) A large amount of solute. c) A small amount of solvent. d) No solute.
Grade 11 Chemistry
10. In which of the following is concentration expressed in percent by volume? a) 10% (v/v) b) 10% (m/v) c) 10% (m/m) d) 10% 11. Which of the following is NOT a colligative property of a solution? a) Boiling point elevation b) Freezing point depression c) Vapour pressure lowering d) Solution saturation 12. What is the maximum amount of KCl that can be dissolved into 150.0 g of water? (The solubility of KCl is 34.0 g/100 mL at STP.) a) 51.0 g b) 22.7 g c) 34.0 g d) 5.10 g 13. Which of the following pairs of substances are miscible? a) Water and gasoline b) Water and salt (NaCl) c) Water and oxygen d) Water and ethanol (alcohol)
10 g . Which of the following solution 100 g water concentrations could represent an unsaturated solution of solute XY? a) b) c) d) 10 g 100 g water 9g 100 g water 5g 50 g water 11 g 100 g water
15. Use the following two diagrams of a gas-liquid solution to help you determine which statement below is FALSE.
a) The increased pressure in diagram B illustrates an increased solubility of the gas in the liquid. b) The increased pressure shown in diagram B forces the gas into contact with the liquid. c) Diagram A shows a greater amount of gas in solution, whereby the liquid holds onto the gas particles. d) When the pressure is reduced in diagram A, the solubility of the dissolved gas is reduced. 16. The solubility of a gas in a liquid a) Increases as the pressure of the gas above the liquid increases. b) Decreases as the pressure of the gas above the liquid increases. b) Increases as the pressure of the gas above the liquid decreases. d) Is unrelated to the pressure of the gas above the liquid.
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Grade 11 Chemistry
17. Which type of mixture could most likely be filtered using filter paper? a) A colloid b) A suspension c) A solution d) An emulsion 18. Which of these statements regarding the water molecule is FALSE? a) Oxygen is more electronegative than the hydrogen. b) The electrons between the hydrogen and oxygen atoms in each bond lie more towards the oxygen than they do towards the hydrogen. c) The hydrogen atoms are bonded to the oxygen at an angle of 104.5, which gives the water molecule its characteristic bent shape. d) The water molecule is a non-polar molecule. 19. Which statement below would NOT ensure greater conductivity of an electric current? a) There must be charged particles or ions present in the solution. b) Particles must move freely through the solution. c) There must be fewer ions present in solution. d) There must be a lower volume of solvent in which the ions are dissolved.
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Use the Solubility Curve for KNO3 below for Questions 20 to 22.
Solubility Curve for KNO3
150 140 Solubility (grams of solute/100 g H2O) 130 120 110 100 90 80 70 60 50 40 30 20 10 0 0 10 20 30 40 50 60 70 80 90 100 unsaturated saturated saturated/ supersaturated
Temperature ( C)
20. Estimate the approximate solubility of KNO3 at 30C. a) 16 g/100 g H2O b) 33 g/100 g H2O c) 48 g/100 g H2O d) 60 g/100 g H2O 21. Estimate the temperature at which the solubility of potassium nitrate is 50 g/100 g. a) About 90C b) About 20C c) About 30C d) About 8C 22. Indicate which of the following sets of data represents a saturated solution of potassium nitrate. a) 25C: 40 g/100 g H2O b) 63C: 140 g/100 g H2O c) 8C: 10 g/100 g H2O d) 74C: 150 g/100 g H2O
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Grade 11 Chemistry
23. How many moles of NaOH would be needed to make 0.0500 L of a 0.750 mol/L solution? a) 15.0 mol b) 0.0375 mol c) 50.0 mol d) 0.750 mol 24. Identify the FINAL step to follow when preparing a solution. a) Mass out the solute and add it to the flask. b) Add more solvent until you reach the required amount. c) Mass out the solvent and add it to the flask. d) Add about half the required volume of solvent to the flask. 25. You start with a solution that is 0.800 mol/L and exactly 0.0700 L. You need to prepare a 0.300 mol/L solution. What is the final volume of the solution? a) 3.43 L b) 0.026 L c) 0.580 L d) 0.187 L 26. Which method of water treatment is useful for controlling disease-causing organisms such as viruses, bacteria, and parasites? a) Water softening b) Filtration c) Chlorination d) Distillation Organic Chemistry (20 marks) 27. Which of these statements does NOT accurately describe tar sands? a) Tar sands provide a synthetically produced source of hydrocarbons. b) Tar sands are a combination of clay, sand, water, and bitumen. c) Tar sands can be mined and processed to extract the oil-rich bitumen. d) Bitumen requires no further refining and can be pumped from the ground in its natural state.
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28. Which type of bond will carbon commonly form? a) Covalent b) Ionic c) Metallic d) None of these 29. All of these hydrocarbons are unsaturated except for a) Benzene b) Alkenes c) Alkanes d) Alkynes 30. Which of the following is the correct condensed structural formula for butane? a) CH3(CH2)3CH3 b) CH3(CH2)2CH3 c) (CH3)3CH3 d) C4H10 31. Name the following alkane: C7H16 a) Heptane b) Hexane c) Decane d) Octane
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Grade 11 Chemistry
32. The correct structural formula for 2,2dimethylhexane is: a) CH2CH3 | CH3CCH2CH2CH2CH3 | CH3 CH3 | CH3CHCH2CH2CH2CH3 | CH3
b)
33. Molecules that have the same molecular formula but different structural formulas are called a) Allotropes b) Sterioisomers c) Structural isomers d) Isotopes 34. Which straight-chain alkane is a structural isomer of 3-propylheptane? a) 10 carbon atoms = decane b) 6 carbon atoms = hexane c) 9 carbon atoms = nonane d) 5 carbon atoms = pentane
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35. The correct name for the alkene CH3CH a) propene b) prop2ene c) 2propene d) prop3ene
CH2 is
CH3
b) CH2 c)
CH3 | CCH2CH3
d) CH3CH
37. The correct name for the alkyne CH a) pent1yne b) 1pentyne c) pentyne d) pent4yne
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Grade 11 Chemistry
38. The correct structural formula for 3ethylpent1yne is a) C b) CH CH2CH3 | CCCH2CH3 CH3 | CCHCH2CH3
c) CH2CH3 | CH2CH2C d) CH
CCH3
CH2CH3 | CCHCH2CH3
39. Give the IUPAC name for the alcohol CH3CH(OH)CH2CH(CH3)CH3. a) 2methylpentan4ol b) 2methyl4pentanol c) 4methylpentan2ol d) 4methyl2pentanol 40. Identify which of the following alcohols is most likely used to make hand soap. a) Isopropyl b) Glycerol c) Ethanol d) Methanol 41. Name the following carboxylic acid: CH3CH2CH(CH3)CH2COOH a) 3methylpentanoic acid b) 2methylbutanoic acid c) methyl3pentanoic acid d) methyl2butanoic acid
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42 Identify which of the following carboxylic acids is responsible for the sting in ant bites. a) Benzoic acid b) Lactic acid c) Formic acid d) Acetic acid 43. Name the ester CH3CH2CH2CH2COOCH3. a) methyl butanoate b) methylpentanoic acid c) pentyl methanoate d) methyl pentanoate 44. A very large molecule made of many smaller repeating units is known as a) A monomer b) A polymer c) An ester d) An allotrope 45. Which of these examples of is NOT a polymer formed by an addition reaction? a) Graphite b) Teflon c) Polypropylene d) Synthetic rubber 46. Which of these polymers is used for moulded plastics and film? a) Polyethylene b) Polyvinyl chloride (PVC) c) Teflon d) Polypropylene
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Grade 11 Chemistry
2.
What quantity of heat is produced in the complete combustion of 60.2 g of ethane gas (C2H6), according to the following balanced chemical reaction? The heat of combustion of ethane is 1560 kJ/mol and its molar mass is 30.0 g/mol. (4 marks) 2C2H6(g) + 7O2(g) 4CO2(g) + 6H2O(g) Answer:
1 mol mol = 60.2 g 30.0 g = 2.01 mol
60.2 g or, mol = 30.0 g /mol = 2.01 mol 1560 kJ energy = 2.01 mol = 3140 kJ 1 mol
(1 mark for each step of the calculation for 3 marks total, 1 mark for the correct answer)
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3.
How many grams of CO2 would be produced if 45 g of C6H12O6 (glucose) reacted completely with oxygen? Glucose = 180.0 g/mol; CO2 = 44.0 g/mol. (4 marks) C6H12O6(s) + 6O2(g) 6CO2(g) + 6H2O(l) Answer:
45 g C 6 H12 O 6 1 mol = 0.25 mol C 6 H12 O 6 180.0 g 6 mol CO 2 44.0 g = 66 g CO 2 1 mol C 6 H12 O 6 mol
(2 marks) (2 marks)
4.
Given 5.0 moles of sulfur and 8.4 moles of oxygen gas, as well as 2S + 3O2 2SO3 a) Identify the limiting factor and the excess reactant. (3 marks) Answer:
3 mol O 2 = 7.5 mol O 2 (2 marks) 2 mol S 7.5 mol O2 is needed to use up all of the S. You are given more than 7.5 moles of O2, so S is the limiting factor, and O2 is the excess reactant. (1 mark) moles O 2 = 5.0 mol S
b) Calculate the moles of excess reactant that remain. (2 marks) Answer: moles O2 remaining = initial moles reacted moles = 8.4 mol 7.5 mol = 0.9 mol O2 excess (2 marks)
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Grade 11 Chemistry
Solutions (7 marks) 5. Describe any three properties that are true of a solution in terms of the particulate view of matter. (3 marks) Answer: Any three of the following properties for one mark each: Solutions are homogeneous, their particles are spread evenly throughout the solution, they have a single phase, their particles are too small to be seen, they are transparent, their particles are too small to reflect light, their components do not settle out, and their parts cannot be separated by filtration.
6.
Write the equation for dissolving Ag2CrO4(s) in water. (2 marks) Answer: Ag2CrO4(s) 2Ag+(aq) + CrO42(aq)
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7.
What is the number of moles of solute in 0.650 L of a 0.40 mol/L solution? (2 marks) Answer:
0.650 L 0.40 mol = 0.26 mol 1 L
Organic Chemistry (10 marks) 8. Draw the structural formulas for the following hydrocarbons. (2 marks x 3 = 6 marks) a) 2,4dimethylpentane Answer: CH3CH(CH3)CH2CH(CH3)CH3 b) hex2ene Answer: CH3CH CHCH2CH2CH3
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Grade 11 Chemistry
9.
Complete the following table. (4 marks) Aliphatic Hydrocarbon Similarities Can be saturated or unsaturated. Aromatic Hydrocarbon Unsaturated.
Differences
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NOTES
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Grade 11 Chemistry
Word Bank
Use the following word bank to help you complete the Fill-in-the-Blank portion of your Final Examination. Note that there may be MORE terms here than you need, so read over the list carefully before choosing the terms that you want to use. You can also use certain words more than once. alcohol(s) aliphatic alkyl allotrope amorphous carbon aqueous aromatics benzene boiling branched-chain buckminsterfullerene carbon carboxyl carboxylic coefficients colligative concentration cracking crude decrease(s) dehydrogenation depression diamond dilution electronegativity electrons electrostatic emulsion endothermic equal esterification excess exothermic graphite greater higher hydrogenation hydrated hydrocarbon hydrogen hydroxyl immiscible increase(s) inorganic insoluble isomers less limiting miscible molarity moles more non-polar number organic percent phenyl polar products proportion(s) ratio(s) R-COOH reactant saturated smaller soluble solute solution solvation solvent stoichiometry substituent supersaturated suspensions theoretical unsaturated vapour water
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Grade 11 Chemistry
Bubble Sheet
Name: ______________________________________ ______________ / 46
For each Multiple Choice question, shade in the circle that corresponds to your answer. DO NOT circle your answers directly on the exam. A 1. 2. 3. 4. 5. 6. 7. 8. 9. B C D 14. A B C D 27. A B C D 40. A B C D
15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26.
28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39.
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Grade 11 Chemistry
Group 1
1 H Hydrogen 1.0
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1 H Hydrogen 1.0
2 He Helium 4.0
3 Li Lithium 6.9
4 Be Beryllium 9.0
19 K Potassium 39.1
2 15 P Phosphorus 31.0 33 As Arsenic 74.9 51 Sb Antimony 121.7 83 Bi Bismuth 209.0 114 Uuq Ununquadium (285) 16 S Sulphur 32.1 34 Se Selenium 79.0 52 Te Tellurium 127.6 84 Po Polonium (209) 116 Uuh Ununhexium (268) 17 Cl Chlorine 35.5 35 Br Bromine 79.9 53 I Iodine 126.9 85 At Astatine (210) 18 Ar Argon 39.9 36 Kr Krpton 83.8 54 Xe Xenon 131.3 86 Rn Radon (222) 118 Uuo Ununoctium (293)
3 21 Sc Scandium 45.0 39 Y Yttrium 88.9 71 Lu Lutetium 175.0 103 104 Lr Rf Lawrencium Rutherfordium (261) (257) 105 Db Dubnium (262) 106 Sg Seaborgium (263) 107 Bh Bohrium (264) 108 Hs Hassium (265) 109 Mt Meitnerium (266) 72 Hf Hafnium 178.5 73 Ta Tantalum 180.9 74 W Tungsten 183.8 75 Re Rhenium 186.2 76 Os Osmium 190.2 77 Ir Iridium 192.2 78 Pt Platinum 195.1 40 Zr Zirconium 91.2 41 Nb Niobium 92.9 42 43 Mo Tc Molybdenum Technetium 95.5 (98) 44 Ru Ruthenium 101.1 45 Rh Rhodium 102.9 46 Pd Palladium 106.4 47 Ag Silver 107.9 22 Ti Titanium 47.9 23 V Vanadium 50.9 24 Cr Chromium 52.0 25 Mn Manganese 54.9 26 Fe Iron 55.8 27 Co Cobalt 58.9 28 Ni Nickel 58.7 29 Cu Copper 63.5 30 Zn Zinc 65.4
11 Na Sodium 23.0 3 4 5 6 7 8 9 10 11 12
12 Mg Magnesium 24.3
19 K Potassium 39.1
20 Ca Calcium 40.1
37 Rb Rubidium 85.5
38 Sr Strontium 87.6
55 Cs Cesium 132.9
56 Ba Barium 137.3
87 Fr Francium (223)
88 Ra Radium (226)
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Grade 11 Chemistry
Electronegativities Table
17 18 13 14 15 16
Group 1
1 H 2.20 5 B 2.01 13 Al 1.47 31 Ga 1.82 48 Cd 1.46 79 Au 1.42 110 Uun 111 Uuu 80 Hg 1.44 112 Cn 49 In 1.49 81 Tl 1.44 14 Si 1.74 32 Ge 2.02 50 Sn 1.72 82 Pb 1.55 114 Uuq 6 C 2.50 7 N 3.07 15 P 2.06 33 As 2.20 51 Sb 1.82 83 Bi 1.67
1 H 2.20 8 O 3.50 16 S 2.44 34 Se 2.48 52 Te 2.01 84 Po 1.76 116 Uuh 9 F 4.10 17 Cl 2.83 35 Br 2.74 53 I 2.21 85 At 1.96
2 He 10 Ne
3 Li 0.97
4 Be 1.47
11 Na 1.01
3 4 5 6 7 8 9 10 11 12
12 Mg 1.23 21 Sc 1.20 39 Y 1.11 71 Lu 1.14 103 Lr 104 Rf 105 Db 106 Sg 107 Bh 108 Hs 109 Mt 72 Hf 1.23 73 Ta 1.33 74 W 1.40 75 Re 1.46 76 Os 1.52 77 Ir 1.55 78 Pt 1.44 40 Zr 1.22 41 Nb 1.23 42 Mo 1.30 43 Tc 1.36 44 Ru 1.42 45 Rh 1.45 46 Pd 1.35 47 Ag 1.42 22 Ti 1.32 23 V 1.45 24 Cr 1.56 25 Mn 1.60 26 Fe 1.64 27 Co 1.70 28 Ni 1.75 29 Cu 1.75 30 Zn 1.66
18 Ar
3
19 K 0.91
20 Ca 1.04
36 Kr 54 Xe
37 Rb 0.89
38 Sr 0.99
55 Cs 0.86
56 Ba 0.97
86 Rn
6
87 Fr 0.86
88 Ra 0.97
118 Uuo
7
Lanthanide Series
57 La 1.08 89 Ac 1.00 90 Th
58 Ce
59 Pr 1.07 91 Pa 1.14
60 Nd 1.07 92 U 1.30
61 Pm 1.07 93 Np 1.29
62 Sm 1.07 94 Pu 1.25
63 Eu 1.01 95 Am
64 Gd 1.11 96 Cm
65 Tb 1.10 97 Bk
66 Dy 1.10 98 Cf
67 Ho 1.10 99 Es
68 Er 1.11 100 Fm
69 Tm 1.11 101 Md
70 Yb 1.06 102 No
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Grade 11 Chemistry
Atomic Mass
(227) 27.0 (243) 121.7 39.9 74.9 (210) 137.3 (247) 9.0 209.0 (264) 10.8 79.9 112.4 40.1 (251) 12.0 140.1 132.9 35.5 52.0 58.9 (277) 63.5 (247) (262) 162.5 (254) 167.3 152.0 (257) 19.0 (223) 157.2 69.7 72.6
Element
Gold Hafnium Hassium Helium Holmium Hydrogen Indium Iodine Iridium Iron Krypton Lanthanum Lawrencium Lead Lithium Lutetium Magnesium Manganese Meitnerium Mendelevium Mercury Molybdenum Neodymium Neon Neptunium Nickel Niobium Nitrogen Nobelium Osmium Oxygen Palladium Phosphorus Platinum Plutonium Polonium Potassium
Atomic Mass
197.0 178.5 (265) 4.0 164.9 1.0 114.8 126.9 192.2 55.8 83.8 138.9 (257) 207.2 6.9 175.0 24.3 54.9 (266) (256) 200.6 95.9 144.2 20.2 (237) 58.7 92.9 14.0 (259) 190.2 16.0 106.4 31.0 195.1 (244) (209) 39.1
Element
Praseodymium Promethium Protactinum Radium Radon Rhenium Rhodium Rubidium Ruthenium Rutherfordium Samarium Scandium Seaborgium Selenium Silicon Silver Sodium Strontium Sulfur Tantalum Technetium Tellurium Terbium Thallium Thorium Thulium Tin Titanium Tungsten Uranium Vanadium Xenon Ytterbium Yttrium Zinc Zirconium
Atomic Mass
140.9 (145) (231) (226) (222) 186.2 102.9 85.5 101.1 (261) 150.4 45.0 (263) 79.0 28.1 107.9 23.0 87.6 32.1 180.9 (98) 127.6 158.9 204.4 232.0 168.9 118.7 47.9 183.8 238.0 50.9 131.3 173.0 88.9 65.4 91.2
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Grade 11 Chemistry
Name magnesium manganese(II) manganese(IV) mercury(I) mercury(II) nickel(II) nickel(III) potassium silver sodium strontium tin(II) tin(IV) zinc
Symbol Mg2+ Mn2+ Mn4+ Hg22+ Hg2+ Ni2+ Ni3+ K+ Ag+ Na+ Sr2+ Sn2+ Sn4+ Zn2+
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Grade 11 Chemistry
Common Ions
Cations (Positive Ions)
1+ charge NH4+ Cs+ Cu+ Au+ H+ Li+ K+ Rb+ Ag+ Na+ Ammonium Cesium Copper(I) Gold(I) Hydrogen Lithium Potassium Rubidium Silver Sodium Ba2+ Be2+ Cd2+ Ca2+ Cr2+ Co2+ Cu2+ Fe2+ Pb2+ Mg2+ Mn2+ Hg22+ Hg2+ Ni2+ Sr2+ Sn2+ Zn2+ 2+ charge Barium Beryllium Cadmium Calcium Chromium(II) Cobalt(II) Copper(II) Iron(II) Lead(II) Magnesium Manganese(II) Mercury(I) Mercury(II) Nickel(II) Strontium Tin(II) Zinc
(continued)
3+ charge Al3+ Cr3+ Co3+ Ga3+ Au3+ Fe3+ Mn3+ Ni3+ Aluminum Chromium(III) Cobalt(III) Gallium Gold(III) Iron(III) Manganese Nickel(III)
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Grade 11 Chemistry