Beruflich Dokumente
Kultur Dokumente
http://cikguadura.wordpress.com/
2.
4541/1
Diagram 1 shows the inter conversion of water, steam and ice. In which conversion do H2O molecules lose speed?
Rajah 1 menunjukkan perubahan keadaan air, ais dan stim. Dalam perubahan manakah molekul H2O hilang kelajuan?
Steam
Stim
Water
Air
Ice
Ais
Diagram 1
Rajah 1
A B C D
Ice water
Ais air
Ice steam
Ais stim
Water steam
Air stim
Steam ice
Stim ais
A B C D 3
A B C D
4541/1
4541/1
Table 1 shows the nucleon numbers and proton numbers of atoms W, X, Y, and Z.
Jadual 1 menunjukkan nombor nukleon dan nombor proton bagi atom-atom W, X, Y, dan Z.
W Nucleon number
Nombor nukleon
X 37 17 Table 1
Jadual 1
Y 40 18
Z 39 19
35 17
Proton number
Nombor proton
A B C D 5
1 2 3 4
Bulb
Mentol
Electrodes
Elektrod
Substance G
Bahan G
Diagram 2
Rajah 2
What is substance G?
Apakah bahan G?
A B C D
Liquid ethanol
Cecair etanol
4541/1
4541/1
In which experiment the limewater does not turn cloudy? Dalam eksperimen manakah air kapur tidak menjadi keruh? A B
Lead(II) iodide is formed when aqueous lead(II) nitrate is added to a solution containing iodide ions. What type of reaction takes place?
Plumbum(II) iodida terbentuk apabila plumbum(II) nitrat akueus dicampur kepada larutan yang mengandungi ion iodida. Apakah jenis tindak balas yang berlaku?
A B C D
Neutralisation
Peneutralan
Oxidation
Pengoksidaan
Reduction
Penurunan
Precipitation
Pemendakan
A salt always ..
Garam sentiasa
A B C D
contains ions
mengandungi ion
dissolves in water
larut dalam air
conducts electricity
mengalirkan arus elektrik
4541/1
4541/1
Diagram 3
Rajah 3
Which alloy is used in making the bodies of aeroplane, car and wheelbarrow?
Antara aloi berikut, yang manakah digunakan untuk membuat rangka kapalterbang, kereta dan kereta sorong?
Aeroplane
Kapalterbang
Car
Kereta
Wheelbarrow
Kereta sorong
A B C D
Magnalium
Magnalium
Brass
Loyang
Steel
Keluli
Duralumin
Duralumin
Steel
Keluli
Steel
Keluli
Pewter
Pewter
Bronze
Gangsa
Brass
Loyang
Steel
Keluli
Stainless steel
Keluli nirkarat
Solder
Pateri
10
Copper wires in an electricity cable are covered in plastic as shown in diagram 4. Plastic is used because it is
Dawai kuprum dalam kabel elektrik disalut dengan plastik seperti Rajah 4. Plastik digunakan sebab ia
Diagram 4
Rajah 4
A B C D
hard.
keras
a polymer.
polimer
an insulator.
penebat
melts easily.
mudah dilebur
4541/1
4541/1
11
Diagram 5
Rajah 5
A B C D
12
A B C D
Ethanoic acid
Asid etanoik
Polythene
Politena
Ethanol
Etanol
Butane
Butana
4541/1
4541/1
13
2 g of marble is added to 10 cm3 of hydrochloric acid in four different test tubes. In which test tube is the reaction fastest?
2 g marmar ditambah kepada 10 cm3 asid hidroklorik dalam empat tabung uji berlainan. Dalam tabung uji manakah menghasilkan tindak balas paling cergas?
A B C D
4541/1
4541/1
15
Diagram 6 shows the apparatus set up used to study the reaction of metal oxide and carbon.
Rajah 6 menunjukkan susunan radas yang digunakan untuk mengkaji tindak balas antara logam oksida dengan karbon.
Diagram 6
Rajah 6
Which of the following metal oxide will turn the lime water cloudy? Antara oksida logam berikut yang manakah mengeruhkan air kapur? A B C D Magnesium oxide
Magnesium oksida
Copper(II) oxide
Kuprum(II) oksida
Calcium oxide
Kalsium oksida
Aluminium oxide
Aluminium oksida
16
The reaction between solution P and solution Q is exothermic. A student confirms this statement by mixing equal volumes of the two solutions and measuring the temperature change. Which two pieces of apparatus should the student use?
Tindak balas antara larutan P dan Q adalah eksotermik. Pelajar mengesahkah pernyataan tersebut dengan mencampurkan isipadu yang sama bagi dua larutan dan mengukur perubahan suhu. Apakah dua radas yang perlu digunakan?
A B C D
4541/1
4541/1
17
Diagram 7 shows a set up where hydrogen is passed over a heated metal oxide.
Rajah 7 menunjukkan susunan radas di mana hidrogen dilalirkan atas logam oksida yang panas.
Diagram 7
Rajah 7
Hydrogen
Hidrogen
Metal oxide
Logam oksida
A B C D
Oxidised
Dioksidakan
Oxidised
Dioksidakan
Reduced
Diturunkan
Oxidised
Dioksidakan
Reduced
Diturunkan
Reduced
Diturunkan
Oxidised
Dioksidakan
Reduced
Diturunkan
18
Diagram 8
Rajah 8
A B C D
4541/1
4541/1
19
Diagram 9 shows an experiment in which magnesium oxide powder is added to dilute hydrochloric acid.
Rajah 9 menunjukkan eksperimen di mana serbuk magnesium oksida ditambah ke dalam asid hidroklorik cair.
Diagram 9
Rajah 9
Exothermic
Eksotermik
Neutralisation
Peneutralan
A B C D
20
A B C D
To relieve pain
Mengurangkan rasa sakit
To treat asthma
Merawat asma
To destroy bacteria
Menghapuskan bakteria
4541/1
10
4541/1
21
Table 2 shows the melting point and boiling points of five compounds J, K, L, M and N. Which substance exists as a liquid at room temperature?
Jadual 2 menunjukkan takat lebur dan takat didih bagi lima sebatian J , K , L , M dan N. Antara bahan berikut yang manakah wujud dalam keadaan cecair pada suhu bilik?
Substance Bahan J K L M N
A B C D
J only
J sahaja
J and K only
J dan K sahaja
K and L only
K dan L sahaja
M and N only
M dan N sahaja
22
When propane is burned in excess oxygen, carbon dioxide and water are formed and is represented by the equation
Apabila propana dibakar dalam oksigen berlebihan, karbon dioksida dan air dihasilkan dan di wakili oleh persamaan berikut
C3H8 + 5O2 r CO2 + s H2O What are the values of r and s that balances the equation?
Apakah nilai r dan s yang mengimbangkan persamaan tersebut?
r A B C D 1 1 3 3
s 3 5 4 8
4541/1
11
4541/1
23
Diagram 11
Rajah 11
A B C D
24
Diagram 12
Rajah 12
Carbon
Karbon
Hydrogen
Hidrogen
Oxygen
Oksigen
A B C D
1 2 2 6
6 5 6 2
2 1 1 1
4541/1
12
4541/1
25
Electrode T Elektrod T
Diagram 13
Rajah 13
Metal T acts as the positive terminal and the potential difference is 1.9 V. Which of the following statements is true?
Logam T bertindak sebagai terminal positif dan beza upaya ialah 1.9V . Antara pernyataan berikut yang manakah benar tentang sel kimia itu?
A B C D
The potential difference will decrease if T is replaced by any other more electropositive metal than T
Beza upaya akan berkurang jika T digantikan oleh logam lain yang lebih elektropositif daripada T
4541/1
13
4541/1
26
Diagram 14 shows the pH values of the soil in part F and part G of a palm oil plantation.
Rajah 14 menunjukkan nilai pH bagi tanah di bahagian F dan G bagi suatu ladang kelapa sawit.
Diagram 14
Rajah 14
The owner wishes to use lime to neutralise the soil in one part of the plantation Which part should the lime(calcium oxide) be added, and why?
Pemilik ladang bercadang menggunakan kapur untuk meneutralkan sebahagian daripada ladangnya. Bahagian manakah yang perlu ditambah kapur dan mengapa?
A B C D
27
Diagram 15
Rajah 15
What is ion W?
Apakah ion W?
A B C D
4541/1
4541/1
28
Polymerization occurs when many small molecules combined to form a long chained molecule (polymer). Diagram 16 shows the structure of a small molecule.
Pempolimeran berlaku apabila banyak molekul kecil bergabung membentuk molekul berantai panjang (polimer). Rajah 16 menunjukkan struktur suatu molekul kecil
Diagram 16
Rajah 16
Which of the following represents the structure of a polymer formed when these small molecules are linked together?
Antara berikut yang manakah mewakili struktur polimer yang terbentuk apabila molekul kecil tersebut bergabung?
4541/1
15
4541/1
29
C2H5OH + CH3COOH CH3COOC2H5 + H2O What is the formula of the ester formed when methanol reacts with butanoic acid, (C3H7COOH)?
Apakah formula bagi ester yang terbentuk apabila metanol bertindak balas dengan asid butanoik, (C3H7COOH)?
A B C D 30
Diagram 17 shows set up of apparatus to study the rate of reaction. Magnesium is added to excess dilute hydrochloric acid at 25 oC
Rajah 17 menunjukkan susunan radas untuk mengkaji kadar tindak balas. Magnesium ditambah kepada asid hidroklorik berlebihan pada suhu 25 oC.
Diagram 17
Rajah 17
Which of the following effects on rate and amount of product are correct when the concentration of acid and temperature are increased?
Antara kesan ke atas kadar dan kuantiti hasil berikut yang manakah betul apabila kepekatan asid dan suhu ditambah?
Increase temperature
Penambahan suhu
Amount of product
Kuantiti hasil
A B C D
no change
Tidak berubah
Increase
Bertambah
Decrease
Berkurang
Increase
Bertambah
4541/1
16
4541/1
31
Water out
Air keluar
Water in
Air masuk
Heat
Haba
Diagram 18
Rajah 18
A B C D
No colour change
Tiada perubahan warna
The mixture in the flask separated into two layers. The upper layer is yellow while the lower layer is green
Campuran dalam kelalang membentuk dua lapisan. Lapisan atas berwarna kuning, lapisan bawah berwarna hijau
4541/1
17
4541/1
32
Diagram 19 shows the apparatus set up used to investigate the rusting of iron.
Rajah 19 menunjukkan susunan radas yang digunakan untuk mengkaji pengaratan besi
Diagram 19
Rajah 19
A B C D 33
I only
I sahaja
II only
II sahaja
Diagram 20
Rajah 20
A B C D
4541/1
18
4541/1
34
Diagram 21 shows apparatus set up used to prepare barium chloride and barium sulphate. In each experiment, the acid is run into the conical flask until the resulting liquid has pH7.
Rajah 21 menunjukkan dua susunan radas untuk menghasilkan barium klorida dan barium sulfat. Dalam setiap eksperimen, asid dititis ke dalam kelalang kon sehingga larutan mencapai pH 7.
Diagram 21
Rajah 21
What are the next steps to obtain samples of the solid salts?
Apakah langkah seterusnya untuk mendapatkan garam dalam bentuk pepejal?
Barium chloride
Barium klorida
Barium sulphate
Barium sulfat
A B C D
Crystallisation
Penghabluran
Crystallisation
Penghabluran
Crystallisation
Penghabluran
Filtration
Penurasan
Filtration
Penurasan
Crystallisation
Penghabluran
Filtration
Penurasan
Filtration
Penurasan
4541/1
19
4541/1
35
For complete combustion, one molecule of an organic compound needs six molecules of oxygen. What could the formula of this compound be?
Untuk pembakaran lengkap, satu molekul sebatian organik memerlukan enam molekul oksigen. Apakah formula bagi sebatian tersebut?
A B C D 36
C2 H4 C2 H6 C4 H8 C H3OH
Redox reaction between iron(II) ion and manganate(VII) ion is represented by the equation:
Tindak balas redoks antara ion ferum(II) dan ion manganat(VII) diwakili oleh persamaan:
5 Fe2+ + MnO4- + 8 H+ 5 Fe3+ + Mn2+ + 4 H2O What can be deduced from the equation?
Apakah yang dapat disimpulkan daripada persamaan ini?
I II III IV A B C D
I and IV only
I dan IV sahaja
4541/1
20
4541/1
37
Particle
Zarah
Number of protons
Bilangan proton
Number of neutrons
Bilangan neutron
Number of electrons
Bilangan elektron
O O 2Na Na+
8 8 11 11 Table 3
Jadual 3
8 8 Q 12
8 P 11 R
P A B C D 9 9 10 10
Q 11 11 12 12
R 10 11 10 11
38
L and M are diatomic elements. L is less reactive than M. Which of the following elements are L and M?
L dan M adalah unsur-unsur dwiatom. Antara berikut yang manakah merupakan unsur L dan M?
L A B C D Bromine
Bromin
M Iodine
Iodin
Iodine
Iodin
Bromine
Bromin
Sodium
Natrium
Potassium
Kalium
Potassium
Kalium
Sodium
Natrium
4541/1
21
4541/1
39
Table 4 gives information about the ability of four substances to conduct electricity.
Jadual 4 menunjukkan maklumat mengenai kebolehan empat bahan untuk mengalirkan elektrik.
Substance
Bahan
Electrical conductivity
Kekonduksian elektrik
R T U W
Table 4
Jadual 4
R A B C D 40 Pb S S S
W S Pb NaCl Pb
Heating ammonium salts with sodium hydroxide will produce ammonia gas. Which of the following ammonium salt can produce the greatest volume of ammonia gas?
Pemanasan garam ammonium dengan natrium hidroksida menghasilkan gas ammonia. Antara garam ammonium berikut yang manakah akan menghasilkan isipadu gas ammonia tertinggi?
A B C D
0.5 mol (NH4)3PO4 0.5 mol (NH4)2SO4 1.0 mol NH4Cl 1.0 mol NH4NO3
4541/1
22
4541/1
41
Diagram 22
Rajah 22
Which of the following diagrams shows the correct completion at X after the solution has been electrolysed for some time?
Antara rajah berikut yang manakah merupakan pelengkap yang betul di X selepas elektrolisis dijalankan beberapa ketika?
4541/1
23
4541/1
42
Diagram 23 shows an electrolytic circuit using inert electrodes. At which electrode is metal deposited?
Rajah 23 menunjukkan satu litar elektrolisis menggunakan elektrod lengai. Pada elektrod manakah logam terenap?
Heat Panaskan
43
Dilute hydrochloric acid was reacted with magnesium ribbon and the volume of hydrogen gas evolved was measured for the first 80 s.
Asid hidroklorik cair ditindak balaskan dengan pita magnesium dan isipadu gas hidrogen terbebas diukur bagi 80 saat pertama.
A B C D
4541/1
24
4541/1
44
Compound J
Sebatian J
Excess HNO3
HNO3 berlebihan
Gas
Colourless solution
Larutan tanpa warna
Excess NaOH
NaOH berlebihan
Diagram 24
Rajah 24
A B C D
Aluminium carbonate
Aluminium karbonat
Magnesium carbonate
Magnesium karbonat
Copper(II) carbonate
Kuprum(II) karbonat
Zinc carbonate
Zink karbonat
4541/1
25
4541/1
45
Calcium carbonate reacts with excess hydrochloric acid at room temperature and is represented by the equation
Kalsium karbonat bertindak balas dengan asid hidroklorik berlebihan pada suhu bilik dan diwakili oleh persamaan.
4541/1
26
4541/1
46
Ethene reacts with steam in the presence of a suitable catalyst. What is the structural formula of the compound formed?
Etena akan bertindak balas dengan stim dalam kehadiran mangkin yang sesuai. Apakah formula struktur bagi sebatian yang terbentuk?
47
Powdered carbon and copper are separately heated as shown in Diagram 25.
Serbuk karbon dan kuprum dipanaskan secara berasingan seperti ditunjukkan dalam Rajah 25.
Diagram 25
Rajah 25
Carbon
Karbon
Copper
Kuprum
A B C D
Decrease
Berkurangan
Decrease
Berkurangan
Decrease
Berkurangan
Increase
Bertambah
Increase
Bertambah
Decrease
Berkurangan
Increase
Bertambah
Increase
Bertambah
4541/1
27
4541/1
48
Halogen added
Halogen ditambah
Larutan halida
XNo reaction
Tiada perubahan
YY2 produced
Y2 dihasilkan
ZZ2 produced
Z2 dihasilkan
I II III
X2 Y2 Z2
Y2 produced
Y2 dihasilkan
No reaction
Tiada perubahan
No reaction
Tiada perubahan
Table 5
Jadual 5
X A B C D 49 Br Br Cl Cl
Y Cl I I Br
Z I Cl Br I
Mg(s) + Fe2+ (aq) Mg2+ (aq) + Fe(s) Which of the following statements are true?
Manakah antara berikut benar?
= -189 kJ mol
I II III IV A B C D
Magnesium is oxidized
Magnesium dioksidakan
Reaction is exothermic
Tindak balas adalah eksotermik
I and II only
I dan II sahaja
II and IV only
II dan IV sahaja
I, II and IV only
I,II dan IV sahaja
4541/1
28
4541/1
50
2 Zn(NO3)2 2 ZnO + 4 NO2 + O2 Which of the following will be produced when 18.9 g of zinc nitrate is heated? [Molar mass Zn(NO3)2 = 189 gmol-1 , molar mass zinc oxide = 81 gmol-1 and 1 mol of gas occupies a volume of 24 dm3 at room temperature and pressure]
Antara berikut yang manakah akan terhasil jika 18.9 g zink nitrat dipanaskan? [Jisim molar: Zn(NO3)2 =189 gmol-1 , molar mass ZnO = 81 gmol-1 dan 1 mol gas menempati isipadu sebanyak 24 dm3 pada suhu dan tekanan bilik]
A B C D
http://cikguadura.wordpress.com/
4541/1 Copyright Reserved MARA
29
4541/1
INFORMATION FOR CANDIDATES MAKLUMAT UNTUK CALON 1. 2. 3. This question paper consists of 50 questions.
Kertas soalan ini mengandungi 50 soalan.
Each question is followed by four alternative answers A, B, C and D. For each question, choose one answer only. Blacken your answer on the objective answer sheet provided.
Tiap-tiap soalan di ikuti oleh empat pilihan jawapan, iaitu A, B, C dan D. Bagi setiap soalan, pilih satu jawapan sahaja. Hitamkan jawapan anda pada kertas jawapan objektif yang disediakan.
4.
If you wish to change your answer, erase the blackened mark that you have made. Then blacken the new answer.
Sekiranya anda hendak menukar jawapan, padamkan tanda yang telah dibuat. Kemudian hitamkan jawapan yang baru.
5. 6.
The diagrams in the questions provided are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan.
4541/1
30
CHEMISTRY
Paper 2 Two hours and thirty minutes DO NOT OPEN THE QUESTION BOOKLET UNTIL BEING TOLD TO DO SO 1. Write your name and index number in the spaces provided.
Tuliskan nama dan angka giliran anda pada ruang yang disediakan.
Kod Pemeriksa
Section Question
Full mark
Marks
1 2 3 A 4 5 6 7 B 8 9 C 10 TOTAL
9 9 10 10 11 11 20 20 20 20
3. Candidate is required to read the information at the back page of the question booklet.
Calon dikehendaki membaca maklumat di halaman belakang kertas soalan ini .
4541/2
Section A
Bahagian A
Diagram 1.1 shows the set up of the apparatus used in an experiment to determine the melting point of a substance M.
Rajah 1.1 menunjukkan susunan radas yung digunakan untuk menentukan takat lebur bahan M.
Diagram 1.1
Rajah 1.1
(a) 1(a)(i) i)
(i)
... [1 mark]
[1 markah]
1(a)(ii)
(ii)
... [1 mark]
[1 markah]
4541/2
4541/2
(b)
Diagram 1.2 shows a graph of temperature against time when solid of substance M is heated.
Rajah 1.2 menunjukkan graf suhu melawan masa apabila pepejal bahan M dipanaskan.
Diagram 1.2
Rajah 1.2
(i)
(ii)
... [1 mark]
[1 markah]
1(b)(ii)
(iii)
... [1 mark]
[1 markah]
1(b)(iii)
4541/2
4541/2
(iv)
(c)
Diagram 1.3
Rajah 1.3
(i) 1(c)(i)
1(c)(ii)
(ii)
... [1 mark]
[1 markah]
4541/2
4541/2
Diagram 2 shows the set up of apparatus of two types of cells. Rajah 2 menunjukkan susunan radas dua jenis sel.
Cell I
Sel I
Cell II
Sel II
Diagram 2
Rajah 2
(a)
(i)
(b)
Cell I : ..
Sel I
2(b)
(c)
(i)
2(c)(i)
[1 mark]
[1 markah] 4541/2 Copyright Reserved MARA
4541/2
(ii) 2(c)(ii)
[1 mark]
[1 markah]
2(c)(iii)
(iii)
... [1 mark]
[1 markah]
(d)
Zinc electrode and zinc sulphate solution in Cell II are replaced by iron electrode and iron (II) sulphate solution. State the changes to the voltmeter reading. Explain your answer.
Elektrod zink dan larutan zink sulfat dalam sel II digantikan dengan elektrod ferum dan larutan ferum (II ) sulfat, Nyatakan perubahan kepada bacaan voltmeter. Terangkan jawapan anda..
2(d)
[2 marks]
[2 markah]
4541/2
4541/2
Diagram 3 shows the apparatus set-up for the preparation of zinc sulphate from zinc carbonate and an acid.
Rajah 3 menunjukkan susunan radas untuk penyediaan zink sulfat daripada zink karbonat dengan suatu asid.
Heat Step II
Step 1
(a)
[1 mark]
[1 markah]
3(a)
(b)
(i)
3(b)(i) [2 marks]
[2 markah]
(ii)
3(b)(ii)
[1 mark]
[1 markah]
4541/2
4541/2
(c)
(i)
3(c)(i)
[1 mark]
[1 markah]
(ii) 3(c)(ii)
[2 marks]
[2 markah]
(d)
Zinc sulphate
Zink sulfat
+ X
X sulphate + zinc
X sulfat + zink
3(d)(i)
(i)
[1 mark]
[1 markah]
(ii) 3(d)(ii)
What is observed when aqueous ammonia is added in excess to zinc sulphate solution?
Apakah yang diperhatikan apabila ammonia akueus ditambah kepada larutan zink sulfat sehingga berlebihan?
[2 marks]
[2 markah]
4541/2
4541/2
Vinegar is aqueous ethanoic acid. The concentration of ethanoic acid in the vinegar was determined by titrating the vinegar with 0.10 mol dm-3 sodium hydroxide solution using phenolphthalein as an indicator. The result of the experiment is shown in Table 4.
Cuka adalah larutan asid etanoik. Kepekatan asid etanoik dalam cuka ditentukan melalui pentitratan dengan 0.10 mol dm -3 larutan natrium hidroksida dengan menggunakan fenoftalein sebagai penunjuk. Keputusan eksperimen di tunjukkan dalam Jadual 4.
CH3COOH + NaOH
Titration II
Penitratan II
Titration III
Penitratan III
0.00 23.40
23.40 47.00
0.00 23.50
Table 4
Jadual 4
(a)
[1 mark]
[1 markah]
4(a)
(b)
4(b) [1 mark]
[1 markah]
(c)
(i)
Complete Table 4 by calculating the volume of sodium hydroxide solution used in each titration
Lengkapkan Jadual 4 dengan menghitung isipadu larutan natrium hidroksida yang digunakan dalam setiap pentitratan.
4(c)(i)
[1 mark]
[1 markah]
4541/2
4541/2
(ii)
Calculate the average volume of 0.10 mol dm-3 of sodium hydroxide solution used to neutralize 25.00 cm3 of vinegar.
Hitung isipadu purata larutan natrium hidroksida 0.10 mol dm-3 yang digunakan untuk meneutralkan 25.00 cm3 cuka.
4(c)(ii) [1 mark]
[1 markah]
(d)
(i)
Calculate the number of moles of sodium hydroxide used to neutralize 25.0 cm3 of vinegar.
Hitung bilangan mol natrium hidroksida yang digunakan untuk meneutralkan 25.00 cm3 cuka.
4(d)(i) [1mark]
[1 markah]
(ii)
4(d)(ii) [3 marks]
[3 markah] 4541/2 Copyright Reserved MARA
10
4541/2
(e)
The experiment is repeated using 0.10 mol dm-3 of barium hydroxide to replace sodium hydroxide. Predict the volume of barium hydroxide solution required to neutralize 25.00 cm3 of vinegar. Explain your answer.
Eksperimen diulangi menggunakan larutan barium hidroksida 0.10 mol dm-3 menggantikan larutan natrium hidroksida.. Ramalkan isipadu larutan barium hidroksida yang diperlukan untuk menutralkan 25.00 cm3 cuka. Terangkan jawapan anda.
[2 marks]
[2 markah]
4(e)
4541/2
11
4541/2
In an experiment, 50.0 cm3 of hydrogen peroxide solution is mixed with 1.0 g of manganese(IV) oxide powder. The total volume of oxygen gas liberated is measured at 30 seconds intervals. Table 5 shows the result of the experiment.
Dalam satu eksperimen, 50.0 cm3 larutan hydrogen peroksida di campurkan dengan 1.0g serbuk mangan(IV) oksida. Jumlah isipadu gas oksigen yang dibebaskan diukur setiap 30 saat. Jadual 5 menunjukkan keputusan ekperimen.
Time (s)
Masa (s)
30
60
90
120
150
180
210
[1 mark]
[1 markah]
(b) 5(b)
[1 mark]
[1 markah]
(c)
Plot a graph of the volume of oxygen gas against time on page 13.
Plotkan graf isipadu gas oksigen melawan masa pada muka surat 13.
[3 marks]
[3 markah]
(d) 5(d)
How long does it take for the decomposition of hydrogen peroxide to be completed?
Berapa lamakah masa yang diambil untuk penguraian lengkap hidrogen peroksida?
[1 mark]
[1 markah]
4541/2
12
4541/2
5(c)
4541/2
13
4541/2
(e)
(i)
5(e)(i) [2 marks]
[2 markah]
(ii)
5(e)(ii) (f)
[1 mark]
[1 markah]
The experiment is repeated using 2.0 g of manganese(IV) oxide. The reaction stops at 120 seconds. Explain.
Eksperimen diulangi menggunakan 2.0 g mangan(IV) oksida. Tindak balas berhenti pada 120 saat. Terangkan.
5(f) [2 marks]
[2 markah]
4541/2
14
4541/2
Diagram 6 shows the apparatus set-up to determine the heat of displacement of copper from its salt solution by lead powder.
Rajah 6 menunjukkan susunan radas untuk menentukan haba penyesaran kuprum daripada larutan garamnya oleh serbuk plumbum.
Diagram 6
Rajah 6
50 cm3 of 0.2 mol dm-3 copper(II) sulphate is poured into a polystyrene cup. The initial temperature of the solution is recorded. Excess lead powder is added into the copper(II) sulphate solution, stirred and the maximum temperature is recorded. Table 6 shows the result of the experiment.
50 cm3 larutan kuprum(II) sulfat 0.2 mol dm-3 dimasukkan ke dalam sebuah cawan polistirena. Suhu awal larutan direkodkan. Serbuk plumbum berlebihan ditambah ke dalam larutan kuprum(II) sulfat, campuran dikacau dan suhu tertinggi larutan direkodkan.. Jadual 6 menunjukkan keputusan eksperimen
Initial temperature / oC
Suhu awal
28.0 33.0
Maximum temperature / oC
Suhu tertinggi
Jadual 6
Table 6
(a)
Give one suggestion on how the above apparatus can be improved to get a better result.
Berikan satu cadangan bagaimana radas di atas dapat diperbaiki untuk mendapatkan keputusan yang lebih baik.
[1 mark]
[1 markah] 4541/2 Copyright Reserved MARA
6(a)
15
4541/2
(b)
6(b)
[1 mark]
[1 markah]
6(c)
(c)
[1 mark]
[1 markah]
(d)
(i)
6(d)(i) [1 mark]
[1 markah]
(ii)
Calculate the amount of heat released in the experiment. [Density of solution = 1.0 g cm-3 and specific heat capacity of water = 4.2 J g-1oC-1]
Hitung jumlah haba yang dibebaskan dalam eksperimen.. [ Ketumpatan larutan = 1.0 g cm 3 dan muatan haba tentu larutan air = 4.2J g-1 oC-1]
6(d)(ii)
[1 mark]
[1 markah]
4541/2
16
4541/2
(iii)
[1 mark]
[1 markah]
6(d)(iii)
(e)
6(e) [2 marks]
[2 markah]
(f)
What happens to the temperature change if lead powder is replaced by magnesium powder? Explain.
Apakah berlaku kepada perubahan suhu jika serbuk plumbum digantikan dengan serbuk magnesium? Terangkan.
[3 marks]
[3 markah]
6(f)
4541/2
17
4541/2
Section B
Bahagian B
[20 marks] [20 markah] Answer any one question from this section.
Jawab mana-mana satu soalan daripada bahagian ini..
(a)
Diagram 7.1 shows the position of chlorine and iodine in the Periodic Table of Elements.
Rajah 7.1 menunjukkan kedudukan klorin dan iodin di dalam Jadual Berkala Unsur.
Cl I
Diagram 7.1
Rajah 7.1
Which group does these elements belongs to? Explain why chlorine is more reactive than iodine.
Dalam kumpulan manakah unsur ini terletak? Terangkan mengapa klorin lebih reaktif berbanding iodin?
[4 marks]
[4 markah]
(b)
Diagram 7.2 shows the reaction between potassium with water. The experiment is repeated using sodium to replace potassium. Observations are recorded in Table 7.1
Rajah 7.2 menunjukkan tindak balas antara kalium dengan air. Eksperimen di ulangi menggunakan natrium menggantikan kalium. Permerhatian dicatatkan di dalam jadual 7.1
Diagram 7.2
Rajah 7.2
4541/2
18
4541/2
Element
Unsur
Proton number
Nombor proton
Observation
Pemerhatian
Potassium
Kalium
19
Metal moves very vigorously on the surface of water. Colourless solution formed and changed red litmus paper blue.
Bergerak sangat cergas di permukaan air. Larutan tanpa warna yang terhasil menukarkan warna kertaslitmus merah kepada biru
Sodium
Natrium
11
Metal moves vigorously on the surface of water with a hissing sound. Colourless solution is formed and changed red litmus paper blue.
Bergerak cergas di permukaan air dengan bunyi hiss. Larutan tanpa warna terbentuk menukarkan kertas litmus merah kepada biru
Table 7.1 Jadual 7.1 (i) Based on the proton number, explain why both elements show similar chemical properties.
Berdasarkan nombor proton, terangkan mengapa kedua-dua unsur menunjukkan sifat kimia yang sama.
[2 marks]
[2 markah]
(ii)
Write a balanced chemical equation for the reaction between potassium and water.
Tulis persamaan kima seimbang untuk tindak balas kalium dan air.
[2 marks]
[2 markah]
(iii)
Describe briefly why the solutions obtained in both reactions turns red litmus paper blue.
Terangkan secara ringkas mengapa larutan yang diperolehi menukarkan kertas litmus merah kepada biru.
[2 marks] [2 markah]
4541/2
19
4541/2
(c)
Element
Unsur
Proton Number
Bilangan proton
C Na O Table 7.2
Jadual 7.2
6 11 8
(i) (ii)
Your answer must include diagrams showing the electron arrangement of compounds P and Q.
Jawapan anda mesti termasuk gambar rajah yang menunjukkan susunan electron bagi sebatian P dan Q.
[10 marks]
[10 markah]
4541/2
20
4541/2
(a)
H H C = C H Cl Diagram 8
Rajah 8
(i)
Vinyl chloride can undergo polymerization. Suggest a name for the polymer formed and write a chemical equation for the reaction.
Vinil klorida boleh mengalami pempolimeran. Cadangkan satu nama bagi polimer terbentuk dan tulis persamaan kimia untuk tindak balas tersebut.
[2 marks]
[2 markah]
(ii)
[3 marks]
[3 markah]
(b)
Ammonia and sulphuric acid are two important chemicals produced in chemical industries. Ammonia gas reacts with aqueous sulphuric acid to form a nitrogenous fertilizer as shown in the equation.
Ammonia dan asid sulfurik adalah dua bahan kimia penting dihasilkan oleh industri kimia. Gas ammonia bertindak balas dengan asid sulfurik membentuk baja bernitrogen seperti yang ditunjukkan oleh persamaan.
2NH3 + H2SO4
(NH4)2 SO4
Calculate the mass of ammonium sulphate produced when an excess ammonia gas is passed into 100 cm3 of 2.0 mol dm-3 of aqueous sulphuric acid solution. [Molar mass of ammonium sulphate = 132 g mol-1]
Hitung jisim ammonium sulfat dihasilkan apabila gas ammonia berlebihan dialirkan ke dalam 100 cm3 asid sulfurik 2.0 mol dm-3. [Jisim molekul relatif ammonium sulfat = 132 g mol-1]
[3 marks] [3 markah]
4541/2
21
4541/2
(c)
Pure aluminium rod is malleable while duralumin which is made of 95% aluminium and 5% copper is not. Explain how the difference in the composition contributes to the difference in properties of aluminium and duralumin. Rod aluminium tulen mudah dibengkokkan tetapi duralumin yang dibuat daripada 95%
aluminium dan 5% kuprum sukar dibengkokkan Terangkan bagaimana perbezaan komposisi membezakan sifat aluminium dan duralumin.
[5 marks]
[5 markah]
(d)
The equation below shows the ionization of a sodium soap molecule in water.
Persamaan di bawah menunjukkan pengionan molekul sabun natrium di dalam air.
Soap becomes less effective when the cleaning is carried out in acidic water. Explain.
Sabun menjadi kurang berkesan apabila pencucian menggunakan air berasid. Terangkan.
[2 marks]
[2 markah]
(e)
Amphicillin is an antibiotic. Patients are advised to finish the whole course of antibiotic prescribed even though he/she has recovered from the sickness. Explain.
Ampisilin adalah antibiotik. Pesakit dinasihatkan untuk menghabiskan ubat tersebut walaupun penyakitnya sudah sembuh. Terangkan.
[3 marks]
[3 markah]
(f)
Explain why aspirin is not advisable to be prescribed to patient with gastric problem.
Terangkan mengapa aspirin tidak digalakkan kepada pesakit yang mengalami penyakit gastrik.
[2 marks]
[2 markah]
4541/2
22
4541/2
Section C
Bahagian C
[20 marks] [20 markah] Answer any one question from this section
Jawab mana-mana satu soalan.daripada bahagian ini.
(a)
Tin (stanum) is used to electroplate food can in industries. Explain why food in a dented can should not be consumed.
Stanum digunakan untuk menyadur tin makanan dalam industri. Terangkan mengapa makanan dalam tin yang kemek tidak boleh dimakan.
[4 marks]
[4 markah]
(b)
Cell I
Sel 1
Cell II
Sel II
Diagram 9.1
Rajah 9.1
Compare and contrast Cell I and Cell II. Your answer should include observation and half equation for the reaction at both electrodes.
Bandingbezakan Sel I dan Sel II. Jawapan anda mesti mengandungi pemerhatian dan setengah persamaan bagi tindak balas yang berlaku di kedua-dua elektrod .
[6 marks]
[6 markah]
4541/2
23
4541/2
(c)
Based on the above statement, describe an experiment to verify the reaction that occured is a redox reaction.
Berdasarkan kenyataan di atas, huraikan satu eksperimen untuk membuktikan tindak balas yang berlaku merupakan tindak balas redoks.
Procedure
Prosedur
Confirmatory test
Ujian pengesahan
Ionic equation
Persamaan ion
[10 marks]
[10 markah]
4541/2
24
4541/2
10
(a)
Methanoic acid is used in rubber industries to coagulate latex. It reacts with magnesium according to the following equation:
Asid metanoik digunakan dalam industri getah untuk membekukan lateks. Asid ini bertindak balas dengan magnesium mengikut persamaan berikut:
2 HCOOH + Mg (HCOO)2Mg + H2
[Relative Atomic Mass: C=12; O=16; H=1; molar volume of gas at room temperature and pressure is 24 dm3 mol-1 ] [Jisim atom relatif: C;12, O;16, H;1. isipadu molar sebarang gas pada suhu dan tekanan
bilik adalah 24 dm3 mol-1]
(i)
Calculate the maximum volume of hydrogen gas released if 50 cm3 of 0.2 mol dm-3 methanoic acid is reacted with 5 g magnesium.
Hitung isipadu maksima gas hidrogen yang terbebas jika 50 cm3 asid metanoik 0.2 mol dm-3 bertindak balas dengan 5 g serbuk magnesium. [3 marks] [3 markah]
(ii)
A sweet smelling substance is formed when methanoic acid is reacted with ethanol, C2H5OH. Name the substance and draw the structural formula.
Apabila asid metanoik bertindak balas dengan etanol, C2H5OH ester. Namakan dan lukis formula struktur ester tersebut membentuk
[2 marks] [2 markah]
(b)
Natural rubber is obtained from rubber tree as shown in Diagram 10.1. Aeroplane tyres as shown in Diagram 10.2 are produced by vulcanizing the natural rubber. Compare the following properties between natural rubber and vulcanized rubber Elasticity Heat resistance Explain the differences
Getah asli diperolehi dari pokok getah seperti ditunjukkan dalam Rajah 10.1. Tayar kapalterbang seperti dalam Rajah 10.2 dihasilkan melalui penvukanan getah asli. Bandingkan sifat berikut antara getah asli dan getah tervulkan. Kekenyalan Tahan haba Terangkan perbezaan tersebut. [5 marks] [5 markah]
Diagram 10.1
4541/2 Copyright Reserved MARA
Diagram 10.2 25
[See next page CONFIDENTIAL
4541/2
(c)
Alcohol
Alkohol
Hydrocarbon
Hidrokarbon
Procedure
Prosedur
Equation
Persamaan
Confirmation of product
Pengesahan hasil
[10 marks]
[10 markah]
http://cikguadura.wordpress.com/
4541/2
26
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... ....
4541/2 Copyright Reserved MARA
27
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... ....
4541/2 Copyright Reserved MARA
28
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... ....
4541/2 Copyright Reserved MARA
29
4541/2
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... ....
4541/2 Copyright Reserved MARA
30
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... ....
4541/2 Copyright Reserved MARA
31
4541/2
1.
This question paper consists of three sections: Section A, Section B and Section C.
Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B dan Bahagian C..
2.
Answer all questions in Section A. Write your answers for Section A in the spaces provided in the question paper.
Jawab semua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam ruang yang disediakan dalam kertas soalan.
3.
Answer one question from Section B and one question from Section C. Write your answers for Section B and Section C on the lined pages at the end of the question paper. Answer questions in Section B and Section C in detail. You may use equations, diagrams, tables, graphs and other suitable methods to explain your answer.
Jawap satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C. Tuliskan jawapan bagi Bahagian B dan Bahagian C pada halaman bergaris di bahagian akhir kertas soalan ini. Jawab Bahagian B dan Bahagian C dengan terperinci. Anda boleh menggunakan persamaan, gambar rajah, jadual, graf dan cara lain yang sesuai untuk menjelaskan jawapan anda..
4. 5. 6. 7.
If you wish to cancel any answer, neatly cross out the answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.
The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan.
Marks allocated for each question or part question are shown in brackets.
Markah yang diperuntukkan kurungan. bagi setiap soalan atau ceraian soalan ditunjukkan dalam
8.
The time suggested to complete Section A is 90 minutes, Section B is 30 minutes and Section C is 30 minutes
Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 minit, Bahagian B ialah 30 minit dan Bahagian C ialah 30 minit.
9. 10.
4541/2
32
Name : .....
Class : ..
MAKTAB RENDAH SAINS MARA SIJIL PELAJARAN MALAYSIA TRIAL EXAMINATION 2008
http://cikguadura.wordpress.com/
CHEMISTRY
Paper 3 One hour and thirty minutes
For Examiners Use 1. Write down your name and class in the space provided
Tuliskan nama dan kelas anda pada ruang yang disediakan.
Question 1 2
Full Mark 33 17 50
Mark
2.
3.
Candidates are required to read the information at the back page of the question booklet.
Calon dikehendaki membaca maklumat di halaman belakang kertas soalan ini.
Total
This question booklet contains 10 printed pages including the front page. [See Next Page 4541/3Copyright Reserve MARA
CONFIDENTIAL
For Examiners Use
4541/3
An experiment was conducted to determine the position of different metals in Electrochemical Series. Diagram 1.1 shows the set-up of apparatus used and copper is the positive terminal in all experiment.
Satu eksperimen dijalankan untuk menentukan kedudukan logam berbeza dalam Siri Elektrokimia. Rajah 1.1 menunjukkan susunan radas yang digunakan dan kuprum adalah terminal positif dalam semua eksperimen.
Porous pot
Pasu berliang
Copper
Kuprum
Diagram 1.1
Rajah 1.1
Experiment is repeated using different pairs of metals. Diagram 1.2 shows the voltmeter reading for all experiments.
Eksperimen diulangi menggunakan pasangan logam berbeza. Rajah 1.2 menunjukkan bacaan voltmeter bagi semua eksperimen.
Mg / Cu
Fe / Cu
Reading:.......................... V
Bacaan:
Reading:.......................... V
Bacaan:
Zn / Cu
Pb / Cu
1(a) Reading:.......................... V
Bacaan:
Reading:.......................... V
Bacaan:
Diagram 1.2
Rajah 1.2
CONFIDENTIAL
4541/3
For Examiners Use
(a) (b)
Construct a table and record the potential difference for each experiment.
Bina sebuah jadual untuk menunjukkan beza keupayaan bagi setiap eksperimen .
1(b)
(c)
1(c)
Table 1.1
Jadual 1.1
CONFIDENTIAL
For Examiners Use
4541/3
(d)
1(d)
........................................................................................................................ ........................................................................................................................ (e) Cell in Diagram 1.1 is left for 5 minutes. Complete the following Table by stating the observations and related inferences in the experiment.
Sel dalam Rajah 1.1 dibiarkan selama 5 minit. Lengkapkan Jadual berikut dengan menyatakan pemerhatian dan inferens yang berkaitan dalam eksperimen tersebut.
Observations
Pemerhatian
Inferences
Inferens
1(e)
(f)
Based on the observations, arrange all the metals in ascending order of their electropositivity
Berdasarkan pemerhatian, susun kesemua logam itu mengikut tertib menaik keelektropositifan
1(f)
........................................................................................................................ (g) Based on the cell in Diagram 1.1, classify the ions present in both solutions into cations and anions.
Berdasarkan sel dalam Rajah 1.1 kelaskan ion-ion yang terdapat dalam kedua-dua larutan kepada kation dan anion.
1(g)
CONFIDENTIAL
4541/3
For Examiners Use
(h)
........................................................................................................................ ........................................................................................................................ (i) A potential difference of 1.5 V is observed when the experiment is repeated by using an unknown metal, R and copper. Predict the position of metal R in the Electrochemical Series.
Beza keupayaan sebanyak 1.5 V dihasilkan apabila eksperimen diulangi menggunakan suatu logam yang tidak diketahui , R dan kuprum. Ramalkan kedudukan logam R dalam Siri Elektrokimia.
1(h)
1(i) ........................................................................................................................ (j) If cell using Zn/Cu is left for 2 hours, state the colour change of copper(II) sulphate solution.
Sekiranya sel menggunakan Zn/Cu dibiarkan selama 2 jam, nyatakan perubahan warna larutan kuprum(II) sulfat.
........................................................................................................................
1(j)
CONFIDENTIAL 2 Diagram 2.1 shows two types of bonfire using sticks and logs.
Rajah 2.1 menunjukkan 2 jenis unggun api menggunakan ranting kayu dan batang kayu.
4541/3
During camping, a group of students discovered that it is easier to start a bonfire using sticks rather than logs. This is due to the differences in the size
Semasa berkhemah, sekumpulan pelajar telah mendapati bahawa lebih senang untuk menghidupkan unggun api menggunakan ranting kayu berbanding batang kayu. Ini disebabkan oleh perbezaan saiz.
Diagram 2.1
Rajah 2.1
Referring to the above situation, plan a laboratory experiment to investigate the effect of size of reactant on the rate of reaction between calcium carbonate and an acid.
Merujuk kepada situasi di atas, rancangkan satu eksperimen dalam makmal untuk mengkaji kesan saiz bahan tindak balas terhadap kadar tindak balas antara kalsium karbonat dengan asid.
Statement of Problem
Pernyataan masalah
Statement of hypothesis
Pernyataan hipotesis
Tabulation of data
Penjadualan data
[17 marks]
http://cikguadura.wordpress.com/
4541/3
For Examiners Use]
.... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... ....
CONFIDENTIAL
For Examiners Use]
4541/3
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... ....
4541/3
For Examiners Use]
.... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... ....
CONFIDENTIAL INFORMATION FOR CANDIDATES MAKLUMAT UNTUK CALON 1. 2. 3. This question paper consists of two questions. Answer all questions.
Kertas soalan ini mengandungi dua soalan. Jawab semua soalan
4541/3
Write your answers for Question 1 in the spaces provided in the question paper.
Tuliskan jawapan bagi Soalan 1 dalam ruang yang disediakan dalam kertas soalan.
Write your answers for Question 2 on the lined pages at the end of the question paper in detail.
Tuliskan jawapan bagi Soalan 2 pada halaman bergaris di bahagian akhir kertas soalan ini dengan terperinci
4. 5. 6. 7. 8.
If you wish to cancel any answer, neatly cross out the answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.
The diagrams in the questions are not drawn to scale unless stated.
Rajah yang terdapat dalam soalan tidak dilukis mengikut skala kecuali dinyatakan sebaliknya
Marks allocated for each question or part of the question are shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam kurungan.
9. 10.
Marks awarded
Pemberian markah
Score Skor
3 2 1 0
10