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Sodium Thiosulfate, Preparation And Properties Of Sodium Thiosulfate, Uses Of Sodium Thiosulfate, Inorganic Chemistry, Homework Assignment Help
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Sodium Thiosulfate
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Sodium thiosulfate
Na2S2O3.52O: It is manufactured by saturating a solution of sodium carbonate with SO2 which gives a solution of sodium sulfite, Na2CO3 + SO2 + H2O Na2SO3 + CO2 + H2O 373K The resulting solution is boiled with powdered sulfur as, Na2SO3 + S > Na2S2O3 The solution is then cooled to get crystals of sodium thiosulfate. Physical properties : (i) Sodium thiosulfate is a colorless crystalline solid. In the hydrated form, it is called hypo. (ii) It melts at 320 K and loses its water molecules of crystallization on heating to 490K. Chemical properties (i) Action with halogens : It reacts with halogens as, (a) Chlorine water oxidizes sodium thiosulphate to sodium sulphate and sulphur is precipitated, Na 2S2O3 + Cl2 + H2O > 2HCl + Na2SO4 +S This property enables it to act as an antichlor in bleaching i.e. it destroys the unreacted chlorine in the process of bleaching. (b) Bromine water also oxidizes sodium thiosulfate to sodium sulfate and sulfur, Na 2S2O3 + Br2 + H2O > Na2SO4 + 2HBr + S (c) With iodine it forms a soluble compound called sodium tetrathionate, 2Na 2S2O3 + l2 > Na2S4O6 + 2NaI Sod. tetrathionate Therefore, hypo is commonly used to remove iodine stains from the clothes. (ii) Action of heat : Upon heating, sodium thiosulfate decomposes to form sodium sulfate and sodium pentasulfide, Heat 4Na 2S2O3 > 3Na2SO4 + Na2S5 Chat now Sodium pentasulphate (iii) Action with acids : Sodium thiosulphate reacts with dilute hydrochloric acid or Sulfuric acid forming sulfur dioxide and sulfur. The solution turns milky yellow due to sulfur. Na2S2O3 + 2HCl > 2NaCl + SO2 + H2O + S (iv) Action with silver halides : Sodium thiosulfate forms soluble complex when treated with silver chloride or silver bromide, 2Na 2S2O3 + 2AgBr > Na3Ag(S2O3)2 + NaBr Sodium disthiosulphate argentate (I)complex

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This property of hypo is made use in photography. Uses of sodium thiosulfate (i) It is largely used in photography as a fixing agent. (ii) It is used as a preservative for fruit products such as jams and squashes. (iii) It is used as an antichlor in bleaching. (iv) It is used as a volumetric agent for the estimation of iodine. (v) It is used in medicine.

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