CHEM 161- Exam 2

Fall 2012 No Cheating. Youve got one hour.

Name:____________________

Failure to Put Name and Student ID on Exam: -5 points TIP: Put Your Name on This Exam and Circle Your Answers SO You Know What You Put

USEFUL EQUATIONS AND FORMULAS 1000 mL in 1 Liter h= 6.626 x 10-34 Js d=g/mL 1 x 10 9 nm in 1 meter c = 2.998 x 10 8 m/s M=moles/Liter 1x106 J in 1 MJ NA = 6.022 x 10 23 c= E=h 1x10 3 J in 1 kJ

(THIS PAGE INTENTIONAL L Y LEFT BLANK)

CHEM 161- Exam 2

Fall 2012

Name:____________________

____1) If 26.5 mL of 0.678 M IO4-1 solution is required to react with 25.0 mL of C 6H12O6 solution, then what is the M of C6H12O6? C6 H12O6 + 5 IO4-1 5 IO3-1 + 5 HCO2H + H2CO

____2) A compound of xenon, fluorine, and oxygen was found to have a mass percent of Xe of 58.80 % and a mass percent of F of 34.04 %. What is the compounds empirical formula?

A) 0.678 M B) 0.718 M C) 0.144 M D) 0.504 M

A) XeF4 B) XeO2 C) XeOF4 D) XeO2F5

____3) A sample of unknown diprotic acid with a mass of 0.4123 g was titrated against a 25.0 mL sample of 0.154 M NaOH until neutralized. What is the Molar Mass of the unknown diprotic acid? H2 A + 2 NaOH 2 Na+1 + 2 H2O + A2A) 214 g/mol B) 107 g/mol C) 195 g/mol D) Not enough information.

____4) How many H 2O molecules are required to balance the reaction below? ___ CH4 + ___O2 ___CO2 + ___H2O

A) 1 B) 2 C) 4 D) 6

CHEM 161- Exam 2

Fall 2012

Name:____________________

____5) Consider the following two-step reaction: N2 + 3 H2 2 NH3 4 NH 3 + 5 O2 4 NO + 6 H 2O If we started out with only 0.35 mole of N2 and 1.20 mole of H2 and excess O2, then how many moles of H2O can be made?

____6) Identify the neutral atom whose PES spectrum is shown below:

A) 1.85 moles of H 2O B) 1.20 moles of H 2O C) 1.50 moles of H 2O D) 1.05 moles of H 2O

A) Al B) C C) B D) S

____7) The Rutherford Gold Foil experiment proved the existence of ________. A) the particle. B) the atomic nucleus. C) the proton. D) the mass of the electron.

____8) How many grams of copper can be made from 1.00 x 102 g of CuO and 3.5 g of H2? CuO + H2 Cu + H2O [Help: The Molar Mass of CuO is 79.545 g/mol and the Molar Mass of H2 is 2.016 g/mol.] A) 103.5 g of Cu B) 190.2 g of Cu C) 79.9 g of Cu D) 68.8 g of Cu

CHEM 161- Exam 2

Fall 2012

Name:____________________ ____10) What is the formula when the Ca+2 cation comes together and forms an ionic compound with the ClO-1 hypochlorite anion?

____9) To what volume must 150 mL of a 1.15M solution of H2O2(aq) be diluted in order to produce a 0.860 M solution?

A) 178 mL of H2O2 B) 112 mL of H2O2 C) 201 mL of H2O2 D) 350. mL of H2O2

A) CaClO B) CaClO2 C) Ca(ClO) 2 D) Ca(ClO2 )2

____11) A student dissolved 0.500 moles of Al2 (SO4 )3 in water and makes a solution with a total volume of 750 mL. What is the Molarity of SO42-(aq) anion? A) 1.33 M B) 2.00 M C) 0.667 M D) 1.13 M

____12) How many atoms of phosphorus are in 1.00 grams of P4? [Help: The Molar Mass of P4 is 123.896 g/mol] A) 5.05 x 10 22 atoms of P B) 1.94 x 10 22 atoms of P C) 7.89 x 10 23 atoms of P D) 4.86 x 10 21 atoms of P

CHEM 161- Exam 2

Fall 2012

Name:____________________

____13) The substance that is dissolved in the solvent is known as the __________.

____14) The outer electrons in Aluminum feels an effective nuclear charge close to ___.

A) solute. B) ion. C) solution. D) isotope.

A) +13 B) +5 C) +1 D) +3

____15) Calculate the wavelength of light in nanometers if the light has a frequency of 3.72 x 10 14 1/s.

____16) What is the ground state electron configuration for Cu?

A) 805 nm B) 1.24 nm C) 124 nm D) 806 nm

A) 1s22s22p63s23p64s13d10 B) 1s22s22p63s23p64s23d9 C) 1s22s23s24s13d10 D) 1s22s22p63s23p63d11

CHEM 161- Exam 2

Fall 2012

Name:____________________

____17) An unknown metal, M, makes ionic compounds M3(PO4)2 and MSO4. What is the metals charge?
-2

____18) How many subshells are in the n=3 shell?

A) M B) M+3 C) M+2 D) M+1

A) 1 subshell B) 3 subshells C) 18 subshells D) 2 subshells

____19) What is the ground state electron Configuration of N-3? A) 1s22s22p3 B) 1s22s22p6 C) 1s22s2 D) 1s22s22p63s23p6

____20) Example(s) of electrons jumping from energy level to energy level in atoms is evidenced by.

A) the color of exploding fireworks B) the color of plugged-in Neon signs C) the color of burning elements D) All of the above

CHEM 161- Exam 2

Fall 2012

Name:____________________

____21) In PE spectroscopy, the hin the Equation IE i = h -KE i stands for.

____22) The image below is showing an example of______________.

A) energy of electromagnetic radiation that hits the sample B) electromagnetic radiation of the electron C) kinetic energy of the electron D) ionization energy for an electron

A) emission B) absorption C) absorbancy D) nuclear scattering

CHEM 161- Exam 2

Fall 2012

Name:____________________

____23) What is the ground state electron configuration of Ti+2? A) 1s22s22p63s23p63d2 B) 1s22s22p63s23p64s2 3d1 C) 1s22s22p63s23p54s1 3d1 D) 1s22s22p63s23p64s23d4

____24) A mole of photon with a wavelength of 767 nm has what energy? A) 3.90 x 10 14 J/mole B) 4.30 x 10-43 J/mole C) 2.59 x 10 -19 J/mole D) 156,000 J/mole

____25) A 5.00 gram sample of a metal with a density of 13.4 g/mL is dropped into water. The resulting water level in the container rises by how many mL?

A) 67.0 mL B) 2.68 mL C) 0.373 mL D) Cannot be determined