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by Marshall Brain, Charles W. Bryant and Clint Pumphrey Browse the article How Batteries Work
How do batteries power our world? See more battery pictures. iStockphoto/Thinkstock
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Test Your Knowledge: Battery Quiz How Lithium-ion Batteries Work When was the first battery invented?
make them work. So cut that cord and click through our informative guide to charge up your knowledge of batteries.
The history of batteries can be traced back to 1800. Learn about the history of batteries and find out how the Daniell cell battery is constructed. HowStuffWorks.com
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Test Your Knowledge: Battery Quiz How Lithium-ion Batteries Work When was the first battery invented?
Battery History
Batteries have been around longer than you may think. In 1938, archaeologist Wilhelm Konig discovered some peculiar clay pots while digging at Khujut Rabu, just outside of present-day Baghdad, Iraq. The jars, which measure approximately 5 inches (12.7 centimeters) long, contained an iron rod encased in copper and dated from about 200 B.C. Tests suggested that the vessels had once been filled with an acidic substance like vinegar or wine, leading Konig to believe that these vessels were ancient batteries. Since this discovery, scholars have produced replicas of the pots that are in fact capable of producing an electric charge. These "Baghdad batteries" may have been used for religious rituals, medicinal purposes, or even electroplating. In 1799, Italian physicist Alessandro Volta created the first battery by stacking alternating layers of zinc, brine-soaked pasteboard or cloth, and silver. This arrangement, called a voltaic pile, was not the first device to create electricity, but it was the first to emit a steady, lasting current. However, there were some drawbacks to Volta's invention. The height at which the layers could be stacked was limited because the weight of the pile would squeeze the brine out of the pasteboard or cloth. The metal discs also tended to corrode quickly, shortening the life of the battery. Despite these shortcomings, the SI unit of electromotive force is now called a volt in honor of Volta's achievement.
The history of batteries can be traced back to 1800. Learn about the history of batteries and find out how the Daniell cell battery is constructed. HowStuffWorks.com The next breakthrough in battery technology came in 1836 when English chemist John Frederick Daniell invented the Daniell cell. In this early battery, a copper plate was placed at the bottom of a glass jar and a copper sulfate solution was poured over the plate to half-fill the jar. Then the zinc plate was hung in the jar, and a zinc sulfate solution was added. Because copper sulfate is denser than zinc sulfate, the zinc solution floated to the top of the copper solution and surrounded the zinc plate. The wire connected to the zinc plate represented the negative terminal, while the one leading from the copper plate was the positive terminal. Obviously, this arrangement would not have functioned well in a flashlight, but for stationary applications it worked just fine. In fact, the Daniell cell was a common way to power doorbells and telephones before electrical generation was perfected. By 1898, the Colombia Dry Cell became the first commercially available battery sold in the United States. The manufacturer, National Carbon Company, later became the Eveready Battery Company, which produces the Energizer brand. Now that you know some of the history, click over to the next page to learn the various parts of a battery.
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Test Your Knowledge: Battery Quiz How Lithium-ion Batteries Work When was the first battery invented?
Anatomy of a Battery
Take a look at any battery, and you'll notice that it has two terminals. One terminal is marked (+), or positive, while the other is marked (-), or negative. In normal flashlight batteries, like AA, C or D cell, the
terminals are located on the ends. On a 9-volt or car battery, however, the terminals are situated next to each other on the top of the unit. If you connect a wire between the two terminals, the electrons will flow from the negative end to the positive end as fast as they can. This will quickly wear out the battery and can also be dangerous, particularly on larger batteries. To properly harness the electric charge produced by a battery, you must connect it to a load. The load might be something like a light bulb, a motor or an electronic circuit like a radio. The internal workings of a battery are typically housed within a metal or plastic case. Inside this case are a cathode, which connects to the positive terminal, and an anode, which connects to the negative terminal. These components, more generally known as electrodes, occupy most of the space in a battery and are the place where the chemical reactions occur. A separator creates a barrier between the cathode and anode, preventing the electrodes from touching while allowing electrical charge to flow freely between them. The medium that allows the electric charge to flow between the cathode and anode is known as the electrolyte. Finally, the collector conducts the charge to the outside of the battery and through the load. On the next page, we'll explore how the cathode, anode, electrolyte, separator and collector work together to produce an electrical current and keep your portable devices going strong.
Powered by Air?
Researchers are currently developing a battery in which the electrodes would be lithium and, amazingly, oxygen from the air. Such an advancement would dramatically decrease battery weight and could boast five to 10 times the energy of traditional lithium-ion batteries. While this technology still has a number of obstacles to overcome, it could one day revolutionize the electric car industry [source: Rahim].
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Test Your Knowledge: Battery Quiz How Lithium-ion Batteries Work When was the first battery invented?
Zinc-carbon battery: The zinc-carbon chemistry is common in many inexpensive AAA, AA, C and D dry cell batteries. The anode is zinc, the cathode is manganese dioxide, and the electrolyte is ammonium chloride or zinc chloride.
Alkaline battery: This chemistry is also common in AA, C and D dry cell batteries. The cathode is composed of a manganese dioxide mixture, while the anode is a zinc powder. It gets its name from the potassium hydroxide electrolyte, which is an alkaline substance. Lithium-ion battery (rechargeable): Lithium chemistry is often used in high-performance devices, such as cell phones, digital cameras and even electric cars. A variety of substances are used in lithium batteries, but a common combination is a lithium cobalt oxide cathode and a carbon anode. Lead-acid battery (rechargeable): This is the chemistry used in a typical car battery. The electrodes are usually made of lead dioxide and metallic lead, while the electrolyte is a sulfuric acid solution.
The best way to understand these reactions is to see them for yourself. Go to the next page for some handson battery experiments.
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Test Your Knowledge: Battery Quiz How Lithium-ion Batteries Work When was the first battery invented?
By now you should be well acquainted with the basic principles by which batteries discharge electricity. Read on to discover how some batteries can be recharged.
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Test Your Knowledge: Battery Quiz How Lithium-ion Batteries Work When was the first battery invented?
Rechargeable Batteries
With the rise in portable devices such as laptops, cell phones, MP3 players and cordless power tools, the need for rechargeable batteries has grown substantially in recent years. Rechargeable batteries have been around since 1859, when French physicist Gaston Plante invented the lead acid cell. With a lead anode, a lead dioxide cathode and a sulfuric acid electrolyte, the Plante battery was a precursor to the modern-day car battery. Non-rechargeable batteries, or primary cells, and rechargeable batteries, or secondary cells, produce current exactly the same way: through an electrochemical reaction involving an anode, cathode and electrolyte. In a rechargeable battery, however, the reaction is reversible. When electrical energy from an outside source is applied to a secondary cell, the negative-to-positive electron flow that occurs during discharge is reversed, and the cell's charge is restored. The most common rechargeable batteries on the market today are lithium-ion (LiOn), though nickel-metal hydride (NiMH) and nickel-cadmium (NiCd) batteries were also once very prevalent. When it comes to rechargeable batteries, not all batteries are created equal. NiCd batteries were among the first widely available secondary cells, but they suffered from an inconvenient problem known as the memory effect. Basically, if these batteries weren't fully discharged every time they were used, they would quickly lose capacity. NiCd batteries were largely phased out in favor of NiMH batteries. These secondary cells boast a higher capacity and are only minimally affected by the memory effect, but they don't have a very good shelf life. Like NiMH batteries, LiOn batteries have a long life, but they hold a charge better, operate at higher voltages, and come in a much smaller and lighter package. Essentially all high-quality portable technology manufactured these days takes advantage of this technology. However, LiOn batteries are not currently available in standard sizes such as AAA, AA, C or D, and they're considerably more expensive than their older counterparts. With NiCd and NiMH batteries, charging can be tricky. You must be careful not to overcharge them, as this could lead to decreased capacity. To prevent this from happening, some chargers switch to a trickle charge or simply shut off when charging is complete. NiCd and NiMH batteries also must be reconditioned, meaning you should completely discharge and recharge them again every once in a while to minimize any loss in capacity. LiOn batteries, on the other hand, have sophisticated chargers that prevent overcharging and never need to be reconditioned. Even rechargeable batteries will eventually die, though it may take hundreds of charges before that happens. When they finally do give out, be sure to dispose of them at a recycling facility. Next, let's take a look at battery arrangement.
Battery arrangement determines voltage and current. Check out serial battery arrangements, parallel arrangements and what maximum current is about. HowStuffWorks.com
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Test Your Knowledge: Battery Quiz How Lithium-ion Batteries Work When was the first battery invented?
Imagine the batteries shown in the diagram are rated at 1.5 volts and 500 milliamp-hours. The four batteries in parallel arrangement will produce 1.5 volts at 2,000 milliamp-hours. The four batteries arranged in a series will produce 6 volts at 500 milliamp-hours. Battery technology has advanced dramatically since the days of the Voltaic pile. These developments are clearly reflected in our fast-paced, portable world, which is more dependent than ever on the portable power source that batteries provide. One can only imagine what the next generation of smaller, more powerful and longer-lasting batteries will bring. For more information on batteries and related topics, check out the links on the next page.