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In a solid lattice, the cation has left a lattice site and is located at interstitial position, the lattice defect is

(a)

Interstitial defect

(b) Vacancy defect

(c) Frenkel defect

(d) Schottky defect

Which of the following metal oxides is antiferromagnetic in nature ?

(a)

MnO 2

(b)TiO 2

(c)NO 2

(d)CrO 2

The intermetallic compound crysta-llizes in cubic lattice in which both lithium and silver have co- ordination number of eight. The crystal class is.

(a)

Simple cube

(b) Body centred cube

(c) Face centred cube

(d) None

Which among the following will show anisotropy ?

(a)

Glass

(b) Barium Chlorid

(c) Wood

(d) Paper

In a crystal, all the lattice sites are found to be occupied by covalent molecules. To which kind of solid

does it belong?

(a)

ionic

(b) molecular

(c) covalent

(d) None of these

Which one of the following is correct?

(a)

(b)

Schottky defect lowers the density

Frenkel defect increases the dielectric constant of the crystals

(c)

Stoichiometric defects make the crystals good electrical conductors

The electrical conductivity of semiconductors

(a)

(c)

Increases with temperature

Remains constants on heating

(b) Decreases with temperature

(d) None of the above

(d) All of these

The unit cell with crystallographic dimen-sions a=bc; α = β= γ= 90 0 is

(a)

cubic

(b) tetragonal

(c) monoclinic

(d) hexagonal

In a crystal of an ionic compound the ions form the close packed lattice and the ions A occupy all the

tetrahedral voids. The formula of the compound is.

(a)

AB

2

(b)

A

2

B

(c) AB

(d)

AB

3

  • 10. An aqueous solution freezes at 0.186 0 C ; (Kf = 1.86 0 ; Kb = 0.512 0 ) what is the elevation in boiling point ?

(a)

0.186

(b) 0.512

(c) 0.86

(d) 0.0512

  • 11. The average osmotic pressure of human blood is 7:8 bar at 37 0 C . What is the concentration of an aqueous NaCl solution that could be used in the blood stream ?

(a)

0.15 mol/L

(b) 0.30 mol/L

(c) 0.60 mol/L

(d) 0.45 mol/L

  • 12. A 5.25 % solution of a substance is isotonic with a 1.5 % solution of urea (molar mass = 60 g ) in the same solvent. If the densities of both the solutions are assumed to be equal to 1.0 g , molar mass of substance will be ..................

(a)

210.0 g (b) 90.0

(c) 115.0 g (d) 105.0 g

  • 13. For the structure give below the site marked as S is a.

(a)

(b)

(c)

(d)

Tetrahedral void

Cubic void

Octahedral void

None of these

  • 14. A 6% solution of urea is isotonic with ...........

(a)

(c)

0.05 M solution of glucose

25% solution of glucose

(b) 6% solution of glucose

(d) 1 M solution of glucose

1. 2. 3. 4. 5. 6. 7. 8. 9. In a solid lattice, the cation

S

  • 15. A student has 100 mL of 0.1 M KCl solution. To make it 0.2 M he has to.

(a)

(c)

evaporate 50 mL of the solution

(b) add 0.01 mole of KCl

both (a) and (b) can be used

(d) neither (a) nor (b) can be used

  • 16. When electricity is passed through molten Al 2 O 3 +Na 3 AlF 6 faradays passedare

13.5g of Al are deposited. The number of

(a)

1.5 (b) 3 (c) 15 (d) 0.15.

  • 17. The electrode potential of an electrode is

(a)

the potential applied to the electrode

(b)

the ionisation potential ofthe material of the electrode

(c)

the tendency of the electrode to lose or gain electrons when it is in contact with its ions.

(d)

the potential energy of the electrons in an electrode.

  • 18. During charging of a lead storage battery, the reaction taking place at anode.

  • (a) PbSO 4

(a) PbSO Pb + (b) Pb + 2e (c) Pb + 2e (d) + Pb 19.

Pb 2+ +

(a) PbSO Pb + (b) Pb + 2e (c) Pb + 2e (d) + Pb 19.

(b) Pb 2+ + 2e

  • (c) Pb 2+ + 2e (d) +

Pb

(a) PbSO Pb + (b) Pb + 2e (c) Pb + 2e (d) + Pb 19.
(a) PbSO Pb + (b) Pb + 2e (c) Pb + 2e (d) + Pb 19.
  • 19. In a galvanic all, a salt bridge is used to

-Pb + + +2e

-Pb

-Pb + + +2e
-Pb + + +2e
-Pb + + +2e
-Pb + + +2e

+ + +2e

-Pb + + +2e
  • (a) complete the circuit

(b) reduce electric resistance in cell

 
  • (c) (d) carry salts for electrons occurring in cell

attain equilibrium

 
  • 20. The time in hours required for a current of 3 ampere to decompose electrolytically 18gm of H 2 O is

    • (A) 9 (B) 18(C) 36 (D) 54

  • 21. The relative lowering of vapour pressure of an aqueous solution containing non-volatile solute is 0.0125. The molality of the solution is ................ (a) 0.70

(b) 0.50

(c) 0.60

(d) 0.80

(e) 0.40

  • 22. One molal solution of a complex of cobalt chloride with in water showed an elevation in boiling point equal to . Assuming that the complex is completely ionized in the solution, the complex is ( for water = 0.52 k kg )

(a)

CO NH

3

6

Cl

3

(b)

CO NH

3

5

Cl

Cl

2

Question no 25 to 32 are two mark questions

(c)

CO NH

3

4

Cl

2

Cl

(d) none of these

  • 23. At , the vapour pressure of pure liquid ‘A’ is 520 mm Hg and that of pure liquid ‘B’ is 1000 mm Hg. If a mixture solution of ‘A’ and ‘B’ boils at and 1 atm pressure then amount of ‘A’ in the mixture is (1 atm = 760 mm Hg) (2 mark) (a) 48 mol percent

(b) 50 mol percent

(c) 52 mol percent

(d) 34 mol percent

  • 24. Calculate the standard free energy change for the reaction

Ag

e

Ag

a) +154.4kJ

is 0.80V (2mark) b) +308.8kJ

c) 154.4kJ

2Ag

2H

H

2

2Ag

given that

d) 308.8Kj

E

0

for

  • 25. A solid has a structure in which W atoms are located at the cube corners of the unit cell, O atoms are located at the face centres and the atoms at the cube centre. The formula of the compounds is.(2mark)

  • (a) NaWO

3

  • (b) Na WO

2

3

  • (c) NaW O

2

3

  • (d) NaWO

2

(a) PbSO Pb + (b) Pb + 2e (c) Pb + 2e (d) + Pb 19.

 

101.38ohm

-1

cm

2

253.62 ohm

-1

cm

2

289.71ohm

-1

cm

2

678.90 ohm

-1

cm

2

 

 

 

 

Cu

2

Cu

2

O

2

=99.79ml, H

2

=48.45ml

O

2

=99.79ml, H

2

=58.48ml

O

2

=87.91ml, H =58.48ml

2

O

2

=100 ml, H =50 ml

2