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Preliminary Design Concentration of Talc by Emphasis on Mineralogy… 127

Preliminary Design Concentration of Talc by Emphasis


on Mineralogy in the Malhamdar Index Mine in Iran
A. Hajati
Department of Mining,
Iran University of Science and Technology, Arak Branch-Iran
E-mail: am_hajati@iustarak.ac.ir, am_hajati@yahoo.com

ABSTRACT: Talc is one of the industrial minerals for paper, ceramic, paint, and textile, and rubber, plastic,
cosmetic and etc industry. Mineralogy is one the applied science for definition of minerals structure in
preliminary study at mineral processing engineering. By mineralogy, different aims are important. In this
research, actions of mineral are studies in sample talc of two indexes, Talc-Sheest and Talc-dolomite in the
Malhamdar village in around of Arak-Markazi state of Iran. The results of mineralogy studies are used in
design of preliminary flow sheet concentration. By know of paragons minerals and vary them (specific
gravity, breaking quality, chemical- physical surface, luster and etc) talc can separate of other minerals. In
this index mine, talc, chlorite, dolomite, quartz, feldspar, ferrous mineral are known and By XRF test it
consist MgO:(28–28.25)%, SiO2:(46.6–56)%, Al2O3:(2.36–8)%, CaO:(1.6–2.1)% and Fe2O3:(4–6)%. By
attention of mineralogy studies and use of especial variation minerals, such as sizing, gravity, magnetite and
etc, it able separation of talc. Finally, talc concentration arrived MgO: 30.5%, SiO2: 52.1%, Al2O3:5.12%,
CaO:0.72% and Fe2O3:5.01%.

Key Words: Mineralogy, Concentration, Gravity, Malhamdar, Talc.

1. INTRODUCTION processing methods, particle size, surface


treatment, (acid-base characterization, hydro-
There are important deposits of talc in China, phobic, hydrophilic, electro kinetic) [2].
Australia, Itly, France, Canada, U.S. and other
Talc, as a mineral has unique surface
countries. Talc, which is a soft, hydrous magne-
sium silicate (Mg3Si4O10(OH)2), is used in a wide properties. Particles of talc have the shape of
range of industries including the manufacture of platelets due to the layer structure of the mineral.
paint, paper, plastic medicine, cosmetic, ceramic, The hydrophobicity of the basal surfaces arises
rubber, face and talcum powder, fire proof from the fact that atoms exposed on the surface
roofing, foundry facings, lubricants, linoleum and are linked together by siloxane bonds and
oilcloth, electrical insulation and pottery. Foundry hence, do not form strong hydrogen bonds with
is coming into being by lower heat water [3].
metamorphism at dolomites with silica and In many of industrial applications, this dual
separation of ultra basic rocks by hydrothermal surface property of the mineral plays an important
effects. Talc can be divided into two groups as role.
with magnesite and with carbonate. Talc includes
63.5% SiO2, 31.7% MgO and 4.8% H2O in ideal The purpose of this study is to investigate
compositions. Talc deposits generally contain some effective parameters for Preliminary design
calcite, dolomite, chlorite, olivine, quartz, concentration of Talc by emphasis on mineralogy
serpentine, graphite, mica and etc [1]. to determine optimum conditions minerolography
The market potentials of the various talc in the Malhamdar index mine in Iran.
products depend on the surface properties of the
mineral, which in turn vary with the ore type, 2. MINERALOGY STUDY
128  Mineral Processing Technology (MPT 2007)
Talc is a hydrated magnesium silicate whit other minerals such as: pyrophyllite, seerpentine,
the theoretical formula Mg6[Si8O20](OH)4. The anthophyllite, chlorite, tremolite and actinolite.
chemical composition of talc found in nature, Likewise, talc has different type, by attention of
however, is quite variable. It is an extremely soft mineralogy complex, shap visible, purity,
mineral and is rated No. 1 in Mohs’ scale of application of industry and etc. they are Steatite,
hardness. It varies in color from snow-white to soap stone, path stone, Renslaerite, French chalk,
greenish gray and various shades of green. Its lava, filament and softness talc. By attention of
specific gravity ranges from 2.58 to 2.83. Talc different application of talc, study of mineralogy
usually derives a secondary mineral by alteration and knowledge of all suitable and gangue
of other magnesium silicates such as serpentine, minerals for concentration and separation of
pyroxene or siliceous dolomite. Talc deposit gangue minerals are very important. For
can be classified into for major categories: investigation of size distribution and con-
(a) Steatite-Compact, (b) Soft Platy talc, centration of minerals after sampling of feed,
(c) Tremolite talc and (d) Mixed talc ores. analyzed by screen in limit size of D1:(–10, +30
Talc is a mineral that meets criteria of a Mesh), D2:(–30, +120 Mesh), D3:(–120, +400
“sheet silicate” mineral. Its structure is like that of Mesh) and D4:(–400 Mesh). In figure 2, it has
pyrophyllite except that the octahedral sites in the shown talc and other minerals, that is accessory.
layers or sheets chemically pure talc is rarely
found in nature commercial quantities [4].

2.1 Geographical and Mineralogy


Case Study

The Malhamdar village talc district is aboat of


75 km long, into west of Arak in Markazy state of
Iran. This deposit is an exploration index and it’s
not very active. By this study, it’s goad for ready
and start of activity. In the Figure 1, it has shown
a vein of this deposit.

Fig. 2: Minerals of talc, chlorite, carbonate and


iron oxide at D2 size

Therefore, they are not liberated in large size.


After crushing sample and size distribution in
small size, it seems that, it has large degree of
liberation minerals.
Knowledge of minerals microscopy, relation
of between, size distribution, degree of liberation
Fig. 1: A part of Malhamdar deposit vein
and characteristic are important parameters into
core design separation process flow sheet.
This talc’s deposit is secondary mineral
dolomite group. Some of associate minerals by
2.2 Size distribution and Degree of
XRD analysis are chlorite, dolomite, iron oxide,
Liberation Study
quartz and calcite. Ditto, by microscopy study this
result accepted. Talc utilities in the industry have
Preliminary Design Concentration of Talc by Emphasis on Mineralogy… 129
In nature, valuable minerals occur together with chlorite and progenies of talc. Then a mount of
non-valuable species. Technological operation of Al2O3 remind on the >D1 screen.
the disjoining of valuable minerals from the rock
matrices is performed by inducing the 80

Distribution of component (%)


compressive failure of the ore fragments and 70

reducing the size of the fragments to the 60 MgO

dimensions ensuring the release of the majority of 50 SiO2


40 Al2O3
inclusions of the targeted mineral from the rock CaO
30
matrices of ores [5]. Thus, the ores are crushed 20
Fe2O3
and ground to fine sizes—to produce near single- 10
mineral particles of the two phases, thus liberating 0
the valuable phase from the gangue. >D1 D1 D2 D3 D4
Size limit
Degree of liberation of ore is one of the
important stages of ore processing for separation Fig. 4: Distribution of component weight
of gangue and minerals in greatest size possible. passing (%)
By this target, we will have the minimum rate of
crushing and reduction energy of use and 100

minimization of cost in the next stage and easily 90

of separation minerals. Then, before of separation 80


70
Comulative passing (%)

process by type deferent methods; it must be 60


completely dissociated by one and one. [6–7]. 50
40
Size distribution: The first stage, to determination 30
of degree of liberation minerals into the ore is size 20

classification. In figure 3 and 4 it has show, size 10

distribution analysis and components weight 0


10 100 1000 10000 100000 1000000
passing percentage respectively. Coarse particle Size(Micron)
production by caving materials in this index, is
almost 50 cm and d80 is 10.2 cm. nearly 60% Fig. 3: Size distribution of feed in Malhamdar
weight is size limit (1 mm–10.2 cm) and under index
10% weight is less than 2 mm. forethought of this
results help for determination of rate crushing Degree of liberation: Liberation size can be
feed by grinding equipment and very important to determined by quantitative mineralogical test
design flow sheet processing of talc concentration. work on size fractions of ground ore, although
Another aim of crushing sample in laboratory this is considerably less common because it is
test is, How distributed of minerals or costly, time consuming, and often technically
components of them by attention of limit size? By difficult Liberation size is a function of the
this result, limit size that minerals concentrated relevant physical or chemical process and may
determined for suitable crushing and simplify of differ greatly between processes.
separation process. The component of MgO and There are different methods base on minerals
SiO2 are showing of Talc. Another gangue property for the determination of degree of
component is Al2O3, Fe2O3, CaO and other things. liberation in laboratory test. There method can be
In Figure 4, percentage weight of CaO is summarized: Image Analyzer, Heavy liquid and
great 52% in size limit D2. It’s passing of >D1 and Magnetite. In this research, the microscopic
concentrate on the D1. Then, it seems that by one particle accounting method is chosen for the
suitable screen (0.5–1) inch among of mineral defining of degree of liberation talc and other
including of CaO will be removed. Almost, other minerals. Relatively, this method is subtle of
minerals crushed by both. Also, Al2O3 relation to determination degree of liberation and action of
mineralogy that duo to liberation of minerals by
130  Mineral Processing Technology (MPT 2007)
reduce of size particle, structure of texture capacity percentage, entering, size and kind of
minerals, size of minerals, hardness and other minerals and other things. Microscopy study is
things. By knowledge of these results, it will be very important to determined methods of
help for analysis of design separation process in separation, increase of grade and recovery, control
low coast operation and simplify flow sheet. In type of minerals in concentrate and tailing,
figure 5 it has shown degree of liberation minerals correction of line process, control efficiency of
of Malhamdar index deposit. equipment, change of process and other things.
Finally, applications of mineralogy in different
100 methods of ore dressing talc in design flow sheet
90
are in: Run of Mine, Milling, Separation and
Production.
Degree of Liberation (%)

80 Talc
Chlorite
70
60
Quartz 4. RESULTS AND DISCUSSIONS
Dolomite&Calsite
50 After investigation and study, analysis of samples
Iron minerals
40 by XRD and microscopy, drawn of curves and
> D1 D1 D2 D3 D4 other operation, results are:
Size Limit
1. Carbonate minerals have more slop of
Fig. 5: Flow diagram of degree of liberation
crushing and degree of liberation.
minerals in Malhamdar index 2. By screen size of (0.5–1) inch, CaO minerals
can remove in first stage.
By attention of Fig. 5, Iron oxide minerals in 3. Talc mineral has more degree of liberation at
coarse particle and carbonate minerals (calcite compare by chlorite.
and dolomite) in fine particle have large degree of 4. Iron oxide minerals are fine crystal and
liberation. In size limit D2 (120 Mesh) they have dispersed on the covering of other minerals
great of 80% liberation. To attend of slop and they have uniform of slop in degree of
liberation talc and chlorite, talc has a larger liberation.
amount and slop than chlorite. 5. Large size of sample feed is almost 50 cm
There are many Hematite and Goethite and D80 is 10.5 cm. nearly 60% weight is size
minerals to cover the over minerals and dispersed limit (1 mm –10.2 cm) and under 10%
all off them. All of minerals in great of 400 mesh weight is less than 2 mm.
have large than 90% liberation. By this result, iron 6. By attention of these results, it seems that
oxide mineral must be crushed under size of 400 continues of exploration and complete of
mesh, until we can separated them in other mineral. them and mineral processing of Malmamdar
talc is justify.
3. APPLICATION OF MINERALOGY IN
FLOWSHEET DESIGN OF TALC REFERENCE

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processing design is investigation and study of ore approach, Alden press, 1987
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mineral process engineer must be accurate in liberation zinc and iron oxide minerals in
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case study, only knowledge of grade is not Iran, 2004.
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component of minerals or metals in part of Uses-A Handbook and Formulary, Ed: P.A.
concentrate and tailing process. By microscopy Cuillo, Noyes Publications, New Jersey, 1996.
study on thin or polished sections we will have [4] Industrial minerals and rocks, 1994.
Preliminary Design Concentration of Talc by Emphasis on Mineralogy… 131
[5] Shena, G. and Chiaruttini, C., a stereological [6] Hajati, A., Khodadadi, A., Koleini, S.M., The
posed mass balance for calculating the distributed Study of degree of liberation of Zinc and Iron
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