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CCEAMODULE2 CCEAMODULE2
2.6.11 2.6.11
IodoformReaction IodoformReaction
Thereactionoccursonlywithalcohols
containingthegroup. CH CH(R)OH CH(R)OH 3 Worksforallsecondaryalcoholsand Worksforallsecondaryalcoholsand ethanol. ethanol. Orcarbonylcompoundscontainingthe Orcarbonylcompoundscontainingthe CH CO CO group group 2
appropriateamountofalcohol. appropriateamountofalcohol. Followed Followedbysodiumhydroxide bysodiumhydroxidesolutionand bysodiumhydroxide solutionand sodiumhypochloritesolution. sodium hypochloritesolution. hypochloritesolution.
AlcoholswiththegroupCH CH(R)OH 3
Carbonylcompoundswiththegroup
CH CH CO(e.g.propanoneCH COCH 2 3 3 usedin thepracticalinthevideo)willalsoforma yellowprecipitatewithanantisepticsmellof tri tri iodomethaneCHI iodomethaneCHI . 3 Theprecipitateisfilteredundersuction. Theprecipitateisfilteredundersuction.
SuctionFiltration
Setupthefilterpump(forsuctionfiltration)andcollecttheyellowcrystals. Setupthefilterpump(forsuctionfiltration)andcollecttheyellowcrystals.
NB:thatsuctionfiltrationisusedbecauseitisquicker thatsuctionfiltrationisusedbecauseitisquicker
SuctionFiltration SuctionFiltration
Dissolve the crude product in a minimum amount of hot solvent to form a hot saturatedsolution saturated solution. . Let the hot saturated solution cool slowly slowly. . Crystalswill Crystals willform form. . Filter off the crystals using suction filtrationin filtration ina aBuchner Buchner funnel. Buchnerfunnel Buchner .
Dryinginadessicator Dryinginadessicator
Allowthecrystalstodryinadessicator Allowthecrystalstodryinadessicator
Recordingthemass Recordingthemass
RecordthemassofthecollectedIodoform
Lossduringtransfer Lossduringfiltrationand recrystallisation recrystallisation Theoretical Theoretical Sidereactions Reactionmaynotgoto completion. completion.
TestingPurity TestingPurity
The melting point of a solid is a good
guide to its purity and may be used for identifyingthe identifying thesolid solid. . Usually a pure substance substance will melt over a a o range of 1 C i. .e e. . it has a sharp melting point. point . Pure Iodoform has a sharp melting melting o pointat point at119 119 C. C .
TakingMeltingPoint TakingMeltingPoint
Ameltingpoint Amelting pointtube tubeis is sealedat issealed is atone oneend end. . The substance is crushed with the sealed endof end ofa amelting melting point pointtube point tubeon ona afilter filterpaper paper orwith or witha apestle pestlein ina aclean clean mortar. cleanmortar clean . The crushed solid is placed to a depth of about2 about 2cm cmin ina amelting meltingpoint melting pointtube tubeclosed closedat at oneend one end. .
The tubeis Thetube isthen thenplaced placedin placed inthe themelting meltingpoint point apparatusand apparatus andheated heated. heated. heated The temperature is recorded when the crystalscollapse crystals collapseto toa a a clear clearliquid liquid. . A pure solid gives gives a a SHARP MELTING POINT. POINT . Impurities Impuritieslower lowerthe themelting the meltingpoint point. .
Testingthemeltingpoint Testingthemeltingpoint