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SPM TRIAL EXAMINATION 2013 MARA JUNIOR SCIENCE COLLEGE

CHEMISTRY Paper 2 MARKING SCHEME

FOR EXAMINERS USE ONLY

The marking scheme consists of 18 printed pages

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2 MARKING GUIDELINES SPM TRIAL EXAMINATION 2013 PAPER 2

Symbol // () [] ___ or bold a.d.p wcr a. r. e.c.f / -

Meaning replace the whole sentence replace the previous word can be summarized from explanation key word avoid double penalty wrong cancel right accept reject error carry forward or

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3 Sub mark 1 1 1

No 1 (a) (i)

Mark Scheme Type : Flavouring agent Function :To improve the taste/aroma of food (ii) Reduce the effect of insect bites/headache/nausea/windy condition/stomach discomfort/pain of toothache/sprains //antibacterial/antifungus (a: any suitable answer)

Total

(b)

(i) Contact Process (ii) 1. Sulphur 2. Oxygen (iii) Name : Ammonium Sulphate ( r. Formula : (NH4)2SO4 ) (iv) Detergent does not form scum/insoluble salt / precipitate (v) Sulphur dioxide react with rain water to produce acid rain / can cause respiratory problems

1 1 1 1

1 1 6

TOTAL

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No 2 (a) Gas

Mark Scheme

Sub mark 1

Total 1

(b)

Aluminium // Al

(c)

(i) 2.8.8 / 2,8,8 (ii) Atom has 8 valence electrons // atom achieved octet electron arrangement (r : stable electron arrangement)

(d)

(i) 1. Attraction / Van der Waals force between molecules / intermolecular forces of carbon dioxide is weak 2. Less heat needed to overcome the forces ( r : particles ) (ii) C + O2 CO2 (iii) 1. Correct electron arrangement of C and O 2. Label nucleus and correct number of shared electrons

1 1

1 1 1

O Y

O Y

TOTAL

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No 3 (a)

Mark Scheme (i) To allow the movement / flow of ions (ii) Magnesium // Mg (iii) Magnesium is more electropositive than copper // Position of magnesium is higher than copper in the Electrochemical Series // Magnesium atom donates electrons // Magnesium oxidized // Oxidation number of magnesium increases from 0 to +2 ( r : more reactive / ECS ) (iv) Reduction

Sub mark 1 1 1

Total

(b)

Silver plate

Iron ring

(i) 1. Correct position of iron ring and silver plate 2. Label (iron ring and silver plate) * P2 dependent on P1 (ii) Grey solid deposited on the iron ring // silver plate becomes thinner : Ag+ + e Ag

1 1

(iii) Iron ring

1 1 1 6

(iv) 1. Remain unchanged 2. The rate of discharge of Ag+ at cathode is same as the rate of ionisation of Ag atom at anode // the number of Ag+ discharge /reduce at cathode is same with the number of Ag+ formed at anode // each Ag+ discharged at cathode is replaced by one Ag+ ion produced at anode TOTAL

10

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No 4 (a)

Mark Scheme (i) Change in quantity of reactant / product per unit time // Change in quantity of reactant/product Time taken (ii) Size / Total surface area of zinc

Sub mark 1

Total

(b) Zn + 2H+ Zn2+ + H2 1. Correct formulae of reactants and product 2. Balanced equation (c) (i)
III II I

1 1

1 1

(ii) 50 cm3 / 60s = 0.833cm3 s-1 // 50 cm3/ 1 min = 50 cm3 min-1 (d) The presence of catalyst/copper(II) sulphate solution in Experiment III lowers the activation energy More colliding particles able to achieve the low activation energy Frequency of effective collision between H+ ions and zinc atoms is higher (r: increases) TOTAL

1 1 3

10

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No 5 (a)

Mark Scheme Heat released when 1 mol of water is produced from neutralisation of acid and alkali. (i) Average initial temperature = 28.0 + 29.0 = 28.5 oC 2 Heat released = (50 + 50) 4.2 (41.5 28.5) = 100 4.2 13.0 = 5460 J (ii) mole of HCl = 2.0 50 1000 = 0.1 mol

Sub mark 1 1

Total 1

(b)

1 1

(iii) 1. 0.1 mol of water / H2O release 5.46 kJ heat 2. 1 mol of water / H2O release 5.460 = 54.6 kJ 0.1 -1 3. H = - 54.6 kJ mol *(ecf for point 1 only) (c) Energy HCl + KOH H = - 54.6 kJ mol-1 KCl + H2O 1. Energy axis and two energy level is drawn correctly 2. Correct chemical formula of reactant and product , H (d) 1. Ammonia is a weak alkali / dissociate partially in water 2. some heat is absorbed to dissociate ammonia molecules completely

1 1 1 6

1 1 1 1

(e)

Plastic cup // paper cup // ceramic /porcelain cup //

TOTAL

12 Max 11

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No 6 (a) (i) Hydrogen ion

Mark Scheme

Sub Total mark 1 1 1

(ii) 1. Without/Absence of water , 2. hydrogen chloride exist as molecules //no hydrogen ions (b) (i) Acid L : ethanoic acid/[any organic acid] [a: formula] (ii) 1. Hydrochloric acid is strong acid / ionise completely in water 2. Concentration of hydrogen ions is higher *If : 1. Acid L is a weak acid / ionise partially in water 2. Concentration of hydrogen ions is lower (c) (i) CaCO3 + 2 HCl CaCl2 + CO2 + H2O - Correct formula of reactants and products - balanced equation (ii) 1. Mole of CaCO3 = 1 /100 = 0.01 mol 0+1

1 1

1 1 1 1
3

2. 1 mole of CaCO3 produce 1 mole of CO2 0.01 mol of CaCO3 produce 0.01 mole of CO2 3. Volume of CO2 = 0.01 x 24 = 0.24 dm / 240 cm
3

1 TOTAL

5 11

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9 MARKS SUB TOTAL

No

MARKING CRITERIA

7 (a)(i) Able to state the physical state of W at room condition correctly Answer Solid Able to give reason correctly Answer The room temperature is below the melting point. (ii) Able to sketch a graph of temperature against time for the heating 1. Both axes with units correctly 2. Correct shape of curve 3. Show the melting of substance W on your graph Answer Temperature (0 C)

1 1 1

1190C

Time ( min or s) ( r : sharp edge of the curve )

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10 (b)(i) Able to write the meaning of isotopes correctly Answer Isotopes are atoms of carbon with same number of protons / 6 protons but different number of neutrons / 6 or 8 neutrons. or Isotopes are atoms of carbon with same proton number but different nucleon number (ii) Able to state one usage for isotope of carbon-14 correctly. Answer To estimate the age of fossils / artefact // carbon dating (iii) Able to compare the number of subatomic particles are present in the atoms carbon-12 and carbon-14. Answer Carbon-12 6 6 6 Carbon-14 6 8 6 1 1 1 1 1 1

Number of proton Number of neutron Number of electron (c)

Able to write a balance chemical equation correctly Answer C + 2 CuO 2 Cu + CO2 1. Correct formula of reactant and product 2. Balanced equation Able to calculate the mass of copper correctly Answer 1. mole of CuO = 4 = 0.05 mol 64 + 16 1 1 1 2

2. 2 mol of CuO produce 2 mol of Cu 0.05 mol of CuO produce 0.05 mol of Cu 3. Mass of Cu = 0.05 x 64 = 3.2 g

1 1 3

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11 (d) Able to state the type of particles present in the solution when purple colour is observed correctly. Answer 1. Molecules / water molecules 2. Ions / manganate ions Able to explain the observation based on the kinetic theory of matter. Answer 1. water/ potassium manganate is made up of tiny/small and discrete particles and move randomly/freely 2. At higher temperature particles move faster/ higher speed /gain higher kinetic energy 3. particles/ions of potassium manganate diffused/ spread more at higher temperature into water 4. from higher concentration to lower concentration of potassium manganate Total 1 1 1 1 4 Max 3 20 1 1

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12 Sub Mark Total Mark

Question 8 (a)

Mark scheme Able to state the general formula, the functional group and the homologous series for these compounds correctly. Sample answer Compound General formula Functional group Homologous series S C n H 2n , n = 2,3,.. C=C or carbon double bond Alkene T C n H 2n+1 OH , n= 1,2,3.. -OH or hydroxyl group Alcohol

1+1

1+1 1+1 6

Notes (a: in a table // without a table) (b) Able to write the balanced chemical equation for the reaction correctly 1. Correct formula for reactants and products 2. Balanced equation Sample answer C4 H9 OH + 6 O2 4CO2 + 5H2 O Able to calculate the volume of carbon dioxide gas 3. Mole of C4H9OH 4. Mole of CO2 5. Volume of CO2 with correct unit Sample answer 3. Mol of C4H9OH = = 0.25 mol 4. 1 mol of C4H9OH produce 4 mol of CO2 0.25 mol of C4H9OH produce 1 mol CO2 gas 5. Volume of CO2 gas = 1 x 24 dm3 // 24 dm3
1

1 1

1 1 1

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13 Sub Mark Total Mark

Question (c)(i) Sample answer

Mark scheme Able to explain the difference in the observation Experiment I 1. Coagulation occurs Experiment II 2. No coagulation

1+1

3. Rubber molecules enclosed by a protein membrane which is negatively charged 4. Bacteria from the air Ammonia solution enter the latex and contains hydroxide ion // produced lactic acid/ acid OH5. The hydrogen ions, H+ OH- ion neutralized the neutralize the negatively acid produced by the charges on the protein bacteria membrane 6. The rubber particles Rubber particles remains collide with each other negatively charged and break the membrane, rubber molecules combined (c)(ii) Able to explain how the vulcanization of rubber improve the weakness of natural rubber Sample answer 1. 2. 3. Sulphur atom make a cross- linkages between rubber molecules reduce the rubber molecules from sliding Total

1 1

1 1 1

3 20

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14 Sub Mark Total mark

No 9 (a)(i)

Description Able to name the solution from the list that react with sodium hydroxide solution to form white precipitates and dissolve in excess of sodium hydroxide solution. Sample answer 1. Aluminium nitrate 2. Lead(II) nitrate 3. Zinc nitrate (ii) Able to name a white precipitates formed and write the ionic equation Sample answer 1. Aluminium hydroxide / Lead(II) hydroxide / zinc hydroxide Sample answer Al3+ + 3OH- Al(OH)3 or Pb2+ + 2OH- Pb(OH)2 or Zn2+ + 2OH- Zn(OH)2 (iii) Able to name any two of the solutions to prepare insoluble salt Sample answer Sodium carbonate + (any other solutions) // Lead(II) nitrate + magnesium sulphate // Calcium nitrate + magnesium sulphate *(a : name of solutions given in procedure) Able to describe how the salt is prepared in the laboratory correctly. (For any of the pair of solutions mentioned above) Sample answer Procedure: 1. (20-100) cm3 of (0.1- 2.0) mol dm-3 sodium carbonate solution is poured into the beaker 2. (20-100) cm3 of (0.1- 2.0) mol dm-3 lead(II) nitrate solution is added . * [adp for concentration and volume if didnt mention in P1 and P2 but word into a beaker must present] 3. [Stir the mixture] 4. Filter

1 1 1

1 1

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15 5. Wash/rinse the residue/solid/PbCO3 / salt/ precipitate Able to write a balanced chemical equation correctly: Sample answer Na2CO3 + Pb(NO3)2 PbCO3 + 2NaNO3 1 1

1. Correct formula of reactants and products 2. Balanced equation (b) Able to describe chemical tests to verify the presence of zinc ion , chloride ion and sulphate ion. Sample answer *Test for zinc ion: 1. Add a small amount / drop by drop ammonia solution until excess into solution 2. White precipitate is formed and dissolve in excess 3. *Zn2+ ion present (*P.3 : can infer from title of the test) Test for anion ion: **4. Pour the two solution into two different test tubes. 5. Add nitric acid followed by silver nitrate solution into each test tube. 6. The solution that produce white precipitate contains chloride ions **Pour the other solution into a test tube 7. Add hydrochloric acid followed by barium chloride solution 8. White precipitate formed confirmed that sulphate ion present . (** Both steps for P4) Total

1 1 1

1 1 1

1 1 8 Max 7 20

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16

Question 10 (a)(i)

Mark scheme Able to name halogen X correctly Sample answer Chlorine // Bromine [r: chemical formula]

Sub mark

Total mark

(ii)

Able to write the half equation correctly 1. Correct formula for reactants and products 2. Balanced equation Sample answer Half equation of reduction Br2 + 2e 2 Br // Cl2 +2e 2 Clor Half equation of oxidation 2 II2 + 2 e

1 1

(iii)

Able to describe a chemical test to verify iodine correctly Sample answer 1. 2. 3. Pour (1 5) cm3 / a few drops of the displaced halogen in a test tube Add a few drops of starch solution Dark blue colour is formed 1 1 1

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17

Question (b) Sample answer 1. 2.

Mark scheme Able to suggest metal M and metal N correctly Metal M : copper // silver Metal N : magnesium // aluminium // zinc

Sub mark

Total mark

1 1

Able to explain the observation of the experiment correctly Sample answer 3. M is less electropositive than iron 4. Iron rust / oxidize to form Fe // iron atom loses electron to form Fe2+ // Fe Fe2+ + 2e 5. Presence of Fe2+ ion produces blue spot 6. N is more electropositive than iron 7. N is oxidized // N atom lose electron to form N ion 8. Inhibits/Prevent iron from rusting (c) Able to draw the labell.ed diagram of rusting of iron correctly 1. correct diagram 2. correct label [cathode, anode, water droplet, iron] Answer 1 1
2+

1 1 1 1 1 1 8

Oxygen

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18

Question

Mark scheme Able to explain how the rusting of iron occurred correctly 3. Iron atom lose electron /oxidized to form iron(II) ion // Fe Fe2+ + 2e

Sub mark

Total mark

4. Oxygen #and/ in water# gains electron / reduction to form hydroxide ion, OH- // O2 + 2 H2O + 4e 4 OH5. Iron(II) ion, Fe2+ and hydroxide ion, OH- combined to form Iron(II) hydroxide // Fe2+ + 2 OH- Fe(OH)2 6. Iron(II) hydroxide is oxidized to form hydrated Iron(III) oxide as a rust. Total

6 20

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