Beruflich Dokumente
Kultur Dokumente
C. J. MacFarlane
University of Strathclyde, Marine Technology Centre, 100 Montrose Street, Glasgow, G40LZ, UK
A personal viewpoint is presented of the problems and unknowns relating to the materials aspects of flexible riser pipes, and possible solutions/indications for future research given. Through a brief description of the functions, materials and construction of flexible risers, the pipe terminations are highlighted as the major problem. A discussion of safety, testing and inspection reveals the major unknowns to be the performance of polymeric materials under extreme service conditions, the effects of long-term erosion/corrosion and the performance of pipes under compression. Three types of termination are then considered in detail.
To differentiate between studies which are specific to flexible risers and those with more general interest, it is Eng. Struct. 1 989, Vol. 1 1, October 281
Contractor
Operator
Goal
Resources
Personnel Objectives
High grade (?) Standard grade Highest grade limited numbers Balance between interference &
risk
Project profit
Notes (1) The regulatory body will review the widest range of possible designs and the contractor will see the ideas of a number of operators, but the operator can be trapped by his own experience and existing equipment. (2) But regulatory authorities have the biggest resource of all - the potential to coordinate information, write and (perhaps) enforce rules. (3) Present economic circumstances and the resulting attitudes/ postures have, however, the effect of reducing the resources available to the contractor.
In future we shall no doubt see the introduction of aramids (such as Du Pont's Kevlar) and other advanced polymers where the properties are obtained both by the incorporation of additives and also by treatments other than heat irradiation, for example. Drawings of the different forms of construction of such pipes are not given here - these may be found in almost every other paper on the subject (see, for example, References 2 and 3) - and, indeed, the drawings show a marked family lineage? It is considered sufficient to note the wide disparity in performance of the various materials under mechanical strain, thermal loads, chemical attack and the long-term effects of loads (creep or relaxation). Table 2 provides values for the generic materials used rather than for the specifics of any construction. In part this is because not all information on materials is freely available, but also because it is not necessary to provide precision in a rapidly changing field to make the main point on the disparity between materials.
useful to define the functions of a flexible riser: to transport hot, corrosive, high-pressure mixtures of hydrocarbon liquids/gases, water and solids for a significant period of time (hopefully in tens of years) under varying internal, external and end-applied load actions; to join up at the ends. Now, .although it may be a difficult task to design and construct a flexible pipe to carry certain fluids in certain conditions, it is implicit in the pipe's use that the problems are seen to be solved. It is less easy to envisage complete solution of the second function as it contains within it a basic dichotomy: that of maintaining continuity of the first function while, at the same time, disrupting that continuity. Although flexible pipes have been widely used, there is, I would suggest, wide recognition that the termination is a basic weak spot. This is considered in more detail below.
Materials and construction
Nylon
Rubber
It is also worthwhile considering at this stage the range of materials which are used in one or other of the types of manufacture: polyamides (nylons) fluorinated polymers cold-formed steel strip resins (terminations) weld metal (stainless steel) reinforced rubbers stainless steel strip and wires rayon/polymer composites steel forgings (terminations)
Elasticity, E (G Pa) Shear modulus, G (GPa) Poisson's ratio Ultimate tensile stress (MPa) Thermal expansion coefficient (10 6/'C) /
~17
~90
~150
*Source mainly Gere, J. M. and Timoshenko, S. P. Mechanics of Materials, 2nd Edn., Van Nostrand Reinhdd (UK) Ltd, Appendix H Tensile and shear moduli are simplified values and are for temperatures around 50"C
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Following my suggestion that all the hose forms used are generically linked in use of materials and form of construction, and since they all carry hydrocarbons of some form at pressure and at various temperatures, one would expect a unified regulatory approach. Perhaps this will come, but it does not exist. In all probability it will not be brought about because of clear vision or coherent thought; rather it will be the usual pressure following a failure and a fatality. There seems to be too much compartmentation of regulations by discipline (drilling, production, marine, etc.) and too little attention to the underlying product and technology. This is difficult to address because it confronts human nature, but at least it should be recognized and regular efforts (audits) made to highlight areas of mismatch.
Testing
Given, therefore, that flexible pipe failure causes (or should cause) damage only to the operations budget
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Basic forms of test Purpose To obtain constitutive relationships so that the component performance can be predicted To confirm the quality of the materials used in manufacture To measure absolute load capacities To identify modes of failure N o t to obtain residual capacity To quantify dimensions and flaw sizes and to confirm tolerances To obtain values of service life under component and combined loads To identify modes of failure under service loads To obtain properties of completed components such as stiffnesses, elongations, fire resistance, etc.
Proof
NDE
Endurance
Characterization
Table 4
Applications of different forms of test Tests applied Materials; proof; endurance; characterization Proof; endurance; character Limited proof test; N DE Materials; proof; NDE; endurance ? Purpose To decide where to use and utility To define a product range To confirm acceptance To identify and define flaws related to failure To identify residual utility or cause of failure
Purpose Prototype
Inspection
The alternative to blanket change-outs or to prediction of endurance is inspection and, since life should not be at risk and the environmental damage potential should be limited, I would suggest that the basis of service inspection of flexible risers can be less rigorous than might be the case for other structural elements. This is not true for manufacturing inspection and this distinction must be clearly made. Service inspection Let us consider first inspection of the pipe incorporated in a system. I suggest that gross failure of these pipes will be signalled well in advance by deformation of the metal components and that inspection should concentrate on this. I would justify this by pointing out that polymer (fatigue) ageing should result only in progressive leakage which could be detected by regular, external n O V sensor scans or, if the leak were sufficiently large, by pressure variations in the riser. A good IFP/Coflexip pape r2
Installation I nspection
Replacement
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Manufacturing inspection
The second area where inspection is important is of course during manufacture, but this is a large subject in itself which I wish to cover only briefly. The most important point to make is that output quality depends as much on testing of incoming raw materials as on control of processes and final measurement of the product, and yet I understand it is unusual for a pipe buyer to put much effort into this aspect. I would consider it critical to obtain and keep records of raw materials and of sampling of the processed materials who knows, it might be useful in post-failure analysis. ! would also suggest it to be good value to have a knowledgable presence at the manufacturing site, certainly when the termination is formed. Particular attention must be paid to the termination, as here a discontinuity is being built into the system (see below). Difficulties arise because of the thickness and mass of metal and the relative transparency of the polymers to conventional NDE (ultrasonic or X-ray). Much, however, can be made of three-dimensional imaging, using ultra-sound or X-rays as a means of maximizing return of information and obtaining both the internal dimensions of the various materials and any gaps within the polymers.
Terminations
In all this discussion of robustness and simplicity of inspection, I wish to exempt the terminations of the pipes. It is unfortunate that all pipes have to end somewhere! In conversation with a retired senior engineer from BICC, a company that claims to have first engineered strengthened hoses in the 1960s but did not develop them as a product, it was clear that one of the reasons for not proceeding was the ability to make a good terminat i o n - o r rather the lack of that ability. (As an aside, a paper by Atochem 4, the makers of Coflexip's raw materials, suggests that IFP foresaw the use of flexibles in or around 1958 and instituted a development programme from that date. This appears to differ from the BICC position, but since IFP and Coflexip have persevered and survived, then perhaps it is correct that their view persists.)
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Cap
Epoxyresin
Flexible pipe./]
.~[
//
Flexible pipe
b
Cm Steel wire Ic
Pipe elastomer 'shaded'
into ebonite
Ebonite fill
/
:el
C
Figure 2
produce both internal and external resistance to flow. The inner (front) seal which holds the product is in effect axial and, if passed, there is no further resistance to flow radially through the termination unless the 'outer' surface of the crimp ring is designed as a further seal; this is not clear. The manufacturing process would appear to be: (1) to strip the pipe to expose sequential layers, fitting the spiral locking ring; (2) to make up the first crimping flange; (3)
to prepare the tensile armours around the termination body; (4) to slide up the cap and, presumably, connect it to the vault; (5) to inject and set the resin; and (6) to make up the final crimping flange. It may be that these last two are reversed, but I know of no published information on the construction of these terminations beyond the brief functional description of Reference 3. Difficulties with this form of termination arise from the
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load-carrying steel wires, one would expect any fatiguelike effects to show just outside the termination proper. The seal area presents a problem similar to Coflexip in that it is axial only and it also has less constraint on it in the axial direction (applied by Coflexip through their driven-up flanges). It may be, however, that the shaped surfaces of the sealing face are sufficient to provide this restraint. Thermal expansion differentials are probably of similar magnitude, but because of the bonding of the pipe could show up as shear tears between layers as well as differential movement on sealing surfaces. Intrusion of water to the strand crimping area is possible, as with Coflexip, but I judge it to be less damaging as any minor corrosion will not reduce the hold on the strands.
Pag- 0 - Flex 'ebon ite ' fi t t ing
Dunlop offer as their main form of termination the 'crimped' fitting shown in Figure 2b. They have a resin-bonded fitting, but I understand that this, although providing a good termination when successfully made, suffers from the exothermic setting reaction of the resin affecting the Duralon anti-permeation layer. The crimped fitting is formed by plastically yielding an external steel sleeve over the sequentially stripped pipe materials and against a steel insert of higher yield than the external sleeve. The steel wires which take axial load are held in a different pocket from the polymeric materials, which are made up against a 'wavy' surface to enhance the seal pressure at the crests and also, perhaps, to minimize creep of polymer along the face. Here the continuity of load capability is obtained by a mixture of friction and clamping with no bonding process and the seal is similar to Coflexip in that the polymer is restrained between metal faces, but a wider sandwich of polymer is enclosed. A special flexible insert closes off the interlocked inner steel liner and bonds it to the main 'forming' insert piece. In theory there is potential to make such a termination in service as the technique is robustly mechanical and forgiving of small alignment errors. There might also be potential to remake the fitting by a further crimp process--rather like a giant 'jubilee' clip. This cannot be carried too far, however, because the external plastically-yielded material will harden after each yielding and the ability to make a seal depends on the differential between the yields of the inner and outer steel sleeves. Again, because of the rigidity of the hold on the
The Pag-O-Flex pipe is rather different from the first two as it has an impermeable corrugated metal liner (of ostensibly any ductile material, but generally of AISI 316 stainless steel). This eases the problem of sealing as this can be welded to the termination 'nipple', but some difficulties remain. From Figure 2c we see that the key to the treatment of the polymers and the steel loadcarrying members is the gradual tailing off of the soft (polychloroprene rubber, CR ?) elastomer into a hard ebonite material. This, when vulcanized with the pipe, shrinks and hardens so that it grips both the strength wires and also the serrated face of the termination nipple. In principle, the hardness of the ebonite is such as to limit differential strain movement between materials. It is not clear, however, what effect high thermal loads might have and, specifically, whether relative displacement of the metals and the polymers might increase the stress in the critical sealing weld between the inner corrugated liner and the nipple. This pipe and the ebonite termination depend very much on the integrity of welds in the stainless steel--both a longitudinal seam weld in the corrugated liner and the radial welds between sections and between pipe and termination. I have yet to see an adequate functional description of a termination design which systematically addresses these problem areas and notes conflicts and resolutions. Considering only the Coflexip and Dunlop terminations, in principle I feel there should be more effort made to produce additional seals to trap any passage of product through the primary axial seals. To counter the problem of differential expansion, one could either use a semiactive rubber seal (held tight by a spring as in valve design) or make use of varying polymer material properties to ensure there is no reduction in seal pressure. Without a doubt a polymer-to-metal seal is to be preferred to polymer-to-polymer and there might therefore be room for inclusion of metal formers, but this argues for a redesign of the termination and would undoubtably cause manufacturing problems. I understand that there is research effort into seal design by at least one of the major manufacturers, and I look forward to a rational discussion of their final products. Finally, the sensitivity of terminations to variations in design loads should be highlighted. It seems eminently possible that it is not static loads which are damaging, nor even cyclic mechanical loads, but that transient pressure effects and thermal cycles will have most impact. Eng. Struct. 1989, Vol. 11, October 287
Materials
Discussion of thermal and mechanical strain leads naturally to consideration of the performance of the various non-metal materials--on the assumption that the behaviour of the metals is reasonably well understood! The fluid environment is basically aggressive: we are concerned with hydrocarbon mixes combined with water, contaminant gases (HzS or COz), perhaps corrosive chemicals and abrasive materials at high flow rates, and high temperatures and/or pressures. The flow rates themselves may not be constant and the phase behaviour of the hydrocarbons may, therefore, be complex. In this paper the aspects of abrasion, variable flow rates and fluid phase behaviour cannot be discussed--this does not mean they are not real problems, rather that they are complex and field-dependent, and worthy of papers in themselves. Briefly, let us consider the materials used by various manufacturers. Coflexip generally use nylon (polyamide 112.4) and are now moving towards fluorinated polymers for higher temperature service. Dunlop state they use a modified polyolefin elastomer 5, which I understand to be a chlorinated polyethylene rubber (CPE) and which allows higher temperature use than the basic polyolefins. I have found no published details of the main polymer used by Pag-O-Flex, but suspect it to be a polychloroprene rubber (CR). The form of polymer used by Pag-OFlex is not, however, relevant to this discussion as it will always be protected (in theory at least) from the fluid environment by the impermeable stainless steel liner used in that pipe: the critical material problem for that pipe must be corrosion fatigue in the crevices and on the weld of the corrugated stainless steel. Selecting a range of papers 2-6, one gets a flavour of some disagreement on the performance of the various contender materials. For example, Coflexip/IFP/Atochem write-off the polyolefins claiming they either lack performance at higher temperatures (above 60C, Reference 4) or because they exhibit too much swelling when in contact with hydrocarbons z. Dunlop would, no doubt, counter these comments by noting that they have modified their basic polymer for higher temperature service so that it is stable up to 130C and that they make a virtue of the swelling of their material by constraining it and thus increasing the osmotic permeation resistance 5 as well as, perhaps, increasing the resistance to explosive decompression 7. Dunlop themselves have criticized nylons--and implicitly, therefore, Coflexip--because of their lower temperature capability and the increased
Neglecting these attempts at market assassination by the various manufacturers, there is still some confusion about the performance of the materials. A degree of commercial sensitivity must, of course, be allowed, but it seems to me that none of the materials used can meet all possible fluid flow environments, which is not unexpected. More alarming, perhaps, it is not clear to me that any material presently used can completely meet even the range of fluid environments which are likely from a single, typical, deepish well over its life. There must, therefore, be some system of checking future performance whenever there is a significant (slow or discrete) change in fluid makeup, additives, temperature or pressure. Thus, most polymers used for resistance to hot hydrocarbons will degrade when exposed to steam, and more so if the water is in any way corrosive or contains inhibitors. There appear to be basic trade-offs between resistance to hot hydrocarbons, mechanical performance, permeability, sensitivity to hydrolysis and to well additives which, because it is not adequately explained by the manufacturers, could produce potentially dangerous situations arising from (perhaps unintentional) misuse of the products. What does happen inside a pipe as a pressure transient passes through? Will the 'bonded' pipe remain bonded everywhere? Will the unbonded portion remain undeformed and what reduction has been irretrievably made in ultimate capacity? It seems to me that increased effort in the design of polymers is the route to take- if only to define present limits on use--and that the fluorinated polymers are the prime contenders for higher temperature service. But the question must be asked, which fluoroelastomer? A pertinent discussion can be found in Reference 8. As these new ingredients are added to the pipes, the customer runs the risk of stepping even further into the dark as far as material performance is concerned. The pressure on the manufacturer is, first, to provide a product to meet a market and, second, to utilize uncomplicated manufacturing processes. Simple manufacture must also be seen as a benefit to the user and regulator, as it minimizes construction errors and variance, but the urge to get a product onto an eager market is a destructive one and any user must be aware of and accept their share (with the supplier) of the risk. On a slightly different tack: if conventional pipes are suffering from enhanced erosion/corrosion, what will happen to the relatively thin stainless steel interlock or corrugated liners in common use? Pag-O-Flex might seem to be the most exposed on this, but the problem must also be addressed for long-term flowline service by all manufacturers as this form of degradation is proving greater than predicted for conventional, rigid-wall oil pipes.
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Compression
The final subject I wish to air is that of compression. Not hydrostatic pressure loading, nor the compressions experienced by the materials on the inner surfaces of a bend, but axial compressive loads on the pipe sufficient to cause lock-up leading to the pipe acting as if rigid over a certain length. This is a complex area. Even if the riser layout meets the criterion of minimum bend radius, it is possible in analysis to predict compressive loads of significant magnitude at the top end and near the mid-span arches. Flexible pipes are not designed for these and their performance must be seen as uncertain. How real are the predictions and what will happen internally? There appears to be two schools of thought: one that the prediction of overall compressive loads is a figment of the analytical tools and can be made to disappear by careful selection of analytical element spacing and solution intervals; the second that these loads are functions of configuration, can occur in practice and could have very severe effects. There is a need for testing of analysis techniques to identify where and when results are spurious, but I believe (and suggest there is some limited experience from small umbilical cables) that there is real potential for lock-up in service. With small umbilicals the effect is to cause 'birdcaging' of the helically wound, wire-reinforcing strands and ultimately loss of containment and strength. With a large diameter flexible pipe I can envisage something similar and suggest this is a mode of loading which needs urgent review both for cause and effect.
materials under extreme service conditions, the effects of long-term erosion/corrosion and the performance of pipes in compression. Users of these pipes have to take a wide view of the safety aspects, where the consequences of pipe and especially termination failure must not have fatal consequences, and a long view so that all the variations of well flow environment in time are predicted for initial design. I take a wide view of flexible pipes and class them generically with umbilicals and ropes/tethers. I believe that a generic numerical model (incorporating wherever possible analytical solutions) can be built now to define the mechanical (static and dynamic), and thermal and electrical performance of these ligaments and perhaps, later, to take into account chemical degradation. The future problem is to design complex multi-function pipes and cables from first principles and predict the performance before building the prototype.
References
1 MacFarlane, C. J. 'The performance of flexible risers', Dept. o/" Energy Rep. OTN 87-130 & OTN 87-130A (Appendices) 2 Dawns, F. A., Jarrin, J., Lefevre, T. O. and Pelisson, M. 'Improved thermoplastic materials for offshore flexible pipes', OTC 5231, 1986 3 Mallen, J., Estrier, P. and Amilhau, S. 'The quality and reliability of flexible steel pipes', Institute of Marine Engineers, 1989 4 Raveau, G. and Simon, J. P. 'Polyamide 11 for use in collecting pipes and submarine operating umbilicals', PRI Conf. on 'Polymers in Offshore Engng', Plastics & Rubber Institute, London, 1988 5 Griffiths, A. D. 'Elastomeric high pressure flexible pipes for high temperature applications', ibid. 6 Seregely, Z. I., Nagy, T. T. and Pfisztner, N. 'Ageing of elastomers under simulated offshore conditions', ibid. 7 Campion, R. P. 'Failure mechanisms in elastomers in high pressure oil and gas conditions', ibid. 8 Weston, R. J. 'A comparison of perfluoroelastomers and other elastomers tested in oilfield media', PRI Con/~ on Polymers in Offshore Eng, op. cir.
Summary
To summarize the problems and unknowns as I see them, I would state the biggest problem as having to end the pipe: without this, these are robust engineering devices. The unknowns (to me) are the performance of polymeric
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