Alkali Khaled PDF

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SilzR 07 Jun 2002
S:\Dept\A600All\Auftrag\Kujafa\Training_KUJAFA\Training onsite\3.1_Process_engineers\Trainingsunterlagen\05_Kiln_Preheater\Preheater.ppt
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The Alkali Bypass
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Alkali Bypass
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Alkali Bypass
1. Improofed plant reliability

- Reduction of Alkali concentration - Reduction of coating build ups - Reduction of production cost (Personal, cleaning work)
2. Improved clinker quality

- Reduction of alkali content of alkalis (z. B. Low - Alkali - Clinker) - Limititation of sulfur (cement quality) - Limitation of Chlor content
3. Possibility of waste material burning

- economical interesting secondary fuels and raw materials contents often high amount of harm components
Bypass - Wherefore ?
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Alkali Bypass
Clean gas emission
Separation Electro filter
Cooling Quenching chamber Conditioning tower
Dust collection
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Alkali Bypass
Bypass Mixed Gas
Bypass Mixing Chamber Quench Air Bypass Hot Gas Duct
Polysius: Actual Bypass Design
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Alkali Bypass
Velocity Distribution
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Alkali Bypass
Air blaster nozzles
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Alkali Bypass
They are chemical components of the raw materials with a low concentration towards the other components.
Although some have no impact on the chemical process, others might lead to major troubles.
In the cement industry, Cl, SO3, Na2O and K2O are, among others, particularly monitored
What are the minor elements ?
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Alkali Bypass
Grinding
Raw Meal
Heating up
Condensation
Temperature
Hot Meal
Raw Materials
Volatilization
Temperature
Clinkerization
Clinker
What happens in the system ?
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Alkali Bypass
Low volatilization temperature
Condensation on cooler particles
Extraction from material
Increase of local concentration
Flowing with gases
PROBLEMS
Problem with volatile elements
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Alkali Bypass
Volatilization temperature + Condensation temperature
2 cycles
Internal Cycle
External Cycle
What are some elements doing ?
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Alkali Bypass
Internal and External Cycles
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Alkali Bypass
Chloride Alkalis Sulfur
start evaporate around 650C start evaporate around 900C start evaporate around 1000C
Conclusion :
The various content of element is different according to the analyzed area (kiln feed, meal cyclone 2, hot meal, clinker,). Nevertheless, most of the highest concentrations are located at the kiln inlet, depending on the salt formation.
Different behaviors
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Alkali Bypass
Example of decision
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Alkali Bypass
1800 1600 Rugver 80
g Stb/Nm3 Byp.HG
1400 K1 1200 Sakufa K2 1
1000
800 600 Yamaver 400 200 0 0 Berfa 5 10 15 20 25 30 Texfa Suezver
ECFA 2 3
Bypassrate (%)
Dust loading of bypass gas
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Alkali Bypass
Bypassanlage
Bypassrate
%
K2O
% 2,8 17,0 10,4 2,3
Na2O
% 0,4 1,3 1,1 0,3
SO3
% 3,1 12,0 7,6 4,4
Chlor
% 0,6 9,0 4,5 0,1
1. Roanoke 2. Rdersdorf 3. Nordzement 4. Davenport
15 15 7 54
5. ECFA
6. Sakufa 7. Yamaver 8. Rugver 80
18
15 9 10
3,4
1,4 2,6 2,0
0,9
0,1 0,3 0,2
2,2
2,3 3,1 8,4
2,7
0,2 2,3 0,3
Analysis of Bypass-Dust
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Alkali Bypass
Decreases the concentration of minors in the kiln inlet by taking out a part of kiln gas Taking part of the heat Taking part of the production
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Alkali Bypass
The volume coming out of the kiln is composed by : 1. The volume of the gas combustion 2. The volume of the decarbonation 3. The volume of excess air - V Comb - V CO2 - V Ex
V V V V Ki ln Comb CO2 Ex
Calculation of V Kiln
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Alkali Bypass
Finally, knowing V Kiln and V BP
Bypass Ratio
VBypass VKi ln
Calculation of the bypass ratio
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Alkali Bypass Conclusion Minor elements are to be considered for operation decisions Chemistry is able to help for any investigation concerning the process troubles The volatilization and cycles of the elements can be handled through process operation A good knowledge of the element circulation is necessary for a good trouble shooting

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Page 1

SilzR 07 Jun 2002

SilzR 07 Jun 2002

The Alkali Bypass

SilzR 07 Jun 2002

SilzR 07 Jun 2002

1. Improofed plant reliability

2. Improved clinker quality

3. Possibility of waste material burning

SilzR 07 Jun 2002

Clean gas emission

Separation Electro filter

Cooling Quenching chamber Conditioning tower

SilzR 07 Jun 2002

Bypass Mixing Chamber Quench Air Bypass Hot Gas Duct

Polysius: Actual Bypass Design

SilzR 07 Jun 2002

SilzR 07 Jun 2002

Air blaster nozzles

SilzR 07 Jun 2002

What are the minor elements ?

SilzR 07 Jun 2002

What happens in the system ?

SilzR 07 Jun 2002

Low volatilization temperature

Condensation on cooler particles

Extraction from material

Increase of local concentration

Flowing with gases

Problem with volatile elements

SilzR 07 Jun 2002

Volatilization temperature + Condensation temperature

What are some elements doing ?

SilzR 07 Jun 2002

Internal and External Cycles

SilzR 07 Jun 2002

Chloride Alkalis Sulfur

SilzR 07 Jun 2002

SilzR 07 Jun 2002

1400 K1 1200 Sakufa K2 1

Dust loading of bypass gas

SilzR 07 Jun 2002

1. Roanoke 2. Rdersdorf 3. Nordzement 4. Davenport

SilzR 07 Jun 2002

SilzR 07 Jun 2002

SilzR 07 Jun 2002

Finally, knowing V Kiln and V BP

Calculation of the bypass ratio

SilzR 07 Jun 2002

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