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0268 mol 24,000 = 643 cm3 (1) moles HNO3 = 2 0.0268 = 0.0536 /0.054 mol (1) (i.e. answer to (i) 2) volume of HNO3 = 0.0536 1000/2.50 = 21.4 cm3 (1) 2
[5]
1.
(i)
2 1
2.
Molar mass of anhydrous calcium nitrate = 164.1 g mol 1 (1) Ratio Ca(NO3)2 : H2O = 69.50/164.1 : 30.50/18 or 0.4235 : 1.694 or 1 : 4 (1) Formula = Ca(NO3)24H2O (1)
[3]
3.
(i) (ii)
because Ca has changed from 0 to +2 (1) and H has changed from +1 to 0 (1) Calcium reacts with water producing hydrogen/H2/calcium/hydroxide/Ca(OH)2 (1) (i.e. one product) Ca(s) + H2O(l) Ca(OH)2(aq) + H2(g) (1) (i.e. full equation) Equation would subsume both two marks
2
[4]
4.
(a)
(atoms of) same element/same atomic number.. with different numbers of neutrons/different masses 1 3 percentage composition protons
85 87
Rb Rb
37 37
mark
Ar =
= 85.6
(c)
1
[7]
5.
(i) (ii)
Simplest (whole number) ratio of atoms/moles/elements ratio Rb : Ag : I = 7.42/85.5 : 37.48/108 : 55.10/127 or 0.0868 : 0.347 : 0.434 or 1 : 4 : 5 = RbAg4I5
2
[3]
6.
(a) (ii)
(i)
4 mol HCl 1 mol Cl2 / moles Cl2 = 0.15 mol vol of Cl2 = 0.15 24 = 3.60 dm3 2nd mark is consequential on molar ratio given 2
(b)
Evidence that the oxidation number of Mn has reduced and one of the oxidation numbers correct (ie MnO2: ox no of Mn = +4 or MnCl2: ox no of Mn = +2 The other oxidation number of Mn is correct, ie in MnO2: ox no of Mn = +4 or in MnCl2: ox no of Mn = +2 2
[5]
7.
(i) (ii)
mass = 0.0500 23.0 = 1.15 g moles H2 = 0.0250 volume H2 = 0.0250 24 = 0.600 dm3 ecf from calculated moles H2 0.0500 mol in 50.0 cm3
1
[4]
(iii)
8.
(i) (ii)
2Na + O2 Na2O2 Na2O2 + 2H2O H2O2 + 2NaOH correct covalent bonds shown electron count (14) for rest of molecule correct
1 1
(iii)
2
[4]
9.
(i) (ii)
1 2
[3]
10.
atoms of the same element with different numbers of neutrons/different masses (1)
79 81
1 2 1
[4]
(1s2)2s22p63s23p63d104s24p5 (1)