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Material Safety Data for: Adipic Acid

1.
Name Synonyms CAS# EuropeEC# ProductUses

PRODUCTINDENTIFICATION
1,6hexanedioicacid 1,4butanedicarboxylicacid,adipicacid 124049 2046733 manufactureofnylon,polyurethanefoam,coatings,adhesives,plasticizers,etc
% 100% TWAEV/TLV 3 mg/m 5 LD50 ORAL 1900 (mg/kg) SKIN >7940
3 LC50 mg/m INHALATION >77oo

2.INGREDIENTS
1,6hexanedioicacid

3.(a)

HAZARDSSUMMARY

Hazards,QuickGuide: irritatingtoeyes,mayformexplosivedust/airmixture CanadaWHMIS


Key:

D2B
o o o B2FlashPoint<38 C,B3FlashPoint>38 C&<93 C D1ImmediatelyToxic,D2ChronicToxicity COxidisingSubstance,ECorrosive

U.S.A.HMIS
Key:

Health1,Fire1,Reactivity0
0=minimal,1=slight,2=moderate,3=serious,4=severe

3.(b)
SkinContact SkinAbsorption EyeContact Inhalation Ingestion

HAZARDSTOXICITY
dryproductisexpectedtohavenoeffect,solutionsmaybemildlyirritating probablynilnotoxiceffectslikelybythisroute dustisamechanicalirritantsomeanimalevidenceofchemicalirritancy 3 dustabove20mg/m reportedtobe irritatingasisthe vapourofstronglyheatedproduct volunteersingested100mg/kg/dayfor8dayswithouteffectnotarouteofindustrial exposure prolongedexposuremaycausedermatitistheinhalationofveryhighdustconcentration provedmildly toxictoratsandingesting3%5%adipicacidreducedgrowthinratsnot relevanttoindustrialexposure notasensitiserinhumansoranimalsoneinstanceofskinsensitisationandtwoof sensitisationsuggestthatthisisaveryrareoccurrence notconsideredatumorigenoracarcinogeninhumansoranimals noknowneffectinhumansoranimals noknowneffectonhumansoranimals notknown 5560mg/kg(rat),11,000mg/kg(rat&rabbit)1900&4200mg/kg(mouse) >7940mg/kg(rabbit) 3 >7700mg/m (rat)

Effects,AcuteExposure

Effects,ChronicExposure

General

Sensitising respiratory Carcinogen/Tumorigen ReproductiveEffect Mutagen SynergisticWith LD50 (oral) LD50 (skin) LC50 (inhalation)

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(AdipicAcid,contd) 4.
SKIN: EYES:

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FIRSTAID

Washwithplentyofwater.Removecontaminatedclothinganddonotreuseuntilthoroughlylaundered. Washeyeswithplentyofwater,holdingeyelidsopen.Seekmedicalassistancepromptlyifthereis irritation. INHALATION: Removefromcontaminatedareapromptly.CAUTION:Rescuermustnotendangerhimself!Ifbreathing stops,administerartificialrespirationandseekmedicalaidpromptly. INGESTION: Giveplentyofwatertodiluteproduct.Donotinducevomiting(NOTEbelow).Keepvictimquiet.Ifvomiting occurs,lowervictimsheadbelowhipstopreventinhalationofvomitedmaterial.Seekmedicalhelppromptly.


Inadvertentinhalation ofvomitedmaterialmayseriouslydamagethelungs.Thedangerofthisisgreaterthantheriskofpoisoningthroughabsorptionofthis relativelylowtoxicitysubstance.Thestomachshouldonlybeemptiedundermedicalsupervision,andaftertheinstallationofanairwaytoprotectthelungs.

5.

PHYSICALPROPERTIES
odourless,whitecrystallinesolidwithsouracidictaste notknownodourless o o 0.073mmHg/0.0097kPa(18.5 C/65 F) nilnotvolatile 5 o o o o 337 C/640 F(101kPa)OR265 C/509 F(100mmHg/13.3kPa) o o decompositiontovalericacid&othersubstancesbeginsabove330 C/626 F o o 152 C/306 F o 1.34kg/litre(20 C) o o 14gramsperlitre(18 C/64 F) verysolubleinethanol&methanolslightlysolubleinacetone&ethylacetate o o 4.54centipoise(160 C/320 Fmoltenmaterial) 2.7(saturatedsolution),3.2(0.1%solution) 3 1ppm=5.96mg/m 146gramspermole

Odour&Appearance OdourThreshold VapourPressure EvaporationRate(ButylAcetate=1) VapourDensity(air=1) BoilingRange MeltingPoint Density WaterSolubility Alsosolublein Viscosity pH ConversionFactor MolecularWeight

6.

FLAMMABILITY&FIREFIGHTING
o o 196 C/385 F(closedcup) o o 420 C/788 F 3 notknowndustignitesatconcentrationsabove35g/m carbonmonoxide,nitrogenoxides,smoke,irritatingfumes&cyclopentane waterfogorwatersprayarepreferredfire fightersmustwearSCBA dustmayaccumulateastaticcharge

FlashPoint AutoignitionTemperature FlammableLimits CombustionProducts Fire FightingPrecautions StaticChargeAccumulation

7.

STABILITY/REACTIVITY
strongoxidisingagentsstrongalkaliesorreducingagents slightlycorrosiveto manybasemetalsstainlesssteelswithCr,Mo,&Niare resistant o o stableupto330 C/626 Fmaypolymeriseviolentlyinpresenceofalcohols,glycols, aldehydes,epoxidesorpolymerisablecompounds o heatabove330 C apartfromHazardousCombustionProducts,thermaldecompositionyieldscyclopentane no

DangerouslyReactiveWith AlsoReactiveWith Stability DecomposesinPresenceof DecompositionProducts SensitivetoMechanicalImpact

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(AdipicAcid,contd) 8.
ACGIH TLV OSHAPEL STEL Ventilation Hands Eyes Clothing

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PROTECTIVEEQUIPMENT/EXPOSURECONTROL
3 30ppm/5mg/m notlisted notlisted mechanicalventilationmayberequiredtomaintainairbornetitrebelowregulatedlimits nospecialprotectiveglovesrequired safetyglasseswithsideshieldsalwaysprotecttheeyes nospecialprotectiveclothingrequired

9.

HANDLING&STORAGE

Storeinacool,dryenvironment,awayfromopenflame,oxidisingagentsandsubstancesnamedinPart7(above). Productdustmayaccumulateastaticchargeontransferfromonecontainertoanother,andignitionofthisdustis possible.Groundalltransferequipmentandcontroldustwithlocalmechanicalventilation.Avoidbreathingproductdust.Use withadequateventilation.Keeptransferequipmentcleananddustfreetominimiseignitionhazard. Nevercut,drill,weldorgrindonornearthiscontainer.Avoidprolongedcontactwithskinandwashworkclothes frequently.Aneyebathandsafetyshowershouldbeavailableneartheworkplace.

10.

SPILLPROCEDURES

LeakPrecaution notrequiredsolidsubstance HandlingSpill ventilatecontaminatedareasweep,shovel,&storeinclosedcontainersforrecyclingordisposal

11.
WasteDisposal Containers

DISPOSAL
donotflushtosewer,iflocalregulationspermit,maybeputinsanitarylandfill,maybeincineratedin approvedfacilityaftermixingwithaflammablewastesolvent Drumsshouldbereused.Reconditionandpressuretestbyalicensedreconditionerpriortoreuse. Pailsmustbeventedandthoroughlydriedpriortocrushingandrecycling. IBCs(intermediatebulkcontainers):polyethylenebottlemustbepressure tested&recertifiedat30months. Replaceat60months(5yrs).Steelcontainersmustbeinspected,pressuretested&recertifiedevery5years. Nevercut,drill,weldorgrindonornearthiscontainer,evenifempty

12.
Bioaccumulation Biodegradation

ENVIRONMENTALINFORMATION
thisproductisreadilymetabolisedorexcretedandisnotabioaccumulator thisproductdegradesreadilyandrapidlyinthepresenceofoxygenbiodegradationratesfrom 83%in30daysto92%in14dayshavebeenrecorded thisproductreactswithatmospherichydroxylradicalsitsestimatedhalflifeinairis3days thisproductiswatersolubleandwillmovereadilyinsoilandwater 230mg/litre (Leuciscusidus),97mg/litre(Pimephalespromelas),11,976mg/litre(Salmogairdneri), 10,287mg/litre(Pimephelaspomoxis) 86mg/litre(Daphniamagna) 26.6&31.3mg/litre(Scenedesmussubspicatus) 91.9mg/litre(Pseudomonasputida)

AbioticDegradation Mobilityinsoil,water AquaticToxicity LC50 (Fish,96hr) EC50 (Crustacea,48hr) EC50 (Algae,72hr) EC50 (Bacteria)

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(AdipicAcid,contd) 13.
CanadaTDG AND U.S.A.49CFR MarinePollutant

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TRANSPORTREGULATIONS
PIN ShippingName Class PackingGroup UNnotregulatedfortransport notregulatedfortransport notregulatedfortransport notregulatedfortransport notamarinepollutant

14.
Canada U.S.A.

EMERGENCYINFORMATION
CallCANUTEC(collect) CallCHEMTREC (613)9966666 (800)4249300

15.

REGULATIONS
oninventory oninventory oninventory

CanadaDSL U.S.A.TSCA EuropeEINECS

ThresholdLimitValues: 8hrTimeWeightedAvg(TWA):5mg/cum.ExcursionLimitRecommendation:Excursionsinworkerexposurelevelsmayexceed3timestheTLVTWAforno morethanatotalof30minutesduringaworkday,andundernocircumstancesshouldtheyexceed5timestheTLVTWA,providedthattheTLVTWAisnotexceeded. AtmosphericStandards: ThisactionpromulgatesstandardsofperformanceforequipmentleaksofVolatileOrganicCompounds(VOC)intheSyntheticOrganicChemical Manufacturing Industry(SOCMI).Theintendedeffectofthesestandardsistorequireallnewlyconstructed,modified,andreconstructedSOCMIprocessunitstousethebestdemonstratedsystemof continuousemissionreductionforequipmentleaksofVOC,consideringcosts,nonairqualityhealthandenvironmentalimpactandenergyrequirements.Adipicacidisproduced,asan intermediateorfinalproduct,byprocessunitscoveredunderthissubpart. CleanWaterActRequirements: Designatedasahazardoussubstanceundersection311(b)(2)(A)oftheFederalWaterPollutionControlActandfurtherregulatedbytheCleanWaterAct Amendmentsof1977and1978.Theseregulationsapplytodischargesofthissubstance. CERCLAReportableQuantities: PersonsinchargeofvesselsorfacilitiesarerequiredtonotifytheNationalResponseCenter(NRC)immediately,whenthereisareleaseofthisdesignated hazardoussubstance,inanamountequaltoorgreaterthanitsreportablequantityof5000lbor2270kg.ThetollfreenumberoftheNRCis(800)4248802IntheWashingtonD.C. metropolitanarea(202)4262675.Therulefordeterminingwhennotificationisrequiredisstatedin40CFR302.4(sectionIV.D.3.b). FDARequirements: Substanceaddeddirectlytohumanfoodaffirmedasgenerallyrecognizedassafe.Thissubstanceisgenerallyrecognizedassafewhenusedasabufferandneutralizing agentinaccordancewithgoodmanufacturingorfeedingpractice.Adipicacidisanindirectfoodadditiveinpolymerusedasabasiccomponentofsingleandrepeatedusefoodcontactsurfaces. Polyurethaneresins(producedwhenoneormoreoftheisocyanateslistedinparagraph(a)(1)ofthissectionismadetoreactwithoneormoreofthesubstanceslistedinparagraph(a)(2)ofthis section/inwhichadipicacidisincluded/)/areapproved/foruseondrysolidswiththesurfacecontainingnofreefatoroil(noendtestrequired).Adipicacidisanindirectfoodadditive polymerforuseasabasiccomponentofsingleand repeatedusefoodcontactsurfaces.Crosslinkedpolyesterresins(producedbythecondensationofoneormoreoftheacidslistedin paragraph(a)(1)ofthissection/inwhichadipicacidisincluded/withoneormoreofthealcoholsorepoxideslistedinparagraph(a)(2)ofthissection,followedbycopolymerizationwithone ormoreofthecrosslinkingagentslistedinparagraph(a)(3)ofthissection),shallmeetthefollowingextractiveslimitations:netchloroformsolubleextractivesnottoexceed0.1mg/sqinof foodcontactsurfacetestedwhentheprescribedfoodsimulatingsolventiswateror8or50%alcoholtotalnonvolatileextractivesnottoexceed0.1mg/sqinoffoodcontactsurfacewhen... solventisheptane.Inaccordancewithgoodmanufacturingpractice,finishedarticlescontainingthecrosslinkedpolyesterresinsshouldbe...cleansedpriorto...firstuseincontactwithfood.

16.

PREPARATIONINFORMATION

PreparedforMegaloidLaboratoriesbyPeterBursztyn,(705)7341577
WithdatafromRTECS,Haz.SubstanceDataBase,Cheminfo (CCOHS), IUCLIDDatasheets (EuropeanChem.SubstanceInfo. System), & others,asavailable

PreparationDate:

August2004,August2007

RevisionDate: August2010

PleaseensurethatthisMSDSisgivento,andexplainedtopeopleusingthisproduct.

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