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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education 0620/13
October/November 2010 45 Minutes Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended)

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CHEMISTRY Paper 1 Multiple Choice

*8947497463*

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16. You may use a calculator.

This document consists of 16 printed pages.

IB10 11_0620_13/RP UCLES 2010

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2 1 In which changes do the particles move further apart? W gas Y A 2 W and X B W and Z liquid Z C X and Y D Y and Z X solid

The table shows the structure of different atoms and ions. particle Mg Mg2+ F F proton number 12 X 9 9 nucleon number 24 24 19 19 number of protons 12 12 9 9 number of neutrons W 12 Y 10 number of electrons 12 10 9 Z

What are the values of W, X, Y and Z? W A B C D 3 10 10 12 12 X 10 12 10 12 Y 9 10 9 10 Z 9 9 10 10

Element X has a nucleon (mass) number of 19 and a proton (atomic) number of 9. To which group in the Periodic Table does it belong? A I B III C VII D 0

A mixture of ethanol and methanol are separated by fractional distillation. This method of separation depends on a difference in property X of these two alcohols. What is property X? A B C D boiling point colour melting point solubility

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3 5 Chromatography is used to find out if a banned dye, P, is present in foodstuffs. The results are shown in the diagram. Which foodstuff contains P?

Which diagram does not show the outer shell electrons in the molecule correctly?
A B C H Cl Cl Cl D

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4 7
2 Two isotopes of hydrogen are 1 1H and 1H .

Which diagram shows the arrangement of particles in the two isotopes?

1 1H 2 1H

e A n

e p e

key e = an electron p = a proton n = a neutron = a nucleus

e B p

e p n

e C p

e p p

e D p n p n

The chemical compositions of two substances, W and X, are given. W Na(Al Si3)O8 X Ca(Al 2Si2)O8

Which statements are correct? 1 2 3 A 1 and 2 W and X contain the same amount of oxygen. W contains three times as much silicon as X. X contains twice as much aluminium as W. B 1 and 3 C 2 and 3 D 1, 2 and 3

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5 9 The electronic structures of atoms X and Y are shown.

X and Y form a covalent compound. What is its formula? A XY5 B XY3 C XY D X3Y

10 Element X is shiny and can be formed into a sheet by hammering. Which row correctly describes the properties of element X? conducts electricity A B C D     melts below 25 C    

11 Substance X was electrolysed in an electrolytic cell. A coloured gas was formed at the anode and a metal was formed at the cathode.
power supply

anode

cathode

substance X

What is substance X? A B C D aqueous sodium chloride molten lead bromide molten zinc oxide solid sodium chloride [Turn over

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6 12 The diagram shows apparatus used in an attempt to electroplate a metal ring with copper.
+ bulb

metal ring

copper electrode aqueous copper(II) sulfate (electrolyte)

The experiment did not work. What change is needed in the experiment to make it work? A B C D Add solid copper(II) sulfate to the electrolyte. Increase the temperature of the electrolyte. Replace the copper electrode by a carbon electrode. Reverse the connections to the battery.

13 When concentrated sodium chloride solution is electrolysed, elements X and Y are formed.
X Y

concentrated sodium chloride solution +

What are X and Y? X A B C D chlorine hydrogen hydrogen oxygen Y hydrogen chlorine oxygen hydrogen

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7 14 Calcium carbonate was reacted with hydrochloric acid in a conical flask. The flask was placed on a balance and the mass of the flask and contents was recorded as the reaction proceeded. During the reaction, carbon dioxide gas was given off. The reaction was carried out at two different temperatures. Which row is correct? change in mass A B C D decrease decrease increase increase temperature at which mass changed more quickly higher temperature lower temperature higher temperature lower temperature

15 Which is an endothermic process? A B C D burning hydrogen distilling petroleum reacting potassium with water using petrol in a motor car engine

16 The diagrams show some pieces of laboratory equipment.

1 balance 2 stop-clock 3 thermometer

60 45 30 15

Which equipment is needed to find out whether dissolving salt in water is an endothermic process? A 1 only B 1 and 3 C 2 and 3 D 3 only

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8 17 Which reaction will result in a decrease in pH? A B C D adding calcium hydroxide to acid soil adding citric acid to sodium hydrogen carbonate solution adding sodium chloride to silver nitrate solution adding sodium hydroxide to hydrochloric acid

18 When pink crystals of cobalt(II) chloride are heated, steam is given off and the colour of the solid changes to blue. CoCl2.6H2O CoCl2 + 6H2O

What happens when water is added to the blue solid? colour A B C D changes to pink changes to pink remains blue remains blue temperature decreases increases decreases increases

19 The red colour in some pottery glazes may be formed as a result of the reactions shown.
heat CuCO3 CuO + SnO CuO + CO2 Cu + SnO2

These equations show that 1 is oxidised and 2 is reduced. Which substances correctly complete gaps 1 and 2 in the above sentence? 1 A B C D CO2 CuCO3 CuO SnO 2 SnO2 CuO SnO CuO

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9 20 Some barium iodide is dissolved in water. Aqueous lead(II) nitrate is added to the solution until no more precipitate forms. This precipitate, X, is filtered off. Dilute sulfuric acid is added to the filtrate and another precipitate, Y, forms. What are the colours of precipitates X and Y? X A B C D white white yellow yellow Y white yellow white yellow

21 The table shows some reactions of the halogens. Which reaction is the most likely to be explosive? reaction reaction with hydrogen reaction with iron chlorine gas A very vigorous bromine gas B less vigorous iodine gas C D

22 Which compound is likely to be coloured? A KMnO4 B KNO3 C K2CO3 D K2SO4

23 A salt is made by adding an excess of an insoluble metal oxide to an acid. How can the excess metal oxide be removed? A B C D chromatography crystallisation distillation filtration

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10 24 The oxide of element X was added to an acid. It reacted to form a salt and water.

oxide of element X

acid

What is the pH of the acid before the reaction and what type of element is X? pH A B C D greater than 7 greater than 7 less than 7 less than 7 type of element X metal non-metal metal non-metal

25 The diagram shows the positions of elements P, Q, R, S and T in the Periodic Table. These letters are not the chemical symbols for the elements.

S P Q R

Which statement about the properties of these elements is correct? A B C D P reacts more vigorously with water than does Q. P, Q and R are all metals. T exists as diatomic molecules. T is more reactive than S.

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11 26 The table compares the properties of Group I elements with those of transition elements. Which entry in the table is correct? property A B C D catalytic activity density electrical conductivity melting point Group I elements low high low high transition elements high low high low

27 Which pollutant, found in car exhaust fumes, does not come from the fuel? A B C D carbon monoxide hydrocarbons lead compounds nitrogen oxides

28 The diagram shows the materials used in the production of steel from impure iron.

impure iron

oxygen
steel an oxide of element X

What could element X be? A B C D calcium carbon nitrogen sulfur

29 Which property do all metals have? A B C D Their boiling points are low. Their densities are low. They conduct electricity. They react with water.

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12 30 Which diagram could represent the structure of an alloy?

A + + + + + + B

31 Some metals react readily with dilute hydrochloric acid. Some metals can be extracted by heating their oxides with carbon. For which metal are both statements correct? A B C D calcium copper iron magnesium

32 Which diagram shows a common use of stainless steel?

A B C D

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13 33 Why is chlorination used in water treatment? A B C D to kill bacteria in the water to make the water neutral to make the water taste better to remove any salt in the water

34 A test-tube containing damp iron wool is inverted in water. After three days, the water level inside the test-tube has risen.
damp iron wool

water

Which statement explains this rise? A B C D Iron oxide has been formed. Iron wool has been reduced. Oxygen has been formed. The temperature of the water has risen.

35 A bag of fertiliser Watch it grow contains ammonium sulfate and potassium sulfate. Which of the three elements N, P and K does Watch it grow contain? N A B C D     P     K    

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14 36 Which information about carbon dioxide and methane is correct? carbon dioxide A B C D formed when vegetation decomposes greenhouse gas present in unpolluted air produced during respiration     methane    

37 Ethene reacts with Y to produce ethanol. ethene + Y ethanol What is Y? A B C D hydrogen oxygen steam yeast

38 In an oil refinery, crude oil is separated into useful fractions. The diagram shows some of these fractions.
refinery gases gasolene X pre-heat 400 C diesel Y Z

What are fractions X, Y and Z? X A B C D fuel oil fuel oil paraffin (kerosene) paraffin (kerosene) Y bitumen paraffin (kerosene) bitumen fuel oil Z paraffin (kerosene) bitumen fuel oil bitumen

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15 39 The diagram shows the structure of a compound.

H C H

H C

H C H

H C H O H

To which classes of compound does this molecule belong? alkane A B C D no no yes yes alkene no yes no yes alcohol no yes yes yes

40 Which structures show compounds that are members of the same homologous series?
1 H H O C H H C H H C H H H H C H H C H 2 O C O H

3 H H C H H C H C H H C H H H C H H C H

4 H C H H C H O H

1 and 2

1 and 4

2 and 3

3 and 4

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University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity.

UCLES 2010

DATA SHEET The Periodic Table of the Elements

Group III
1

I H
Hydrogen

II

IV

VI

VII

0
4

He
Helium

1 11 12 14 16 19

2 20

Li
Boron Carbon

Be
5 27 28 6 7

N
Nitrogen

O
Oxygen

F
Fluorine

Ne
Neon

Lithium

Beryllium

8 31 32

9 35.5

10 40

23

24

Na
Aluminium

Mg
13 51 52 55 56 59 59 64 65 70

Al
14

Si
Silicon

P
Phosphorus

S
Sulfur

Cl
Chlorine

Ar
Argon

Sodium

Magnesium

11

12

15 73 75

16 79

17 80

18 84

39

40

45

48

K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc

Ca
23 93 96 101 103 106 108 112 24 25 26 27 28 29 30

Sc

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn
31

Ga
Gallium

Ge
Germanium

As
Arsenic

Se
Selenium

Br
Bromine

Kr
Krypton

Potassium

Calcium

Scandium

Titanium

19

20

21

22

32 115 119

33 122

34 128

35 127

36 131

16

85

88

89

91

Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver

Sr
41 181 184 186 190 192 195 197 42 43 44 45 46 47

Zr

Nb

Mo

Tc

Ru

Rh

Pd

Ag
48

Cd
Cadmium

In
Indium

Sn
Tin

Sb
Antimony

Te
Tellurium

I
Iodine

Xe
Xenon

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49 201

Rubidium

Strontium

Yttrium

Zirconium

37

38

39

40

50 204 207

51 209

52

53

54

133

137

139

178

Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum

Ba
73 77 74 75 76 78

La Ta W Re Os Pt

Hf

Ir

Au
Gold

Hg
Mercury

Tl
Thallium

Pb
Lead

Bi
Bismuth

Po
Polonium

At
Astatine

Rn
Radon

Caesium

Barium

Lanthanum

Hafnium

55

56

57

72

79

80

81

82

83

84

85

86

226

227

Fr
140 141 144 150

Ra

Ac
152 157 159 162 165 167 169 173 175

Francium

Radium

Actinium

87

88

89

*58-71 Lanthanoid series 90-103 Actinoid series Ce

Cerium Praseodymium Neodymium Promethium

Pr
59 60 238 61

Nd

Pm
62

Sm
Samarium

Eu
Europium

Gd
Gadolinium

Tb
Terbium

Dy
Dysprosium

Ho
Holmium

Er
Erbium

Tm
Thulium

Yb
Ytterbium

Lu
Lutetium

58 232

63

64

65

66

67

68

69

70

71

a = relative atomic mass

Key Th
Thorium Protactinium Uranium

X Pa
91 92

X = atomic symbol
90

U
93

Np
Neptunium

Pu
Plutonium

Am
Americium

Cm
Curium

Bk
Berkelium

Cf
Californium

Es
Einsteinium

Fm
Fermium

Md
Mendelevium

No
Nobelium

Lr
Lawrencium

b = proton (atomic) number

94

95

96

97

98

99

100

101

102

103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).