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Reg.No.:

M 20889

Name:

Vlll SemesterB.Tech.- Including Part Time Degree(Reg./Sup./lmp.) Examination,April 2012 , ' (2AATAdmn. Onwards) 2KG AEI 802 : ANALVTICALINSTRUMENTS
Time:3 Hours Max.Marks: 100

Instructians: Q. I is of shortanswertype(Answerall I questions). Q. Il to V are of long answertype (Answer PartNB of each question). typequestions : Shortanswer (Answer all) l. 1) Briefly the different typesof filtersusedin Uv-visspectrophotometry. explain 2l Briefly the spectral methods explain andseparational methods of analysis. 3) Givea briefaccount techniques on the measurement adopted for dissolved oxygenin a givensample solution technique 4) Explain the analyzing to measure adopted hydrogen sulphide content

inanairsample.
in briefaboutthe working of a typicalMRIscanner. 5) Explain in briefaboutpulsedF.T.NMRspectroscopy. 6) Explain HPLCanditsadvantages 7\ Briefly explain overotherchromatographic techniquet EddyDiffusion andalsoitseffect on bandbroadening 8) Explain ina chromatographic ? column (8x5=40) Longanswer typequestions : ll. A) Givea detailed account on atomicabsorption spectroscopy. Howis it different

fromflame emission spectroscopy. OR

15

B) 1) Explain in detailaboutattenuated totalreflectance lR spectroecopy. 10 2) Findthe criticalangleand the estimated angleof incident radiation (lH) required to obtaina properATFIspectrum indices ; giventhatthe refractive of the prismandsampleused are2.03and 1.34respectively. s
P.T.O.

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lll"A) Explain thesources andbehaviour of nitrogen dioxide in atmosphere. Also, explain the detectors forthesame. OR thesources anddetectors of sulphur , B) Explain present oxides in air samples. fV-A) Givea detailed account on instrumentation of a typica I X-ray spectroscoiry.' OH B) Givesuitable reasons forthefolfowing : (5x3= 1) Solidsample cannot be examined clirectly in NMRwithout priortreatments. 2) c-13 responds to NMRwhilec-lzdoes not. 3) Ethyl chloride canhaveonlytwo NMRsignals. 4) rf Signals are usedin NMRspectroscopy. 5) fdeally, two pure(expected) NMHsignal peaks areshown by 1-1-2tribromo ethane. practically, However, it is ,s'. V- A),Explain thevariours ionization techniques usedin Massspectrometry. OH B) ExPfain thefoflowing : 1) Ratetheory andplatetheory (inchromatography). 2') Mobile phasedelivery systems in HPLC. 3) Different typesof ionsformedin MS (ie massspectrometry). (3xS=.