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AMERICAN AGIP CO. INC.

HEAVY NAPHTHA

MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET


HEAVY NAPHTHA SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION: DESCRIPTION: PRODUCT CAS NO: GENERIC/CHEMICAL NAME: MANUFACTURER/ SUPPLIER: A COLORLESS, COMBUSTIBLE LIQUID 64741-68-0 PETROLEUM HEAVY NAPHTHA, AROMATIC NAPHTHA C7 FEEDSTOCK EMERGENCY TELEPHONE # AMERICAN AGIP CO., INC. CHEMTREC: 1-800-424-9300 485 Madison Avenue New York, New York 10022 Tel # 646-264-2100 Fax: 646-264-2222

SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS: CHEMICAL INGREDIENT A complex mixture of hydrocarbons of paraffinic, cycloparaffinic and aromatic hydrocarbons in the range of C6 to C12 Components include: Paraffins Cycloparaffins Aromatic Hydrocarbons Xylene Cyclohexane n-Hexane 1,2,4-Trimethylbenzene Toluene Benzene EXPOSURE LIMITS Substance (CAS No.) Heavy Naphtha (64741-41-9) Paraffins (68551-20-2) Cycloparaffins Aromatic Hydrocarbons COMPOSITION % 100 CAS No. 64741-41-9

40-70 20-40 7-20 5-10 2-3 0.1-5 1-2 0.5-1.5 0.1-0.5 OSHA PEL
TWA | Ceiling

68551-20-2 Mixture Mixture 1330-20-7 110-82-7 110-54-3 95-63-6 108-88-3 71-43-2 ACGIH TLV
TWA | STEL

None Established None Established None Established None Established PAGE 1 OF 8

None Established None Established None Established None Established

OTHER / COMMENT Not Applicable Not Applicable Not Applicable Not Applicable

AMERICAN AGIP CO. INC. HEAVY NAPHTHA EXPOSURE LIMITS Substance (CAS No.) Xylenes (1330-20-7) Cyclohexane (110-82-7) n-Hexane (110-54-3) 1,2,4 Trimethylbenzene (95-63-6) Toluene (108-88-3) Benzene (71-43-2)
NOTES:

OSHA PEL
TWA | Ceiling

ACGIH TLV
TWA |

100 ppm 300 ppm 500 ppm

N/A N/A N/A

100 ppm 100 ppm 50 ppm 25 ppm 50 ppm 0.5 ppm

OTHER / COMMENT 150 ppm Not Applicable N/A Not Applicable N/A ACGIH Skin
STEL

None Established 100 ppm 150 ppm 1 ppm 5 ppm

N/A N/A 2.5 ppm

Not Applicable ACGIH Skin ACGIH Skin

PEL = Permissible Exposure Limit (OSHA). TLV = Threshold Limit Value (ACGIH). TWA = Time-Waited Average over a work day (usually 8-12 hr. day) Ceiling = maximum allowable human exposure limit for an airborne substance; never to be exceeded even momentarily, (even if the 8-hr. TWA is not exceeded). STEL = Short-Term Exposure Limit = 15 minute Time-Weighted Average maximum allowable human exposure limit for an airborne substance; never to be exceeded even momentarily during a workday (even if the 8-hr. TWA is not exceeded). Skin = There is potentially significant contribution to the overall exposure via contact of vapors, liquids, and/or solids with the skin, eyes, or mucous membranes.

SECTION 3. HAZARD IDENTIFICATION: EMERGENCY OVERVIEW APPEARANCE / STATE: Clear colorless combustible liquid HEALTH HAZARDS: WARNING! COMBUSTIBLE LIQUID. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. MAY BE HARMFUL IF INHALED OR ABSORBED THROUGH THE SKIN. LIQUID CONTACT MAY CAUSE EYE AND SKIN IRRITATION. OVEREXPOSURES MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION AND TARGET ORGAN EFFECTS. MAY CAUSE DIZZINESS AND DROWSINESS. SELF-CONTAINED BREATHING APPARATUS MAY BE REQUIRED BY RESCUE WORKERS. CONTAINS BENZENE CANCER HAZARD. LONG TERM EXPOSURE TO BENZENE VAPOR HAS CAUSED CANCER IN LABORATORY ANIMALS. AVOID SPILLS. SPILLS MAY PRESENT BOTH A PHYSICAL AND AN ENVIRONMENTAL HAZARD. ROUTES OF ENTRY: Skin contact, eye contact, inhalation and ingestion. TARGET ORGAN EFFECTS: Refer to Sec. 11, Toxicological Information.

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AMERICAN AGIP CO. INC. HEAVY NAPHTHA POTENTIAL HEALTH EFFECTS: (Signs & Symptoms of Exposure) INHALATION (Breathing): Toxic and harmful if inhaled. May cause irritation to the nose, throat and respiratory tract. Breathing of high vapor concentrations may cause central nervous system depression, evidenced by dizziness, light-headedness, headache, nausea, drowsiness and loss of coordination. Continued inhalation may result in unconsciousness. (Refer also to Sec. 8 & 11 for more information). EYE CONTACT: May be irritating to the eyes causing a burning sensation, redness, swelling and/or blurred vision. SKIN CONTACT: May be irritating to the skin causing a burning sensation, redness and/or swelling. Prolonged or repeated skin contact can cause defatting and drying of the skin that may result in a burning sensation and a dried, cracked appearance. Remove contaminated clothing. INGESTION (Swallowing): This material may be harmful if swallowed. Ingestion may result in vomiting; aspiration (breathing) of vomitus into lungs must be avoided as even small quantities may result in aspiration pneumonitis. CHRONIC EXPOSURE: Intentional misuse by deliberately concentrating and inhaling Heavy Naphtha can be harmful or fatal. Altered mental state, drowsiness, peripheral motor neuropathy, irreversible brain damage, delirium, seizures and sudden death are associated with repeated abuse. Prolonged and repeated exposure of pregnant animals to high levels of toluene (greater than 1500 ppm) have been reported to cause fetal developmental effects. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: Persons with pre-existing medical conditions such as disorders of the skin, respiratory system, liver, kidneys, central nervous system, cardiovascular and blood systems my be more susceptible to the toxic effects. SECTION 4. FIRST AID MEASURES: INHALATION (Breathing): Remove to fresh air. If not breathing, give artificial respiration If breathing is difficult, give 100 percent humidified oxygen. Get medical attention immediately. . EYE CONTACT: Remove contact lenses if worn. Immediately flush eyes with cool water and continue washing for at least fifteen minutes, keeping eyelids open. Seek medical attention. SKIN CONTACT: remove contaminated shoes and clothing. Flush affected area with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. Do not use ointments. If skin surface is not damaged, clean affected area thoroughly with mild soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists. INGESTION (Swallowing): Do not induce vomiting. If spontaneous vomiting is about to occur, place victims head below knees. If victim is drowsy or unconscious, place on the left side with head down. Never give anything by mouth to a person who is not fully conscious. Do not leave victim unattended. Seek medical attention immediately.

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AMERICAN AGIP CO. INC. HEAVY NAPHTHA SECTION 5. FIRE FIGHTING MEASURES: Fire: Flashpoint: >100F/37C Autoignition temperature: No data available Decomposition temperature: No data available Flammable limits in air (%volume): No data available

FIRE EXTINGUISHING MEDIA: Dry chemical, foam, and carbon dioxide. Water fog or water spray are of value for cooling, but may not achieve extinguishment. SPECIAL INFORMATION: This product has been determined to be a combustible liquid per the OSHA Hazard Communication Standard and should be handled accordingly. For additional fire related information, see NFPA 30 or North American Emergency Guide 128. SECTION 6. ACCIDENTAL RELEASE MEASURES: Take proper precautions to ensue your own health and safety before attempting spill control or cleanup. Evacuate all non-essential personnel from immediate area and establish a regulated zone with site control and security. In natural environments, seek advice from ecologists. Use proper protective equipment. Eliminate all ignition sources. All equipment used when handling this material must be grounded. Stop the leak if it can be done without risk. Do not touch or walk through spilled material. Remove spillage immediately from hard, smooth walking areas. Prevent spilled material from entering waterways, sewers, basements, or confined areas. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to appropriate waste containers. Notify the National Response Center (800-424-8802) and comply with all laws. SECTION 7. HANDLING AND STORAGE: Store and transport in accordance with all applicable laws. Keep away from heat, sparks, and open flame. Keep containers closed. Ground all drums and transfer vessels when handling. All electrical equipment in heavy naphtha storage and/or handling areas should be installed in accordance with applicable requirements of the National Electrical Code, N.F.P.A. Keep out of reach of children. SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION: EXPOSURE LIMITS: Refer to Section #2 ENGINEERING CONTROLS: VENTILATION: Provide ventilation or other engineering controls to keep the airborne concentrations of vapor or mists below the applicable workplace exposure limits. All electrical equipment should comply with the National Electric Code. An emergency eye wash station and safety shower should be located near the workstation. PAGE 4 OF 8

AMERICAN AGIP CO. INC. HEAVY NAPHTHA PERSONAL PROTECTION: The selection of personal protective equipment varies, Depending upon conditions of use. A hazard assessment of the work area for PPE requirements should be conducted by a qualified professional pursuant to OSHA regulations. EYES: Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. Chemical goggles should be worn during transfer operations or when there is likelihood of misting, splashing, or spraying of this material. A suitable emergency eye wash and safety shower should be located near the workstation. SKIN: Avoid skin contact. Use gloves. Wash hands with plenty of mild soap and water before eating, drinking, smoking, use of toilet facilities or leaving work. Do not use this material as a skin cleaner. RESIRATORY: For known vapor concentrations above the occupational exposure guidelines use a NIOSH-approved organic vapor respirator if adequate protection is provided. Protection factors vary depending upon the type of respirator used. Respirators should be used in accordance with OSHA requirements. For airborne vapor concentrations that exceed the recommended protection factors for organic vapor respirators, use a full-face, positive-pressure, supplied air respirator. WORK HYGIENIC PRACTICES: Use explosion-proof mechanical ventilation equipment. (Refer also to Sec. 2 & 5 for Exposure Limits) SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES: APPEARANCE / STATE: liquid, transparent, clear ODOR: hydrocarbon-like SOLUBILITY: Not determined SPECIFIC GRAVITY: ca. 0.75 pH: Not applicable % VOLATILES BY VOLUME @ 70F/21C: Not determined BOILING POINT: 149-446F/65-230C MELTING POINT: No data available VAPOR DENSITIY (AIR = 1): No data available VAPOR PRESSURE: ca. 80 mm Hg @ 100F/37C SECTION 10. STABILITY AND REACTIVITY: STABILITY: Stable HAZARDOUS DECOMPOSITION PRODUCTS: Burning or excessive heating may produce carbon monoxide and other harmful gases and vapors. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITIES: Strong acids, alkalis, and oxidizers such as liquid chlorine, other halogens, nitrates, hydrogen peroxide, and oxygen. CONDITIONS TO AVOID: keep away from heat, flame and other potential ignition sources. PAGE 5 OF 8

AMERICAN AGIP CO. INC. HEAVY NAPHTHA SECTION 11. TOXICOLOGICAL INFORMATION: Heavy Naphtha Inhalation: No data available Oral: No data available Dermal: No data available

CARCINOGENICITY: Cancer Lists Ingredient Heavy Naphtha (CAS 64741-41-9) Benzene (CAS 71-43-2) ---NTP Carcinogen--Known Anticipated NE N/A Yes IARC Category N/A 1

No other constituents of this product listed in Section #2 are classified as carcinogenic by IARC, NTP, or OSHA. SECTION 12. ECOLOGICAL INFORMATION: ENVIRONMENTAL FATE: When released into the soil: Heavy Naphtha may result in environmental damage when it absorbs and penetrates the soil. When released into the water: Ground water may be contaminated. When released into the air: The components of Heavy Naphtha evaporate slowly. ENVIRONMENTAL TOXICITY: Heavy Naphtha contains components that are potentially toxic to freshwater and saltwater ecosystems SECTION 13. DISPOSAL CONSIDERATIONS: Hazard characteristics and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and residues at the time of disposition. SECTION 14. TRANSPORTATION INFORMATION: DOT: DOMESTIC (LAND, DOT) Proper Shipping Name: Petroleum Distillates, N.O.S. UN 1268 Hazard Class: 3 Packaging Group: III

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AMERICAN AGIP CO. INC. HEAVY NAPHTHA IMO: INTERNATIONAL (WATER, I.M.O.) Proper Shipping Name: Petroleum Distillates, N.O.S. Hazard Class: 3 UN/NA: 1268 Packing Group: III SECTION 15. REGULATORY INFORMATION: Chemical Inventory Status Part 1 Ingredient Heavy Naphtha (64741-41-9) Federal, State & International Regulations Part 1 Ingredient Heavy Naphtha (64741-41-9) Federal, State & International Regulations Part 2 - CERCLA Ingredient Heavy Naphtha (64741-41-9) Chemical Weapons Convention: No SARA 311/312: Acute: Yes Pressure: No Yes TSCA 12(b): Yes Chronic: Yes Reactivity: No Fire: Yes - RCRA 261.33 Yes - TSCA8(d) Yes

TSCA Yes

EC Yes

Japan Australia Yes Yes

- SARA 302 - SARA 313 RQ TPQ List Chemical Catg. No No No No

WHMIS: This MSDS has been prepared to the hazard criteria of the Controlled Products Regulations (CPR) and contains all of the information required by the CPR. SECTION 16. OTHER INFORMATION: NFPA RATINGS: Health: 2 Flammability: 2 Reactivity: 1

LABEL HAZARD WARNING: WARNING! COMBUSTIBLE LIQUID. LABEL PRECAUTIONS: Avoid breathing vapor. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep away from heat, sparks and flame.

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AMERICAN AGIP CO. INC. HEAVY NAPHTHA LABEL FIRST AID: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Launder clothing before reuse. In all cases get medical attention immediately. DISCLAIMER: Although the information and recommendations set forth herein (information) are presented in good faith and believed to be correct as of the date hereof, American AGIP Company, Inc., makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its safety and suitability for their purposes prior to use. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OR MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE, ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Revision: Original 9-1-2006 Supersedes: --MSDS Prepared by: Proactive Management Systems MSDS Reviewed by: Leslie R. Andrews, Dr.PH, CIH, Leslie R. Andrews & Associates, Inc. THIS MATERIAL SAFETY DATA SHEET CONTAINS THE INFORMATION REQUIRED TO COMPLY WITH THE FEDERAL OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 (g) (2).

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