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http://www.bluffton.edu/~bergerd/classes/cem221/errata.html
The structure of benzaldehyde at the top of page 652 is incorrect. The correct and incorrect structures are shown below.
page 804 (Chapter 17), last paragraph. The text uses "amine" rather than "amide." The
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05/11/2013 18:48
Bruice errata
http://www.bluffton.edu/~bergerd/classes/cem221/errata.html
paragraph should read The mechanisms for the reaction of LiAlH4 with unsubstituted and N,N-disubstituted amides are somewhat different... (emphasis shows the corrected word) page 886, Chapter 18, Mechanism for the malonic ester synthesis: The second structure is missing an oxygen from the left-hand ethoxy group, that is, "C2H5" should be "C2H5O" page 887, Chapter 18, mechanism: In the second structure, the negatively-charged carbon should have only a single hydrogen (CH), not two hydrogens (CH2).
incorrect structures correct structures page 191, Chapter 6, problem 27e: the correct name is 1,5-cyclooctadiene, not 1,6. page 192, Chapter 6, problem 34e, the answer should be 1-methyl-1,3,5-cycloheptatriene page 218, Chapter 7, problem 47, #10. The answer key has mistakenly inserted an oxygen atom between the carbonyl group and the ethyl group. This does not change the essentials of the answer.
page 282, Chapter 9, problem 12, from p. 406 in the text: on p. 282 of the Study Guide, the answers for parts a-2 and a-3 are switched. page 289, Chapter 9, problem 32b. Somehow or other, the answer-key guys started with six carbons and ended with seven. The correct answer is cyclohexene, not 1-methylcyclohexene.
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05/11/2013 18:48
Bruice errata
http://www.bluffton.edu/~bergerd/classes/cem221/errata.html
page 324, Chapter 10, problem 51c: In older printings, the second structure in the answer should be cyclohexanol, not cyclohexene. This has been fixed in the newer editions. page 366, Chapter 12, problem 7, 35Br and 37Br should be 79Br and 81Br. This does not affect the result of the problem, only the 50:50 ratio between the isotopes matters! page 489, Chapter 16, problem 64d has an incorrect structure:
page 501, Chapter 16, problem 87, from p. 787 in the text: the final structure in the synthesis of saccharin is missing one of the aromatic ring bonds. You should be able to figure out which one...
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