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Kultur Dokumente
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CORE CURRICULUM
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CHEMISTRY
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CHEMISTRY.
COURSE STRUCTURE
Closs Xl (Theory)
One Poper
Units
l
Time: 3
Hours
Title
Some Bosic concepts of Structure of
chemislry Properlies
3
6
4
ii
Atom Struclure
iii
;V
5
4
Liquids
VI
Thermodynomics Equilibrium
Redox
6
6
vtl
vill
IX
3
3 5
7
Hydrogen
s-Block
XI
Some p-Block
xll xlll
XIV
Hydrocorbons
Environmentol
8
3 7A
Chemistry
Totol Objeciives of lhe syllobus should be well defined. Depth of eoch topic should be given.
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:omposilion, empiricol ond moleculor formulo; chemicol reoclions, stoichiomelry ond colculolions bosed on stoichiomefry.
Discovery of electron, proion ond neutron; otomic number, isotopes ond isobors.
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Rulherford's model ond its limitolions. Bohr's model ond its limitolions, concept of
p, ond d orbiiols, rules for filling elecirons in orbitols - Aufbou principle, Pouli
: -
/':.
!.;.
!. -.
r-li'
<:i-
f-i.' l
(Periods 8)
periodic toble, Significonce of clossificoiion, brief history of the developmenl of periodic lrends in modern periodic row ond the preseni form of periodic tobre.
goin properties of elements -olomic rodii, ionic rodii. lonizoiion entholpy, electron with olomic enlholpy, eleclro negolivily, volence, Nomencloiure of elements
number greoler thon l0O.
c, --
l.-
:,,
(Periods l6)
Volence electrons, ionic bond, bond porometers, covolent bonc: Born Hober
of Cycle. Lewis siruclure, polor chorocter of covolent bond, covoleni chorocler
some simple molecules, moleculor orbitol tIeory of homonucleor diotomic molecules ond hYdrogen bond.
(Periods l4)
melling ond Three slotes of motler. Inlermoleculor interoctions, types of bonding, the molecule, Boyle's boiling points. Role of gos lows in elucidoting ihe concepi of empiricol low. chorles' lcw, Goy Lussoc's low. Avogodro's low. ldeol behoviour, Derivoiion from derivolion of gos equoiion, Avogodro's number. ldeol gos equolion'
\
d
moleculor speeds (elementory ideo) -iquid Stote - Vopour pressure, viscosity ond surfoce tension (quolifofive ideo only,
-
I
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: mothemolicol
derivofions).
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Thermodynomics
(Perlodsl6)
:-d
=
-st
F F F \
Ld \ l\
r.l),
:nd nonspontoneous
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Equilibrium
(Perlods 20)
l!-. la.
ll\ \ \ \ \ \ \ \_
lquilibrium in physicol ond chemicol prrccesses, dynomic nofure of uquitiUrium, low of moss oction, equilibrium conslonl, fociors offecling equilibrium - Le Chotelier's crinciple; ionic equilibrium - ionizolion of ocids ond boses, strong ond weok
elecfrolytes, degree of ionizolion. ionizotion of polybosic ocids, ocid strenglh,
Reoctions
(periods 6)
'
number.
Unlt lX :
Hydrogen
(periods g)
ond uses of hydrogen; hydrides - ionic, covolenl ond inlerstiiiol; physicol ond chemicol properties of woler, heovy woler; hydrogen peroxide-preporotion,
properties, slructure ond use; hydrogen os o fuel.
Unil X: s-Block Elemenfs (Alkoli ond Alkoline eorlh melols) (periods 12)
Group I ond Group 2 elemenls:
Generol inlroduction, electronic configurotion. occurrence, onomolous properlies
of fhe firsl elemeni of eoch group, diogonol relotionship, trends in ihe voriotion of,
propertigs (such os ionizotion entholpy, otomic ond ionic rodii), lrends in chemicol
-)
a
a_ ,
O
a
a
:rd
Co
(Perlods l4)
t-
croperfies of first elemenf of the group; Boron- physicol ond chemicol properties, scme imporlont compounds: borox. boric ocid, boron hydrides. Aluminium:
Group 14 elements: Generol introduction, electronic configurotions, occunence, voriofion of properlies, oxidotion slotes, trends in chemicol reoclivify, onomolous behoviour of first elemenl, Corbon - colenoiion, ollotropic forms, physicol ond
tat
J J
O rt
.
D
;
Unil Xll: Orgonic Chemislry - Some Bosic Principles ond Techniques
,
ond IUPAC nomencloture of orgonic compounds
(Periods 16)
Unil Xlll:
Hydrocorbons
(Periods 16)
Closslffcolion of hydrocorbons
Alkones - Nomencloture, isomerism, conforrnoiions (eihone only), physicol
"
reoction of - hydrogen, hologens, hydrogen holides ond woler. Aromotic hydrocorbons: lnlroduction, IUPAC nomencloture; Benzene: resononce
- nifrotion
\_.-
j \_
-\ D
ond ioxicily.
(Periods 8)
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:;fects of depletion of ozone loyer, greenhouse effect ond globolworming icllution due fo industriol wostes; green chemistry os on ollernofive fool for reducing
:.:llution. strotegy for conlrol of environmentol pollulion-
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al
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a,
Procticols
Evoluotlon Scheme for Exominollon
Morks r0
X
Volumetric Anolysis
Solt Anofysis
6
6
30
PRAcTlcAts
A. Bosic Loborolory
syLtABUs
Totor periods 60
(periods 3)
Techniques
gloss rod
substonces
(periods 7)
(Perlods 7)
{o) . . . b)
Anyone of lhe following experiments: Determinotion of pH of some solulions obtoined from fruit juices, voried concenlrotions of ocids. ,boses ond solls using pH poper or universol inoicofor. Comporing fhe pH of solutions of strong ond weok ocid of some concenfrotion.
S-tudV
boses.
D.
Chemicol equilibrium
(Periods 5)
io) Study the shifl in equilibrium between ferric ions ond fhiocyonote ions by increosing/decreosing the concentrotion of eilher ions.
(b) Study the shift in equilibrium between [Co(HzO)o]z- ond chloride ions by chonging
Quoniitotive estimolion
(Periods l8)
. . . .
Preporolion of stondord solution of oxolic ocid. Determinotion of strenglh of o given solution of sodium hydroxide by titroting il ogoinst slondord solution of oxolic ocid.
Preporotion of stondord solulion of sodium corbonole.
Delerminolion of strenglh of o given solulion of hydrochloric ocid by tikoting it ogoinsf stondord sodium corbonole solution.
F.
Quolilolive onolysis
(Periods l8)
Anions- COs2-',S2-, SOs2-, SOo2-, NOz-, NOr-, Cl-, Br-, l'. POo3-, Czao2', CH:COO (Note: lnsoluble solls excluded)
(Periods l2)
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Mox. Morks:70 morks
Morks
4
Iime:3
Titles
Hours
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Unils
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ill
1V
Eleclrochemisiry
1
5
q
Chemicol kineiics
Surfoce chemislry'
VI
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Elements
B q
t-
vill
IX
Coordinolion Compounds
Holoolkones ond Holoorenes Alcohols, Phenols ond Ethers
3
4 4
XI
,
t
xtl
6 4 4
xlt
XIV
O
XV XVI
3
3
a
Chemisfry in Everydoy life
Totol:
t, e
70
, -
Unll l: Solld
Slote
(Perlods
12)
covolenl in of
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,:
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i.
:
ond melollic solids, omorphous ond cryslolline solids (elemenf ory ideo), unit cell
two dimensionol ond three dimensionol lotlices, pocking efficierrcy, colculotion
density of unil cell, pocking in solids, voids, number of oloms per unit cell in o
!':
cubic
unif cell, poinl defecls, eleclricol ond mognefic properlies.Bond lheory of melols,
semiconductors.
(Periods l2)
t
Unit ll: Solulions
osmotic pressure, delerminolion of moleculor mosses using colligotive properlies, obnormol moleculor moss, von't Hoff foctor ond colculotions involvino it.
(Periods l4)
tt
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Nernst equotion ond its opplicofion io chemicol cells, Relotion between Gibbs
;
a a
Kinefics
-
(Perlods 12)
Fnrc of (overoge ond instontoneous), foctors offecting rotes of reoction; o reoction vr l\VlV l-'"
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(Periods 8)
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Adsorption
enzyme cotolysis; colloidol stcle: distinction between lrue solutions, colloids ond
suspensions; lyophilic,
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Unlt Vl: Generol Prlnclples ond Processes of lsolollon of Elemenis
ii
i: i:
"
;'..
(Perlods 8)
Principles ond melhods of extroclion - concenlrolion, oxidolion,
reduclion of
.o
lron.
Erements
(perrods
14)
,.
occurrence,
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oxidolion sloles, lrends in physicol ond chemicol properlies; niirogen - preporolion, properlies ond uses; compounds of nirrogen: prepororion ond properties of ommonio ond nilric ocid, oxides of nitrogen (slruclure only); phosphorus-olloiropic
forms; compounds 'of phosphorus: preporoiion ond properiies of phosphine, holides
(PCls, PCls)
Group l6 elemenfs: Generol inlroduction, electronic configuroiion, oxidotion sloles. occurrence' frends in physicol ond chemicol properties; dioxygen: preporotion. properlies ond uses; clossificotion of oxides; ozone. Sulphur - ollotropic forms; compounds of sulphur: preporotion, properlies ond uses of sulphur dioxide; sulphuric
ocid: industriol process of monufoclure, properlies ond uses. other oxides ond
oxoocids of sulphur (slruclures only).
a
D
D
t
(Period 14)
ironsilion melols, generol trends in properlies of the first row lronsifion metols
metollic chorocter. ionizolion entholpy, oxidoiion stotes, ionic rodii, colour, cotolytic properly, mognelic properfies, inlerstitiol compounds, olloy formotion. Preporotion
l
C D
ond properlies of
KzCrzOz
ood KMnOr.
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J
lonthonoid controction ond ils consequences. Actinoids - Electronic configurotion, oxidotion slofes ond'comporison with
a,
4t
lonthonoids.
:
unil lX: coordinoiion
compounds
(period 12)
mognelic properties ond shopes, rupAc nomencroture of mononucreor coordinolion compounds- Bonding {werner's theory. vBT ond CFT}; structurol ond
stereo isomerism importonce of coordinoiion comp,cunds {in quoliiolive inclusion of
onolysis, extroction of metors ond piorogicor sysrems).
Holoorenes.
(periods 12)
Noture of C-X bond, subslitution reoctions {directive influence of hologen for mon.osubsfiluted compounds onry, stobirity of corbocotions R-s ond configurolions)
Llses d_l
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Amlnes: Nomenclojutt, clossificolion, slructure, methods of preporotion, physicol
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Cyonldes ond lsocyonldes - will be mentioned ol relevonl ploces in context. Diozonium solls: Preporolion, chemicol reoclions ond imporlonce in synlhetic
orgonic chemislry.
(Periods l2)
ond fruclose),
'
primory sfruclure, secondory slruclure, terfiory slrucf ure ond quoternory structure
(Periods 8)
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biodegrodoble polymers.
(Perlod 8)
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J
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Procliccils
Evqluolion Scheme for
t.
Exominotion
Morks
Volumetric
Solt
l0
B
Anolysis
Conlenl Bosed
6 6
Tolol
30
Proclicols Syllobus
A. Surfoce
Chemistry
sor.
(periods 6)
of differenr
B.
chemicol
Kinetics
'(periods
4)
{o) {b)
ol room temperoture
Sr
t_-
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s_ r
lr
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C.
Thermochemistry
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Entholpy of dissolution of copper sulphote or potossium nilrofe. Entholpy vr neulrolizotion rrvvrrvrr4vrrvrr vr strong of Jrrvrrv ocid {HC1) vvrv utt\ ond strong bose (NoOH) / of tttvt,
t..,
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D. Eleclrochemistry
\'/^'i^+ion
(perlod 2)
E.
Chromotogrophy
(periods 2)
i) ii)
t\
,)
-\ -\
F.PreporolionoflnorgonicCompounds(Periods4) i) ii)
.
':-:'::
Preporolion of double soll of ferrous ommonium sulphole or polosh Preporofion of polossium ferric
olum.
;:.
oxoloie.
(perlods
''
G. Preporolion of orgonlc
compounds
4)
i) ii)
Acelonilide
Di-benzol
,,
lodoform
l. J.
Choroclerislic lesls of corbohybrotes, fqts ond proteins in pure somples ond lheir deleclion in given food
sluffs. of:
(Periods 4)
r )
>
K.
Quolilotive onolysis
(Periods 14)
Anions- CO:2' ,52, SO:2-, SO,.2', NOz, NO:, Cl , Br-, l-, PO.3-, CzOo2', CH:COO
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