THERMODYNAMICS

Objective Questions
16. For the reaction : C(s) + O 2
(g) CO OBJECTIVE
(g) H = –393 kJ
2 QUESTIONS 308
mole –1 (1) 200 × J (2) 200 × 10 J
298
(1) H = –ve, S = –ve, G = –ve 298
(2) H = –ve, S = 0, G = –ve (3) 200 × (4) None of these
300
(3) H = –ve, S = +ve, G = +ve
1. The (4)
difference between 25. Given :
H= –ve, heats of reaction
S = +ve, G = at
–veco nstant (1) –2.764 k cal (2) 2.674 k cal
p ress ure and co n st ant v ol um e fo r th e rea ctio n NH (g) + 3Cl (g) NCl (g) + 3HCl(g) ..... H
17. For a reaction : X + Y Z there is no entropy change. (3) +2.764 3k cal (4) None
2 of these 3 1
2C 2 H6 (l) + 15O 2 (g) 12CO 2 (g) + 6H 2 O(l) at 25ºC in kJ is N + 3H 2NH ..... H
2 2 3 2
Enthalpy
(1) –7.43 change for the reaction is 200 J mol
(2) +3.72
–1 . G is 9. The heat capacity of liquid water at constant pressure,
H + Cl 2HCl .... H
(1) –100 J mol –1 (2) 200 J mol –1
2
(C p ), is 18 cals 2deg –1 mol –1 . The value
3
of heat capacity of
(3) –3.72 (4) None of these
(3) Zero (4) Infinite The heat of formation of NCl will be
water is constant volume, (C 3 ), is approximately
2. The maximum work done in expanding 16 g oxygen at 300 H 2
v 3
18. A system is changed from state A to state B by3 one path (1) –18 cal deg
(1) H + – 1 mol
– –1
H(2) 16 cal deg –1 mol –1
K and occupying a volume of 5 dm isothermally until the 1
(3) 10.8 cal deg
2– 1 mol –21 3
(4) Cannot be predicted
and from B to A by another3path. If E and E2 are the H2
volume become 25 dm is approximately: 1
corresponding changes in internal energy, then 10. The(2) – H + co-efficient
Joule-Thomson – isHdefined as
(1) –2.01 × 10 3 J (2) +2.01 × 10 3J
1 2 3
(1) +2.01E×1 +
10 E2 –3 = J+ve
(4)(2) E1 + E2 –=6 J–ve
(3) +2.01 × 10 T H2 T
(3) E1 + E2 = 0 (4) None of these (3)
(1) – H + (2)
3. The temperature at which the reaction,
P1 2 H
H H
19. Internal energy and pressure of a gas of unit volume are (4) None of these
Ag 2 O(s) 2Ag(s) + ½O 2 (g) H P
related as :
is at equilibrium is ...; Given H = 30.5 kJ mol – 1 and S= 26. Ten(3)
grams of methanol
T (4)under reversible
(l) is vapourized H
2 3 H H
0.066
(1) P =kJ K
–1 mol – 1
E (2) P = E conditions at its boiling temperature of 78ºC an d the
(1) 462.12 K 3(2) 362.12 K 2 11. Which of theare
vapours following
allowed is
tothe correct
expand expression
at constant for theof 1
pressure
E
(3) 262.12 K (4) 562.12 K first law of thermodynamics where W of is methanol
the workisof
atmosphere. If the heat of vapourization
(3) P = (4) P = 2E
2 expansion
4.67 byper
calories the gram,
gas ? for the overall change which of the
4. If 25 calories of heat are given to a system and the system
(1) W = will be
following E –zero
q (2)? E=q–W
20. Onedoes
mole15ofcalories
an idealofgas at 25ºC
work then is
thesubjected
change intothe
expansion
internal
(3) q + WE=(2)
(1) E (4) E = q + PV
S
reversibly ten times
energy of system is of its initial volume. The change in
entropy (3) H (4) G
(1) 20 calof(2)
expansion
50 cal is 12. Given that
(1)
(3) 19.15
40 cal J(4)
k None – 1 mol –1
of these (2) 16.15 J k –1 mol –1
O(g)specific
27. If the + e – heat
O – of
(g)a gas at constant
H =pressure
–34 k caland
mole –1

(3) 22.15 J k – 1 mol –1 (4) None of these O(g) + 2e

specific –
heat of aOgas
2 – (g) H = 168
at constant volume k cal mole
are C –1
and C
5. If the enthalpy of vaporisation of water is 186.5 J mol –1 , p v
The enthalpythen
respectively, change for the reaction O – (g) +e O 2 – (g)
21. Thetheenthalpy
entropyofofreaction at 273 K iswill
its vapourisation –3.75
be kJ. The enthalpy
is C
(1) –C =R
of
(1)reaction
0.5 JK at 373 K when
–1 mol –1 C(2)
= 0 will be –1 mol
p 1.0 JK –1 p v
(1) C
(2) –202 K.
–CCal =mole
R –1 (2) –134 K. Cal mole –1
(1) 1.5
(3) –375JKkJ (2)–1–3.75
mol kJ
–1 (4) 2.0 JK –1 mol –1 v p
(3) (C
(3) +134 K.–Cal
C mole –1
) × (molecular (4) of
mass +202
gas)K.= Cal
R mole –1
373 p v
(3) –3.75
6. A system × 10 kJ of heat at constant
absorbs (4) None
volume
of and
these (4) (C – C ) × (molecular mass of gas) = R
273 13. In a quasi-equilibrium
v p process
its temperature rises from 27ºC to 37ºC. The E of reaction
22. XY, X and Y are diatomic molecules. If bond enthalpies of (1) The entropies of reactants 1and products are equal
(1)YDecreases
X, by in
and XY are 100thekJratio 1 : 0.5 : 1 and enthalpy of 28. In the
(2)reaction : P(s) +of a reatants and
The enthalpies O (g)
productsPO(g) the amount of
are equal
(2) Decreases by 10 kJ 2 2
formation of XY from X, Y is –100 kJ. The B.E. of X 2
is (3)
heatDeviation
evolved isfrom thermodythe
x kJ.Consider namics equ ilib
following rium is in
statements
(3)
(1) Zero
200 kJ/mol (2) 100 kJ/mol infinitesimally
this regard : small
(4) None of these
(3) 300 kJ/mol (4) 1/3 (4) None
The x canofbethese
termed as :
7. Work
23. If S done inH
0 for reversible
, Cl andisothermal process
HCl are 0.13, is given
0.22 by KJ K
and 0.19 –1 mol – (a) Heat of reaction (b) Heat of combustion of P
14. Which of the following has highest entropy ?
2 2
V in standard entrop y for nR (c)
respectively. The total change
2 (1) Heat of formation
10 g ice of PO
at 100ºC (2) 10 g water at 0ºC
(1) 2.303 nRT log (2) – 1 × (T 2 – T 1 ) (1) a, b and c are correct (2) a and c are correct
the reaction, H + Cl V1 2HCl is (3) 10 g water at 100ºC (4) 10 g steam at 100ºC
2 2
(1) 30 JK –1 mol –1 V (2) 40 JK –1 mol –1 (3) a and b are correct (4) b and c are correct
1
(3) 15. A system absorbs 10 kJ of heat and does 4 kJ of work. The
(3) 2.303
60 JK nRT–1log
mol –1
V2
(4) None
(4) None of
of these
these
29. If P , T and V represent the initial state and P , T V the
internal
1 energy
1 of the system 2 2

24. Thestandard
change inGibb’s
free energy when one molefor
ofaagaseous
gas absorbs final state of an
(1) Decreases byideal gas Increases
6 kJ (2) then entropy
by 6change
kJ may be
8. The free energy change
200 J of heat at constant expressed as
reaction at 27ºC will bevolume and(Given
_______. temperature rises
equilibrium (3) Decreases by 14 kJ (4) Decreases by 14 kJ
from 298=K100).
constant to 300 K is

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Objective Questions THERMODYNAMICS

T P (1) 67 : 33 (2) 33 : 67
2 2
(1) S = C ln + R ln (3) 40 : 60 (4) 50 : 50
p T1 P1
T P 31. Four grams of helium is expanded from one atm to one
1 1
(2) S = C ln – RT ln
v T2 2 P2 tenth of its original pressure at 303 K. Change in entropy
T P (assuming ideal gas behaviour) is
2 1
(3) S = C ln + R ln
p T1 P2 (1) 191.5 JK –1 (2) 1.915 JK –1

(4) None of these (3) 19.15 JK –1 (4) None of these

30. Under the same condition how many ml of 1 M KOH and 32. For the reaction at 300 K
0.5 M H SO solutions, respectively when mixed for a A(g) + B(g) C(g)
2 4
total volu me o f 10 0 ml produ ce the high es t rise in E = –3.0 kcal, S = –10.0 cal/K/mole
temperature. calculate G.
(1) –600 Cal (2) –60 Cal
(3) +600 Cal (4) None of these

ANSWERS (OBJECTIVE)
(OBJECTIVE)
ANSWERS
Thermodynamics (OBJECTIVE)
&&Thermochemistry
Thermochemistry
Thermodynamics &&Thermochemistry
Thermochemistry
1. (1) 2. (1) 3. (1) 4. (4) 5. (1)
Thermodynamics & Thermochemistry
6. (4) 7. (3) 8. (1) 9. (4) 10. (1)
11. (3) 12. (4) 13. (3) 14. (4) 15. (2)
16. (2) 17. (2) 18. (3) 19. (1) 20. (1)
21. (2) 22. (1) 23. (1) 24. (4) 25. (1)
26. (4) 27. (3) 28. (2) 29. (3) 30. (4)
31. (1) 32. (1)

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