UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education CHEMISTRY Paper 1 Multiple Choice May/June 2004

45 minutes
Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended)

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w w w e tr .X m ap eP s er om .c

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the answer sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C, and D. Choose the one you consider correct and record your choice in soft pencil on the separate answer sheet. Read the instructions on the answer sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16. You may use a calculator.

This document consists of 16 printed pages.

IB04 06_0620_01/3RP UCLES 2004

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2 1 Some students are asked to describe differences between gases and liquids. Three of their suggestions are: 1 2 3 gas molecules are further apart; gas molecules are smaller; liquid molecules vibrate around fixed positions.

Which suggestions are correct? A 2 1 only B 2 only C 3 only D 1, 2 and 3

A coloured liquid vaporises easily at room temperature. Some of the liquid is placed at the bottom of a sealed gas jar. Which diagram shows the appearance of the jar after several hours?
A B C coloured vapour coloured vapour coloured liquid coloured vapour D

Measurements are made on some pure water. its boiling point, b.p. its freezing point, f.p. its pH Sodium chloride is now dissolved in the water and the measurements repeated. Which measured values change? b.p. A B C D     f.p.     pH    

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3 4 The diagram shows a chromatogram obtained from three sweets, X, Y and Z.

red yellow red sweet X sweet Y yellow red yellow red sweet Z

How many different red dyes are present in the sweets? A 5 1 B 2 C 3 D 4

Which properties does a Group VI element have? forms covalent bonds A B C D     forms ionic bonds     conducts electricity when solid    

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4 6 The electronic structure of an element is shown.

e e e e e e e e e e e e

key e electron nucleus

Which diagram shows the electronic structure of another element in the same group in the Periodic Table?
A e e e e e e e e e e e B e e e e e e e e

C e e e e e e

D e e e e e e e e

In the diagrams, circles of different sizes represent atoms of different elements. Which diagram can represent hydrogen chloride gas?
A B C D

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5 8 How many electrons are shared between the atoms in a molecule of methane, CH4, and in a molecule of water, H2O? methane A B C D 9 4 4 8 8 water 2 4 2 4

The oxide Pb3O4 reacts with dilute nitric acid to form lead(II) nitrate, lead(IV) oxide and another product. What is the equation for this reaction? A B C D Pb3O4 Pb3O4 Pb3O4 + 4HNO3 2Pb(NO3)2 + PbO2 + 2HNO3 2PbNO3 + 4HNO3 Pb(NO3)4 + PbO4 + 2PbO + 2H2O + H2 + 2H2O

2Pb3O4 + 2HNO3 2Pb2NO3

+ 2PbO2 + H2

10 The compound ethyl mercaptan, C2H5SH, has a very unpleasant smell. What is its relative molecular mass? A 34 B 50 C 61 D 62

11 The proton number of helium is 2. What information does this give about helium? A B C D Its atom has two electrons. Its atom is twice as heavy as a hydrogen atom. It is a Group II element. Its molecule has two atoms.

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6 12 In the circuit shown the bulb does not light.

bulb carbon electrode carbon electrode beaker solid copper(II) sulphate

Which change would cause the bulb to light? A B C D add more solid copper(II) sulphate to the beaker add water to dissolve the copper(II) sulphate replace the carbon electrodes with copper electrodes reverse the connections to the electrodes

13 The following electrolysis circuit is set up, using inert electrodes P, Q, R and S.

+ P molten lead(II) bromide Q

+ R S concentrated hydrochloric acid

At which of the electrodes is a Group VII element produced? A P only B P and R C Q only D Q and S

14 When it is used as a fuel, hydrogen combines with substance X. What is X? A B C D carbon methane nitrogen oxygen

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7 15 The table compares the strengths of the bonds for reactions of the type below. X2 + Y2 2XY Which reaction is most exothermic? bonds in X2 A B C D strong strong weak weak bonds in Y2 strong strong weak weak bonds in XY strong weak strong weak

16 In an experiment, copper(II) oxide is changed to copper by a gas X. What happens to the copper(II) oxide and what is X? copper(II) oxide A B C D oxidised oxidised reduced reduced gas X carbon dioxide carbon monoxide carbon dioxide carbon monoxide

17 In an experiment, a 2 g lump of zinc and 2 g of powdered zinc are added separately to equal volumes of dilute sulphuric acid. The solid line on the graph shows the volume of gas given off when the 2 g lump is used. Which dotted line is obtained when the zinc is powdered?
A B volume of gas C D

time

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8 18 Which process is endothermic? A B C D adding water to anhydrous copper(II) sulphate burning magnesium to make the oxide heating water to make steam neutralising acidic industrial waste

19 An aqueous solution contains either aluminium sulphate or zinc sulphate. Which aqueous reagent can be used to confirm which salt is present? A B C D ammonia barium chloride sodium hydroxide sulphuric acid

20 Compound X does not dissolve in water, does not react with water, is used to control soil acidity.

What is X? A B C D calcium carbonate calcium chloride calcium hydroxide calcium oxide

21 Aqueous sodium hydroxide is added to two different solutions with the results shown.
X green precipitate formed Y light blue precipitate formed

Which cation is present in X and in Y? X A B C D

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Y iron(II) ammonium copper(II) ammonium

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ammonium copper(II) iron(II) iron(II)

9 22 The diagrams show the arrangement of electrons in three different atoms.

1 2 e e e e e e e e 3 e e e e e e e key e electron nucleus

ee

Which atoms are metals? A 1 and 2 only B 1 and 3 only C 2 and 3 only D 1, 2 and 3

23 Which property do all metals have? A B C D They are hard. They conduct electricity. They form acidic oxides. They react with water.

24 The diagram shows a light bulb.

filament argon

Why is argon used instead of air in the light bulb? A B C D Argon is a good conductor of electricity. Argon is more reactive than air. The filament glows more brightly. The filament lasts for a longer time.

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10 25 Which element is likely to be a transition metal? melting point in oC A B C D 98 328 651 1240 density in g / cm3 1.0 11.3 1.7 7.4 colour of oxide white yellow white black

26 Three metals are extracted as shown in the table. metal X Y Z method of extraction electrolyse molten metal oxide heat metal oxide with carbon occurs naturally as the metal

What is the order of reactivity of the metals? most reactive A B C D X X Y Z Y Z Z X least reactive Z Y X Y

27 Haematite is reduced to iron in the blast furnace. haematite + carbon monoxide iron + X What is X? A B C D carbon carbon dioxide hydrogen oxygen

28 Which object is least likely to contain aluminium? A B C D a bicycle frame a hammer a saucepan an aeroplane body
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11 29 A sample of clean, dry air is passed over hot copper until all the oxygen in the air reacts with the copper.
clean dry air copper

heat

The volume of air decreases by 30 cm3. What was the starting volume of the sample of air? A 60 cm3 B 100 cm3 C 150 cm3 D 300 cm3

30 The pH of some aqueous sodium hydroxide is measured. The solution is then distilled as shown.

thermometer

flask NaOH(aq)

heat

distillate collected

How do the pH values of the distillate and of the solution left in the flask compare with the original? pH of the distillate A B C D pH of the solution left in the flask higher lower higher lower

higher higher lower lower

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12 31 Which two gases produced from the burning of petrol in motor vehicles contribute to the formation of acid rain? A B C D carbon dioxide and carbon monoxide carbon monoxide and sulphur dioxide carbon monoxide and nitrogen dioxide nitrogen dioxide and sulphur dioxide

32 An old railway carriage is being restored. Metal strips are secured on to the outside of the wooden carriage by means of screws. After a few weeks open to the wind and rain, the screws are heavily corroded but the metal strips are not.
metal strip metal screw

wood

Aluminium is more reactive than both steel and copper. Which two metals would give this result? screws A B C D aluminium copper copper steel strips steel aluminium steel aluminium

33 The diagram shows how oxygen is used in welding.

gas, X flame

oxygen, O2

What is gas X? A B C D acetylene argon neon nitrogen

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13 34 The diagrams show the growth of four plants.

before treatment

after treatment

NH4Cl(aq)

(NH4)2SO4(aq)

NaNO3(aq)

Na2SO4(aq)

Which element is acting as a fertiliser? A Cl B N C Na D S

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14 35 Gas is released in all of the examples below.

WINE

acid rain on a limestone statue

a candle burning

a dog panting

fermenting grapes

Which gas do they all produce? A B C D carbon dioxide hydrogen methane oxygen

36 What is formed when calcium carbonate is heated? A B C D calcium and carbon calcium and carbon dioxide calcium oxide and carbon calcium oxide and carbon dioxide

37 Which compound contains three elements? A B C D ethanol ethene methane poly(ethene)

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15 38 Four fractions obtained from crude oil (petroleum) are listed below. Which fraction is paired with a correct use? fraction A B C D bitumen diesel lubricating paraffin use making waxes fuel for aircraft making roads fuel for oil stoves

39 The structures of three compounds are shown.

H C H H C H H H C H H C C H H C H H H H C H H C H H C C H H C H H C H H

Why do these substances all belong to the same homologous series? A B C D They all contain an even number of carbon atoms. They all contain the same functional group. They are all hydrocarbons. They are all saturated.

40 The table shows some suggested reactions involving ethanol. Which suggestions about the reactants and products are correct? reaction A B C D reactants ethanol and oxygen ethene and steam glucose and oxygen glucose and water products carbon dioxide and water ethanol and hydrogen ethanol and carbon dioxide ethanol and oxygen

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DATA SHEET The Periodic Table of the Elements

Group III
1

I H
Hydrogen

II

IV

VI

VII

0
4

He
Helium

1 11 12 14 16 19

2 20

Li
Boron Carbon

Be
5 27 28 6 7 31

N
Nitrogen

O
Oxygen

F
Fluorine

Ne
Neon

Lithium

Beryllium

8 32

9 35.5

10 40

23

24

Na
Aluminium

Mg
13 51 52 55 56 59 59 64 65 70 14 73

Al Si

P
Phosphorus

S
Sulphur

Cl
Silicon Chlorine

Ar
Argon

Sodium

Magnesium

11

12

15 75

16 79

17 80

18 84

39

40

45

48

K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc

Ca
24 93 96 101 103 106 108 112 25 26 27 28 29 30 31

Sc

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn

Ga
Gallium

Ge
Germanium

As
Arsenic

Se
Selenium

Br
Bromine

Kr
Krypton

Potassium

Calcium

Scandium

Titanium

19

20

21

22

23

32 115 119

33 122

34 128

35 127

36 131

16

85

88

89

91

University of Cambridge International Examinations is part of the University of Cambridge Local Examinations Syndicate (UCLES) which is itself a department of the University of Cambridge.

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Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver

Sr
42 181 184 186 190 192 195 197 43 44 45 46 47 48

Zr

Nb

Mo

Tc

Ru

Rh

Pd

Ag

Cd
Cadmium

In
Indium

Sn
Tin

Sb
Antimony

Te
Tellurium

I
Iodine

Xe
Xenon

Rubidium

Strontium

Yttrium

Zirconium

37

38

39

40

41

49 201 204

50 207

51 209

52

53

54

133

137

139

178

Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum

Ba
74 77 75 76 78 79

La Ta W Re Os Pt

Hf

Ir

Au
Gold

Hg
Mercury

Tl
Thallium

Pb
Lead

Bi
Bismuth

Po
Polonium

At
Astatine

Rn
Radon

Caesium

Barium

Lanthanum

Hafnium

55

56

57

72

73

80

81

82

83

84

85

86

226

227

Fr
140 141 144 150

Ra

Ac
152 157 159 162 165 167 169 173 175

Francium

Radium

Actinium

87

88

89

*58-71 Lanthanoid series 90-103 Actinoid series Ce

Cerium Praseodymium Neodymium Promethium

Pr
59 60 238 61

Nd

Pm
62

Sm
Samarium

Eu
Europium

Gd
Gadolinium

Tb
Terbium

Dy
Dysprosium

Ho
Holmium

Er
Erbium

Tm
Thulium

Yb
Ytterbium

Lu
Lutetium

58 232

63

64

65

66

67

68

69

70

71

a = relative atomic mass

Key Th
Thorium Protactinium Uranium

X Pa
91 92

X = atomic symbol
90

U
93

Np
Neptunium

Pu
Plutonium

Am
Americium

Cm
Curium

Bk
Berkelium

Cf
Californium

Es
Einsteinium

Fm
Fermium

Md
Mendelevium

No
Nobelium

Lr
Lawrencium

b = proton (atomic) number

94

95

96

97

98

99

100

101

102

103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).