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CONFIDENTIAL 4541/3 Chemistry Paper 3 September 2013 1 hours MAKTAB RENDAH SAINS MARA SIJIL PELAJARAN MALAYSIA TRIAL EXAMINATION 2013

CHEMISTRY Paper 3 One hour and thirty minutes

DO NOT OPEN THIS QUESTION BOOKLET UNTIL BEING TOLD TO DO SO

1.

Write down your name and class in the space provided

Tuliskan nama dan kelas anda pada ruang yang disediakan.

For Examiners Use Question Full Mark 18 15 17 50 Mark

2. 3.

The question booklet is bilingual.

Buku soalan ini adalah dalam dwibahasa .

1 Candidates are required to answer all questions.

Calon dikehendaki soalan menjawab semua

2 3 Total

This question booklet has 10 printed pages and 2 unprinted pages

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For Examiners Use Answer all Questions

Jawab semua soalan

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1 Diagram 1.1 shows the apparatus set-up for an experiment to study the hardness of pure copper by using 1.0 kg weight.
Rajah 1.1 menunjukkan susunan radas bagi eksperimen untuk mengkaji kekerasan kuprum tulen dengan menggunakan pemberat 1.0 kg.

Meter rule
Pembaris meter

Thread
Benang

Weight
Pemberat

Retort stand
Kaki retot

Steel ball bearing

Bebola keluli

Cellophane tape
Pita pelekat

Copper block
Blok kuprum

Diagram 1.1
Rajah 1.1

The experiment was carried out according to the following steps:

Eksperimen telah dijalankan seperti langkah-langkah berikut:

Step 1 Step 2

: A steel ball bearing is taped onto a copper block. : A 1 kg weight is hung at a height of 50 cm above the copper block as shown in Diagram 1.1.

Langkah 1 : Bebola keluli dilekatkan di atas blok kuprum.

Langkah 2 : 1 kg pemberat digantung pada ketinggian 50 cm di atas blok kuprum seperti ditunjukkan di dalam Rajah 1.1

Step 3 Step 4 Step 5

: The weight is allowed to drop onto the steel ball bearing. : The diameter of the dent made on the copper block is measured. : Steps 1 to 4 are repeated on two other parts of the copper block in order to obtain an average value for the diameter of dents formed.

Langkah 3 : Pemberat dijatuhkan ke atas bebola keluli

Langkah 4 : Diameter lekuk yang terbentuk di atas blok kuprum diukur.

Langkah 5 : Langkah 1 hingga 4 diulangi di atas dua bahagian lain di permukaan blok kuprum untuk memperoleh nilai purata bagi diameter lekukan yang terhasil.

Step 6

: Steps 1 to 5 are repeated by replacing the copper block with bronze block.

Langkah 6 : Langkah 1 hingga 5 diulangi dengan menggantikan blok kuprum dengan blok gangsa.

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Table 1. 2 shows the recorded diameter of dents formed on the blocks.

Jadual 1.2 menunjukkan rekod bacaan diameter lekuk yang terhasil di atas kedua-dua blok.

For Examiners Use

Type of block
Jenis blok

Diameter of dents / mm
Diameter lekuk / mm

Average diameter of dent / mm

Purata diameter lekuk / mm

I 3.60 2.50

II 3.50 2.45

III 3.70 2.55 Table 1.2

Jadual 1.2

Copper
Kuprum

3.50 2.50

Bronze
Gangsa

(a)

Complete Table 1.3 based on the experiment.

Lengkapkan Jadual 1.3 berdasarkan eksperimen ini.

Type of variables
Jenis pemboleh ubah

Action to be taken
Tindakan untuk diambil

(i)

Manipulated variable :
Pemboleh ubah dimanipulasikan:

(ii)

Method to manipulate variable :

Cara memanipulasikan pemboleh ubah:

. . (iii) Responding variable :

Pemboleh ubah bergerak balas:

..... ........................ (iv) What to observe in the responding variable :

Apa yang diperhatikan bagi pemboleh ubah bergerak balas

. . (v) Controlled variable :

Pemboleh ubah yang dimalarkan:

..... ........................ Method to maintain the controlled variable :

Cara menetapkan pemboleh ubah yang dimalarkan:

(vi)

....................................................

..... 1(a) ............................. Table 1. 3

Jadual 1.3

[6 marks] (b) State the hypothesis for this experiment.

Nyatakan hipotesis untuk eksperimen ini.

1(b)

[3 marks]
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For Examiners Use 1(c)

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(c)

Based on the data in Table 1.2, state the inference of the experiment.
Berdasarkan data dalam Jadual 1.2, nyatakan inferens bagi eksperimen tersebut .

.. 3 .. [ 3 marks] (d) 1(d) Based on the experiment, state the operational definition for alloy.
Berdasarkan eksperimen, nyatakan definisi secara operasi bagi aloi.

.. ..........................

.......................................................................................................................................... [ 3 marks] (e) Diagram 1.4 shows a few materials.

Rajah 1.4 menunjukkan beberapa bahan.

Duralumin
Duralumin

Magnesium
Magnesium

Tin
Timah

Cupronickel
Kupronikel

Brass
Loyang

Mercury
Merkuri

Diagram 1.4
Rajah 1.4

Classify the materials into metals and alloys by completing the Table 1.5.
Kelaskan bahan-bahan itu kepada logam dan aloi dengan melengkapkan Jadual 1.5

Metals
Logam

Alloys
Aloi

1(e)

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Table 1.5
Jadual 1.5

[3 marks]

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Diagram 2.1 shows the apparatus set-up to construct the Electrochemical Series. The voltage produced when copper and magnesium electrodes are dipped into the copper(II) sulphate solution is measured. The experiment is repeated by replacing magnesium with aluminium and zinc.
Rajah 2.1 menunjukkan susunan radas yang digunakan untuk membina Siri Elektrokimia. Voltan yang dihasilkan apabila elektrod kuprum dan magnesium dicelup ke dalam larutan kuprum (II) sulfat diukur. Eksperimen ini diulangi dengan menggantikan magnesium dengan aluminium dan zink .

For Examiners Use

Magnesium
Magnesium

Copper
Kuprum

Copper(II) sulphate solution

Larutan kuprum(II) sulfat

Diagram 2.1
Rajah 2.1

( a)

Diagram 2.2 shows the readings of three voltmeters each using different metals paired with copper.
Rajah 2.2 menunjukkan tiga bacaan voltmeter yang menggunakan logam berlainan berpasangan dengan kuprum.

Copper and Magnesium

Kuprum dan magnesium

Copper and zinc

Kuprum dan zink

Copper and aluminium

Kuprum dan aluminium

Diagram 2.2
Rajah 2.2

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For Examiners Use

Based on Diagram 2.2, record the voltmeter readings in Table 2.3

Berdasarkan kepada Rajah 2.2, rekodkan bacaan voltmeter dalam Jadual 2.3

Pair of metals
Pasangan logam

Negative Terminal
Terminal negatif

Voltage/ V
Voltan /V

Cu and Mg Cu and Zn 2(a) Cu and Al

Magnesium Zinc Aluminium Table 2.3

3 (b)

Jadual 2.3

[3 marks] Based on Table 2.3 , state the relationship between the voltage and the position of the metals in the Electrochemical Series.
Berdasarkan Jadual 2.3 , nyatakan hubungan antara bacaan voltan dan kedudukan logamlogam dalam Siri Elektrokimia.

2(b)

. ..............

.............................................................................................................................. [ 3 marks]
(c ) Based on the voltmeter readings, arrange aluminium, copper, magnesium and zinc in ascending order of tendency to release electrons.
Berdasarkan bacaan voltmeter, susunkan aluminium, kuprum, magnesium dan zink mengikut kecenderungan menderma elektron dalam turutan menaik.

2(c)
Tendency to release electron increases

3
( d)

Kecenderungan menderma elektron bertambah

[3 marks]
The experiment is repeated using the pair of metals; magnesium and zinc. Predict the voltmeter reading.
Eksperimen ini diulangi dengan menggunakan pasangan logam; magnesium dan zink. Ramalkan bacaan voltmeter.

2(d)

.................... [3 marks]

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(e)

The experiment is repeated using two copper electrodes dipped in copper(II) sulphate solution. The voltmeter does not show any reading. Explain why.
Eksperimen diulangi menggunakan dua elektrod kuprum yang dicelup ke dalam larutan kuprum(II) sulfat. Voltmeter tidak menunjukkan sebarang bacaan. Terangkan mengapa.

For Examiners Use

2(e)

....................................................................................................................... ....................................................................................................................... [3 marks] 3

Total 2 15
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Diagram 3.1 shows a conversation between two students about the solubility of an ionic compound in water and organic solvents.
Rajah 3.1 menunjukkan perbualan di antara dua orang pelajar mengenai keterlarutan sebatian ion di dalam air dan pelarut organik.

I tested the solubility of a white solid in water. I observed that the white solid disappeared. A colourless solution was formed
Saya telah menguji keterlarutan pepejal putih di dalam air. Saya dapati pepejal putih tidak kelihatan lagi. Satu larutan tanpa warna terhasil.

I tested the solubility of the white solid in cyclohexane. I didnt see any change. The white solid still remained.
Saya telah menguji keterlarutan pepejal putih itu di dalam sikloheksana. Saya mendapati tiada perubahan. Pepejal putih masih kelihatan.

Diagram 3.1
Rajah 3.1

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Based on the situation, plan a laboratory experiment to study the solubility of an ionic compound in water and organic solvent.
Berdasarkan situasi tersebut, rancangkan satu eksperimen makmal untuk mengkaji keterlarutan sebatian ionik dalam air dan pelarut organik.

Your planning should include the following aspects:

Perancangan anda hendaklah mengandungi aspek-aspek berikut

(a)

Problem statement
Penyataan masalah

(b)

All the variables.

Semua pemboleh ubah.

(c)

Statement of the hypothesis

Pernyataan hipotesis

(d)

Lists of materials and apparatus

Senarai bahan dan radas

(e)

Procedure for the experiment

Prosedur eksperimen

(f)

Tabulation of data
Penjadualan data

[17 marks]

END OF QUESTION PAPER

KERTAS SOALAN TAMAT

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INFORMATION FOR CANDIDATES

MAKLUMAT UNTUK CALON

1. 2.

This question paper consists of three questions. Answer all questions.

Kertas soalan ini mengandungi tiga soalan. Jawab semua soalan.

Write your answers for Question 1 and Question 2 in the spaces provided in this question paper.
Tulis jawapan anda bagi Soalan 1 dan Soalan 2 pada ruang yang disediakan dalam kertas soalan ini.

3. 4. 5. 6. 7.

Write your answers for Question 3 on the answer sheet provided.

Tuliskan jawapan bagi Soalan 3 pada kertas jawapan yang dibekalkan.

Show your working, it may help you to get marks.

Tunjukkan kerja mengira, ini membantu anda mendapatkan markah.

The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukis mengikut skala kecuali dinyatakan.

The marks allocated for each question or sub-part of a question are shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam kurungan.

If you wish to change your answer, cross out the answer that you have done. Then write down the new answer.
Jika anda hendak menukar jawapan, batalkan jawapan yang telah dibuat. Kemudian tulis jawapan yang baru.

8. 9.

You may use a scientific calculator.

Anda dibenarkan menggunakan kalkulator saintifik.

You are advised to spend 1 hour to answer Question 1 and Question 2 and 30 minutes for Question 3.
Anda dinasihati supaya mengambil masa 1 jam untuk menjawab Soalan 1 dan Soalan 2 dan 30 minit untuk Soalan 3.

10.

Hand in all your answer sheets at the end of the examination.

Serahkan semua kertas jawapan anda di akhir peperiksaan.

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