Chapter II

EXPERIMENT
II.1.

Variable :
Concentration acetic acid

II.2.

Equipment
1. A set of distillation equipment.
2. Erlenmeyer.
3. Beaker glass.
4. Thermometer.
5. ASTM (Thermometer)
6. Calorimetric.
7. Pycnometer.
8. Measurement pipet.
9. Measurement glass
10. Buret and Statif
11. Measurement flask

II.3

Materials
1. Acetic acid
2. NaOH
3. Oxalic acid
4. PP Indicator
5. Aquadest.

II.4

Experiments Procedure
1. Make acetic acid solution % volume.
2. Incorporating 400 mL acetic acid solution with a concentration of %
(v / v) specific to the flask.
II-1

3. Replacing the condenser and distillate reservoir, then drain the

coolant into the condenser.
4. Turned on the heater heating mantle on track lap 9 and record the
temperature at first as he lit a stopwatch. Record the temperature
changes that occur every minute.
5. In 5 minutes in a row, analyze the volume and concentration after
equilibrium is reached which is characterized by a constant
temperature of distillate and residue.
6. Repeat steps 2-5 for concentrations.
Determination of the molar volume of the dissolving, heat of
solution, and the price of water kalorimeter:
1. Mixing a number of glacial acetic acid and akuades who have
measured the temperature initially in a kalorimeter so that when
mixed into a solution of acetic acid concentration of 6%.
2. Stir until the constant temperature is reached, release the solution
from kalorimeter and measuring denstitasnya with piknometer.
3. Repeat steps 1 and 2 for the composition of the 12 and 18%.
4. Mixing hot water and cold water with volumes each of as many as 50
mL where temperature is known in kalorimeter.
5. Stir until the temperature is constant.
II.5

Equipment Figure

II-2

II.6

Data Experiment
Environment Data
Humidity
(%)

Pressure
(mmHg)

Air Temp.
( C)

Water Temp.
( C)

88

759

31

30

Standardization NaOH with H2C2O4

Oxalic acid mass=
N H2C2O4
=

11,219 gram
1,7485 N

Table II.1 Titration Data For Standardization NaOH with H2C2O4

V NaOH (mL)
11.1
10
9,8

V H2C2O4 (mL)
10
10
10

Density Calculation
Pycnometer mass =
Pycnometer + water mass =
Pycnometer+CH3COOH 10% (feed) mass=
Pycnometer+CH3COOH 14% (feed) mass=
Pycnometer+CH3COOH 18% (feed) mass =
Pycnometer+CH3COOH 10% (Distillate) mass=
Pycnometer+CH3COOH 18% (Waste) mass =
II-3

23,77
48,82
49,23
49,27
49,43
49,11
49,24

gr
gr
gr
gr
gr
gr
gr

Heat Mixing
Hot water temperature =
Cold water temperature =
T Cold water (100 mL) + Hot water (100 mL) =

62 C
10,5 C
33 C

Heat of Dissolving
T CH3COOH =
T Water =
T CH3COOH 10% (90 mL Water) =
T CH3COOH 14 % (86 mL Water) =
T CH3COOH 18 % ( 82 mL Water) =

29
31
31
30
30

C
C
C
C
C

Table II.2 Temperature Calibration

Type of

ASTM

Termometer

Water
Cold Water
Hot Water
Water
Cool Water
Warm Water

(C)
10,5
52
30
26
38

(C)
10,5
54
31
27,5
39

T2 (C)

T1 (C)

10,4
53,3
30,6
27,4
38,4

7,5
51,4
29
25,7
36,3

Table II.3 Titration CH3COOH with NaOH

Acetic Acid

Volume (mL)
10
10
10
10
10
10
10
10
10
10
10
10
10
10

Feed

10%

Destilat

Residu
14%
Feed
Destilat

II-4

Volume NaOH (mL)

10,4
10,3
10,2
7,5
7,5
7,2
11,1
11
11
14,4
14
14
10,2
10

10
10
10
10
10
10
10
10
10
10
10
10
10

Residu

Feed

18%

Destilat

Residu

10
15,4
15,1
14,8
18,2
18,3
18,1
13,1
12,9
13,1
19
18,9
18,6

Table II.4 Acetic Acid 10%

t (minute)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23

Tliquid (C)
28,3
28,7
29,3
30
30,9
31,9
33
34
35,7
37,2
39,7
40,8
43
45,1
47,7
50,2
53
55,8
59
61,8
64,8
67,8
70,6
II-5

Tvapor (C)
29,8
30,4
30,9
31,7
32,4
33,5
34,8
36
37,3
38,9
40,6
42,5
44
46
48,4
50,1
53
55,4
56,8
59,7
62,1
62,3
63,4

24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42

67,7
76,5
79,3
81,9
84,9
87,7
93,1
92,4
94,7
97,6
99,3
99,5
99,3
99,5
99,5
99,5
99,5
99,5
99,5

65,5
69,5
73
76,7
79,5
81,7
83,6
86
89,3
91,9
96,3
100,8
100,7
100,7
100,8
100,8
100,8
100,8
100,8

Table II.5 Acetic Acid 14%

t (minute)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16

Tliquid (C)
31
31,7
32,4
33,5
34
34,9
36
37,2
38,5
40,1
41,6
43,1
44,9
46,9
48,9
51,1

II-6

Tvapor (C)
32,9
33,7
33,4
35,3
35,6
36,6
37,5
38,7
39,4
40,5
41,8
42,8
43,9
45,3
47,6
47,5

17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43

53,5
55,8
58,6
61,4
64,2
67,1
70
72,8
75,5
78,2
81
83,1
86
88,5
91
92,9
95,5
98
99,6
99,6
99,6
99,6
99,6
99,6
99,6
99,6
99,6

51,3
53,5
55,6
58,8
59,1
60,9
62,3
64,1
66,8
69,9
73,1
76,6
78,4
81
85
85,5
89,7
93,3
100,4
100,8
100,8
100,8
100,9
100,9
100,9
100,9
100,9

Table II.6 Acetic Acid 18%

t (minute)
1
2
3
4
5
6
7
8

Tliquid (C)
33,3
34
34,9
36
37
38,1
39,5
40,8

II-7

Tvapor (C)
35,4
36,1
36,6
37,5
38,1
38,8
39,1
40,1

9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40

42,5
44,3
46,6
47,8
49,9
51,9
54
56,2
58,8
61,3
63,9
67,7
69,6
72,6
75,4
78,4
81,1
84,3
86,7
89,6
91,9
94,7
97,3
99,3
99,7
99,7
99,7
99,7
99,7
99,7
99,7
99,7

II-8

40,8
40,8
45,5
46,8
48,7
51
52,8
54,9
56
58
60,5
63,3
66,2
69
72,6
75,5
78,3
81,5
85,3
87
89,9
93,1
95,5
98,1
100,8
100,9
100,8
100,9
100,9
100,9
100,9
100,9