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III B.Tech I Semester Supplementary Examinations, February 2007
CHEMICAL ENGINEERING THERMODYNAMICS-II
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
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3. (a) Define and explain partial property along with necessary equting.
(b) The partial molar volume of ethanol in a 60% ethanol-water solution is 5.5x10−6
m3 . The density of the mixture is 849.4 kg/m3 . Calculate the partial molar
volume of water in the mixture. [8+8]
4. (a) What is meant by data reduction? Explain how P − x − y data is reduced?
(b) The excess Gibbs free energy of a binary liquid mixture at T and P is given
E
by G RT
= ( 1.42x1 + 0.59x2 )x2 x1 . The vapour pressures are P1Sat = 82.37
Kpa, P2Sat = 37.31 Kpa. For given T and P, Using Margules equation find
γ1 , γ2 and γ1α , γ2α . [8+8]
5. Explain bubble T calculations with neat flowchart along with relevant equations.
[16]
6. For a mixture of 10mole % methane, zomole% ethane and 20 mole% propane at
500 F Determine the dew print pressure and the bubble point pressure. (Deprister
chart should be provided during examination). [16]
7. Name the different types of binary mixtures in terms of solubility. What are the
critical solution temperatures and the three phase temperature for a partially mis-
cible liquid solution. Show them on diagram. [16]
8. Derive an equation from the fundamentals to describe the effect of temperature on
‘K’ in terms of ∆H 0 , ∆α ∆β ∆γ etc. Discuss the practical application of above
derived equation with reference to any chemical reaction. [16]
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Code No: RR310802 Set No. 1
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Code No: RR310802 Set No. 2
III B.Tech I Semester Supplementary Examinations, February 2007
CHEMICAL ENGINEERING THERMODYNAMICS-II
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆
1. (a) Calculate the heat required to raise the temperature of 1 mol of methane
from 2600 C to 6000 C in steady flow process at a pressure sufficiently low that
methane may be considered an ideal gas. Given the data,
A = 1.702, B = 9.081x10−3 , and C = 2.164 x 10−6
(b) For steady flow in a heat exchanger at appropriate atmospheric pressure, what
is the final temperature?
i. When 10 mol of SO2 is heated from 200 to 1,1000 C? A=47.381, B=66×
10−3 ; C=1.1×10−9 .
ii. When 12 mol of propane is heated from 250 to 1, 2000C? A= - 4.798,
B=0.307, C= -0.16×10−3. [8+8]
2. Calculate the theoretical flame temperature of gas mixture consisting of 20% CO
and 80% N2 when burned with 100% excess air, both air and gas initially being at
298K. The standard heat of reaction at 298K is -293.178 J/mol. The Heat capacity
(J/mol.K) are given by Cp = a+bT +CT 2 . [16]
a b∗103 c∗106
CO2 26.54 42.45 -14.298
O2 25.61 13.26 -4.208
N2 27.03 5.815 -0.289
∧ ∧
3. Derive the expressions for φ1 and φ2 in a binary liquid mixture system. [16]
4. (a) Show that the partial molar mass of a species in a solution is equal to its molar
mass (molecular weight).
(b) The excess Gibbs free energy of a binary liquid mixture at T and P is given
E
by G
RT
= ( -2.6 x1 -1.8x2 )x2 x1 . For the given T and P, find lnγ1 . and lnγ2 .
(c) Define acitivity and activity coefficient. [4+8+4]
5. (a) Discuss the Phase behavior for Vapor / Liquid systems.
(b) Discuss about Retrograde Condensation. [10+6]
6. Calculate the fraction of liquid, liquid composition and vapor composition in a two
phase system consisting of acetone
acetonitrile - nitromethane at 800 C and 110 Kpa. The overall composition of the
mixture is Z=0.45, Z=0.35 and Z=0.2. The vapor pressures of the components (1),
(2) and are 195.8 Kpa, 97.84 Kpa and 50.32 Kpa respectively. [16]
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Code No: RR310802 Set No. 2
7. Show three types of constant pressure liquid-liquid solubility diagram with proper
labeling. What do you mean by upper and lower consolute temperature. [16]
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Code No: RR310802 Set No. 3
III B.Tech I Semester Supplementary Examinations, February 2007
CHEMICAL ENGINEERING THERMODYNAMICS-II
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆
1. (a) Calculate the heat required to raise the temperature of 1 mol of methane
from 2600 C to 6000 C in steady flow process at a pressure sufficiently low that
methane may be considered an ideal gas. Given the data,
A = 1.702, B = 9.081x10−3 , and C = 2.164 x 10−6
(b) For steady flow in a heat exchanger at appropriate atmospheric pressure, what
is the final temperature?
i. When 10 mol of SO2 is heated from 200 to 1,1000 C? A=47.381, B=66×
10−3 ; C=1.1×10−9 .
ii. When 12 mol of propane is heated from 250 to 1, 2000C? A= - 4.798,
B=0.307, C= -0.16×10−3. [8+8]
2. Methane is burned with 20% excess air, both methane and air being at 298K.
The standard heat of combustion of methane at 298K is (-802.625) kJ. The heat
capacities (J/mol.K) are:Cp =a+bT+cT 2 .
a b ∗103 c ∗106
Cp (CH4 ) 14.15 75.499 -17.9915
Cp (O2 ) 30.255 4.207 -1.8873
Cp (N2 ) 27.27 4.930 3.3256
Cp (CO2 ) 45.369 8.688 9.6193
Cp (H2 O) 28.850 12.055 1.006
Calculate the adiabatic flame temperature attained. [16]
3. (a) Define and explain partial property along with necessary equting.
(b) The partial molar volume of ethanol in a 60% ethanol-water solution is 5.5x10−6
m3 . The density of the mixture is 849.4 kg/m3 . Calculate the partial molar
volume of water in the mixture. [8+8]
4. (a) Show that the partial molar mass of a species in a solution is equal to its molar
mass (molecular weight).
(b) The excess Gibbs free energy of a binary liquid mixture at T and P is given
E
by G
RT
= ( -2.6 x1 -1.8x2 )x2 x1 . For the given T and P, find lnγ1 . and lnγ2 .
(c) Define acitivity and activity coefficient. [4+8+4]
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Code No: RR310802 Set No. 3
compressed till the mixture condenses. Determine the pressures at which
condensation begins and terminates and also the compositions of the vapor
and liquid phases. The saturation pressures of A and B at 100 C are 120 Kpa
and 150 Kpa, respectively. [6+10]
[16]
8. Consider the reaction C4 H4 (g)→C4 H6 (g) + H2 (g). the standard free energy change
is given by:
∆G0T = 24,760 − 5.01T ln T + 3.09T
where ∆G0T is in J / mol butene and T is in K.
(a) Over what range of temperature is the reaction promising from a thermody-
namic viewpoint?
(b) For reaction of pure butene at 800 K, calculate the equilibrium conversion for
operation at 1 and 5 atm total pressure, assuming ideal gases.
(c) Repeat part (b) at 1 atm for a feed of 50 mol % butene and 50 mol % inert
gas and compare the results. [6+5+5]
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Code No: RR310802 Set No. 4
III B.Tech I Semester Supplementary Examinations, February 2007
CHEMICAL ENGINEERING THERMODYNAMICS-II
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆
1. (a) What are various empirical relations to calculate latent heat accompanying a
phase change?
(b) How can you calculate the latent heat of vaporization at some temperature
from the knowledge of its value at a single temperature?
(c) Write short notes on effect of temperature on heat capacity for gaves. [6+4+6]
a b∗103 c∗106
CO2 26.54 42.45 -14.298
O2 25.61 13.26 -4.208
N2 27.03 5.815 -0.289
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Code No: RR310802 Set No. 4
7. Why does Immiscibility occur in liquid solution. How would you estimate the
composition of the vapor phase in equation with two immiscible liquid phase?[16]
8. Calculate the dissociation pressure of Ag2 O at 2000 C use the following data:
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