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ESPECTROSCOPA INFRARROJA
Hermenegildo Garca Gmez Departamento de Qumica Instituto de Tecnologa Qumica Universidad Politcnica de Valencia 46022 Valencia E-mail: hgarcia@qim.upv.es Telephone: +34 96 387 7807 or ext. 78572/73441 Fax: + 34 96 387 7809
ESPECTROSCOPA DE INFRARROJOS
- Niveles vibracionales dentro de un nivel electrnico - Diferencia de energa mucho menor - Hace falta onda con frecuencia ms pequea
- A molecule contains two or more atoms and several bonds - The position of each atom is indicated by three coordinates - If we have n atoms we need 3n coordinates - Three degrees of freedom are wasted in translation - Degree of freedom for vibration: 3n-3
x A A y A z A x B B y B z B x C C yC z C
1- A molecule may contain many atoms and bonds. In reality a vibration is not located in a single bond or group of atoms, but
2- In a simplified model, the rest of the molecule can be considered as having infinite mass.
3- The conclusion of the previous point is that each covalent bond has specific absorptions irrespective of the rest of the molecule.
H2O
CO
CH2
HYDROGEN BOND
1- All the covalent bond has a typical wavenumber irrespective of the concentration at which the IR spectrum is recorded.
FH Cl H
Hydrogen bonded to an electronegative element
R OH R NH |
3- The intensity of the hydrogen bond depends on the difference of electronegativity on other inductive effects
HYDROGEN BONDS
1.
density =
+d volume
FOTMETRO
ALCANOS
A: CH2 and CH3 symmetric and asymmetric stretching B: CH2 bending. Sharp peak at 1370 cm-1 corresponds to CH3; C: rocket band
ALQUENOS
A: CH2 and CH3 asymmetric and symmetric stretching B: CH2 bending. With several CH3 at 1370 cm-1
A: C-H stretching. Above 3000 cm-1 C-H (sp2); below 3000 cm-1 C-H (sp3) B: CH2=CH stretching vibration. Not visible in symmetric alkenes C: CH2 bending + CH3 D: CH2=C bending
ALQUINO
ALCOHOLES
TER
COMPUESTOS CARBONLICOS
PROBLEMA 2
PROBLEMA 3
PROBLEMA 4
PROBLEMA 5
PROBLEMA 6
PROBLEMA 7
PROBLEMA 8
PROBLEMA 9
PROBLEMA 10
PROBLEMA 11
PROBLEMA 12
PROBLEMA 13
PROBLEMA 14
PROBLEMA 15
PROBLEMA 16
PROBLEMA 17
PROBLEMA 18
PROBLEMA 19
PROBLEMA 20
PROBLEMA 21
PROBLEMA 22
PROBLEMA 23
PROBLEMA 24