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MATERIAL SAFETY DATA SHEET

24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE CHEMTREC: 800-424-9300 TRANSPORT MURPHY: 870-862-6411 800-441-3637 MEDICAL ----------------------------------------------------------------------------------------------------------------------------------SECTION 1: IDENTIFICATION PRODUCT NAME: Condensate SYNONYMS: Natural Gasoline; Casinghead Gasoline

CHEMICAL NAME: Natural Gas Condensate CHEMICAL FAMILY: Petroleum Hydrocarbon ----------------------------------------------------------------------------------------------------------------------------------SECTION II: GENERIC COMPOSITION / COMPONENTS OSHA PERMISSIBLE EXPOSURE LIMIT/ COMPONENT CAS# _% ACGIH THRESHOLD LIMIT VALUE Natural Gas Condensate 64741-47-5 100 Gasoline TLV: 300 ppm, STEL: 500 ppm Naturally occurring components include: Benzene PEL: 1 ppm, STEL: 5 ppm TLV: 0.5 ppm, STEL: 2.5 ppm Hydrogen Sulfide 7783-06-4 <1 PEL: Ceiling 20 ppm TLV: 10 ppm, STEL: 15 ppm ----------------------------------------------------------------------------------------------------------------------------------SECTION III: SUMMARY OF HAZARDS 71-43-2 <5

DANGER! FLAMMABLE LIQUID AND VAPOR. MAY CONTAIN HYDROGEN SULFIDE MAY BE FATAL IF INHALED. MAY CAUSE DELAYED LUNG INJURY. CAN CAUSE NERVOUS SYSTEM DEPRESSION. ASPIRATION HAZARD IF SWALLOWED, CAN ENTER LUNGS AND CAUSE DAMAGE. CANCER HAZARD, CONTAINS BENZENE. CAN CAUSE KIDNEY, LIVER AND BLOOD DISORDERS. Keep away from heat, sparks and flame. Avoid breathing vapor. Use ventilation adequate to keep vapor below recommended exposure limits. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. NFPA HAZARD RATING: LEAST-0; SLIGHT-1; MODERATE-2; HIGH-3; EXTREME-4 HEALTH 1 FLAMMABILITY 3 REACTIVITY __0__ -----------------------------------------------------------------------------------------------------------------------------------

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SECTION IV:

PHYSICAL / CHEMICAL DATA

BOILING POINT <80->300 F SPECIFIC GRAVITY (60/60F) (H20=1) 0.5-0.97 VAPOR DENSITY (AIR=1) 3-4 VAPOR PRESSURE, Reid (100F) 0.6-15 VOLATILES BY VOLUME <50 SOFTENING POINT, C (F) _N/A___ SOLUBILITY IN H20 (% BY WT) Negligible EVAPORATION RATE (BUTYL ACETATE=1) >1___ APPEARANCE AND COLOR Clear, colorless, to yellow or dark brown liquid. ODOR May range from mild sweet aromatic odor to pungent odor to offensive or strong sulfurous odor. ----------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE AND EXPLOSIVE HAZARDS AUTOIGNITION: 500-850F LEL 0.9 UEL _7.6

FLASH POINT/METHOD: 45F Min./TCC FLAMMABLE LIMITS (% VOLUME IN AIR):

SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS: Use dry chemical, carbon dioxide, or foam as extinguishing media. Water may be ineffective to extinguish flame but is to be used to keep fire exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from areas of potential exposure. Prevent runoff from fire control or dilution from entering sewers or waterways. UNUSUAL FIRE AND EXPLOSIVE HAZARDS: Vapors heavier than air could travel, be ignited by other ignition sources and flash back. Products of combustion may contain carbon dioxide, carbon monoxide and various hydrocarbon compounds. Do not enter enclosed or confined space without a self contained breathing apparatus and other protective equipment. STORAGE: Keep container grounded, tightly closed and away from heat and strong oxidizers (NFPA Class IB Flammable). Do not store with strong oxidizers. Empty containers may contain product residue, which could produce flammable or explosive vapors. ----------------------------------------------------------------------------------------------------------------------------------SECTION VI: HEALTH HAZARD AND FIRST AID INFORMATION PRIMARY ROUTES OF EXPOSURE / ENTRY: SKIN / INHALATION ACUTE EXPOSURE SYMPTOMS: SKIN CONTACT: Irritation

INHALATION: May cause headache, nasal and respiratory irritation, nausea, drowsiness, breathlessness, fatigue, central nervous system depression, convulsions and loss of consciousness.
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Hydrogen sulfide paralyzes the respiratory system rapidly causing unconsciousness and death; may cause loss of sense of smell; immediately dangerous to life concentration is 700 ppm. EYE CONTACT : Irritation. INGESTION: Possible burning of mouth and gastrointestinal disturbances. May cause vomiting and diarrhea, depression of the central nervous system, sedation, coma, pneumonitis, pulmonary edema. CHRONIC EXPOSURE SYMPTOMS: SKIN: Drying, cracking, redness, itching, burning, or inflammation of skin (Dermatitis).

INHALATION: May cause respiratory tract irritation, central nervous system, kidney, liver and blood disorders. Benzene has been classified as a carcinogen, and may produce blood disorders including anemia and leukemia. API studies on unleaded gasoline vapors indicated unleaded gasoline may be carcinogenic to laboratory animals. AGGRAVATED MEDICAL CONDITIONS: Pre-existing skin, kidney, liver and blood disorders. NOTE TO PHYSICIAN: THIS IS A LOW VISCOSITY MATERIAL. HIGH POSSIBILITY OF PULMONARY ASPIRATION, POSSIBLY PRODUCING LIPOID PNEUMONIA IF SWALLOWED AND VOMITING OCCURS. IF NECESSARY, USE CAREFUL GASTRIC LAVAGE WITH TIGHT FITTING, CUFFED ENDOTRACHEAL TUBE. HEALTH HAZARD CLASSIFICATION: CORROSIVE NO IRRITANT YES SENSITIZER HIGHLY TOXIC NO TOXIC YES 0.3 to 8 OZ. MAY BE LETHAL ORAL DOSE FOR 150 LB. HUMAN. NO

PRODUCT LISTED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY: NTP NO IARC NO OSHA NO FIRST AID PROCEDURES: SKIN CONTACT: Immediately remove contaminated clothing and wash skin with soap and water. Launder clothing before wearing again. Get medical attention promptly. INHALATION: Remove exposed person to fresh air. If breathing has stopped, perform artificial respiration. Get medical attention promptly. EYE CONTACT: Immediately flush eyes for a minimum of 15 minutes, occasionally lifting the lower and upper lids. Get medical attention promptly. INGESTION: Do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call physician immediately.
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SECTION VII:

REACTIVITY DATA X Unstable

STABILITY: Stable

CONDITIONS AND MATERIALS TO AVOID: Undue exposure to air, oxidizing materials, all sources of ignition. Material is incompatible with strong acids and caustics. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION: Not Applicable

----------------------------------------------------------------------------------------------------------------------------------SECTION VIII: SPILL OR LEAK PROCEDURES PROCEDURES IF MATERIAL IS SPILLED: Material is flammable. Remove all sources of ignition. Advise National Response Center (1-800-424-8802) if spill enters a watercourse. -SMALL SPILLS: Take up with non-combustible absorbent material. Place into containers for later disposal. -LARGE SPILLS: Contain spill immediately in smallest possible area (ex. earthen dikes). Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Control ignition sources around spill area. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing materials to sanitary sewers. WASTE DISPOSAL: Recycle as much of the recoverable product as possible. It is the responsibility of the user to determine if the material is a hazardous waste at the time of disposal. Treatment, storage, transportation and disposal must be in accordance with applicable federal, state, and local regulations. ----------------------------------------------------------------------------------------------------------------------------------SECTION IX: SPECIAL PROTECTION INFORMATION VENTILATION REQUIREMENTS: Use sufficient ventilation to maintain air concentrations below regulatory limits. Select appropriate NIOSH approved respiratory protection where necessary (determined by potential exposure and published respiratory protection factors). For unknown concentration or fire fighting use self-contained breathing apparatus with positive pressure. PERSONAL PROTECTIVE EQUIPMENT: EYES: Safety glasses, chemical goggles or face shield as appropriate. SKIN: Gloves: Nitrile, neoprene or other material resistant to gasoline. Flame retardant clothing.
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ADDITIONAL PROTECTIVE MEASURES: While loading, unloading, tank gauging, etc., remain upwind. Request assistance of safety and industrial hygiene personnel to determine air concentrations. Know the location of eye wash stations and safety showers. ----------------------------------------------------------------------------------------------------------------------------------SECTION X: DEPARTMENT OF TRANSPORTATION (DOT) INFORMATION:

PROPER SHIPPING NAME GASOLINE HAZARD CLASS 3 HAZARD IDENTIFICATION NUMBER UN 1203 PLACARD FLAMMABLE PACKAGING EXCEPTIONS / RESTRICTIONS REFER TO 49CFR 172.101 PACKING GROUP II ----------------------------------------------------------------------------------------------------------------------------------SECTION XI: ENVIRONMENTAL INFORMATION SARA TITLE III: SECTION 313 - TOXIC CHEMICALS COMPONENTS Benzene Toluene Xylene Cyclohexane Ethylbenzene Cumene 1,2,4 Trimethylbenzene Napthalene SECTION 311 - HAZARD CATEGORIES SUDDEN PRESSURE RELEASE NO FIRE HAZARD ACUTE (IMMEDIATE HEALTH HAZARD) YES CHRONIC (DELAYED HEALTH HAZARD) YES SECTION 304 - EXTREMELY HAZARDOUS SUBSTANCES Hydrogen Sulfide CAS 7783-06-4 <1% RQ-100 TOXIC SUBSTANCES CONTROL ACT, 40 CFR 710 This material is listed on the TSCA inventory of chemical substances. YES REACTIVITY NO CAS# 71-43-2 108-88-3 1330-20-7 110-82-7 100-41-4 98-82-8 95-63-6 91-20-3 _% <2 <3 <6 <1 <1 <1 <1 <1

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RESOURCE CONSERVATION AND RECOVERY ACT, 40 CFR 261 This material is not listed but is subject to characteristic testing if discarded or spilled. If it tests hazardous, 40 CFR 262-266 and 268 may apply. CLEAN WATER ACT: Under Section 311(b)(4) of CWA, discharges of crude oil and petroleum products that may cause a film or sheen upon or discoloration of the water surface or adjoining shoreline must be immediately reported to the National Response Center (1-800-424-8802). COMPREHENSIVE, ENVIRONMENTAL, RESPONSE, COMPENSATION & LIABILITY ACT (CERCLA), SECTION 102 - HAZARDOUS SUBSTANCES: Petroleum and petroleum fractions are currently excluded from the list of CERCLA hazardous substances, by Section 101(14). ----------------------------------------------------------------------------------------------------------------------------------THIS INFORMATION RELATES ONLY TO THE MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. ALL STATEMENTS, INFORMATION, AND DATA PROVIDED ARE BELIEVED TO BE ACCURATE AND RELIABLE, BUT ARE PRESENTED WITHOUT ANY GUARANTEE, REPRESENTATION, WARRANTY, OR RESPONSIBILITY OF ANY KIND, EXPRESSED OR IMPLIED. ANY AND ALL REPRESENTATIONS AND/OR WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE SPECIFICALLY DISCLAIMED. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS AS TO THE SUITABILITY OF THE INFORMATION OR PRODUCT FOR THEIR PARTICULAR PURPOSE. NOTHING IN THIS DOCUMENT IS INTENDED AS PERMISSION, INDUCEMENT, OR RECOMMENDATION TO VIOLATE ANY LAWS OR TO PRACTICE ANY INVENTION COVERED BY EXISTING PATENTS, COPYRIGHTS OR INVENTIONS. WE DO NOT ACCEPT LIABILITY FOR ANY LOSS OR DAMAGE THAT MAY OCCUR FROM THE USE OF THIS INFORMATION. DATE OF ISSUE: November 2003 TITLE: Director, Corporate Safety & Environmental Affairs

PREPARED BY: C. L. Russell

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