The following two questions relate to the reaction between water and a complex ion of Co2+; the rate

varies with concentration as follows. (The rate has no dependence on [ 2!".# Trial ( 2 + ) [Co2+ complex"$ % &nitial rate$ % min'( (.() (*'+ +.2 (*', 2.2- (*'+ ..) (*', +.)2 (*'+ /.. (*', (.() (*'2 +.2 (*'.

0. The rate law for the reaction is rate 1 a. 22[Co2+ complex". b. 2[Co2+ complex". c. 22[Co2+ complex". d. 2[Co2+ complex"32. e. 2[Co2+ complex"2. 456789: b .. The value and units of the rate constant are: a. +.. (*+ % min'(. b. 2.- (*') % min'(. c. +.. (*+ min'(. d. 2.- (*') min'(. e. +.. (*+ %'( min'(. 456789: d (+. Consider the reaction 5!2 + !+ 5!+ + !2 ;se the data shown to determine the rate law for the reaction. Experiment ( 2 + ) a. rate 1 2[5!2" [!+" b. rate 1 2[5!2"2 [!+" [NO2] M *.2( *..+ *.2( *.)2 [O3] M *.,* *.,* *.+0 *.+0 Rate M s-1 ..+* (*'+ (.-/ (*'2 +.(0 (*'+ ..+* (*'+

c. rate 1 2[5!2" [!+"2 d. rate 1 2[5!2" e. rate 1 2[5!+" [!+"3 [5!2" [!2" (,. 4 certain reaction is studied at room temperature$ and gives a straight line plot for (3 [reactant" versus time. 7hich one of the following statements is true< a. The same reaction at a higher temperature would =ield a similar plot parallel to the original graph$ with a larger value for the ='intercept. b. The same reaction at a higher temperature would =ield a similar plot parallel to the original graph$ with a smaller value for the ='intercept. c. The reaction is second'order. d. The same reaction at a higher temperature would =ield a plot with a smaller slope than the original graph$ but with the same ='intercept. e. 4 graph of ln[reactant" versus (3time will be a straight line at both temperatures. 2(. &f an elementar= reaction is exothermic$ then a. The activation energ= for the forward reaction is smaller than that for the reverse reaction. b. The sum of activation energies gives the value of for the reaction. c. The activation energ= for the forward reaction is larger than that for the reverse reaction. d. The activation energ= for the forward reaction is positive$ and for the reverse reaction$ negative. e. The activation energ= for the forward reaction is negative$ and for the reverse reaction$ positive. 2). Consider the reaction with the mechanism shown: 25! 52!2 52!2 + 52! + 2 52! + 2 52 + 2! 2! slow fast slow

The first step is >>>>>; the second step is >>>>>; and the third step is >>>>>. a. unimolecular; unimolecular; unimolecular b. unimolecular; bimolecular; bimolecular c. bimolecular; unimolecular; bimolecular d. bimolecular; bimolecular; unimolecular e. bimolecular; bimolecular; bimolecular 2-. The rate constant for the reaction 2 &(g# 2(g# + &2(g# doubles on raising the temperature from )(* oC to )20 oC. The activation energ=$ in ?3mol$ is a. 0.+ x (*0.

b. (.- x (*0. c. /.( x (*). d. .., x (*). e. ' (./ x (*0. 456789: b @or the following three questions$ consider the following reaction mechanism: 6tep ( 2A + B 7 + 2C 6tep 2 7 + C 7 + ; + D 6tep + D + C 2 7 + B ++. The intermediates in this reaction are a. C and D. b. A and B. c. B onl=. d. 7 and B. e. There are no intermediates in this reaction. 456789: a +). The catal=sts in this reaction are a. C and D. b. A and B. c. B onl=. d. 7 and B. e. There are no catal=sts in this reaction. 456789: c +0. The rate'limiting step in this reaction is 6tep >>>>>$ because >>>>>. a. +; the last step is alwa=s the rate'limiting step b. 2; it uses a product of the first step c. 2; it is the slow step d. (; it is bimolecular e. (; the first step must occur before an= others can occur fast slow fast