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Question 1. For an equilibrium reaction

If 1.0 mole of A, 1.4 moles of B and 0.5 moles of C are placed in a 1 litre flask and allow ed to reach equilibrium, the final concentration of C is 0.75 M. Hence Kc for the reaction is : [A] [B] [C] [D] 1.00 0.75 0.5 0.25 --

Your Answ er:

Correct Answ er: C Explanation:

t=0 (moles)

1.4

0.5

0.5 + 2x

[Note V = 1L]

Question 2. Ammonium carbamate dissociates as

In a closed vessel containing ammonium carbamate in equilibrium w ith ammonia and carbon dioxide, ammonia is added such that partial pressure of NH3 now equals to three times the original total pressure. The ratio of total pressure to the original pressure now is: [A] [B] [C] [D] Your Answ er: --

Correct Answ er: C Explanation:

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t = 0 (new )

t = teq (new )

Question 3. A mixture of air at 1 atm pressure and 1500 K w as passed through an electric arc to produce NO

What fraction of O2 is converted into NO if the composition of air is N2 and O2 in the ratio of 4 : 1 ? [A] [B] [C] [D] 40% 60% 20% 80% --

Your Answ er:

Correct Answ er: D Explanation:

t=0 0.8 (Partial P)

0.2

2x

% of O2 converted into NO =

Question 4. At temperature T, a compound AB2(g) dissociated according to the reaction

With a degree of dissociation 'x' w hich is small compared to unity. The value of x is: [A]
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[B]

[C] [D] Your Answ er: --

Correct Answ er: B Explanation:

t=0 (moles)

ax

ax /2

Question 5. Melting of ice is an endothermic process and take place w ith decrease in volume because density of ice is less than that of w ater. Therefore at constant volume there is decrease in pressure. Thus increase of pressure on system at a constant

temperature w ill shift the equilibrium tow ards right i.e., it w ill cause the ice to melt. Hence in order to retain ice in equilibrium w ith w ater at the higher pressure it w ill low er the melting point or freezing point of ice.

The boiling of w ater at [A] [B] [C] [D]

is :

Spontaneous reaction Non-spontaneous reaction Chemical reaction None of these --

Your Answ er:

Correct Answ er: B Explanation: Boiling of w ater is spontaneous only at a temp. .

Question 6. Melting of ice is an endothermic process and take place w ith decrease in volume because density of ice is less than that of w ater. Therefore at constant volume there is decrease in pressure. Thus increase of pressure on system at a constant

temperature w ill shift the equilibrium tow ards right i.e., it w ill cause the ice to melt. Hence in order to retain ice in equilibrium w ith w ater at the higher pressure it w ill low er the melting point or freezing point of ice.

A liquid is in equilibrium w ith its vapours in a sealed container at constant temperature. Which of the follow ing is correct for the above equilibrium ?
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[A] [B] [C] [D]

The vapour pressure w ill fall due to sudden increase in volume The vapour pressure remains constant The vapour pressure w ill decrease w ith decreasing the volume All are correct --

Your Answ er:

Correct Answ er: B Explanation: Vapour pressure of a liquid in equilibrium w ith its vapours, remains same as long as temperature of the liquid is constant.

Question 7. Melting of ice is an endothermic process and take place w ith decrease in volume because density of ice is less than that of w ater. Therefore at constant volume there is decrease in pressure. Thus increase of pressure on system at a constant

temperature w ill shift the equilibrium tow ards right i.e., it w ill cause the ice to melt. Hence in order to retain ice in equilibrium w ith w ater at the higher pressure it w ill low er the melting point or freezing point of ice.

The yield of w ater is maximum at : [A] [B] [C] [D] High temperature and high pressure Low temperature and low pressure High temperature and low pressure Low temperature and high pressure --

Your Answ er:

Correct Answ er: A Explanation:

For more w ater to form, pressure should be high and temperature should be high.

Question 8. Statem ent : 1 For the reaction: , at the given temperature, there w ill be no effect by

addition of inert gas either at constant pressure or at constant volume. Statem ent : 2 For the reaction w here , there is no effect of inert gas either at constant volume or at constant pressure

because Kp becomes purely a number. [A] [B] [C] [D] Both Statement 1 and Statement 2 are true and Statement 2 is the correct explanation of Statement 1. Both Statement 1 and Statement 2 are true and Statement 2 is not the correct explanation of Statement 1 Statement 1 is true but Statement 2 is false Statement 1 is false but Statement 2 is true --

Your Answ er:

Correct Answ er: A Explanation: Statem ent 1 : Correct statement as Statem ent 2 :Correct statement and is the correct reason for statement 1.

Question 9.
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Statem ent : 1

When calcium carbonate is heated in a closed vessel at a definite temperature, the pressure of CO2 formed remains The concentration of pure solid remains constant through the reaction and taken as unity.

constant irrespective of the amount of calcium carbonate taken. Statem ent : 2 [A] [B] [C] [D]

Both Statement 1 and Statement 2 are true and Statement 2 is the correct explanation of Statement 1 Both Statement 1 and Statement 2 are true and Statement 2 is not the correct explanation of Statement 1 Statement 1 is true but Statement 2 is false Statement 1 is false but Statement 2 is true --

Your Answ er:

Correct Answ er: B Explanation: Statem ent 1 : Correct statement since and w ill remain const. at constant temperature.

Statem ent 2 :Correct statement but not the correct reason.

Question 10. For w hich of the follow ing reactions, the degree of dissociation cannot be calculated from the vapour density data. I. II.

III. The correct option is: [A] [B] [C] [D] I and III II and IV I and II III and IV --

IV.

Your Answ er:

Correct Answ er: A Explanation: To calculate from vapour density, there should be an increase in the gaseous number of moles.

Question 11. Consider the equilibrium in aqueous medium : We start w ith 1 mol of I2 and 0.5 mol of [A] [B] [C] [D] 1.33 2.66 2.00 3.00 -in 1.0 L flask. After equilibrium is reached, excess of AgNO3 gave 0.25 mol of yellow ppt.

(AgI), the value of equilibrium constant w ill be:

Your Answ er:

Correct Answ er: A Explanation:

t=0 (moles)

0.5

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Moles AgI =

Question 12. One mole of at 300 K is kept in a closed vessel under 1.0 atm pressure. It is heated to 600 K w hen 20% by mass of decomposes to give [A] [B] [C] [D] 1.2 atm 2.4 atm 2.0 atm 1.0 atm -. The resultant pressure is :

Your Answ er:

Correct Answ er: B Explanation: Use : to get :

t=0 (Partial P)

2x

Now ,

Question 13. Which of the follow ing changes in external conditions w ill not disturb the equilibrium state of the reaction ?

I. III.

Change in pressure Addition of catalyst

II. IV.

Change in temperature Addition of helium gas

The correct option is : [A] [B] [C] [D] I I, II I, IV I, III, IV --

Your Answ er:

Correct Answ er: D

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Explanation:

* * *

Addition of catalyst Addition of He gas at either const. P or V. Change in pressure as

Question 14. Kp/Kc for the reaction, , is: [A] [B] [C] [D] (RT) 1/2 -1 RT

Your Answ er:

Correct Answ er: C Explanation:

Question 15. The vapour density of the equilibrium mixture of the reaction: SO2Cl2 is: [A] [B] [C] [D] 33.33 35.0 30.0 66.67 -is 50. The percent dissociation of

Your Answ er:

Correct Answ er: B Explanation:

t=0 (moles)

x Also,

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Question 16. For w hich of the follow ing figures Qc > Kc .

[A]

[B]

[C]

[D]

Your Answ er:

--

Correct Answ er: A , B , D Explanation: If As Reaction moves in backw ard direction.

Question 17. Which of the follow ing is(are) correct ? [A] [B] [C] [D] The reaction quotient (Q) is constant at a given temperature When Qc < Kc , the equilibrium shifts in forw ard direction When Qc > Kc , the equilibrium shifts in backw ard direction When Qc = Kc , the reaction is in equilibrium --

Your Answ er:

Correct Answ er: B , C , D Explanation: Refer to module.

Question 18.
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In w hich of the follow ing, the position of equilibrium w ill shift tow ards forw ard reaction by adding inert gas? [A] [B] [C] [D] Your Answ er: --

Correct Answ er: A , C Explanation: Addition of inert gas shifts the reaction in a direction w here .

Question 19. For a gas phase reaction

Carried out in a vessel, the equilibrium conc. of C2H4 can be increased by: [A] [B] [C] [D] increasing the temperature decreasing the pressure removing some H2 adding some C2H6 --

Your Answ er:

Correct Answ er: A , B , C , D Explanation:

can be increased by

, removing H2,

, adding C2H6.

Question 20. For the reaction [A] [B] [C] [D] Low pressure High pressure Low temperature Catalyst -, w hich of the follow ing favour the reactants?

Your Answ er:

Correct Answ er: A , C Explanation: Reactants w ill be favoured by : .

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