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A comparison between conventional recuperative gas


turbine and hybrid solid oxide fuel cell –gas turbine
systems with direct/indirect integration
D Sánchez1*, R Chacartegui1, T Sánchez1, J Martı́nez2, and F Rosa3
1
Universidad de Sevilla, Escuela Técnica Superior de Ingenieros de Sevilla, Camino de los descubrimientos s/n, Sevilla,
Spain
2
AICIA, Camino de los descubrimientos s/n, Sevilla, Spain
3
Instituto Nacional de Técnica Aerospacial INTA, Carretera San Juan del Puerto – Matalascañas, Mazagón, Spain

The manuscript was received on 7 May 2007 and was accepted after revision for publication on 23 November 2007.

DOI: 10.1243/09576509JPE472

Abstract: Conventional recuperative micro gas turbines have a 30 per cent low heating value
(LHV) maximum efficiency at full load. Therefore, if they are to be used in a potential distributed
energy scenario, solutions must be developed that increase efficiency. An innovative gas
turbine-based technology is the fuel cell – gas turbine hybrid system. This work is aimed at
studying how the basic performance of a conventional Brayton cycle changes when heat
addition is done at a fuel cell. Two layouts are considered: a direct system where the compressor
feeds the fuel cell directly and an indirect system where only heat is transferred between
subsystems.
Direct and indirect systems have been studied at full and part load, concluding that the
efficiency versus pressure ratio curves of hybrid systems change substantially with respect to
a traditional gas turbine; part-load efficiency hardly decreases.
Maximum efficiency of hybrid systems doubles the efficiency of state of the art micro gas tur-
bine and remains high at part load. Furthermore, the benefit of a certain increase in tempera-
ture is higher for hybrid systems than for conventional engines.
Finally, a simple economic analysis shows that the total installation and operation/mainten-
ance costs of hybrid systems make them competitive against conventional gas turbines.

Keywords: fuel cell, gas turbine, hybrid system

1 INTRODUCTION The reason for this poor performance is found in


a very low turbine inlet temperature [1]. Low power
Small scale gas turbines have usually lacked efficiency is coupled to low air mass flow and, hence, to
either at full or part load, this being a major disadvan- radial turbomachinery which cannot be cooled.
tage when compared with piston engines or other Current materials can withstand temperatures of up
power devices. Using a recuperative gas turbine can to 1000 8C for continuous operation and, occasionally,
counteract this fact partially, increasing rated effi- rise to 1100 8C for a temporary peak load demand.
ciency to over 25 per cent and approaching the mile- After years of focusing all efforts in developing new
stone 30 per cent. However, in any cases, running at materials capable of withstanding temperatures over
part load significantly reduces these figures and 1000 8C, a new interest for innovative cycles has
means a penalty over the performance of the system. recently grown up parallel to the increasing notoriety
of fuel cells in the power sector. In a similar way to gas
*Corresponding author: Thermal Power Group, Universidad de and steam combined cycles in the industrial power
Sevilla, Grupo de Motores Térmicos, Escuela Técnica Superior de generation market, where the combination of gas
Ingenieros, Camino de los descubrimientos s/n, Sevilla 41092, and steam turbines can lead to efficiencies over
Spain. email: davidsanchez@esi.us.es 50 per cent low heating value (LHV), hybrid cycles

JPE472 # IMechE 2008 Proc. IMechE Vol. 222 Part A: J. Power and Energy
150 D Sánchez, R Chacartegui, T Sánchez, J Martı́nez, and F Rosa

composed of high temperature fuel cells and micro- with the protons to form water. Water joins the
gas turbines are being considered for distributed anodic gas and is exhausted from the cell.
power applications. Recent analyses of this kind of A flow of electrons is established from the anode to
hybrid systems report efficiencies over 60 per cent the cathode through an external circuit, i.e. electrical
LHV [2]. load. This electric current is coupled to a voltage
A lot of research in the analysis of fuel cell – gas tur- difference between electrodes, which appears as a
bine hybrid systems has been done in recent years, consequence of the reaction taking place in the cell.
covering different types of fuel cells and a number It can be ideally described by the Nernst equation,
of integration schemes, and conclusions have been equation (2)
drawn about the capabilities of this sort of devices.
!
However, although many different system layouts Rg  T pH2  p1=2
O2
have been presented in these works, most studies E ¼ E0 þ ln ð2Þ
ne  F pH2 O
concentrate in a particular integration sketch, usually
neglecting other layouts, and have developed a
full set of characteristics curves which describe the E is the Nernst or ideal potential established between
performance of the system under different working electrodes and it depends only on temperature and
conditions, either at full or part load. composition as shown in equation (2). E0 is the stan-
The present work covers the fundamentals of inte- dard potential which is the potential at reference con-
grating a solid oxide fuel cell and a micro gas turbine. ditions. The power developed by the cell is the
An analysis is made about the impact of modifying a product of voltage and electric current
basic recuperative gas turbine cycle with a fuel cell for
the external heat addition process. Optimal pressure Wideal ¼ E  I ð3Þ
ratio, cell temperature, and other parameters are
studied in order to establish a maximum efficiency Regrettably, not all this power Wideal is useful due to
for each of the systems considered. After this basic irreversibilities arising in the process described
thermodynamic study, a comparison of part-load above. In fact, a voltage drop DV takes place. There-
behaviour is done and conclusions are drawn about fore, the real work produced by the cell is
which of the systems is more convenient for different
working environments.
Wreal ¼ ðE  DV Þ  I ð4Þ
A brief description of the model used is presented –
a full description of the model is out of the scope of
this work – and, later, the three systems considered There are three contributors to the voltage drop:
in the analysis are described. To complete this techni- ohmic losses, activation losses, and concentration
cal study, a simplified economic analysis of installa- losses; these losses are usually called polarizations.
tion and operation costs of the systems presented is The ohmic polarization is caused by the resistance
included. Conclusions are written in the final section. to the flow of electric current in electrodes and elec-
trolyte and it can be easily described by the following
equation
2 DESCRIPTION OF THE FUEL CELL MODEL
DVohm ¼ Z  I ð5Þ
Fuel cells are devices where hydrogen is oxidized to
water electrochemically, i.e. no combustion takes Z is the equivalent resistance of the cell. It depends
place, in a strongly exothermic reaction (Dhf ¼ mainly on materials and temperature through the
2242 kJ/mol), equation (1) electronic/ionic resistivity and, secondarily, on the
cell internal configuration, i.e. planar, tubular,
1 mixed. The calculation of Z is not complex although
H2 þ O2 ! H2 O ð1Þ
2 it involves very large equations which are not of inter-
est for this work. Readers who wish to know the pro-
A hydrogen stream enters the anode where hydro- cess to evaluate the ohmic polarization are referred to
gen molecules are dissociated into protons at the reference [3].
anodic surface. These protons migrate through the Activation losses are related to the need to over-
electrode towards the contact surface between anode come the activation energy of the half reactions
and electrolyte, usually called three-phase layer, taking place at each anode. They depend on
where the oxidation takes place. At the same time, materials, temperature, composition, and intensity.
an oxygen stream feeds the cathode. At this electrode, The calculation of the activation loss is more com-
oxygen ions are formed which migrate through the plex than the previous one and it involves evaluating
electrolyte to the three-phase layer where they react some necessary material properties, which is not an

Proc. IMechE Vol. 222 Part A: J. Power and Energy JPE472 # IMechE 2008
Comparison between conventional recuperative gas turbine and hybrid SOFC–GT systems 151

easy task. Therefore, simplified methods are used to large piston engines, and a very vast supply network
predict activation losses, Tafel equations being the is already available at almost any site where a
most common. Equation (6) shows the aspect of a power plant is set. In addition, the process where
Tafel line relating current intensity and voltage drop hydrogen is formed from natural gas, mainly
methane, is well known in heavy industries and its
DVact ¼ a þ b  lnð jÞ ð6Þ application to fuel cells is therefore easy.
When dealing with natural gas, it is quite usual to
However, using Tafel equations can lead to a not assume that it is formed exclusively by methane. If
negligible error at low current densities, up to longer chained hydrocarbons appear, they are con-
20 per cent, so, for the present work, a more general verted to equivalent methane. Thus, the following
equation has been used. This expression is derived reforming process is considered to take place inside
from a general Butler Volmer equation after assuming the cell
the commonly accepted hypothesis of symmetric
transfer coefficients equal to 0.5 [4] CH4 þ H2 O ! 3H2 þ CO ð8Þ
 
Rg  T j0 Equation (8) is called the reforming reaction and is
DVact ¼ sinh1 ð7Þ
F 2j strongly endothermic (Dhf ¼ 206 kJ/mol). In addition,
the following water–gas shift reaction occurs, which
Equation (7) is applicable to both anode and cath- is slightly exothermic (Dhf ¼ 241 kJ/mol)
ode as j0, which stands for the so called exchange cur-
rent density, is different for each of them. The sum of CO þ H2 O ! H2 þ CO2 ð9Þ
the activation loss at both electrodes is the total acti-
vation loss. As deduced from equations (8) and (9), hydrogen is
A more detailed analysis of the method to calculate obtained from methane if water is present. To guar-
activation losses and the hypotheses made to obtain antee the presence of water and avoid undesirable
equation (7) is given in reference [4]. reactions that would form atomic carbon and block
Concentration losses are related to the velocity at the catalyst, part of the gases exhausting the anode
which species diffuse through the porous electrodes is recirculated and joins the raw fuel. This exhaust
and are consumed at the active sites where the oxi- stream contains up to 50 per cent (vol) of water
dation reaction takes place. Its calculation is there- coming from the oxidation of hydrogen.
fore related to the capacity of feeding the reaction Recirculating exhaust gases not only supplies water
with hydrogen and oxygen at a high enough rate. If but also promote the endothermic reforming reac-
the concentration of any of the species reacting tion. Note that the exhaust gases are at a very high
were too low or if their rate of reaction were too temperature and can be used as a heat source for
high or if they diffused slowly, the concentration the reforming process, which is favoured by high
losses would increase. However, this type of polariz- temperatures.
ation is very low compared with the previous ones; Despite this, not all the methane feeding the cell
in fact, one order of magnitude smaller. Thus, most can be reformed inside it. If pure methane entered
authors dismiss the concentration polarization and the anode, the endothermic behaviour of the reform-
only consider ohmic and activation losses. This has ing process, which is not balanced by the exothermi-
been done in the present work. city of both hydrogen oxidation and shift reactions,
would cause a strong decrease in temperature. In
this situation, high stresses would appear in the
3 FUEL CONDITIONING elements of the cell which would eventually deterio-
rate its performance noticeably and, eventually,
3.1 Prereforming break it. Thus, a prereforming reactor is placed
outside the cell in order to have part of the methane
Up to now, hydrogen has been considered to be the
reformed before entering it. This prereforming reac-
only component of the fuel stream feeding the
tor is considered to be adiabatic and both reactions,
anode. This is not usual. Hydrogen is not found as a
reforming and shift, are supposed to reach chemical
free gas in nature and it has to be obtained as a pro-
equilibrium at its exit. The equilibrium constant of
duct from an industrial process.
both reactions is related to the temperature at
There are several techniques to produce hydrogen
which equilibrium is reached and it can be obtained
from other compounds such as water, natural gas or
from the following equation
other and all of them imply a waste of energy.
Among these, natural gas is extensively used as fuel
for power producers, such as gas turbines or even log kp;i ¼ aT 4 þ bT 3 þ cT 2 þ dT þ e ð10Þ

JPE472 # IMechE 2008 Proc. IMechE Vol. 222 Part A: J. Power and Energy
152 D Sánchez, R Chacartegui, T Sánchez, J Martı́nez, and F Rosa

where T is temperature in K and kp,i stands for the fuel utilization factor
equilibrium constant of both reactions
nH2 ; oxidized nH2 ; oxidized
  Uf ¼ ¼ 
p3 pCO n3 nCO p 2 nH2 ; supplied 3  nCH4 þ nCO þ nH2 raw fuel
kp;ref ¼ H2 ¼ H2 ð11Þ
pCH4 pH2 O nCH4 nH2 O ntot ð14Þ

pH2 pCO2 nH2 nCO2


kp;shift ¼ ¼ ð12Þ As long as natural gas, methane, is used in most
pCO pH2 O nCO nH2 O
cases as raw fuel, an equivalent hydrogen flow
must be calculated to determine how much fuel
Molar flows are evaluated at the prereformer exit in feeds the cell. This equivalent hydrogen flow is
equations (11) and (12). Coefficients a to e in shown in the denominator of the rightmost term
equation (10) are different for each reaction as in equation (14).
shown in Table 1 [5]. Finally, the amount of anodic exhaust gases being
recirculated to the prereforming reactor is deter-
mined by the steam to carbon ratio (STCR),
3.2 Internal reforming equation (15). This parameter measures the ratio
of water molecules to atomic carbon at the entrance
About 20 – 40 per cent of the methane in the raw fuel of the prereformer and its value must be in the
is prereformed outside the cell, the rest of it being range from 1.5 to 3. A too high STCR would
completely reformed at the anode. For the water – ensure a high degree of prereforming but would
gas shift reaction, chemical equilibrium is assumed dilute the hydrogen flow and lower the efficiency
again, this time at the operating temperature of the at the same time. Oppositely, if STCR were too
cell. Equations (10) and (12) can be used to evaluate low, atomic carbon would probably be formed and
the rate of the latter reaction. block the catalyst, causing a decrease in efficiency
as well.

4 FUEL CELL MASS AND ENERGY BALANCE nH2 O 
STCR ¼ ð15Þ
nCH4 þ nCO prereformer inlet
Section 3 has shown the procedure to evaluate how
much methane and carbon monoxide react accord-
A mass balance equation can now be applied to the
ing to equations (8) and (9). In order to apply a
fuel cell in order to calculate the outlet flow and com-
mass balance equation, the rate of hydrogen being
position of the exhaust gas at both electrodes. How-
oxidized to water must still be evaluated.
ever, as said in the introductory section of this
The amount of hydrogen demanded by the cell is
work, air is supplied to the cathode well in excess
related directly with the current intensity between
with respect to stoichiometry in order to cool down
electrodes through Faraday’s law
the cell. The precise air flow is obtained by applying
jA a heat balance equation to the cell, not the prerefor-
nH2 ¼ ð13Þ mer, and calculating the amount of air needed to
2F
maintain the operating temperature of the cell at
where j is the current density and A the active cell the desired value.
area. However, in order to avoid a lack of hydrogen Compositions, molar flows, and temperatures are
in a sudden change in the operational conditions the result of the application of both heat and mass
and to improve the performance of the cell, hydrogen balance equations to prerefroming reactor and cell,
is supplied in excess with respect to what equation equations (16) and (17), respectively
(13) establishes. This excess is defined through the
Hfuel þ Hrecirculation  nref Dhref  nshift Dhshift
¼ Href effluent ð16Þ
Table 1 Coefficients in equation (10)
Href effluent þ Hair  nref Dhref  nshift Dhshift
Reforming Shift
 noxid Dhoxid ¼ Hexhaust þ Welec þ Qloss ð17Þ
a 22.6312  10211 5.47  10212
b 1.2406  1027 22.5748  1028
c 22.2523  1024 4.6374  1025 All total enthalpies considered in equations (16) and
d 1.9503  1021 3.9150  1022
e 266.1395 13.2097
(17) are temperature and composition dependent. In
addition, a heat loss to the surroundings has been

Proc. IMechE Vol. 222 Part A: J. Power and Energy JPE472 # IMechE 2008
Comparison between conventional recuperative gas turbine and hybrid SOFC–GT systems 153

Fig. 1 Prereformer and fuel cell block diagram


Fig. 3 SOFC – GT indirect hybrid system

considered as Qloss. A block diagram of the whole


system to which equations apply is depicted in Fig. 1.
leaving the compressor feeds the cathode of the
fuel cell after being preheated by the exhaust gas
of the turbine. The exhaust gas of the cell enters
5 HYBRID SYSTEMS
the turbine where power is produced. Under this
configuration, the fuel cell is pressurized to up to
5.1 Configurations
3 or 4 bar, increasing useful power and efficiency
A conventional micro gas turbine has been taken as considerably. In this sense, the efficiency of the
reference system in this work. These gas turbines cell depends on the pressure ratio of the turbine.
comprise a centrifugal compressor, backflow single Figure 3 shows an indirect hybrid system. In this
combustion chamber, radial turbine, and re- case, there is no mass exchange between fuel cell
cuperator. and gas turbine and only heat is transferred between
Radial turbines cannot be cooled internally, what subsystems. The air leaving the compressor is heated
means that turbine inlet temperature is relatively up by the exhaust gas of the cell at a heat exchanger.
low in comparison with heavy duty axial flow tur- This hot air enters directly into the gas turbine where
bines. As a result, efficiency decreases, this being a it is expanded to produce power. Once expanded, the
major disadvantage of this kind of power generators. exhaust air of the turbine is used to raise the tempera-
To offset this characteristic of micro gas turbines, ture of the air feeding the fuel cell, which works at
hybrid systems are proposed. The heat addition to atmospheric pressure. Thus, the efficiency of the
the system is not done through a conventional com- cell is lower than in the previous case but, on the
bustion process as in the former system, but through other hand, does not depend on the pressure ratio
an electrochemical process. During this controlled of the turbine.
oxidation not only heat is released but a considerable
amount of work is done, i.e. electrical work. The elec-
trical work is about three to five times higher than the
gas turbine if turbine inlet and cell temperatures are 5.2 Microturbine model
the same. This means a remarkable boost in effi-
ciency, which reaches values close to 65 per cent The operation of heavy duty gas turbines is difficult to
depending on the configuration of the hybrid system. model as long as many parameters are involved.
Figures 2 and 3 show two different layouts for Firing temperature, inlet guide vanes position, inlet
integrating gas turbines and fuel cells. Figure 2 is air temperature and moisture, gas generator rotating
representative of the direct hybrid system. The air speed, variations of compressor and turbine efficien-
cies, inlet filters pressure drop, and turbine backpres-
sure are just some of the factors which have to be
considered. However, micro gas turbines are much
easier to model as most of its technology comes
from the piston engine supercharging industry.
In the present work, a high speed compressor –
turbine coupling has been considered whose charac-
teristic curves are shown in Fig. 4. A variable speed
operating line is shown dashed in Fig. 4, where hori-
zontal axis is the ratio of actual to design point cor-
rected mass flows, see equation (18), and vertical
axis is the pressure ratio. Corrected speed curves
Fig. 2 SOFC – GT direct hybrid system have been drawn for completion of the model,

JPE472 # IMechE 2008 Proc. IMechE Vol. 222 Part A: J. Power and Energy
154 D Sánchez, R Chacartegui, T Sánchez, J Martı́nez, and F Rosa

Fig. 4 Characteristic curves of a compressor-turbine Fig. 5 Useful work versus pressure ratio for a
coupling conventional recuperative gas turbine

equation (19) engineer. Maximum work and efficiency are reached


pffiffiffiffiffiffiffiffi at different pressure ratios.
m Tair Some aspects of Figs 5 and 6 must be pointed out.
_c¼
m ð18Þ
pair First, a maximum efficiency of 30 per cent LHV is
expected for the highest turbine inlet temperature;
N slightly lower values can be obtained for state of the
Nc ¼ pffiffiffiffiffiffiffiffi ð19Þ
Tair art engines. Second, choosing the pressure ratio for
the highest possible efficiency leads to a reduction
Efficiency lines have not been considered. Con- in useful work and conversely. However, for recup-
stant efficiency lines for centrifugal compressors are erative engines, this is a minor effect as pressure
ellipses whose major axe is almost parallel to the ratios for maximum work and efficiency are very
surge line and with a large major to minor axe ratio close; for the 900 8C case shown in Figs 5 and 6,
[6]. Therefore, efficiency does not change substan- these are 2.5 and 3.2, respectively. Finally, it is very
tially with corrected mass flow as long as operation important to notice that, without being concerned
follows the dashed line shown in Fig. 4. Thus, con- about which of the two parameters is to be maxi-
stant efficiency is assumed for both compressor and mized, both optimum pressure ratios are in the work-
turbine. Mechanical and electrical efficiencies are ing range of state of the art single stage radial
considered constant as well. turbomachinery. This is not the case for non-
recuperative engines.
Figure 7 shows the power ratio between fuel cell and
6 MODEL RESULTS gas turbine for both types of hybrid systems and for

6.1 Full-load operation


Graphics in this section are design figures and, there-
fore, the use of performance maps like Fig. 4 is not
applicable [6]. Instead, a characteristic efficiency is
chosen for both compressor and turbine and, after,
a sensitivity analysis to pressure ratio and turbine
inlet temperature is carried on. The objective of this
‘design analysis’ is to identify the optimum perform-
ance parameters, if any, of a hybrid system in order to
adopt a particular design point. Once the design
point is chosen, performance maps are generated
for the part-load analysis presented in section 6.2.
The analysis has been done from the gas turbine
perspective. Figures 5 and 6 show the useful work
and efficiency versus pressure ratio curves of a recup-
erative gas turbine for different turbine inlet tempera- Fig. 6 Efficiency versus pressure ratio for a
tures which are well known for any gas turbine conventional gas turbine

Proc. IMechE Vol. 222 Part A: J. Power and Energy JPE472 # IMechE 2008
Comparison between conventional recuperative gas turbine and hybrid SOFC–GT systems 155

decrease in efficiency which is visible in Fig. 8.


There is still an influence of temperature on the
value of optimum pressure ratio but, once stabiliz-
ation is reached, the efficiency is almost independent
of pressure ratio. Therefore, the following conclusion
is drawn from a practical point of view. Optimum
pressure ratios are out of the working range of state
of the art single stage centrifugal compressors,
which is limited to 4 or 5. However, for this maximum
affordable working pressure ratio, efficiency is quite
close to its maximum value. This statement is less
true as temperature increases over 1000 8C as working
temperature increases.
Figure 9 is similar to Fig. 8 but it applies to indirect
hybrid systems. As it was expected, these hybrid sys-
Fig. 7 Power ratio from fuel cell to gas turbine for tems are less efficient than direct ones as long as the
direct and indirect hybrid systems fuel cell works at atmospheric pressure; i.e. the power
and efficiency enhancement caused by the effect of
different cell temperatures. Curves are referred to the pressure over the cell is not present now. Thus, the
same active area of the fuel cell, i.e. number of unit general shape of the curve is closer to the custom
cells in the stack. It is shown that the fuel cell produces engine shown in Fig. 6, though shifted upwards. As
between three to five times more power than the gas a consequence, the value of the optimum pressure
turbine for direct and indirect integrations, respect- ratio for maximum efficiency at each cell tempera-
ively. Therefore, it is concluded that the pressure ture is well defined and there is a considerable
ratio for maximum useful work at the turbine is not decrease in efficiency when working pressure ratios
of interest any more, since most of the power of the differ from that optimum value.
system is produced by the fuel cell. Instead, global However, there is a characteristic of indirect hybrid
efficiency is the main concern. systems that make them very interesting. It is shown
Substituting the combustion chamber with a fuel in Fig. 9 that the value of pressure ratio which gives
cell affects the shape of the efficiency curves depicted maximum efficiency is almost independent of temp-
in Fig. 6. As shown in Fig. 8 for direct hybrid systems, erature. Therefore, it is guaranteed that although gas
a rapid increase in efficiency is followed by stabiliz- turbine technology develops, and as a consequence
ation. This trend is very close to that which character- turbines can withstand higher temperatures, opti-
izes fuel cells, for which pressure increases efficiency mum pressure ratios will still be attainable for
in an asymptotic pattern. This behaviour is enhanced single stage radial compressors. This is an advantage
initially by the improvement in gas turbine efficiency of this kind of integration that is not present in direct
with pressure ratio. The inversion of this trend for the systems except for the almost stabilized fashion of the
gas turbine, which is shown in Fig. 7, causes a slight curves at current working temperatures.

Fig. 8 Efficiency versus pressure ratio for a direct Fig. 9 Efficiency versus pressure ratio for an indirect
hybrid system hybrid system

JPE472 # IMechE 2008 Proc. IMechE Vol. 222 Part A: J. Power and Energy
156 D Sánchez, R Chacartegui, T Sánchez, J Martı́nez, and F Rosa

6.2 Part-load operation smooth quadratic shape that leads to an initial


increase in efficiency followed by a slight reduction.
A comparison has been done in the previous section
This quadratic shape is due to the effect of pressure
for gas-turbine-based power systems working at on the cell. When reducing the load initially, a
design conditions. Among other advantages, hybrid decrease in mass flow is followed by both a reduction
systems have shown to be capable of reaching
in pressure ratio and current density for compressor
higher efficiencies than custom recuperative gas tur- and fuel cell, respectively. The latter effect prevails
bines. Part-load operation will be analysed now. and, as a consequence, efficiency increases. However,
Part-load operation of gas turbine engines is very
a further load reduction reverses this trend. The effect
difficult to describe. Several strategies for load control of pressure, which increases exponentially towards
are available and, generally, the same engine can be low pressures, is more important and cannot be
fitted with any of them depending on the turbine balanced by the improved efficiency of the cell.
duty. Furthermore, the load control system of a par- Indirect hybrid systems do not follow the same pat-
ticular running engine can be changed upon request tern at part load as indirect systems. The fuel cell runs
to the OEM at a major overhaul. permanently at ambient pressure and its perform-
Figure 10 shows the efficiency– load curves for ance is only influenced by the reduction in current
conventional gas turbine, direct, and indirect hybrid density. The effect of pressure ratio is now almost
systems. For the first case, a 4.5 MW, 38.5 per cent limited to the gas turbine and therefore, reducing
LHV efficiency, single shaft recuperated gas turbine the load will always increase the global efficiency at
working at part load and fitted with a two step a similar rate as for standalone fuel cells.
load control system is considered. For the first
10 per cent load change, variable inlet guide vanes
are used to decrease air mass flow through the 7 ECONOMIC ANALYSIS
compressor. Pressure ratio decreases, improving the
effectiveness of the recuperating process at constant
A brief economic analysis has been done in order to
shaft speed. Below 90 per cent load demand, and
complete the previous technical study. It is well
with IGVs at its closest position, turbine inlet temp-
known that both fuel cells and micro gas turbines
erature is reduced. By using this sequential load
are presently very expensive technologies and, there-
control system, part-load efficiency is kept at its
fore, they do not share a big piece of the electricity
best for slight load reductions. However, if load is to
market yet. However, as long as environmental
be reduced to a very low level, say between 50 and
issues are promoting cleaner technologies and the
75 per cent, a dramatic decrease in efficiency
general layout of the electricity chain from supplier
cannot be avoided. Working at variable speed bal-
to consumer is evolving towards a decentralized net –
ances this effect partially but an efficiency reduction
commonly referred to as distributed generation –
will still be present.
the interest for these power systems is increasing.
The behaviour reflected in Fig. 10 is expected from
In order to develop an economic analysis, cost
the next generation micro gas turbine equipped with
estimators for the costliest components of the
variable geometry centrifugal compressors.
power systems exposed previously are considered.
Direct hybrid systems are now considered. For
These estimators are taken from reference [7],
them, the efficiency – load curves in Fig. 10 show a
though correction factors have been applied to
adjust the turnkey cost of each technology to the
value suggested by the International Energy Agency
in reference [8]. Thus, the reference installation cost
for the micro gas turbine is around 1000 USD/kW
for a 150 kW rated power engine, 1000– 1300 USD/
kW suggested in reference [8], while for the fuel cell
cost, it increases to 2000 USD/kW for the same
power capacity, 1900 – 3500/USD/kW suggested in
reference [8]. Note that these are reference values
that are expected to change with rated power. The
cost of auxiliary or secondary equipment – inverters,
combustors, and fuel compressors – is calculated as a
percentage of the cost of major equipment, Table 2,
as suggested in reference [7].
For the case of heat exchangers, a difference is
made depending on whether they are part of a stan-
Fig. 10 Part-load efficiency for the systems considered dalone fuel cell or gas turbine or a complete hybrid

Proc. IMechE Vol. 222 Part A: J. Power and Energy JPE472 # IMechE 2008
Comparison between conventional recuperative gas turbine and hybrid SOFC–GT systems 157

Table 2 Installation cost estimators Table 3 Performance assumptions for O&M


cost calculation
Component Cost (USD)
Parameter Reference value
Gas turbine Cturb ¼ 0.6(298.328 ln(Pturb) þ 1318.5) Pturb (20)
Pcomp 0.67 GT efficiency 27 per cent
Compressor Ccomp ¼ 0.6.915 62( ) (21)
445 SOFC efficiency 40 per cent
GT auxiliary Caux ¼ 0.15(Cturb þ Ccomp) (22) Direct hybrid system efficiency 60 per cent
equipment Indirect hybrid system efficiency 45 per cent
Solid oxide CSOFC ¼ 1.7 . p . Nt . Dcell . Lcell (23) Natural gas cost 39 USD/MWh HHV
fuel cell (2.96 . Tcell 2 1907) Rated power 150 kW
PSOFC 0.7
Inverter Ccomp ¼ 105 ( ) (24)
500
SOFC Caux,sa ¼ 0.1 . CSOFC (25)
auxiliary Figure 12 shows the effect of the operating time on
equipment the total, installation and O&M, costs for the different
Caux,hs ¼ 0.4 . CSOFC (26)
technologies considered in this work. It is very inter-
esting to see that, due to the enhanced efficiency and
despite the higher installation cost, fuel-cell-based
system. For the former, the cost of this equipment is technologies are economically attractive in the mid
considered to be a 10 per cent of the major equip- and long term.
ment cost. For the latter, this value increases to If a moderate 50 per cent load factor is assumed,
40 per cent of the fuel cell cost. which is equivalent to 4380 full load equivalent work-
From data in Table 2, a calculation of the installa- ing hours a year, the increased initial investment of
tion cost is done and presented in Fig. 11. The plot installing a direct hybrid system is counterbalanced
shows that, as expected, the cost of standalone gas after 2 years with respect to conventional microgas
turbines is significantly lower than any of the systems turbine technology. If, on the other hand, an indirect
incorporating fuel cells. Furthermore, for the case of hybrid system is considered, or a standalone fuel cell,
hybrid systems, it is shown that the indirect system the time needed to offset the initial investment
is more expensive than the standalone fuel cell, increases to more than 4 years. These compensation
due to the high cost of heat exchangers while hardly periods are shorter for higher power factors.
any revenue in terms of increased power is obtained. The comparison shown in this section is a simpli-
A second issue is now considered in the economic fied economic analysis that does not include the con-
analysis as it is not only the installation cost that sideration of how the investment is done – initial
influences the adopted technology but also the oper- equity, interest rate. . .– but allows for some general
ation and maintenance (O&M) cost. This second conclusions to be drawn. In this sense, although
analysis has been carried out with the assumptions fuel-cell-based power systems are more expensive
shown in Table 3, related to performance parameters than conventional gas turbines by a factor of 2,
and fuel cost. Efficiency data are taken from the Fig. 11, the enhanced efficiency of such hybrid sys-
analysis in section 6.1. The cost of natural gas is tems leads to reduced O&M costs that offset their
assumed to be 39 USD/MWh high heating value higher initial investment. Furthermore, this compen-
(HHV), which is the average value of the industrial sation time is even shorter than shown in Fig. 12 if the
price in Spain for 2006. difference in part-load efficiency, Fig. 10, is taken into

Fig. 11 Installation cost versus rated power Fig. 12 Total cost versus operating hours

JPE472 # IMechE 2008 Proc. IMechE Vol. 222 Part A: J. Power and Energy
158 D Sánchez, R Chacartegui, T Sánchez, J Martı́nez, and F Rosa

account for derated operation. It can be assumed 9. The initial investment or installation cost of a
therefore that hybrid systems are competitive techni- hybrid system is around two times higher than
cally and economically as long as reliability problems a conventional gas turbine engine of the same
that are currently affecting them are solved. rated power. However, when operation and
maintenance costs are included, the total cost
of a fuel-cell-based plant is lower in the mid –
direct hybrid systems – or long term – indirect
8 CONCLUSIONS
hybrid systems.
10. Increasing the load factor shortens the compen-
Hybrid systems are not a new concept for the scienti-
sation period needed for the hybrid system to
fic community. Studies have been done on inte-
be more interesting economically than a recuper-
gration layouts and pilot plants are running with
ated gas turbine.
highly satisfactory performance [2]. However, a
mature technology has still to be developed, even Readers might find contradictory the last conclusion.
though these systems enter a commercial phase. Reducing the current density increases efficiency but,
Despite this, hybrid systems are frequently studied at the same time, increases substantially the active
from the fuel cell perspective. The cell is considered area, i.e. number of cells in the stack, which is
as a power system which is overcharged by means needed to generate the same power. From an econ-
of a turbocharger which, in addition, generates a omical perspective, it is more interesting to reduce
small amount of power. Thus, the global efficiency the installation cost of the system, i.e. cell area,
is increased by around 15 points. although operating cost increases due to a lower
The work presented here adopts a new perspective. efficiency.
The gas turbine user considers the hybrid system as a
gas turbine engine where the combustion chamber
has been substituted by a fuel cell. It is expected ACKNOWLEDGEMENT
that such a system performs similarly to a conven-
tional gas turbine with some deviations which must The authors wish to acknowledge the Spanish
be identified. This work is aimed at finding the differ- National Institute for Aerospace Technology (INTA)
ences between three different concepts of small scale for funding this research project.
gas turbines by applying the principles of traditional
gas turbine theory.
The following particular conclusions are drawn.
REFERENCES
1. At the moment, hybrid systems cannot be con-
sidered for base load due to the high manufactur- 1 Romier, A. Small gas turbine technology. Appl. Thermal
ing cost and low power density of the fuel cell. Eng., 2004, 24, 1709–1723.
2. However, for small scale applications, particu- 2 Veyo, S. E., Shockling, A., Dederer, J. T., Gillett, J. E., and
larly distributed generation, hybrid systems are Lundberg, W. L. Tubular solid oxide fuel cell/gas turbine
much more efficient than state of the art conven- hybrid cycle power systems status. J. Eng. Gas Turbines
tional recuperative gas turbines. Power, 2002, 124, 845– 849.
3 Nisancioglu, K. Ohmic losses. In Proceedings of the IEA
3. Hybrid systems of any kind are between 50 and
Workshop on Mathematical Modelling, Charmey, 1998,
100 per cent more efficient than recuperative pp. 87 –98.
gas turbine engines. 4 Sánchez, D., Chacartegui, R., Muñoz, A., and Sánchez, T.
4. SOFC – GT hybrid systems have a pressure ratio Thermal and electrochemical modelling of internal
for maximum efficiency like conventional gas reforming solid oxide fuel cell with tubular geometry.
turbines. J. Power Sources, 2006, 160, 1074–1087.
5. The efficiency curve for a direct hybrid system is 5 Massardo, A. F. and Lubelli, F. Internal reforming solid
almost independent of pressure ratio near its oxide fuel cells – gas turbines combined cycle
maximum point. (IRSOFC-GT): part A – cell model and cycle thermodyn-
6. The pressure ratio for maximum efficiency of an amic analysis. J. Eng. Gas Turbines Power, 2000, 122, 27–35.
indirect hybrid system is almost independent of 6 Cohen, H., Rogers, G. F. C., and Saravanamootoo,
H. I. H. Gas turbine theory, 2001 (Prentice Hall, Harlow).
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7 Calise, F., Dentice d’Accadia, M., Vanoli, L., and von
7. The part-load efficiency of a hybrid system is Spakovsky, M. R. Full load synthesis/design optimiz-
remarkably higher than in the gas turbine ation of a hybrid SOFC-GT power plant. Energy, 2007,
engine and it keeps close to the rated value inde- 32, 446 –458.
pendently of the load demand. 8 Various authors. Distributed generation in liberalised
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Proc. IMechE Vol. 222 Part A: J. Power and Energy JPE472 # IMechE 2008
Comparison between conventional recuperative gas turbine and hybrid SOFC–GT systems 159

APPENDIX Q total heat flow (J)


Rg ideal gas constant (J/mol K)
Notation STCR steam to carbon ratio
T temperature (K)
A cell active area (m2) Uf fuel utilization factor (per cent)
DHS direct hybrid system V voltage (V)
E Nernst potential (V) W work (J/mol)
F Faraday constant Z ohmic resistance (V)
GT gas turbine
h specific molar enthalpy (J/mol) DV voltage loss (V)
H total enthalpy (J)
I current intensity (A)
IGV inlet guide vanes
Subscripts
IHS indirect hybrid system
j current density (A/m2) 0 standard
j0 exchange current density (A/m2) act activation
kp equilibrium constant aux auxiliary
m mass flow (kg/s) comp compressor
n molar flow (mol/s) hs hybrid system
ne number of exchanged electrons ohm ohmic
N rotating speed (r/min) ref reforming
OEM original equipment manufacturer sa standalone
p partial pressure (bar) shift water – gas shifting
P power (kW) turb turbine

JPE472 # IMechE 2008 Proc. IMechE Vol. 222 Part A: J. Power and Energy

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