1 Which of the following substances is made up of atoms?
Antara berikut, bahan yang manakah terdiri daripada atom?
A
B
C
D Iron Ferum
Oxygen gas Gas oksigen
Naphthalene Naftalena
Sodium chloride Natrium klorida
2 The equation below shows the reaction between magnesium and hydrochloric acid, Persamaan di bawah menunjukkan tindakbalas antara magnesium dan asid hidroklorik
Mg(s) + 2HCl(aq) MgCl 2 (aq) + H 2 (g)
Which of the following statements is true? Antara pernyataan berikut, yang manakah benar?
[Relative atomic mass of H = 1. Mg = 24, Cl = 35.5] [Jisim atom relatif H = 1, Mg = 24, Cl = 35.5]
A
B
C
D 1 g magnesium react with 2 g hydrochloric acid to produce 1 g magnesium chloride and 1 g hydrogen gas 1 g magnesium bertindak balas dengan 2 g asid hidroklorik menghasilkan 1 g magnesium klorida dan 1 g gas hidrogen
24 g magnesium react with 36.5 g hydrochloric acid to produce 95 g magnesium chloride and 2 g hydrogen gas 24 g magnesium bertindak balas dengan 36.5 g asid hidroklorik menghasilkan 95 g magnesium klorida dan 2 g gas hidrogen
1 mol magnesium react with 2 mol hydrochloric acid to produce 1 mol magnesium chloride and 1 mol hydrogen gas 1 mol magnesium bertindak balas dengan 2 mol asid hidroklorik menghasilkan 1 mol magnesium klorida dan 1 mol gas hidrogen
1 magnesium atom reacts with 2 hydrochloric acid molecule to produce 1 magnesium chloride molecule and 1 hydrogen gas molecule 1 atom magnesium bertindak balas dengan 2 molekul asid hidroklorik menghasilkan 1 molekul magnesium klorida dan 1 molekul gas hidrogen
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3 Which of the following chemists arranged the elements in order of increasing atomic mass in The Periodic Table ? Antara ahli kimia berikut, yang manakah menyusun unsur-unsur dalam Jadual Berkala berdasarkan pertambahan jisim atom?
A
B
C
D Dmitri Mendeleev
Johann Dobereiner
John Newlands
Henry Moseley
4 Element J has 11 electrons Unsur J mempunyai 11 elektron.
Which of the following electron arrangements represent ion J? Antara susunan elektron berikut, yang manakah mewakili ion J?
5 The ions that are present in copper(II) sulphate solution are Ion-ion yang wujud dalam larutan kuprum(II) sulfat ialah
A
B
C
Cu 2+ , SO 4 2-
Cu 2+ , SO 4 2- , H +
Cu 2+ , SO 4 2- , OH -
A D C B http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
3 D Cu 2+ , SO 4 2- , H + , OH -
6 Which of the following is a strong acid? Antara yang berikut, yang manakah asid kuat?
A
B
C
D
Alkyl sulphonic acid Asid Alkil sulfonik
Ethanoic acid Asid etanoik
Palmitic acid Asid palmitik
Nitric acid Asid nitrik
7 Which of the following is a salt ? Antara berikut, yang manakah merupakan garam? A
B
C
D Lead (II) oxide Plumbum(II) oksida
Barium hydroxide Barium hidroksida
Aluminium nitrate Aluminium nitrat
Hydrogen sulphate Hidrogen sulfat
8 Which of the following is true about manufactured substance in industry and its uses? Antara yang berikut,,yang manakah benar tentang bahan buatan dalam industri dengan kegunaannya?
Manufactured substance in industry Bahan Buatan I ndustri Uses Kegunaan A Polythene Politena Lenses Kanta B Lead glass Kaca Plumbum Mirror Cermin C Photochromic glass Kaca fotokromik Optical lenses Kanta cermin mata D Plastic reinforced with glass Plastik yang diperkukuhkan dengan kaca Test tube Tabung uji http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
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9 Which of the following statements best explain the decrease in rate of decomposition of hydrogen peroxide with time? Antara pernyataan berikut,yang manakah menerangkan pengurangan kadar penguraian hidrogen peroksida dengan masa ?
A
B
C
D Product of reaction decreases Hasil tindak balas berkurang
Temperature of hydrogen peroxide decreases Suhu hidrogen peroksida berkurang
Volume of hydrogen peroxide decreases Isipadu hidrogen peroksida berkurang
Concentration of hydrogen peroxide decreases Kepekatan hidrogen peroksida berkurang
10 Which of the following chemicals is used to keep latex in its liquid state? Antara bahan kimia berikut, yang manakah digunakan untuk mengekalkan lateks dalam keadaan cecair?
A
B
C
D
Aqueous ammonia Ammonia akueous
Ethanoic acid Asid ethanoik
Methanol Metanol
Water Air
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12 What is the meaning of heat of reaction? Apakah maksud haba tindak balas?
A The energy needed to break the chemical bond Tenaga yang diperlukan untuk memecahkan ikatan kimia
B The energy needed to start a reaction Tenaga yang diperlukan untuk memulakan tindak balas
C The energy involved when change of state of matter occurs Tenaga yang dibebaskan apabila perubahan keadaan bahan berlaku
D The change in the energy contained in the products and in the reactants Perubahan kandungan tenaga dalam hasil tindak balas dan bahan tindak balas
11 Diagram 1 shows the set up of apparatus for a chemical reaction. Rajah 1 menunjukkan susunan radas bagi satu tindak balas kimia.
DIAGRAM 1 RAJAH 1 Which of the following statements is true for the reaction? Antara pernyataan berikut, yang manakah benar mengenai tindak balas itu?
A
B
C
D
Iron
is reduced Ferum diturunkan
Iron is an oxidising agent Ferum adalah agen pengoksidaan
Magnesium releases electron Magnesium membebaskan elektron
The oxidation number of magnesium decreases Nombor pengoksidaan magnesium berkurang Magnesium strip Kepingan magnesium Agar solution Larutan agar-agar Iron strip Kepingan ferum http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
6 13 The body of an aeroplane is made up of alloy X. Badan sebuah kapalterbang dibina dari sejenis aloi X.
What is the alloy X? Apakah aloi X itu?
A
B
C
D Pewter Piuter
Brass Loyang
Bronze Gangsa
Duralumin Duralumin
14 Which of the following is true about the charges of an electron, a neutron and a proton? Antara yang berikut, yang manakah benar tentang cas-cas bagi elektron, neutron dan proton?
15 Which of the following pair of compounds and formulae is correct? Antara berikut, yang manakah pasangan sebatian dan fomulanya betul?
A
B
C
D
Compound Formula Sebatian Formula
Sodium sulphate NaSO 4
Natrium sulfat
Copper(II) oxide Cu 2 O
Kuprum(II) oksida
Iron(III) chloride FeCl 3 Ferum(III) klorida
Zinc nitrate Zn(NO 2 ) 3 Zink nitrat http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
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16 Astatine is below iodine in Group 17 of Periodic Table. Astatine terletak di bawah iodin dalam Kumpulan17 Jadual Berkala.
Which of the following statements is true for astatine? Antara pernyataan berikut, yang manakah benar tentang astatine?
A
B
C
D Form basic oxide Membentuk oksida alkali
Exists as monoatom Wujud sebagai monoatom
Solid at room temperature Pepejal pada suhu bilik
More electronegativity than iodine Lebih elektronegatif daripada iodin
17 The diagram 2 shows the electron arrangement of a molecule of water ,H 2 O Rajah 2 menunjukkan susunan elektron bagi molekul air ,H 2 O
DIAGRAM 2 RAJAH 2 Which of the following statements is true about the molecule? Antara pernyataan berikut, yang manakah benar tentang molekul itu ?
A
B
C
D The compound has high melting point Sebatian mempunyai takat lebur yang tinggi
Oxygen atom ,O has four pairs of electrons to share Atom oksigen, O mempunyai empat pasang elektron untuk di kongsi
The bonding between molecules of water, H 2 O is of Van der Waals forces Ikatan antara molekul air, H 2 O ialah daya Van der Waals
Each oxygen atom , O receives two electrons to form an oxide ion Setiap atom oksigen, O menerima dua elektron untuk membentuk satu ion oksida.
H O H http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
8 18 The diagram 3 shows the set up of the apparatus of a simple chemical cell. The reading on the voltmeter is 0.5 V. Rajah 3 menunjukkan satu radas bagi satu sel kimia yang ringkas. Bacaan pada voltmeter ialah 0.5 V.
DIAGRAM 3 RAJAH 3
Which of the following will give the biggest increment in the reading on the voltmeter? Antara berikut, yang manakah akan meningkatkan bacaan paling tinggi pada voltmeter?
A
B
C
D Increase the volume of iron(II) sulphate solution Tambahkan isipadu ferum(II) sulfat
Substitute the iron plate with a silver plate Gantikan kepingan ferum dengan kepingan argentum
Use a more dilute iron(II) sulphate solution Gunakan larutan ferum(II) sulfat yang lebih cair
Substitute the zink plate with an aluminium plate Gantikan kepingan zink dengan kepingan aluminium
19
Which of the following is true about alloy and its major component? Antara berikut yang manakah benar tentang aloi dan juzuk utamanya
Alloy Aloi Major component Komponen utama A Duralumin Duralumin Magnesium Magnesium B Steel Keluli Tin Stanum C Bronze Gangsa Copper Kuprum D Pewter Piuter Zinc Zink Iron(II) sulphate solution Larutan ferum(II) sulfat Iron plate Kepingan ferum
Zinc plate Kepingan zink
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9 20
Which of the following solutions contain the same number of hydrogen ion, H + ? Antara larutan berikut, yang manakah mengandungi bilangan ion hidrogen, H + yang sama?
[Avogadro number = 6.02 x 10 23 mol -1 ] [Nombor Avogadro = 6.02 x 10 23 mol -1 ]
I
II
III
IV
A
B
C
D
50 cm 3 of 1.0 mol dm -3 of nitric acid 50 cm 3 of 1.0 mol dm -3 acid nitrik
100 cm 3 of 0.5 mol dm -3 of hydrochloric acid 100 cm 3 of 0.5 mol dm -3 acid hidroklorik
25 cm 3 of 1.0 mol dm -3 of sulphuric acid 25 cm 3 of 1.0 mol dm -3 acid sulfurik
200 cm 3 of 0.5 mol dm -3 of ethanoic acid 200 cm 3 of 0.5 mol dm -3 acid etanoik
I and III only I dan III sahaja
II and IV only II dan IV sahaja
I, II and III only I, II dan III sahaja
II, III and IV only II, III dan IV sahajay
21
Which of the following explains the meaning of effective collision? Antara pernyataan berikut, yang manakah menjelaskan maksud perlanggaran berkesan?
A
B
C
D The collision that causes a reaction Perlanggaran yang menghasilkan tindak balas
The collision that has a low energy Perlanggaran yang mempunyai tenaga yang rendah
The collision which takes place before a reaction Perlanggaran yang berlaku sebelum sesuatu tindak balas
The collision where its energy is less than the activation energy Perlanggaran yang tenaganya kurang daripada tenaga pengaktifan
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Diagram 4 shows the set of apparatus of an experiment. Rajah 4 menunjukkan susunan radas bagi satu eksperimen.
DIAGRAM 4 RAJAH 4 Which of the following can be used to differentiate these solutions? Antara yang berikut, yang manakah boleh digunakan untuk membezakan larutan-larutan tersebut ?
23 Diagram 5 represents the structural formula of a carbon compound Rajah 5 menunjukkan formula struktur satu sebatian karbon
DIAGRAM 5 RAJAH 5 Name of the above carbon compound is Nama sebatian karbon di atas ialah
A
B
C
D Ethyl ethanoate Etil etanoat
Propil ethanoate Propil etanoat
Ethyl propanoate Etil propanoat
Diethyl methanoate Dietil etanoat H H O H H | | || | | H C C C O C C H | | | | H H H H Aluminium chloride solution Larutan Aluminium klorida Zinc chloride solution Larutan zink klorida http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
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24 Which of the following reactions shows that tin is a reducing agent? Antara tindak balas kimia berikut, yang manakah menunjukkan stanum sebagai agen penurunan?
I
II
III
IV
A
B
C
D Reaction of tin with silver oxide Tindak balas stanum dengan argentum oksida
Reaction of tin with lead(II) nitrate solution Tindak balas stanum dengan larutan Plumbum(II) nitrat
Electrolysis of tin(II) nitrate solution using tin electrodes Elektrolisis larutan stanum(II) nitrat dengan menggunakan elektrod stanum
Chemical cell with tin and zinc electrodes in sodium sulphate solution. Sel Kimia yang menggunakan elektrod stanum dan zink dalam larutan natrium sulfat.
I and II only I dan II sahaja
II and IV only II dan IV sahaja
I, II and III only I, II dan III sahaja
I, III and IV only I, III dan IV sahaja
25 The following chemical equation shows the reaction of the formation of lead (II) sulphate precipitate. Persamaan kimia berikut menunjukkan tindak balas pembentukan mendakan plumbum (II) sulfat.
Pb 2+ (ak) + SO 4
2- (ak) PbSO 4 (p) H = - 42 kJ mol -1
Which of the following is true about the reaction? Antara yang berikut, yang manakah benar tentang tindak balas itu?
Heat change Perubahan haba Type of reaction J enis tindak balas A Heat is released Haba dibebaskan Endothermic Endotermik B Heat is absorbed Haba diserap Exothermic Eksotermik C Heat is released Haba dibebaskan Exothermic Eksotermik D Heat is absorbed Haba diserap Endothermic Endotermik
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26 Which of the following molecules is soap? Antara molekul berikut, yang manakah merupakan sabun?
A
B
C
D CH 3 (CH 2 ) 14 COOH
CH 3 (CH 2 ) 2 COONa
CH 3 (CH 2 ) 14 COONa
CH 3 (CH 2 ) 14 COOCH 3
27 The diagram 6 shows the cooling curve for a sample of a pure substance X Rajah 6 menunjukkan lengkuk penyejukan bagi satu contoh bahan X yang tulin.
DIAGRAM 6 RAJAH 6
Which of the following statements is true about the arrangement of particles at time t? Antara berikut, yang manakah pernyataan yang benar tentang susunan zarah-zarah pada masa t?
A
B
C
D All the molecules move freely Semua zarah bergerak bebas
All the molecules only vibrate and rotate at their fixed position Semua zarah hanya bergetar dan berputar pada kedudukan yang tetap
Some of the molecules move from one point to another and the others move randomly Sebahagian zarah bergerak dari satu tempat ke tempat yang lain dan yang lainnya bergerak bebas
Some of the molecules vibrate and rotate at their fixed positions and the others move from one point to another Sebahagian zarah bergetar dan berputar pada kedudukan yang tetap dan yang lainnya bergerak dari satu tempat ke tempat yang lain t
Temperature/ o C Time/s http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
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28 Diagram 7 shows the molecular formulae of two compounds, X and Y Rajah 7 menunjukkan formula molekul bagi dua sebatian, X dan Y.
Compound X Compound Y Sebatian X Sebatian Y DIAGRAM 7 RAJAH 7
Which of the following statements are similar for compound X and Y? Antara pernyataan berikut, yang manakah sama bagi sebatian X dan Y?
A
B
C
D
The empirical formula Formula empirik
Reaction with bromine water Bertindak balas dengan air bromine
Hydration to produce an alcohol Penghidratan menghasilkan suatu alkohol
Complete combustion in oxygen to produce water and carbon dioxide gas Pembakaran sempurna dalam oksigen menghasilkan air dan gas karbon dioksida
29 Table 1 shows the proton number of elements W,X,Y and Z. The letters used are not the actual symbol of the elements. Jadual 1 menunjukkan nombor proton bagi unsur-unsur W,X,Y ,dan Z. Huruf yang digunakan bukan simbol sebenar unsur itu.
TABLE 1 JADUAL 1 Which of the following shows the ascending order of the atomic size of the elements? Antara ynag berikut yang manakah menunjukkan susunan menaik saiz atom bagi unsur-unsur itu?
Element Unsur Proton number Nombor proton W X Y Z 11 13 17 19 A B C D W,X,Y,Z Z,W,X,Y Y,X,W,Z Z,Y,X,W
C 2 H 6
C 5 H 10 http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
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30 Which of the following is true about covalent compound? Antara berikut, yang manakah benar tentang sebatian kovalen?
A
B
C
D Conduct electricity in molten or aqueous state Mengalir elektrik dalam keadaan lebur atau akueus
Low melting point Takat lebur rendah
Soluble in water Larut dalam air
Not volatile Tidak meruap
31 Diagram 8 shows a set up of chemical cell using a pair of zinc and copper as electrodes. Rajah 8 menunjukkan susunan radas sel kimia menggunakan pasangan elektrod zink dan kuprum.
DIAGRAM 8 RAJAH 8
The blue copper(II) sulphate solution turns pale. Warna biru larutan kuprum(II) sulfat luntur
Which of the following explains the observation? Antara pernyataan berikut yang manakah menerangkan pemerhatian itu?
A
B
C
D Zinc atom ionizes Atom zink mengion
Copper atom ionizes Atom kuprum mengion
Sulphate ion is discharged Ion sulfat dinyahscas
Copper(II) ion is discharged Ion kuprum(II) dinyahcas
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32
Which of the following explains the above statement? Antara berikut, yang manakah menerangkan pernyataan di atas?
A
B
C
D
Hydrochloric acid is a weak acid while ethanoic acid is a strong acid Asid hidroklorik ialah asid lemah sementara asid etanoik ialah asid kuat
Hydrochloric acid dissociates partially while ethanoic acid dissociates completely in water Asid hidroklorik bercerai separa sementara asid etanoik bercerai sempurna di dalam air
The number of hydrogen atom in hydrochloric acid is smaller than in ethanoic acid Bilangan atom hidrogen di dalam asid hidroklorik lebih kecil berbanding di dalam asid etanoik
The concentration of hydrogen ion in hydrochloric acid is higher than in ethanoic acid Kepekatan ion hidrogen di dalam asid hidroklorik adalah lebih tinggi berbanding di dalam asid etanoik
33 The following equation shows the preparation of salt R. Persamaan berikut menunjukkan penyediaan garam R
Solution P + Solution Q Solid R + Solution S Larutan P + Larutan Q Pepejal R + Larutan S
Which of the following set represents compound P,Q,R and S? Antara set berikut, yang manakah merupakan sebatian P,Q,R dan S? P Q R S I Pb
NaBr PbBr 2 Na
II Ca(NO) 3 K 2 SO 4 CaSO 4 KNO 3 III AgNO 3 NaCl AgCl
NaNO 3
IV NH 4 OH HCl
NH 4 Cl H 2 O
A I and II only I dan II sahaja
B I and IV only I dan IV sahaja
C II and III only II and III sahaja
D III and IV only III and IV sahaja The pH value of 0.1 mol dm -3 hydrochloric acid,HCl is smaller than the pH value of 0.1 mol dm -3 ethanoic acid, CH 3 COOH Nilai pH bagi 0.1 mol dm -3 asid hidroklorik, HCl adalah lebih kecil berbanding dengan nilai pH bagi 0.1 mol dm -3 asid etanoik, CH 3 COOH
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34 The manufacturing of sulfuric acid involves several reactions. Pembuatan asid sulfurik melibatkan beberapa tindak balas.
Which of the following equations represents the sulfuric acid reaction that uses a catalyst? Antara persamaan berikut, yang manakah mewakili tindak balas asid sulfurik yang menggunakan mangkin?
A
B
C
D S + O 2 SO 2
2SO 2 + O 2 2SO 3
SO 3 + H 2 SO 4 H 2 S 2 O 7
H 2 S 2 O 7 + H 2 O
2H 2 SO 4
35 Diagram 9 shows the graph of volume of oxygen gas against time . Curve P is obtained from an experiment of the decomposition of 25 cm 3 of 0.1 mol dm -3 hydrogen peroxide solution. Rajah 9 menunjukkan graf isipadu gas oksigen melawan masa. Lengkung P diperolehi daripada tindak balas penguraian 25 cm 3 larutan hidrogen peroksida 0.2 mol dm -3 .
DIAGRAM 9 RAJAH 9 Which of the following solutions will produce curve Q? Antara larutan berikut, yang manakah akan menghasilkan lengkung Q?
A
B
C
D 25 cm 3 hydrogen peroxide 0.15 mol dm -3 25 cm 3 hydrogen peroxide 0.15 mol dm -3
20 cm 3 hydrogen peroxide 0.15 mol dm -3 20 cm 3 hydrogen peroxide 0.15 mol dm -3
15 cm 3 hydrogen peroxide 0.15 mol dm -3 15 cm 3 hydrogen peroxide 0.15 mol dm -3
10 cm 3 hydrogen peroxide 0.25 mol dm -3 10 cm 3 hydrogen peroxide 0.25 mol dm -3
P Q Time/s Masa/s Volume of O 2 gas/cm 3
Isipadu gas O 2 /cm 3
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36 The equation below shows the chemical equation of the combustion of ethanol in excess oxygen Persamaan di bawah menunjukkan persamaan kimia bagi pembakaran etanol dalam oksigen berlebihan
2C 2 H 5 OH + 7O 2 4CO 2 + 6H 2 O
What is the volume of carbon dioxide gas released when 9.20 g ethanol reacts completely? Berapakah isi padu gas karbon dioksida terbebas apabila 9.2 g etanol bertindak balas lengkap?
[Relative atomic mass of H = 1, C = 12, O = 16, 1 mol of gas occupies 24 dm 3 at room condition] [Jisim atom relatif H = 1, C = 12, O = 16, 1 mol of gas memenuhi 24 dm 3 pada keadaan bilik]
A B C D
4.8 cm 3
9.6 cm 3
96.0 cm 3
9600 cm 3
37
Diagram 10 shows the set up of the apparatus to study the redox reaction . Rajah 10 menunjukkan susunan radas untuk mengkaji tindak balas redoks.
DIAGRAM 10 RAJAH 10 Carbon X is a negative terminal. Karbon X merupakan terminal negatif.
Which of the following are solution X and solution Y? Antara berikut, yang manakah merupakan larutan X dan larutan Y?
Solution X Larutan X Solution Y Larutan Y A Iron(II) sulphate Ferum(II) sulfat Bromine water Air bromin B Iron(III) sulphate Ferum(III) sulfat Potassium bromide Kalium bomida C Acidified potassium dicromate(VI) Kalium dikromat(VI) berasid Potassium chloride Kalium klorida D Acidified potassium manganat(VII) Kalium manganat(VII) berasid Iron(II) sulphate Ferum(II) sulfat Carbon Y Karbon Y
Porous pot Pasu telap Solution X Larutan X Carbon X Karbon X
Solution Y Larutan Y
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38 The reaction between 25.00 cm 3 of hydrochloric acid and 25.00 cm 3 of sodium hydroxide solution releases the heat of 2100 J. [Specific heat capacity of a solution = 4.2 J g -1 o C -1 Assume that 1 cm 3 of a solution is equal to 1 g of the solution ] Tindak balas antara 25.00 cm 3 asid hidroklorik dan 25.00 cm 3 larutan natrium hidroksida membebaskan haba sebanyak 2100 J. [Muatan haba tentu larutan = 4.2 J g -1 o C -1 Anggap 1 cm 3 larutan sama dengan 1 g larutan ]
What is the temperature change of the mixture ? Berapakah perubahan suhu campuran itu?
A B C D 1 O C 2 O C 10 O C 20 O C
39 Which of the following is true about soap or detergent ? Antara yang berikut, yang manakah benar tentang sabun atau detergen ?
A
B
C
D
Soap forms scum in soft water Sabun membentuk kekat dalam air lembut
Detergent forms scum in hard water Detergen membentuk kekat di dalam air liat
The presence of magnesium ions in detergent forms scum Kehadiran ion magnesium di dalam detergen membentuk kekat
Scum decreases the effectiveness of the cleansing action of a soap Kekat mengurangkan keberkesanan tindakan pencucian sabun
40 Bromine-79 has 44 neutrons. Bromin-79 mempunyai 44 neutron
Which of the following symbols represent the bromine atom? Antara simbol berikut, yang manakah mewakili atom bromin?
A
B
C
D
79 35 Br 44 Br 35 79 44 Br 79 35 Br http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
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41
What is the empirical formula of metal oxide J? Apakah formula empirik bagi oksida logam J?
[Relative atomic mass of J = 24, O = 16 ] [Jisim atom relatif: J = 24, O = 16 ]
A B C D JO JO 2 J 2 O J 2 O 2
42 In the Periodic Table, element X is in group 1 and element Y is in group 17 The letters used are not the actual symbol of the elements. Dalam Jadual Berkala Unsur, unsur X berada dalam kumpulan I dan unsur Y berada dalam kumpulan 17. Huruf yang digunakan bukan simbol sebenar unsur itu.
Which of the following chemical equation is true for the reaction between element X and element Y? Antara persamaan kimia berikut, yang manakah benar bagi tindak balas antara unsur X dan unsur Y?
A B C D 2X + Y 2 2
XY X + Y 2 XY 2 2X + Y X 2 Y X + Y XY
43 The table 2 shows the electron arrangements of elements R, S, T dan U. Jadual 2 menunjukkan susunan elektron bagi unsur R, S, T dan U
Which of the following pair of elements can form ionic compound? Antara pasangan unsur berikut, yang manakah boleh membentuk sebatian ion? Elements Unsur R S T U Electron arrangement Susunan elektron 2.4 2.8 2.8.7 2.8.8.2 A
B
C
D R and S R dan S
S and U S dan U
T and U T dan U
R and T R dan T 2.0 g metal oxide J contains 1.2 g of element J 2.0 g oksida logam J mengandungi 1.2 g logam J http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
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44 The reaction between hydrochloric acid and calcium carbonate produces carbon dioxide gas. The reaction is complete in 50 seconds and the maximum volume of gas produced is 25 cm 3.
Tindakbalas antara asid hidroklorik dengan kalsium kabonat menghasilkan gas karbon dioksida. Tindak balas lengkap dalam masa 50 saat dan isipadu maksimum gas ialah 25 cm 3 .
What is the average rate of reaction? Berapakah kadar tindak balas purata?
A B C D 0.5 cm 3 s -1
1.0 cm 3 s -1
2.0 cm 3 s -1
4.0 cm 3 s -1
45 Diagram 11 shows the set-up of apparatus for the titration of sodium hydroxide solution with sulphuric acid. Rajah11 menunjukkan susunan radas bagi titratan larutan natrium hidroksida dengan asid sulfurik
DIAGRAM 11 RAJAH 11 What is the volume of 0.5 mol dm -3 of sulphuric acid solution required to completely neutralize 25 cm 3 of 0.5 mol dm -3 sodium hydroxide solution? Berapakah isi padu 0.5 mol dm -3 asid sulfurik diperlukan untuk meneutralkan lengkap 25 cm 3
25 cm 3 of 0.5 mol dm -3 sodium hydroxide + phenolphthalein 25 cm 3 0.5 mol dm -3 larutan natrium hidroksida + fenolftalein
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46
The following chemical equation shows the reaction of preparation lead(II) iodide salt. Persamaan kimia berikut menunjukkan tindak balas penyediaan garam plumbum(II) iodida.
Pb (NO 3 ) 2 (aq) + 2KI(aq) PbI 2 (s) + 2KNO 3 (aq) Pb (NO 3 ) 2 (ak) + 2KI(ak) PbI 2 (p) + 2KNO 3 (ak)
What is the volume of potassium iodide 0.5 mol dm -3 solution needed to produce 4.61 g lead(II) iodide salt? Berapakah isipadu larutan kalium iodida 0.5 mol dm -3 yang diperlukan untuk menghasilkan 4.61g garam plumbum(II) iodida? [Relative atomic mass of Pb= 207, I= 127] [Jisim atom relatif P= 207, I= 127]
A
B
C
D 20 cm 3
40 cm 3
400 cm 3
1440 cm 3
47 Diagram 12 shows the stages I, II, III and IV in the Contact Process during the preparation of sulphuric acid. Rajah 12 menunjukkan peringkat I, II, III dan IV bagi penyediaan asid sulfurik melalui proses Sentuh.
S I SO 2 II SO 3 III H 2 S 2 O 7 IV
H 2 SO 4
Which of the following chemicals is used at each stage? Antara bahan kimia berikut, yang manakah digunakan pada peringkat itu?
I II III IV A O 2 O 2 H 2 O H 2 SO 4
B O 2 O 2 H 2 SO 4 H 2 O C O 2 H 2 O O 2 H 2 SO 4
D H 2 O O 2 H 2 SO 4 O 2
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48 Diagram 13 shows the set up of the apparatus for an experiment to determine the rate of reaction between sodium thiosulphate solution and sulphuric acid solution. Rajah 13 menunjukkan susunan radas bagi eksperimen untuk menentukan kadar tindak balas antara natrium tiosulfat dengan asid sulfurik.
DIAGRAM 13 RAJAH 13
Which of the following combination of conditions take the longest time for the mark X to disappear from sight? Antara kombinasi keadaan berikut, yang manakah mengambil masa paling lama untuk tanda X hilang daripada penglihatan?
A
B
C
D
Sulphuric acid solution Larutan asid Sulfurik
Sodium thiosulphate solution Larutan natrium tiosulfat Temperature/ 0 C Suhu/ 0 C Volume/cm 3
Sodium thiosulphate solution and sulphuric acid Larutan natrium tiosulfat dan asid sulfurik
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49 Diagram 14 shows the structural formula of carbon compound J Rajah 14 di bawah menunjukkan formula struktur sebatian karbon J
DIAGRAM 14 RAJAH 14
Which of the following statements are true? Antara pernyataan berikut, yang manakah benar? [Relative atomic mass of H = 1, C = 12 ] [Jisim atom relatif H = 1, C = 12 ]
I
II
III
IV
A
B
C
D
Empirical formula of J is C 4 H 8 Formula empirik J ialah C 4 H 8
Name of the compound J is but-1-ene Nama sebatian J ialah but-1-ena
Hydration of compoud J produce butan-1ol Penghidratan sebatian J menghasilkan butan-1-ol
Complete combustion of compound J produce carbon dioxide gas and water Pembakaran lengkap sebatian J menghasilkan gas karbon dioksida dan air
I and II only I dan II sahaja
III and IV only III dan IV sahaja
I, II and III only I, II dan III sahaja
II, III and IV only II, III dan IV sahaja
H H H H | | | | H C C C = C H | | H H http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 1
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50
Metal W is between iron and copper in the reactivity series of metal. The letters used are not the actual symbol of the elements. Logam W berada di antara ferum dan kuprum dalam siri kereaktifan logam. Huruf yang digunakan bukan simbol sebenar unsur itu
Which of the following metal oxides can be reduced by metal W? Antara oksida logam berikut, yang manakah boleh diturunkan oleh logam W?
A
B
C
D
Zinc oxide Zink oksida
Silver oxide Argentum oksida
Magnesium oxide Magnesium oksida
Aluminium oxide Aluminium oksida
END OF QUESTION PAPER KERTAS SOALAN TAMAT http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 2 4541/2
2 1. Table 1 shows proton number and nucleon number for atom W, X and Y. Jadual 1 menunjukkan nombor proton dan nombor nukleon bagi atom W, X dan Y.
Atom Proton number / Nombor Proton Nucleon number / Nombor Nukleon W 11 23 X 17 35 Y 17 37 TABLE / JADUAL 1
(a) (i) What is meant by proton number? Apakah yang dimaksudkan dengan nombor proton ?
.............................................................................. [1 mark] (ii) What is the number of neutron in atom W ? Apakah bilangan neutron dalam atom W?
......................................................... [1 mark] (b) Which atoms are isotopes? Explain why. Atom atom yang manakah adalah isotop? Jelaskan mengapa.
.................................................................................................................................. [2 marks] (c) Write the electron arrangement of atom X . Tuliskan susunan elektron bagi atom X.
(d) (i) Draw the electron arrangement of atom Y. In your diagram , show the number of proton and the number of neutron in the nucleus. Lukiskan susunan elektron atom Y. Dalam rajah anda, tunjukkan bilangan proton dan bilangan neutron dalam nukleus.
[2 marks]
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3 (ii) What is the number of valence electron of atom Y? Apakah bilangan elektron valen bagi atom Y?
................................................................................................................ [1 mark] (iii) Write the formula of ion Y. Tuliskan formula ion Y.
(b) (i) Element U, V, W and X are placed in the same period in the Periodic Table. State the period. Unsur U, V, W dan X berada dalam kala yang sama dalam Jadual Berkala. Nyatakan kala itu.
................................................................................................................................... [2 marks ]
(c) Element V can react with element W to form a compound. Unsur V boleh bertindak balas dengan unsur W membentuk satu sebatian.
(i) Write the chemical formula for the compound. Tuliskan formula kimia bagi sebatian itu.
................................................................................................................................. [1 mark ]
(ii) State one physical property for the compound formed. Nyatakan satu sifat fizikal bagi sebatian yang terbentuk.
............... [1 mark ]
(d) When element U react with element W, a compound is produced. Apabila unsur U bertindak balas dengan unsur W, satu sebatian terhasil.
(i) State the type of the compound produced. Nyatakan jenis sebatian yang terhasil.
...................................................................................................................... [1 mark ]
(ii) Draw the electron arrangement for the compound in (d) (i). Lukiskan susunan elektron bagi sebatian dalam (d) (i).
[2 marks]
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3 Diagram 3 shows the set-up of apparatus of a voltaic cell. Rajah 3 menunjukkan susunan radas satu sel kimia.
DIAGRAM / RAJAH 3.1
Based on Diagram 3 , answer the following questions. Berdasarkan Rajah 3, jawab soalan- soalan berikut:
(a) What is the energy change that occurs in the voltaic cell? Apakah perubahan tenaga yang berlaku dalam sel kimia?
.................................................................................................................................. [1 mark] (b) Write the formula of all ions in copper (II) sulphate solution. Tuliskan formula semua ion dalam larutan kuprum (II) sulfat.
.................................................................................................................................. [1 mark] (c) (i) Name the negative terminal of the voltaic cell. Namakan terminal negatif bagi sel kimia.
Copper (II) nitrate solution / Larutan kuprum (II) nitrat Copper plate / Kepingan kuprum Zinc Plate / Kepingan zink V http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 2 4541/2
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(ii) Write the half equation for the reaction occur at the copper plate. Tuliskan persamaan setengah bagi tindak balas yang berlaku pada kepingan kuprum.
(e) What is the colour change of the copper(II)sulphate solution? Explain your answer. Apakah perubahan warna larutan kuprum (II) sulfat ? Jelaskan jawapan anda.
(f) Another experiment is carried out by replacing the zinc plate with P , Q and R metals. Table 3.2 shows the results. Eksperimen lain dijalankan bagi menggantikan kepingan zink dengan logam P, Q dan R. Jadual 3.2 menunjukkan keputusannya.
Pair of metal/ Pasangan logam Voltage/ Voltan (V) Negative terminal/ Terminal negative P/Cu 2.7 P Q/Cu 2.0 Q R/Cu 0.5 R
TABLE/ JADUAL 3.2
(i) Arrange P, Q, R and Cu metal in accending order of electropositivity. Susunkan logam P, Q, R dan Cu mengikut tertib menaik keelektropositifan.
.................................................................................................................................. [1 mark] (ii) Predict the voltage for pair of Q/R. Ramalkan nilai voltan bagi pasangan Q/R
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4 (a) Diagram 4.1 shows the set-up of apparatus to prepare soap. Rajah 4.1 menunjukkan susunan radas untuk menyediakan sabun.
DIAGRAM / RAJAH 4.1
(i) Name the process of preparing soap. Namakan proses penyediaan sabun.
. [1 mark] (ii) Name the solution P. Namakan larutan P.
. [1 mark]
(iii) State the purpose of adding sodium chloride to the reaction mixture in the experiment. Nyatakan tujuan menambahkan natrium klorida kepada campuran tindak balas dalam eksperimen itu.
. [1 mark]
(iv) Diagram 4.2 shows the structure of a soap ion. Rajah 4.2 menunjukkan struktur satu ion sabun.
Part / Bahagian X Part/ Bahagian Y
DIAGRAM/RAJAH 4.2
Which part is soluble in the water and grease based on Diagram 4.2? Bahagian manakah yang larut dalam air dan gris berdasarkan CH 2 CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 C-O -
|| O Heat / Panaskan Palm oil / Minyak sawit + Solution/ Larutan P Distilled water / Air suling + Sodium chloride / Natrium klorida Cool/ Sejukkan Mixture/ Larutan Soap/ Sabun http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 2 4541/2
8 Rajah 4.2?
Water/air:
Grease/gris: . [1 mark]
(b) Glass and ceramic are widely used in our daily life. Kaca dan seramik digunakan secara meluas dalam kehidupan harian.
(i) Name a chemical of the main component of glass and ceramic Namakan bahan kimia yang menjadi bahan utama dalam kaca dan seramik
. [1 mark]
(ii) State a reason why glass is used as laboratory apparatus instead of metal. Nyatakan satu alasan mengapa kaca digunakan sebagai radas makmal bukannya logam.
[1 mark]
(iii)
Test tube Beaker Combustion tube Tabung uji Bikar Tiub Pembakaran
DIAGRAM/RAJAH 4.3
State the type of glass that used in making the apparatus in Diagram 4.3 Nyatakan jenis kaca yang digunakan untuk membuat alat radas dalam Rajah 4.3
[1 mark]
(c) Photo chromic glass is a composite material. Kaca fotokromik adalah salah satu bahan komposit
(i) What is composite material? Apakah bahan komposit?
. [1 mark]
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(ii) Name one of the component in photo chromic glass? Namakan salah satu daripada komposisi dalam kaca fotokromik?
. [1 mark]
(iii) State one of the characteristic of lenses made from photo chromic glass. Nyatakan satu ciri lensa yang diperbuat daripada kaca fotokromik.
. [1 mark]
5 Table 5 shows the formulae of three organic compounds. Jadual 5 menunjukkan formula bagi tiga sebatian organik
Organic compound Sebatian organik Formula Formula Butan-1-ol Butan-1-ol C 4 H 10 O Butanoic acid Asid Butanoik C 4 H 8 O 2 But-1-ene But-1-ena C 4 H 8
TABLE / JADUAL 5
Use the information in Table 5 to answer the following questions. Gunakan maklumat dalam Jadual 5 untuk menjawab soalan berikut.
(a) Name the homologous series for butan-1-ol. Namakan siri homolog bagi butan-1-ol
.. [ 1 mark ]
(b) (i) Draw the structural formula of butan-1-ol Lukiskan formula struktur bagi butan-1-ol
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[ 1 mark ] (ii) The following structural formula is isomer of butanol. Formula struktur berikut ialah isomer bagi butanol
CH 3
CH 3 - C - CH 3
OH
Name the isomer. Namakan isomer itu.
. [ 1 mark ]
(c ) Butan-1-ol can react with butanoic acid to form compound X and water. Butan-1-ol boleh bertindak balas dengan asid butanoik untuk menghasilkan sebatian X dan air.
(i) What is the name of this reaction? Apakah nama tindak balas ini.
. [ 1 mark ] (ii) Write the chemical equation for the reaction. Tuliskan persamaan kimia bagi tindak balas itu.
. [ 1 mark ]
(iii) State one physical property of compound X. Nyatakan satu sifat fizik bagi sebatian X.
. [ 1 mark ]
(d) Dehydration of butan-1-ol using porous pot chips produce but-1-ene. Draw the set up of apparatus used in the dehydration. Pengdehidratan butan-1-ol menggunakan serpihan pasu berliang menghasilkan but-1-ena. Lukiskan susunan radas yang digunakan dalam pengdehidratan itu.
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[ 2 marks ]
(e) When but-1-ene is mixed with bromine water , a reaction occur. Apabila but-1-ena dicampurkan dengan air bromin , satu tindak balas berlaku.
(i) Name the reaction . Namakan tindak balas itu.
. [ 1 mark ] (ii) State one observation in the reaction. Nyatakan satu pemerhatian dalam tindak balas itu. . [ 1 mark ]
6 Diagram 6 shows the set- up of apparatus to investigate the reaction between potassium iodide solution and chlorine water through the transfer of electrons at a distance.. Rajah 6 menunjukkan susunan radas untuk menyiasat tindak balas di antara larutan kalium iodide dan air klorin melalui pemindahan elektron pada satu jarak.
DIAGRAM / RAJAH 6
(a) What is the function of dilute sulphuric acid? Apakah fungsi asid sulfurik cair?
[1 mark ]
(b) On the diagram 6, draw the direction of the flow of electrons. Dilute sulphuric acid G Electrode Q Chlorine water Potassium iodide solution Electrode P http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 2 4541/2
12 Pada rajah 6, lukiskan arah pengaliran elektron elektron. [1 mark ]
(c) (i) What is the colour change in the solution around electrode P? Apakah perubahan warna dalam larutan di sekitar elektrod?
.................................................................................................................................. [1 mark ]
(ii) Describe a chemical test to determine the product formed in the solution at electrode P. Huraikan satu ujian kimia untuk menentukan hasil yang terbentuk dalam larutan di elektrod P.
..............
............... [2 marks ]
(d) What is the substance that is being oxidised in the experiment? Explain why. Apakah bahan yang dioksidakan dalam eksperimen?Terangkan mengapa.
.....
..... [2 marks ] (e) Write a half equation for the reaction that occurs at electrode Q. Tuliskan satu persamaan setengah bagi tindak balas yang berlaku di elektrod Q.
.... [1 mark ]
(f) Suggest another reagent that can replace chlorine water. Cadangkan reagen lain yang boleh menggantikan air klorin.
.................... [1 mark ] (g) What is the change in oxidation number of chlorine in the reaction? Apakah perubahan nombor pengoksidaan bagi klorin dalam tindak balas?
...... [1 mark ]
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Section B [20 marks]
Answer any one question. The time suggested to answer this section is 30 minutes.
7 (a) Table 7 shows the incomplete observation for two experiments to construct balanced chemical equation. Jadual 7 menunjukkan pemerhatian yang tidak lengkap bagi dua eksperimen untuk membina persamaan kimia yang seimbang.
Experiment Eksperimen Procedure Prosedur Observation Pemerhatian A Copper(II)carbonate is heated and the gas produced is passed through lime water. Kuprum(II)karbonat dipanaskan dan gas yang terhasil dialirkan melalui air kapur. Green solid turns black. The lime water turns milky. Pepejal hijau menjadi hitam. Air kapur menjadi keruh. B Potassium iodide solution is added to lead(II) nitrate solution. Larutan kalium iodida ditambah kepada larutan plumbum(II)nitrat.
TABLE / JADUAL 7
(i) Based on the observation, name the products in experiment A and write the chemical equation for the reaction. Berdasarkan pemerhatian , namakan hasil tindak balas dalam eksperimen A dan tuliskan persamaan kimia bagi tindak balas itu. [ 3 marks ]
(ii) State one observation in experiment B and name the product. Write the chemical equation for the reaction. Nyatakan satu pemerhatian dalam eksperimen B dan namakan hasil tindak balas itu. Tuliskan persamaan kimia bagi tindak balas itu. [ 4 marks ]
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(b) The reaction between acid , HX and ionic compound , QY 2 can be represented by chemical equation below. Tindak balas antara asid , HX dan sebatian ion , QY 2 boleh diwakili oleh persamaan kimia di bawah.
2HX(aq) +QY 2 (aq) QX 2 (s) + 2HY(aq).
State three statement to describe the chemical equation above. Suggest an acid of HX and an ionic compound of QY 2 . Nyatakan tiga pernyataan untuk menghuraikan persamaan kimia di atas. Cadangkan asid HX dan sebatian ion QY 2 .
[ 5 marks]
(c) The information below is regarding substance X Maklumat di bawah berkaitan dengan bahan X
(i) Determine the empirical formula of substance X. [Given that the relative atomic mass of C = 12 , H = 1] Tentukan formula empirik bagi sebatian X [Diberi jisim atom relatif C = 12 , H = 1]
(ii) Determine the molecular formula of substance X. Tentukan formula molekul bagi bahan X.
(iii) Based on the answers in (a)(i) and (a)(ii) , compare and contrast the empirical formula and the molecular formula. Berdasarkan jawapan dalam (a)(i) dan (a)(ii), banding dan bezakan formula empirik dan formula molekul.
[ 8 marks]
Carbon 85.70% Karbon
Hydrogen 14.30% Hidrogen
Relative molecular mass = 56 Jisim molekul relatif
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8 (a) State three factors affecting the rate of reaction. Nyatakan tiga faktor yang mempengaruhi kadar suatu tindak balas. [3 marks]
(b) An experiment is carried out to study the rate of reaction between magnesium and hydrochloric acid. The time taken by magnesium to dissolve in acid in each experiment is recorded in Table 8. Satu eksperimen dijalankan untuk mengkaji kadar tindak balas antara magnesium dan asid hidroklorik. Masa magnesium larut di dalam asid dalam setiap eksperimen dicatat seperti dalam jadual 8
Experiment Eksperimen Reactant Bahan tindak balas Temperature suhu ( 0 C) Time masa (s) I 20 cm 3 of 0.5 mol dm -3 hydrochloric acid + 2 g of magnesium strip
20 cm 3 asid hidroklorik 0.5 mol dm -3 + 2 g pita magnesium 30 120 II 20 cm 3 of 1.0 mol dm -3 hydrochloric acid + 2 g of magnesium strip
20 cm 3 asid hidroklorik 1.0 mol dm -3 + 2 g pita magnesium 30 60 III 20 cm 3 of 1.0 mol dm -3 hydrochloric acid + 2 g of magnesium powder
20 cm 3 asid hidroklorik 1.0 mol dm -3 + 2 g serbuk magnesium 30 40 IV 20 cm 3 of 1.0 mol dm -3 hydrochloric acid + 2 g of magnesium strip + 5 drops of copper(II) sulphate solution
20 cm 3 asid hidroklorik 1.0 mol dm -3 + 2 g pita magnesium + 5 titik larutan kuprum(II) sulfat 30 45
TABLE/JADUAL 8
(i) Write an ionic equation for the reaction between magnesium and acid. Tuliskan persamaan ionik yang berlaku antara magnesium dan asid. [1 mark] http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 2 4541/2
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(ii) Compare the rate of reaction for experiment I and experiment II, experiment II and experiment III. experiment II and experiment IV
Explain your answer based on the collision theory.
Bandingkan kadar tindak balas antara eksperimen I dan eksperimen II eksperimen II dan eksperimen III eksperimen II dan eksperimen IV
Terangkan jawapan andaberdasarkan teori perlanggaran [9 marks]
(iii) If experiment II is repeated at 40 0 C, predict the time taken for the 2 g magnesium to dissolve completely. Explain your answer. Jika eksperimen II diulangi pada suhu 40 0 C, cadangkan masa yang diambil untuk 2 g magnesium larut sepenuhnya. Jelaskan jawapan anda. [3 marks]
(c) Based on the collision theory, explain why we need to store fresh milk in a refrigerator. Berdasarkan Teori Perlanggaran, terangkan mengapa kita perlu menyimpan susu segar dalam peti sejuk. [4 marks]
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Section C [20 marks]
Answer any onequestion. The time suggested to answer this section is 30 minutes
9 (a) Diagram 9 shows the reactions involved in the preparation of soluble salts.
DIAGRAM/ RAJAH 9
(i) Sodium, potassium and ammonium salts can be prepared using reaction between acid and alkali. State the reaction X, Y and Z. Garam natrium, kalium dan ammonium dapat disediakan melalui tindak balas antara asid dan alkali. Nyatakan tindak balas X, Y dan Z. [3 marks]
(ii) By choosing one of the reactions in (a) (i), suggest example of reactants used and products formed. Write the chemical equation for the reaction based on your suggestion. Dengan memilih satu daripada tindak balas dalam (a) (i), cadangkan contoh bahan- bahan tindak balas yang digunakan dan hasil-hasil tindak balas yang terbentuk. Tuliskan persamaan kimia bagi tindak balas berdasarkan cadangan anda itu. [3 marks] Soluble salts / Garam larut Sodium salts / Garam natrium Potassium salts / Garam kalium Ammonium salt / Garam ammonium Other salts / Garam lain Asid + alkali salt + water Asid + alkali garam + air Reaction / Tindak balas X Reaction / Tindak balas Y Reaction / Tindak balas Z http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 2 4541/2
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(b)
Answer the following questions based on the above statement. Jawab soalan- soalan berikut berdasarkan pernyataan di atas.
(i) Describe a laboratory experiment to prepare a dry magnesium sulphate. In your description, include the chemical equation involved. Huraikan satu eksperimen makmal untuk menyediakan garam magnesium sulfat yang kering. Dalam huraian anda sertakan persamaan kimia bagi tindak balas yang terlibat. [10 marks] (ii) Describe a simple chemical test of how you could differentiate between magnesium sulphate and magnesium nitrate. Huraikan satu ujian kimia ringkas bagaimana anda membezakan antara larutan magnesium sulfat dan magnesium nitrat. [4 marks]
10 Table 10 shows the molecular formula and heat of combustion of three types of alcohol. Jadual 10 menunjukkan formula molekul dan haba pembakaran bagi tiga jenis alkohol.
Alcohol/ Alkohol Molecular formula / Formula molekul Haba pembakaran / Heat of combustion (kJ mol -1 ) Methanol CH 3 OH 725 Ethanol C 2 H 5 OH 1 376 Propan-1-ol C 3 H 7 OH 2 015
TABLE / JADUAL 10
(a) (i) What is the meaning of the heat of combustion of an alcohol? Apakah yang dimaksudkan dengan haba pembakaran alkohol? [ 1 mark]
(ii) Explain why there are differences in the value of heat of combustion of the alcohols in Table 10. Terangkan mengapa terdapat perbezaan nilai haba pembakaran bagi alkohol-alkohol dalam Jadual 10. [ 3 marks] Magnesium sulphate is a soluble salt. Magnesium sulfat adalah garam terlarutkan. http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 2 4541/2
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(b) Describe an experiment that you can carry out in your school laboratory to determine the heat of combustion of one of the alcohol in Table 10. Your description should include precautionary steps and the steps involved in the calculation. Huraikan satu eksperimen yang anda boleh jalankan di makmal sekolah anda bagi menentukan haba pembakaran salah satu alkohol dalam Jadual 10. Huraian anda perlu mengandungi langkah berjaga-jaga dan langkah-langkah perhitungan yang terlibat. [12 marks]
(c) In another experiment to determine the heat of precipitation of lead (II) sulphate, 50.0 cm 3 of 2.0 mol dm -3 lead(II) nitrate solution is reacted with 50.0 cm 3 of 2.0 mol dm -3 sodium sulphate solution. Increment of the temperature in the mixture is 10 o C. Dalam satu eksperimen lain bagi menentukan haba pemendakan plumbum(II) sulfat, sejumlah 50 cm 3 larutan plumbum(II) nitrat 2.0 mol dm -3 dicampur dengan 50 cm 3 larutan natrium sulfat 2.0 mol dm -3 . Kenaikan suhu campuran ialah 10 o C.
The equation for the reaction is : Persamaan bagi tindak balas tersebut adalah :
Pb(NO 3 ) 2 + Na 2 SO 4 PbSO 4 + 2NaNO 3
Calculate the value of the heat of precipitation of lead(II) sulphate in this reaction. Hitungkan haba pemendakan plumbum(II) sulfat dalam eksperimen ini.
[Use the information that the specific heat capacity of water is 4.2 J g -1 o C -1 ] [Gunakan maklumat muatan haba tentu larutan adalah 4.2 J g -1 o C -1 ] [4 marks]
END OF QUESTION PAPER
http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 3 4541/3 4541/3 [Next page 3 Answer all questions The time suggested to complete Question 1 and Question 2 is 45 minutes
1 A student carried out two experiments to determine the concentration of HX acid solution. Seorang pelajar menjalankan dua eksperimen untuk menentukan kepekatan larutan asid HX.
Experiment I Eksperimen I
Titration of HX acid solution of unknown concentration with 20cm 3 of sodium hydroxide solution 1.0 mol dm -3 using phenolftalein as indicator. Pentitratan larutan asid HX yang tidak diketahui kepekatannya dengan 20cm 3 larutan natrium hidroksida 1.0 mol dm -3 menggunakan penunjuk fenolftalein.
Experiment II Eksperimen I I
Titration of similar HX acid solution of difference concentration with 20cm 3 of sodium hydroxide solution 1.0 mol dm -3 using phenolftalein as indicator. Pentitratan larutan asid HX lain yang tidak diketahui kepekatannya dengan 20cm 3 larutan Natrium Hidroksida 1.0 mol dm -3 menggunakan penunjuk fenolftalein.
Diagram 1 shows the initial and final burette readings for both experiments. Rajah 1 menunjukkan bacaan awal dan bacaan akhir buret bagi kedua-dua eksperimen.
Experiment 1 Eksperimen 1
Initial burette reading Final burette reading Bacaan awal buret Bacaan akhir buret
20 1 0 21 For Examiners Use http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 3 4541/3 4541/3 [Next page 4 Experiment II Eksperimen II
Initial burette reading Final burette reading Bacaan awal buret Bacaan akhir buret
Diagram 1 Rajah 1
(a) Construct a table to record the initial and final burette readings and the volumes of the acid used for both experiments. Bina jadual dan catat bacaan awal dan bacaan akhir buret serta isipadu asid yang digunakan bagi kedua-dua eksperimen di atas.
[ 3 marks]
(b) State the colour change of phenolftalein in the titration. Nyatakan perubahan warna fenolftalein dalam titratan tersebut.
.. [ 3 marks]
1(a)
1(b) 25 16 15 26 For Examiners Use http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 3 4541/3 4541/3 [Next page 5
(c) The chemical equation for the reaction in the experiment is : Persamaan kimia bagi tindak balas dalam eksperimen ini ialah :
Calculate the concentration of HX acid solutions used in both experiments. Hitung kepekatan larutan asid HX yang digunakan dalam kedua-dua eksperimen.
Experiment I Eksperimen I
Experiment II Eksperimen II
[ 3 marks]
(d) State the hypothesis in this experiment. Nyatakan hipotesis bagi eksperimen ini.
..
.. [ 3 marks]
HX + NaOH NaX + H 2 O
1(c)
1(d) For Examiners Use For Examiners Use http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 3 4541/3 4541/3 [Next page 6 (e) If HX acid is replaced with sulphuric acid of the same concentration, it is found that the volume of the sulphuric acid used in the titration is half of the volume of HX acid. Explain why. Jika asid HX digantikan dengan asid sulfurik yang mempunyai kepekatan yang sama, didapati isipadu asid sulfurik yang digunakan dalam titratan ialah separuh daripada isipadu asid HX. Terangkan mengapa.
[ 3 marks]
2 Diagram 2 shows the apparatus set-up for an experiment to compare the heat of combustion of methanol and ethanol. 200 cm 3 of water is used in this experiment. Rajah di bawah menunjukkan susunan radas bagi eksperiment untuk membandingkan Haba pembakaran antara metano dengan etanol. 200 cm 3 air digunakan dalam ekperimen ini.
Diagram 2 Rajah 2
Thermometer Thermometer
Tripod stand Tungku kaki tiga Copper container Bekas kuprum Spirit lamp Pelita Wooden block Blok kayu Alcohol Alkohol Water Air Wind shield Penghadang
1(e)
Total For Examiners Use http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 3 4541/3 4541/3 [Next page 7 The table below shows the results obtained from the experiment I the heat of combustion of methanol and experiment II the heat of combustion of ethanol. Jadual di bawah menunjukkan keputusan eksperimen I haba pembakaran methanol dan eksperimen II haba pembakaran etanol.
Experiment I Eksperimen I Experiment II Eksperimen I I
Initial temperature of water: .................. Suhu awal air
Initial temperature of water: ......................... Suhu awal air
Highest temperature of water: ........................... Suhu tertinggi air
Highest temperature of water: .......................... Suhu tertinggi air
Initial mass of spirit lamp and methanol: .............g Jisim awal pelita dan metanol
Initial mass of spirit lamp and ethanol: ....... g Jisim awal pelita dan metanol
Final mass of spirit lamp and methanol: ......g Jisim akhir pelita dan metanol
Final mass of spirit lamp and ethanol: ............. g Jisim akhir pelita dan etanol 20 25 15 20 25 15 60 65 55 60 65 55 150.50 245 150.50
149.37
151.35
For Examiners Use http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 3 4541/3 4541/3 [Next page 8 (a) Write the readings of the temperature and the mass of spirit lamp and alcohol in the spaces above. Tuliskan bacaan suhu dan jisim pelita dan alkohol dalam ruangan di atas. [3 marks]
(b) Based on the information above, complete the table below. Berdasarkan kepada maklumat di atas lengkapkan jadual di bawah.
Name of variables Nama pemboleh ubah Action to be taken Tindakan yang dibuat (i) Manipulated variable: Pemboleh ubah dimanipulaskan:
............
...........
(i) The way to manipulate variable: Cara mengubah pemboleh ubah dimanipulasi:
....................
....................
(ii) Responding variable: Pemboleh ubah bergerak balas:
(ii) What to observe in the responding variable: Apa yang diperhatikan bagi menentukan pemboleh ubah gerak balas:
....................
....................
(iii) Fixed variable: Pemboleh ubah yang dimalarkan:
...
...
(iii) The way to maintain the controlled variable: Cara menetapkan pemboleh ubah dimalarkan :
[3 marks]
(c) (i) Calculate the energy change in the experiment I and II. Hitungkan perubahan tenaga dalam eksperimen I dan II [Given: Energy change = mc, specific heat capacity of water, c = 4.2 Jg -1o C] [Diberi: perubahan tenaga = mc, muatan haba tentu air, c = 4.2 Jg -1o C]
[3 marks]
2(a)
2(b)
2(c)(ii) For Examiners Use http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 3 4541/3 4541/3 [Next page 9 (ii) Calculate the number of moles of methanol and ethanol burnt in this experiment. Hitungkan bilangan mol methanol dan etanol yang terbakar dalam eksperimen ini. [Molar mass of methanol = 32 g mol -1 ] [Molar mass of ethanol = 46 g mol -1 ] [Jisim molar metanol = 32 g mol -1 ] [Jisim molar etanol = 46 g mol -1 ]
[3 marks]
(iii) Calculate the heat of combustion of methanol in this experiment. Hitungkan haba pembakaran metanol dalam eksperimen ini.
[3 marks]
(d) Predict the heat of combustion of ethanol compare to the heat combustion of methanol. Ramalkan haba pembakaran etanol berbanding dengan haba pembakaran methanol.
[3 marks]
2(c)(ii)
2(c)(iii)
2(d)
Total For Examiners Use http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry paper 3 4541/3 4541/3 [Next page 10
You are given the copper strip, lead strip, iron strip, zinc strip, aluminium strip, magnesium strip and copper(II) sulphate solution.Referring to the statement above, plan a laboratory experiment to construct the electrochemical series of the potential differences using different pair of metals. Your explanation should include all the followings: Anda dibekalkan dengan kepingan kuprum, kepingan plumbum, kepingan ferum, kepingan zink, kepingan aluminium, kepingan magnesium dan larutan kuprum(II) sulfat. Merujuk kepada situasi di atas, rancangkan satu eksperimen dalam makmal untuk membina siri elektrokimia . Penerangan anda hendaklah mengandungi perkara-perkara berikut:
(a) Aim of the experment Tujuan eksperimen
(b) All the variables Semua pemboleh ubah yang terlibat
(c ) Statement of the hypothesis Pernyataan hipotesis
(d) List of materials and apparatus Senarai bahan dan alat radas
(e) Procedure of the experiment Prosedur eksperimen
(f) Tabulation of data Penjadualan data
[ 17 marks ]
END OF QUESTION PAPER
The further the distance between two metals in the electrochemical series, the bigger the potential difference. Semakin jauh kedudukan pasangan logam dalam siri elektrokimia, semakin besar nilai voltan.
http://chngtuition.blogspot.com SPM Chemistry skema gerak gempur paper 1
1 A 21 A 41 A 2 C 22 A 42 A 3 A 23 C 43 C 4 C 24 C 44 A 5 D 25 C 45 A 6 D 26 C 46 B 7 C 27 D 47 B 8 C 28 D 48 C 9 D 29 C 49 D 10 A 30 B 50 B 11 C 31 D 12 D 32 D 13 D 33 C 14 D 34 B 15 C 35 C 16 C 36 D 17 C 37 A 18 B 38 C 19 C 39 D 20 C 40 C
http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 2 4541/2
1 Section A
1 (a) (i) The number of protons in an atom 1 (ii) 12 1
(b) X and Y 1 Because same proton number/the number of proton but difference number of neutron/nucleon number
1
(c) 2.8.7 1
(d) (i)
Electron arrangement Label 17p & 18n
1 1 (ii) 7 1 (iii) Y - 1
(e) X 35 17
1 10
2 (a) 2.7 1
(b) (i) Period 2 1 (ii) Atomic size of X is smaller than V // Atomic size of V bigger than X. 1 (iii) The number of proton in atom X is more than V. The attraction by the nucleus on electron in atom X is stronger than V. or The number of proton in atom V is less than X. The attraction by the nucleus on electron in atom V is weaker than X. 1 1
1 1...2
(c) (i) VW 4 1 (ii) has low melting / boiling point // cannot conduct electricity in any state // soluble in organic solvent
1
(d) (i) Ionic compound 1
(ii)
U W 17p 18n http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 2 4541/2
2
[Number of electron each shells are correct] [Number of charge symbol are correct]
1 1
10
3 (a) Chemical to electrical 1
(b) Cu 2+ , H + , OH - and SO 4 2- 1
(c) (i) Zinc 1 (ii) Zinc atom releases electrons//Zinc more electropositive // Zn above in electrochemical series
1
(d) (i) Brown solid deposited 1 (ii) Cu 2+ + 2e Cu 1
(e) Blue to colourless// Blue become fade/ paler // The intensity of blue colour decreases. The number of copper(II) ions decreases //The concentration of copper(II) ions decr 1
1
(f) (i) Cu, R, Q, P 1 (ii) 1.5 V 1
10
4 (a) (i) Saponification 1 (ii) Concentrated sodium hydroxide solution 1 (iii) to lower the solubility of soap 1 (iv) Water: x Grease: y 1
(b) (i) silicon dioxide 1 (ii) inert towards chemicals 1 (iii) Borosilicate glass 1
(c) (i) Structural material that is formed by combining two or more different subtances.
1 (ii) silver bromide / Copper(I) chloride 1 (iii) darken when exposed to sunlight 10 5 (a) (i) alcohol 1
(b) (i) H H H H
H C C C C-O-H
1 http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 2 4541/2
3 H H H H (ii) 2-methylpropan-2-ol 1
(c) (i) Esterification 1 (ii) C 4 H 9 OH + C 3 H 7 COOH C 3 H 7 COOC 4 H 9 + H 2 O 1 (iii) Insoluble in water // sweet smell // volatile 1
(d) [Functional diagram] [Label] 1 1
(e) (i) Addition reaction 1 (ii) The colour of bromine water change from brown to colourless 1
10
6 (a) To allow the movement of ions. 1 (b)
1
(c) (i) Colourless change to brown 1 (ii) Place a few drops of starch solution. A blue precipitate is formed. 1 1
(d) Iodide ion // potassium iodide Loss electron//increase in oxidation number 1 1
(e) Cl 2 + 2e 2Cl - 1
(f) Bromine water // acidified KMnO 4 solution // acidified K 2 Cr 2 O 7
Dilute sulphuric acid G Electrode Q Chlorine water Potassium iodide solution Electrode P e e e e http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 2 4541/2
4 (ii) Yellow precipitate Lead(II) iodide
2KI + Pb(NO 3 ) 2 PbI 2 + 2KNO 3 Formula of reactants and products are correct Balance 1 1
1 1...4
(b) XH react with QY 2 to produce QX 2 and HY // Reactants : XH and QY 2 Products : QX 2 and HY
HX aqueous solution react with QY 2 aqueous solution to produce QX 2 solid and HY aqueous solution
2 mole of HX react with 1 mole of QY 2 to produce 1 mole of QX 2 and 2 mole of HY.
1..3 (iii) Empirical formula Molecular formula The formula shows that carbon and hydrogen are present The formula shows that carbon and hydrogen are present The formula shows that the ratio of carbon to hydrogen is 1:2 The formula shows that one molecule of X consists of 4 carbon atoms and 8 hydrogen atoms
1 + 12 20
8 (a) Size of solid particles Concentration of solution 1 Temperature 1 Catalyst 13 [any three] http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 2 4541/2
5
(b) (i) Mg + 2H + Mg 2+ + H 2 1
(ii) Comparing experiment II and experiment I
The concentration of hydrochloric acid in experiment II is higher than experiment I . 1
The frequency of collision between H + ions and magnesium atom increases. 1
The frequency of effective collision increases. 1
Comparing experiment II and experiment III
The total surface area of magnesium in experiment III is larger than experiment II. 1
The frequency of collision between H + ions and magnesium atom increases. 1
The frequency of effective collision increases. 1
Comparing experiment II and experiment IV
Copper(II) sulphate solution is a catalyst 1 It lower the activation energy 1 The number of effective collision increases. 1.. 9
(iii) The time taken becomes shorter / less than 60s 1
When the temperature increases, the kinetic energy of H +
ions increases / H + ions move faster. 1
The frequency of effective collision between H + ions and magnesium atom increases // The number of effective collision increases. 1........3
(c) The temperature inside the refrigerator is lower 1 Bacteria are not active at low temperature 1 Decomposition of milk caused by bacteria will slow down 1 This will keep the milk fresh for a longer period 1...4 20 Section C
9. (a) (i) 1. acid and metal oxide 1 2. acid and reactive metal 1 http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 2 4541/2
6 3. acid and metal carbonate 1 3
(ii) Sample answer [ Name any acid ] and [ Name any metal / metal oxide / metal carbonate ] 1 [ Name equivalent salt and water// water + CO 2 // water + H 2 ] 1 [ Balanced equation ] 1 3
Sample answer : 1. [chemical substances] magnesium powder /magnesium oxide(Hydroxide, carbonate) and sulphuric acid 1 2. [ apparatus] Beaker, filter funnel, filter paper, glass rod 1 3. [procedure] [20 100] cm 3 sulphuric acid [0.5 2.0 ] mol dm -3 is poured into a beaker 1 4. magnesium powder is added to sulphuric acid until undissolved /excess / no more effervescence 1 5. Stir 6. the mixture is filtered 1 7. the filtrate is evaporated until saturate (one-third of it original volume) 1 8. the saturated solution is then allowed to cool to room temperature. 1 9. crystals is dried between filter paper 1 10. [chemical equation] Mg + H 2 SO 4 MgSO 4 + H 2 // MgO + H 2 SO 4 MgSO 4 + H 2 O// MgCO 3 + H 2 SO 4 MgSO 4 + CO 2 + H 2 O 1.... 10
(ii) [ test for sulphate ]
1. Each of solution is filled into a two test tube 1 2. Lead (II) nitrate/ Silver nitrate is added to both of test tube 1 3. If no change occur magnesium nitrate solution 1 4. If white precipitate is formed magnesium sulfat solution 1.... 4
OR [test for nitrate]
1. Each of solution is filled into a two test tube 1 2. [Add] dilute sulphuric acid, Iron (II) sulphate solution, concentrated sulphuric acid to both of test tube 1 3. if brown ring is formed magnesium nitrate solution 1 4. If no changes occur magnesium nitrate solution 1... 4 20
10 (a) (i) The heat given off when onemole of an alcohol is burnt completely in an excess of oxygen.
1 (ii) As the number of carbon atom increase, the value of heat combustion increase. 1
http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 2 4541/2
7 The greater the number of carbon atoms, the more products will be obtained. More heat is released for the formation of bonds 1
1
(b) Procedure :
1. Measure [100 -250] cm 3 of water and pour it into the copper container /aluminium can 2. Measure and record the initial temperature of the water. 3. Fill the small lamp with alcohol* then weigh it and record the initial mass. 4. Light the wick of the lamp. 5. Place the lamp as near as possibleto the copper container.// [ Diagram : Using wooden block ] 6. [The apparatus is protected by a wind shield] // [Diagram] 7. Stir the water continuously. 8. Put out / blown out the flame when the temperature rises [ 10 30 ] o C and record the highest temperature of the water. 9. Weigh the lamp as quickly as possibleand record the final mass.
1 1
1 1
1 1 1
1 1
Result :
Initial temperature of the water/ o C = T 1 Highest temperature of the water/ o C = T 2 Temperature rise of the water/ o C = T 2 T 1
Initial mass of lamp + alcohol* / g = m 1 Final mass of lamp + alcohol* / g = m 2
Mass of alcohol that was burnt / g = m 1 m 2
1
Calculation :
Energy chage/heat given off = 200 4.2 (T 2 T 1 )
Number of mole of alcohol =
Heat of combustion of alcohol*, H =
=
1
1
1
13 Max 12
(c) Number of mole of lead(II) nitrate = 50 x 2 1000 = 0.1 mol or
m 1 m 2
M r of alcohol* Energy change Number of mole of alcohol 200 4.2 (T 2 T 1 ) m 1 m 2
M r of alcohol* http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 2 4541/2
8 Number of mole of sodium sulphate = 50 x 2 1000 = 0.1 mol
1
Ratio of mole :
1 mol Pb(NO 3 ) 2 / Na 2 SO 4 1 mol PbSO 4
0.1 mol Pb(NO 3 ) 2 / Na 2 SO 4 0.1 mol PbSO 4
1
Energy chage/heat given off = 200 4.2 10 = 4200 J
1
Heat of precipitation of PbSO 4 = 1 . 0 4200
= 42000 J mol -1 / 4.2 kJ mol -1
14
20
END OF MARKING SCHEME
http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 3
1 Question Number Rubric Score 1(a) [Able to exhibit the tabulation of data correctly]
Tabulation of data has the following element : 3 columns and 4 rows Table contains topics, labeled with two decimal place and unit Example :
Experiment I II Initial reading/ cm 3 0.45 15.45 Final reading / cm 3 20.45 25.45 Volume of HX /cm 3 20.00 10.00 3 [Able to exhibit the tabulation of data less accurately, without unit/ one decimal place] 2 [Able to state an idea about tabulation of data] Table contains at least two columns and two rows 1 [ No response or wrong response] 0
Question Number Rubric Score 1(b) [Able to state one observation accurately] Example : Red/Pink to colourless 3 [Able to state one observation less accurately] Example : colourless 2 [Able to state an idea about the observation] The colour changes // pink 1 [ No response or wrong response] 0
http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 3
2
Question Number Rubric Score 1(c) [Able to show the calculation of HX acid concentration with the unit for both experiment correctly]
Example : Experiment I The concentration of HX acid = (1)(20) / 20 = 1.0 moldm -3 or (i) Number of mole for NaOH = (1)(20)/1000) = 0.02 mol (ii) Based on the equation, 1 mol of NaOH reacts with 1 mol of HX acid, 0.02 mol of NaOH reacts with 0.02 mol of HX acid. (iii) Concentration of HX acid = ( 0.02 x 1000 ) / 20 = 1.0 moldm -3
Experiment II The concentration of HX acid = (1)(20) / 10 = 2.0 moldm -3 or (i) Number of mole for NaOH = (1)(20)/1000) = 0.02 mol (ii) Based on the equation, 1 mol of NaOH reacts with 1 mol of HX acid, 0.02 mol of NaOH reacts with 0.02 mol of HX acid.
(iii) Concentration of HX acid = ( 0.02 x 1000 ) / 10 = 2.0 moldm -3
3 [Able to show the calculation of HX acid concentration without unit for both experiment less correctly]
2 [Able to show an idea to calculate the concentration] 1 [ No response or wrong response] 0 http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 3
3
Question Number Rubric score 1(e) [Able to compare HX acid with sulphuric acid correctly] Example : HX acid is a monoprotic/monobasic acid Sulphuric acid is a diprotic/dibasic acid Number of hydrogen ion in 1 mol of sulphuric acid is double of HX acid// total number of hydrogen ions in both solution are the same 3 [Able to state any two of the above mentioned answers less correctly]
2 [Able to state any one of the above mentioned answers ]
1 [ No response or wrong response] 0
Question Number Rubric Score 2(a) [Able to write initial and final temperature with one decimal, initial and final mass of spirit lamp and methanol and ethanol with two decimal in experiment I and II with unit accurately] Answer : Experiment I : Initial temperature of water : 25.0 o C Highest temperature of water : 65.0 o C Initial mass of spirit lamp and methanol: 150.50 g Final mass of spirit lamp and methanol : 149.37 g
Experiment II : Initial temperature of water : 25.0 o C Highest temperature of water : 65.0 o C Initial mass of spirit lamp and ethanol: 151.35 g Final mass of spirit lamp and ethanol : 150.50 g 3 Question Number Rubric Score 1(d) [Able to state hypothesis correctly ] Example : The higher/lower the concentration of HX acid, the lower/higher the volume of the acid to neutralize the sodium hydroxide solution / alkali. 3 [Able to state hypothesis almost correct ] Example : The lower/higher the volume of the acid to neutralize the alkali, the higher/lower the concentration of HX acid. 2 [Able to state an idea about the hypothesis] Example: Concentration of the acid affects the volume of acid 1 [ No response or wrong response] 0 http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 3
4 [Able to write initial and final temperature of water with one decimal without unit, initial and final mass of spirit lamp and methanol and ethanol with two decimal in experiment I and II accurately] 2 [Able to write at least one initial or final temperature of water without unit, initial or final mass of spirit lamp and methanol and ethanol in experiment I and II ] 1 [ No response / wrong response ] 0
Question Number Rubric Score
2 (b)
[ Able to state three variables and the way to control them correctly ] Example : Manipulated variable : Types of alcohol//ethanol and methanol
Using difference alcohol Responding variable : Heat of combustion
The different of mass of difference alcohol Fixed variable : Volume of water// same increment of temperature
Using the same volume of water // same increment of temperature 3 [ Able to state any pair of variable and action correctly ] ] 2 [ Able to state any variable and any action correctly // any two variables correctly // any two action correctly] 1 [ No response or wrong response] 0
Question Number Rubric Score 2(c)(i) [ Able to show the calculation correctly with unit ] Example : Experiment I Energy change = 200 x 4.2 x 40 = 33 600 J Experiment II Energy change = 200 x 4.2 x 40 = 33 600 J
3 [ Able to show the calculation correctly without unit ]
2 [ Able to state an idea the calculation the energy change]
1 [ No response or wrong response] 0 http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 3
5
Question Number Rubric Score 2(c)(ii) [ Able to show the calculation correctly with unit] Example : The number of moles methanol = 1.13 = 0.035 mol 32 The number of moles ethanol = 0.85 = 0.018 mol 46
3 [ Able to show the calculation correctly without unit]
2 [ Able to state an idea the calculation the number of mole]
1 [ No response or wrong response] 0
Question Number Rubric Score 2(c)(iii) [ Able to show the calculation correctly with unit ] Example : The heat combustion of methanol = 33 600 J 0.035 = 960 000 J mol -1 = 960 kJ mol -1
3 [ Able to show the calculation correctly without unit]
2 [ Able to state an idea the calculation the heat of combustion of methanol]
1 [ No response or wrong response] 0
Question Number Rubric Maxi mum Score 2(d) [Able to predict the heat combustion of ethanol correctly] Example: Higher than heat combustion of methanol 3 [Able to state the heat combustion of ethanol] Example: 1818 kJ mol -1 [The heat combustion of ethanol from calculation ] 2 [Able to state an idea the heat combustion of ethanol] Example: same 1 [ No response or wrong response] 0
http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 3
6
Question Number Rubric Score 3(a) [ Able to give the aim of the experiment correctly ] Example : To construct the electrochemical series based on the potential differences between metals 3 [ Able to give the aim of the experiment incorrectly ] Example : To construct the electrochemical series //How to construct an electrochemical series based on the potential difference between metals? 2 [ Able to state an idea the aim of the experiment] Example : To study the potential difference between the metals 1 [ No response or wrong response] 0
Question Number Rubric Score 3(b) [ Able to state All variables correctly ] Example : Manipulated variable : Pairs of different metals//Different types of metals Responding variable : Potential differences Constant variable : Concentration of Copper(II) sulphate // positive terminal 3 [ Able to state any two variables correctly ] 2 [ Able to state any one variables correctly ] 1 [ No response or wrong response] 0
Question Number Rubric Score 3(c) [ Able to give the hypothesis correctly] Example : The distance between two metals increase/decrease, the potential difference will increase/ decrease 3 [ Able to give the hypothesis almost correct] Example : The potential difference will increase if the distance between two metals increase 2
[ Able to state an idea of the hypothesis ] Example : The potential difference affects the position of the metals 1 [No response or wrong response] 0
http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 3
7
Question Number Rubric Score 3(d) [ Able to give the list of the apparatus and materials correctly and completely] Example : List of apparatus and materials Copper strip, lead strip, iron strip, zinc strip, aluminium strip, magnesium strip, copper (II) sulphate solution, sand paper, voltmeter, beaker, connecting wires with crocodile clip 3 [ Able to give the list of the apparatus and materials correctly and but not completely] Example : List of apparatus and materials Copper strip, lead strip, zinc strip, magnesium strip[at least 4 metal strips], copper (II) sulphate solution, voltmeter, connecting wires 2
[ Able to give an idea about the list of the apparatus and materials correctly] Example : Any one apparatus and one material 1 [No response or wrong response] 0
Question Number Rubric Score 3(e) [ Able to state all procedures correctly ] Example : 1. Clean the metals with sand paper 2. Fill a beaker with copper(II)sulphate solution 3. Dip the magnesium strip and copper strip into the copper(II)sulphate solution 4. Complete the circuit//switch-on the circuit 5. Record the potential difference between the metals 6. Determine and record which metal strip is the negative terminal 7. Repeat steps 1 to 6 using other metals to replace magnesium strip
3 [ Able to state 4 steps of procedures correctly ] Steps 2,3,5,7 2 [ Able to state 2 steps of procedures correctly ] Steps 3,5 1 [No response or wrong response] 0
http://chngtuition.blogspot.com Gerak Gempur SPM Chemistry skema paper 3
8
Question Number Rubric Score 3(f) [ Able to exhibit the tabulation of data correctly ] Tabulation of data has the following element : 1. 3 columns and 6 rows Example : Pair of metals Potential difference (V) Negative terminal Mg and Cu Al and Cu Zn and Cu Pb and Cu Fe and Cu 3 [ Able to exhibit the tabulation of data almost correctly ] Example : Pair of metals Potential difference
2 [ Able to state an idea about the tabulation of data ]