Book of Abctracts Cnfa2013

The 5-th National Conference of Applied Physics
Iasi, Romania, May 23 - 24, 2013

ORGANIZED by: Gheorghe Asachi Technical University of Iasi Faculty of Machine Manufacturing and Industrial Management Department of Physics
under auspices of the Romanian Ministry of Education, Research, Youth and Sport supported by National Authority for Scientific Research Romania Romanian Physical Society
The 5-th National Conference of Applied Physics _______________________________________________________________________ Iasi, Romania May 23 - 24, 2013 _______________________________________________________________________
Foreword
CNFA-2013 is the fifth Conference of Applied Physics that is organized by "Gheorghe Asachi" Technical University of Iasi, Department of Physics and Romanian Ministry of Education, Research, Youth and Sport. The first conference was organized in 2004, the second in 2006, the third in 2008 and the fourth in 2010. More than 200 scientists participated at these conferences from various countries: France, USA, Ireland, Israel, Finland, Sweden, Russia, Ukraine, Rep. Moldova, and Estonia. From Romania all major universities are represented: Iasi, Bucharest, Cluj, Timisoara, Constanta, Brasov, Sibiu, Bacau, Craiova, etc. The aim of CNFA 2013 is to provide a national forum for all participants, established scientists, young researchers and students, from academia and industry to review the latest research and developments in the field of applied physics. Accepted papers presented by their author(s) will be published in a special number of the journal Bulletin of the Polytechnic Institute of Iasi, Mathematics. Theoretical Mechanics. Physics (recognized by CNCSIS, as a B+ category journal).
Sponsors:
Committees
Chairs:
Gheorghe Nag, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Cristian Foca, PhD. (University of Sciences and Technologies of Lille, France) Rodica Bdescu, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Ciprian Dariescu, PhD. (Al. I. Cuza University of Iasi, Romania.) Dana Ortansa Dorohoi, PhD. (Al. I. Cuza University of Iasi, Romania.) Eugen Neagu, PhD. (Universidade Nova de Lisboa, Caparica-Portugal).
Members:
Maricel Agop, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Octav Baltag, PhD. (Gr.T.Popa University of Medicine and Pharmacy Medicine, Iasi, Romania) Horia Chiriac, PhD. (The National Institute for R&D of Technical Physics Iasi, Romania) Silviu Gurlui, PhD. (Al. I. Cuza University of Iasi, Romania) Pavlos D. Ioannou, PhD. (University of Athens, Greece.) Jose N. Marat-Mendez, PhD. (Lisabona Univ., Portugal) Shuji Miyamoto, PhD. (Hyogo Univ., Japan) Takayasu Mochizuky, PhD. (Hyogo Univ., Japan) Viorel-Puiu Pun, PhD. (Polytechnical University, Bucureti, Romania) Viorel Pop, PhD. (Babe-Bolyai University, Cluj-Napoca, Romania) Sebastian Popescu, PhD. (Al. I. Cuza University of Iasi, Romania) Georgeta Strat, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Mitachi Strat, PhD. (Al. I. Cuza University of Iasi, Romania.) Mihai Visinescu, PhD. Mgurele, Romania) Dumitru Vulcanov, PhD. (West University of Timioara, Romania) Gheorghe Zet, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Nicoleta Lupu, PhD. (The National Institute for R&D of Technical Physics Iasi, Romania) Adriana Savin, PhD. (The National Institute for R&D of Technical Physics Iasi, Romania) 3 (Horia Hulubei National Institute of Physics and Nuclear Engineering,
Raimond Grimberg, PhD. (The National Institute for R&D of Technical Physics Iasi, Romania) Dan DImitriu, PhD. (Al. I. Cuza University of Iasi, Romania.) Mariana Aura Dariescu, PhD. (Al. I. Cuza University of Iasi, Romania.) Gheorghe Cata-Danil, PhD. (Polytechnical University, Bucureti, Romania) Aurel Mihai Vlaicu, PhD. (The National Institute for R&D of Materials Physics Mgurele, Romania) Gabriel Lazar, PhD. (University of Bacu, Romnia) Daniel Condurache, (Gheorghe Asachi Technical University of Iasi, Romania)
Local organizing committee:

Brndusa Ciobanu, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Petru Edward Nica, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Rodica Bdescu, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Lcrmioara Salomeia, PhD (Gheorghe Asachi Technical University of Iasi, Romania) Gabriela Apreotesei, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Magda Gherghel, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Liviu Bdeli, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Simona-Elena Bci, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Cristina-Delia Nechifor, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Sorin-Bogdan Balmu, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Marian Lucanu. (Gheorghe Asachi Technical University of Iasi, Romania)
Local Committee for Conference Programme:

Maricel Agop, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Irina Radinschi, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Rodica Bdescu, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Petru Edward Nica, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Brndusa Ciobanu, PhD. (Gheorghe Asachi Technical University of Iasi, Romania) Cristina-Delia Nechifor, PhD. (Gheorghe Asachi Technical University of Iasi, Romania)
Conference Sections:
1. Theoretical, Mathematical and Computational Physics. 2. Physics and Technology of Condensed Matter. 3. Polymer Physics and Engineering. 4. Optics, Spectroscopy and Plasma Physics. 5. Technical Physics and Interdisciplinary.
CONFERENCE PROGRAMME:
Thursday 23th May 2013: 800-1000- Registration 1000 -1015 Opening Ceremony 1015 -1145- Plenary Session (Invited Talks) 1145 -1215- Coffee Break 1215 -1345- Plenary Session (Invited Talks) 1100-1900- Physics Instruments Exposition 1315-1600- Lunch Break 1600-1715- Oral Session (Section 1) 1715 -1730- Coffee Break 1730-1900- Poster Session (All Sections) 2100 Festive Dinner Friday 24th May 2013: 1000-1115- Oral Session (Section 2, and 3) 1115 -1130- Coffee Break 1130-1220- Oral Session (Sections 4 and 5) 1220-1230- Closing Ceremony 1000-1200- Physics Instruments Exposition Auditorium T1 Corp T Hall Corp T Hall Auditorium T1 Corp T Hall Auditorium T1 Corp T Hall Corp T Hall Cornelius Restaurant Corp T Hall Auditorium T1 Auditorium T1 Corp T Hall Auditorium T1 Corp T Hall
Thursday 23 May 2013:

10.00 -10.15 10.15-11.45
Opening Ceremony
Plenary Session (Invited Talks) Chairman: dr. Dana-Ortansa DOROHOI
TITLE OF THE PAPER AUTHORS High Technological Potential Materials Explored by Laser Ablation Supramolecular Chemistry Generating New Properties Through Physical Interactions AFFILIATION Laboratoire de Physique des Lasers, Atomes et Molcules (UMR CNRS 8523), Universit Lille 1 Sciences & Technologies, 59655 Villeneuve dAscq, France
3
I 10.15-10.45
Cristian Focsa
II 10.45-11.15
Valeria HARABAGIU Nicoleta LUPU Horia Chiriac, Sorin Corodeanu, Gabriel Ababei, Marian Grigoras COFFEE BREAK
Petru Poni Institute of Macromolecular Chemistry Iai. National Institute of Research and Development for Technical Physics, 47 Mangeron Boulevard, 700050 Iasi, Romania
Low TC Fe-Nb-Cr-B Glassy Alloys for Medical 11.15-11.45 Applications

III 11.45-12.15 12.15-13.45 IV
Plenary Session (Invited Talks) Chairman: dr. Mihai VLAICU

Mihaela Racuciu, Dorina CREANG, Vasile Badescu, Anton Airinei University Alexandru Ioan Cuza, Physics Faculty, 11 Blvd. Carol I, Iasi, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Blvd., 700506 Iasi, Romania
Magnetizable Nanofluids as Biocompatible 12.15-12.45 Suspensions with Various Molecules Coating Magnetite Grains On the Hysteresis V Phenomenon in NonEquilibrium Phase 12.45-13.15 Transitions Molecular Spin Crossover Materials: New Perspectives in Molecular Spintronics and Nanoelectronics
Sebastian POPESCU
VI 13.15-13.45
13.45-16.00
Aurelian ROTARU C. Lefter,1 R. P. Tan,3 I. A. Guralskiy,2,4 L. Faculty of Electrical Engineering Salmon2, P. Demont5, and Computer Science, Stefan 3 J. Carrey , G. cel Mare University, Suceava, Molnr,2 M. Romania Respaud3 and A. Bousseksou2 LUNCH BREAK
16.00-17.15
Oral Session (Section 1) Chairman: dr. Sebastian POPESCU Section 1. Theoretical, Mathematical and Computational Physics Title of the paper Authors Affiliation
Faculty of Physics, Alexandru Denisa-Andreea Mihu, MarinaIoan Cuza University of Iasi, Aura Dariescu, Carol I, no.11, 700506, Iasi, Ciprian Dariescu Romania Corina Faculty of Physics, Alexandru Dynamical Analysis of S1-O2 Atefnoaei, Ioan Cuza University of Iasi, Visuospatial Saccadic System Dorina Creang, Carol I, no.11, 700506, Iasi, Applying Chaos Diagnosis Elena Pretegiani, 16.25-16.50 Romania Tests Lance M. Optican Faculty of Physics, Al. I. Cuza S1-O3 The Numerical Solve of Lucian-Mihai University, Bd. Carol I, 11, Lane-Emden Equation for COSOVANU 700506, Iai, Romania 16.50-17.15 the Solar Internal Structure 17.15-17.30 COFFEE BREAK 17.30-19.00 Poster Session ( All Sections) An Analytical Approach to the Kompaneets Equation in Highly Magnetized Neutron 16.00-16.25 Stars Magnetosphere S1-O1
2100
Festive Dinner
Friday, 24 May 2013

10.00-11.45
Oral Session (Section 2, 3 and 4) Chairman:dr. Cristian FOCA Section 2. Physics and Technology of Condensed Matter. Title of the paper Authors Affiliation
Corneliu Srbu National Institute of R&D for Materials Physics (MgureleBucharest, 105bis Atomistilorstreet, POBox-MG7, 077125, Romania Petru Poni Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda, 41A, 700487, Iasi, Romania
Towards a New Technology S2-O2 of Tailoring Enhanced Surface Parameters of 10.00-10.25Stainless Alloys S3-O1 Laser Light Scattering Study 10.25-10.50 on Salted Solutions of Grafted Pullulans.
Section 3. Polymer Physics and Engineering

Anca Giorgiana Grigoras, Vasile Cristian Grigoras
Section 4. Optics, Spectroscopy and Plasma Physics.

Characterization of Particle Emission from Carbon Laser 10.50-11. 15 Ablation Using a 3-Grids Faraday Cup S4-O1 Petru-Edward Nica, Cristian Ursu Gheorghe Asachi Technical University of Iasi, Blvd. Mangeron no.63, Iasi 700050, Romania
11.15-11.30 11.30-12.20 S4-O2 11.30-11.55
COFFEE BREAK
Oral Session (Section 4 and 5) Chairman: Silviu GURLUI

Chuas Circuit: Chaotic Dynamics and Control of Oscillations Stefan-Andrei Irimiciuc, Ovidiu Vasilovici, DanGheorghe Dimitriu Aurel L. Strat , Ryan Falk , Ramin Pashaie Faculty of Physics, Alexandru Ioan Cuza University, 11 Carol I Blvd., RO-700506 Iasi, Romania,
Section 5. Technical Physics and Interdisciplinary

Optogenetics: New Paradigm Requesting Adapted Tools 11.55-12.20 and Technologies 12.20-12.30 S5-O1 University of Medicine Gr. T. Popa, Department of Pharmacology - Algesiology, Iasi, Romania
Closing Ceremony
Poster Session
Section 1. Theoretical, Mathematical and Computational Physics Title of the paper
S1-P1 On a Schrdinger-Like Equation with Some Special Potential Energy-Momentum Localization for a Space-Time Geometry Exterior to a Black Hole in the Brane World Travelling Waves and Shapiro Steps in a Tumor - Growth Model
Authors
Ciprian Creu
Affiliation
Faculty of Physics, Alexandru Ioan Cuza University of Iasi, Bd.Carol I, no. 11, 700506 Iai, Romania Gheorghe Asachi University of Iasi, Bd. D. Mangeron, no. 67
S1-P2
Irina Radinschi, Theophanes Grammenos, Andromahi Spanou
S1-P3
S1-P4
Perumpananis Malignant Invasion Model with a Small Amount of Diffusion in the Framework of Scale Relativity Theory
Clin Gheorghe Buzeaa, Mihaela Maria Opreab, National Institute of Manuela Oprianb, Research and Development Anioara Anghelacheb, for Technical Physics, D. b Irina Butuc ,Alina Mangeron 47, Iai 700050, Rogojanub, Drago Romania c Iancu Clin Gheorghe Buzeaa, Mihaela Maria Opreab, National Institute of Manuela Oprianb, Research and Development Anioara Anghelacheb, for Technical Physics, D. Irina Butucb,Alina Mangeron 47, Iai 700050, Rogojanub, Drago Romania Iancuc 9
National Institute of Research and Development for Technical Physics, Iasi, 47 Mangeron Boulevard, Romania
S1-P5
New Landmark in the Study of Geometry and Parallel Computation Applied to NanoWires Magnetic Properties
Sergiu Mohorianu
Section 2. Physics and Technology of Condensed Matter.

S2-P1 Sequential Pulsed Laser Deposition of Al-doped ZnO Thin Films: Doping Concentration and Oxygen Partial Pressure Influences Structural Properties of Zirconia Thermal Barriers for Aerospace Applications Obtained by Plasma Jet Deposition Capacitive Mems Switches: The Modification of the Pull-In Voltage by The Trapped Space Charge Magnetic Properties and Thermal Stability of Nd2Fe14 B/SmCo-Based Hybrid Magnets The Properties of Ferrofluid with Modified Stabilisant Characteristics of Negative Photoconduction at Some Schottky Structures with Electric Field Effect Based on Photosynthetic Pigments Considerations on Scattered Fields of Some Equipments Working in the 75 3000 Mhz Bands Cristian Ursu , Tudor Coman b and Ovidiu Florin Caltun b I. Mercioniu a, C. Ghica, A.M. Vlaicu a, V. S. Teodorescu a, A.V. Maraloiu a, R. Negrea, A. Stefanb, V. Manoliub, Gh. Ionescub E. R. Neagu and J. N. Marat-Mendes1 Marian Grigorasa, Margaritis Gjokab, Mihaela Grigorasa, Nicoleta Lupua, Horia Chiriaca R. Badescu, D. Condurache, M. Ivanoiu
1,2 a
Faculty of Physics, Al. I. Cuza University, 11 Carol I Blvd., 700506 Iasi, Romania National Institute of Materials Physics, Atomistilor str. 105bis,PO Box MG7, 077125 Magurele, Ilfov, Romania Department of Physics, Technical University of Iasi, B-dul D. Mangeron 67, Iasi 700050, Romania National Institute of Research and Development for Technical Physics, 700050 Iasi, Romania Department of Physics, Technical University of Iasi, B-dul D. Mangeron 67, Iasi 700050, Romania Department of Physics, Technical University of Iasi, B-dul D. Mangeron 67, Iasi 700050, Romania Department of Physics, Technical University of Iasi, B-dul D. Mangeron 67, Iasi 700050, Romania
S2-P2
S2-P3
S2-P4
S2-P5
S2-P6
Magda Gherghel
S2-P7
Sorin-Bogdan Balmus , Dumitru D. Sandu2
10

S3-P1 Surface Properties of Some Polystyrene-Based Nanocomposites Razvan Florin Barzica, Iuliana Stoicab, Luiza Madalina Gradinarub, Andreea Irina Barzicb, Gheorghe Dumitrascua Razvan Florin Barzica, Iuliana Stoicab, Andreea Irina Barzicb, Gheorghe Dumitrascua Madalina Zanoaga, Raluca Darie, Vasile Cristian Grigoras, Fulga Tanasa Madalina Zanoaga, Raluca Darie, Fulga Tanasa Faculty of Mechanics,Gheorghe Asachi Technical University, Iasi, 700050, Romania Faculty of Mechanics,Gheorghe Asachi Technical University, Iasi, 700050, Romania Petru Poni Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, Iasi, Romania Petru Poni Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, Iasi, Romania Petru Poni Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, Iasi, Romania Petru Poni Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, Iasi, Romania Petru Poni Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, Iasi, Romania Petru Poni Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, Iasi, Romania Petru Poni Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, Iasi,
S3-P2
Morphology, Dielectric, and Thermal Properties of Some P4VP/ALN Nanocomposites
S3-P3
Thermal Behaviour of Novel Ternary Copolyamide-Clay Hybrid Composites Influence of Composition and Processing on the Properties of Some PolyamidePolypropylene Blends Shear Thinning/Structure Relationship and Biocompatibility Studies of Quaternized Polysulfone/Poly(Vinylidene Fluoride) Blends Newtonian and Thinning Processes Involving Specific Morphology of New Quaternized Polysulfone Miscibility of Poly(NVinylcarbazole) with Nitroaromatic Low-Molecular Compounds. DSC Study.
S3-P4
S3-P5
Luminita-Ioana Buruianaa, Ecaterina Avrama, Adriana Popab, Silvia Ioana
S3-P6
Raluca Marinica Albu, Ecaterina Avram, Iuliana Stoica, Silvia Ioan
S3-P7
Anca Giorgiana Grigoras, Vasile Cristian Grigoras Andreea Irina Barzica,b, Cristina Delia Nechiforc, Dana-Ortansa Dorohoib Andreea Irina Barzica,b, Dana-Ortansa Dorohoib 11
S3-P8
Release Ability of Glucose Embedded in a Polysaccharide
S3-P9
Molecular Rotation Dispersion of a Chiroptical Polymer
Romania Petru Poni Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, Iasi, Romania Faculty of Textile-Leather Engineering and Industrial Management, Technical Gheorghe Asachi University of Iasi Bvd. D. Mangeron No. 67, 700050, Romania
S3-P10
Theoretical and Experimental Aspects on the Spin-Coated Polyamide 6 Thin Films Theoretical and Experimental Aspects on the Electrical Conductivity in PA6-CNT Nanowebs
M. Teodorescu
S3-P11
Monica. A. Clin, L. Schacher, D. Adolphe, Nabyl Khenoussi, M. Agop
Section 4. Optics, Spectroscopy and Plasma Physics

S4-P1
Highly Surface Enhanced Raman Active Silver and Gold Nanoparticles Covered in Glucose Alteration of Bovine Serum Albumin Aggregation Capacity After Exposure to Atmospheric Pressure Plasma, UV Laser and Pulsed Ultrasound Fields Popcorn Shaped Gold Nanoparticles with Absorbance in NIR Main Physical and Structural Properties of Phenobarbital Molecule Changes in Polarizability by 1,6 Diphenyl-1,3,5 Hexatriene (Dph) Excitation in Some Homogeneous Solutions Spectral Characteristics of PPhenyl-Pyridazinium-Benzoyl2,4,6-Picril Methylid (PPBPM) Ternary Hydroxyl Solutions Contribution of Each Type of Interactions to the Total Spectral Shift in Some Cycloimmonium-Ylids Solutions Radu A. Boitor, Nicolae Leopold Faculty of Physics, BabeBolyai University, Koglniceanu 1, 400084 Cluj-Napoca, Romania Plasma Physics Laboratory, Faculty of Physics, Alexandru Ioan Cuza University of Iasi, Bd. Carol I No. 11 Iasi 700506, Romania Faculty of Physics, BabeBolyai University, Koglniceanu 1, 400084 Cluj-Napoca, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania Department of Physics, Technical University of Iasi, B-dul D. Mangeron 67, Iasi 700050, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania
S4-P2
Alexandra Demeter, R. Jijie, I. Mihaila, V. Pohoata, I. Topala
S4-P3
IstvnSz. Tdor, Nicolae Leopold, Lszl Szab, Vasile Chi Andreea Celia Benchea, Liliana Mihaela Ivan, Dana Dorohoi Ion Hurjui1, Liliana Mihaela Ivan2, Dana Dorohoi2 Daniela Babusca1, Mihaela Maria Dulcescu 2,3 , Cristina Delia Nechifor4, Dana Ortansa Dorohoi2 Valentina Closc, Dana Ortansa Dorohoi
S4-P4
S4-P5
S4-P6
S4-P7
12
S4-P8
UV Spectra of Some Dipeptides and N-Mustards
S4-P9
Metameric Colour in Art Conservation Finemet-Type Thin Films Obtained by Hipims: Influence of Deposition Conditions on the Deposition Rate Optical Compensators Used in Determining the Birefringence of Uniaxial Crystalline Plates Birefringence of Some Liquid Crystalline Samples
Faculty of Physics, Corina Cheptea1, Dana Alexandru Ioan Cuza Ortansa Dorohoi2, Mihaela 3 University of Iasi, 11 Carol I Holban and Valeriu 3 Boulevard, Iasi, Romania Sunel Faculty of Physics, Andrei Hrib, Dana Alexandru Ioan Cuza Ortansa Dorohoi University of Iasi, 11 Carol I Boulevard, Iasi, Romania Ioana-Laura Velicu, Vasile Tiron, Gheorghe Popa Irina Dumitrascua, Leonas Dumitrascu b, Dana Ortansa Dorohoic Leonas Dumitrascua, Irina Dumitrascu, b Dana Ortansa Dorohoic Marius Mihai Cazacua, b, Florin Ungaa, Adrian Timofteb, c, Ioana Popovicia, Alin Ionut Pascarua, Dan Dimitriua, Silviu Gurluia Strat Mitachia, Marius Mihai Cazacua, b, Adrian Timoftea,c , Dan Dimitriua, Silviu Gurluia Cristina Stana, Cristina Maria Cristescua, Dumitru Alexandroaeib, C. P. Cristescua Ion Hurjui a,b , Andrei Neamtu c, Dana Ortansa Dorohoi a Cristina Marcela Rusu1,Claudia Nadejde1, Cristina Delia Nechifor2 Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania
S4-P10
S4-P11
S4-P12
S4-P13
A Study of Some Urban and Industrial Mixtures Aerosols Over Iasi Region
S4-P14
Aerosols Chemical Compositions: Detection and Ranging Correlations in Light Intensity Fluctuations Induced by Gaussian White Noise in a Symmetrical Discharge Plasma Changes Induced By Solvents Nature in 1,6 - Diphenyl - 1,3,5 Hexatriene Fluorescence Spectra: Computational Argues Theoretical and experimental study of B12 vitamin in polar solvents
S4-P15
S4-P16
S4-P17
13

S5-P1 Electromagnetic Shielding Properties of Multilayered Glass Coated Amorphous Wires Gabriel Ababei and Horia Chiriac National Institute of Research and Development for Technical Physics, 47 Mangeron Blvd., Iasi, Romania
14
INVITED TALKS
_____________________________________________________________________________
I. HIGH TECHNOLOGICAL POTENTIAL MATERIALS EXPLORED BY LASER ABLATION
C. Focsa
Laboratoire de Physique des Lasers, Atomes et Molcules, Universit Lille 1 Sciences & Technologies, 59655 Villeneuve dAscq, France, cristian.focsa@univ-lille1.fr
Our group has developed for several years experimental and theoretical capabilities for the study of plasma ablation for nano-technology applications. Fundamental studies on laser ablation plasma plume dynamics have been performed both experimentally by optical (ICCD fast imaging, space- and time-resolved optical emission spectroscopy) and electrical (Langmuir probes, mass spectrometry) methods, and theoretically (development of a new model based on fractal concepts). These fundamental studies were further applied to the study of innovative materials of high interest for the nanotechnology field: pulsed laser deposition of chalcogenide glasses and magnetoelectric materials thin films. The deposited thin films have been characterized by various surface and solid state specific methods (TOF-SIMS, optical and mechanical profilometry, XRD, EDX, SEM, ellipsometry, Raman etc.). Another application is the study of the accelerated erosion of ceramic materials used in plasma space propulsion (Hall Effect Thrusters - HETs). These experiments were developed both in our laboratory and on a running HET at the national ground test facility PIVOINE-2G in Orlans, France. We will present an overview of these fundamental and applied studies [1-6].
References: 1 S. Gurlui, M. Agop, P. Nica, M. Ziskind, C. Focsa, "Experimental and Theoretical Investigations of a Laser Produced Aluminum Plasma ", Phys. Rev. E, 78, 026405 (2008) 2 C. Focsa, P. Nemec, M. Ziskind, C. Ursu, S. Gurlui, V. Nazabal, Laser ablation of AsxSe100-x chalcogenide glasses: Plume investigations, Appl. Surf. Sci., 255, 5307 (2009) 3 P. Nica, M. Agop, S. Gurlui, C. Focsa, Oscillatory Langmuir probe ion current in laser-produced plasma expansion, Eur. Phys. Lett., 89, 65001 (2010) 4 C. Ursu, O.G. Pompilian, S. Gurlui, P. Nica, M. Agop, M. Dudeck, C. Focsa, Al2O3 ceramics under high-fluence irradiation: plasma plume dynamics through space- and time-resolved optical emission spectroscopy, Appl. Phys. A, 101, 153 (2010) 5 L. Balika, C. Focsa, S. Gurlui, S. Pellerin, N. Pellerin, D. Pagnon, M. Dudeck, LIBS in a Running Hall Effect Thruster for Space Propulsion, Spectrochim. Acta B, 74-75, 184 (2012) 6 G. Dascalu, G. Pompilian, B. Chazallon, V. Nica, O. Caltun, S. Gurlui, C. Focsa, Rare earth doped cobalt ferrite thin films deposited by PLD, Appl. Phys. A, 110, 915 (2013)
____________________________________________________________________________
15
III. LOW TC Fe-Nb-Cr-B GLASSY ALLOYS FOR MEDICAL APPLICATIONS

N. Lupu, H. Chiriac, S. Corodeanu, G. Ababei, M. Grigoras
National Institute of Research and Development for Technical Physics, Iasi, Romania
For a number of years the only metallic material with a Curie temperature (TC) around 300 K was Gd. In the recent years, it turned out that the addition of Cr, Ba and Ni to some Fe or Co-based metallic glasses is shifting the ferromagneticparamagnetic transition of the amorphous phase below 400 K [1-3], which makes them interesting for temperature sensors [3] or biomedical applications [4]. In this work we will present comparatively our recent results on the magnetic and ferromagnetic resonance characterization of Fe79.7-xNb0.3CrxB20 (x = 11.513.5 at.%) glassy melt-spun ribbons and glass coated microwires with TC ranging from 290 to 330 K (the lowest ever reported for metallic glasses), depending on the Cr content (the lower the Cr content the higher the temperature of the ferromagnetic-paramagnetic transition). All samples have a glassy structure consisting of very small -Fe clusters of 3-5 nm embedded within the Fe80B20 residual amorphous matrix. The ferromagnetic behavior drastically deteriorates with the increase of the temperature and above TC the material becomes paramagnetic, indicating these materials for hyperthermia applications. The large values of the magnetic permeability in the as-quenched state (1000020000) are also very important, especially for sensing applications. The stable behavior of low TC glassy alloys up to very high frequencies (10 GHz) is another important feature for sensing and medical applications. This work was supported by a grant of the Romanian National Authority for Scientific Research, CNDIUEFISCDI, project number 148/2012.
References: 1 I.I. Danilova et al., Steel in Translation 38 (2008) 419. 2 J. Sort et al., Small 6 (2010) 1543. 3 V. Zhukova et al., Sensor Actuat B 126 (2007) 318. 4 M. Niinomi, Metall. Mater. Trans. 33A (2002) 477.
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16
IV. MAGNETIZABLE NANOFLUIDS AS BIOCOMPATIBLE SUSPENSIONS WITH VARIOUS MOLECULES COATING MAGNETITE GRAINS
Mihaela Racuciua, Dorina Creangab, Vasile Badescuc, Anton Airineid
University Lucian Blaga, Science Faculty, Sibiu, Romania University Alexandru Ioan Cuza, Physics Faculty, 11 Blvd. Carol I, Iasi, Romania, mdor@uaic.ro c National Institute of Research & Development for Technical Physics, 47 Mangeron Blvd., Iasi, Romania d Institute of Macromolecular Chemistry "Petru Poni", 41, Grigore Ghica Voda, Iasi, Romania
b a
Considering wide application field of nanostructured matter with magnetic properties, modified Massarts method was utilized to prepare magnetite nanoparticles for stable biocompatible suspensions. The attempts of stabilizing magnetic grains in water resulted in various magnetizable nanofluids each including other organic coating shell for ferrophase dispersion: tetramethyl ammonium hydroxide (electrostatic stabilization), citric acid, perchloric acid, tartaric acid (steric stabilization) - all having almost physiological pH. Ferophase volume fraction, density, electric conductivity, superficial tension and viscosity coefficient were estimated from rheological investigation. Physical diameter size was provided by Transmission Electron Microscopy (mean diameter from 7.4 nm to 10.5 nm) while magnetic core largest size (from 5.5 nm to 7.1 nm) was deduced from Langevins theory and magnetization curves (Fig. 1) - none presenting hysteresis phenomenon. Thinnest non-magnetic shell was evidenced for citric acid coated magnetite where the density of magnetic particles (given by the saturation magnetization and magnetic diameter) has reached the highest value (about 71023m-3 compared to 0.41023m-3for tartaric acid). Coating molecule interaction with magnetite iron ions was confirmed by FTIR spectroscopy.
Fig. 1: Magnetization curves for Fe3O4 nanoparticles coated with various organic shells
Citric acid coated magnetite nanoparticles seems to be most suitable biocompatible suspensions adequate for contrast agents in magnetic resonance imagistic; biomedical application in magnetically targeted drug delivery could be developed with other magnetizable nanofluids in relation also with the properties of drug intended for grafting on the colloidal nanoparticles.
References: 1 Rcuciu, M., Creang, D., Airinei,A., Chicea, D., Bdescu, V., Mater. Sci. Pol. 2010, 3(28),609. 2 Racuciu, M., Creang, D.E., Sulitanu, N., Badescu, V., Appl. Phys. A. 2007, 89(2), 565. 3 Racuciu, M, Curr. Appl. Phys. 2009, 9 (5), 1062.
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V. ON THE HYSTERESIS PHENOMENON IN NON-EQUILIBRIUM PHASE TRANSITIONS
Sebastian Popescu
Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Blvd., 700506 Iasi, Romania
Non-equilibrium phase transitions represent a topical problem of research in various fields of physics. As they appear in complex systems, an alternative approach of their understanding is that of the nonlinear dynamics. Hysteresis is the property of an evolving complex system which emphasizes the dependence of its states on the previous ones, or, with other words, on the systems history. Because the equilibrium thermodynamics properties of a system are completely determined by the state parameters, as pressure and temperature, and they are independent of the way the system reached that state, it follows that hysteresis is a characteristic of the system driven outside the thermodynamic equilibrium. Complex systems are nonlinear and dissipative systems, the evolution of which can be described by an adequate evolution equation or system of equations, which relates the dependence of the order parameter(s) of the system on the control parameter(s) that can be externally modified as desired. In the present contribution two types of reaction functions are analyzed, together with the associated Lyapunov-like functionals. These functionals can describe two different types of Thoms catastrophes, as well as the first-, respectively the second-order phase transitions. Using the functional ascribed to the first-order phase transitions, the stationary structured states are found and their stability to perturbations is analyzed. The bifurcation types and the critical points are established. The sudden jumps, instabilities, the bistability range and the hysteresis phenomenon are also studied. Also, a quantitative discussion of the stability exchange in the bistability domain is done from the nonlinear dynamics point of view. For the functional ascribed to the second-order phase transitions an analysis similar to that for the first-order ones is performed and the results showed that the entire bistability domain collapses to the critical point. In order to highlight the presence of hysteresis in the phase transitions governed by a functional specific to the second-order ones, a symmetrybreaking perturbation is used and the analytic results clearly mimic the experimental results reported in the literature, e.g., for the paraelectric-ferroelectric transitions.
Acknowledgments: This contribution was realized in the frame of the POSDRU/89/1.5/S/63663 Project.
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VI. MOLECULAR SPIN CROSSOVER MATERIALS: NEW PERSPECTIVES IN MOLECULAR SPINTRONICS AND NANOELECTRONICS
C. Lefter1, A. Rotaru1, R. P. Tan3, I. A. Guralskiy2,4, L. Salmon2, P. Demont5, J. Carrey3, G. Molnr2, M. Respaud3 and A. Bousseksou2
1
Faculty of Electrical Engineering and Computer Science, Stefan cel Mare University, Suceava, Romania, rotaru@eed.usv.ro 2 Laboratoire de Chimie de Coordination, CNRS & Universit de Toulouse, UPS, INP, Toulouse, France 3 LPCNO, CNRS & Universit de Toulouse, INSA, UPS, Toulouse, France 4 Department of Chemistry, National Taras Shevchenko University, Kiev, Ukraine 5 LPP-CIRIMAT, CNRS & Universit de Toulouse III, Toulouse, France
In the last years, great progresses have been achieved in the field of molecular materials on the optical, electrical and magnetic properties and nanolectronics devices. These achievements are exemplified by the development of organic LEDs (OLEDs), organic thin film field-effect-transistor, molecular magnets, etc. Herein we focus on the charge transport properties of bulk and nano-sized samples of the [Fe(Htrz)2(trz)](BF4) spin crossover compound. This complex displays a thermal hysteresis loop in the dc electrical conductivity, which we could clearly associate with the molecular spin state switching phenomenon the low spin state being more conductive [1]. We used electric-field-assisted directed assembly to organize high aspect-ratio spin crossover nanorods between interdigitated electrodes with a very high degree of alignment [2]. The temperature-dependent current-voltage characteristics of each device revealed a bistability of the current intensity associated with the spin-state switching, providing appealing perspectives for nano-scale switching and memory devices.
Left panel: Schematic representation of the device elaboration. The SCO nanorods were organized between the electrodes by dielectrophoresis. FDEP represents the dielectrophoretic force acting on a nano-object. Right panel: Device electrical characterization. Current intensity recorded under a bias voltage of 10 V as a function of temperature in the heating and cooling modes. Acknowledgements: This work was supported by the bilateral grant of the Romanian National Authority for Scientific Research (CNCSUEFISCDI) and Agence Nationale de la Recherche (ANR), Contract number: 9RO-FR/01.02.2013. References: 1 A. Rotaru, I. A. Guralskiy, G. Molnr, L. Salmon, P. Demont, A. Bousseksou, Chem. Commun. 48 (2012) 4163. 2 A. Rotaru, J. Dugay, R. P. Tan, I. A. Guralskiy, L. Salmon, P. Demont, J. Carrey, G. Molnr, M. Respaud, A. Bousseksou, Adv. Mater., 25 (2013) 17451749
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Section 1. Theoretical, Mathematical and Computational Physics

S1-O1
AN ANALYTICAL APPROACH TO THE KOMPANEETS EQUATION IN HIGHLY MAGNETIZED NEUTRON STARS MAGNETOSPHERE
Denisa-Andreea Mihua, Marina-Aura Dariescub, Ciprian Dariescub
a
Faculty of Physics, ''Alexandru Ioan Cuza'' University of Iasi, Carol I, no.11, 700506, Iasi, Romania, denisa.mihu@gmail.com
b
Faculty of Physics, ''Alexandru Ioan Cuza'' University of Iasi, Carol I, no.11, 700506, Iasi, Romania, marina@uaic.ro
The present work focuses on the study of the Kompaneets equation [1], as applied to Compton scattering effects in magnetars magnetosphere [2]. In the non relativistic case, we analytically solve the photon diffusion equation and express the wave functions in terms of the Heun double confluent functions [3]. The approach tackled in determining the solutions of the Kompaneets kinetic equation is considered in the stationary regime. References: 1 Kompaneets, A. S. Zh. ksp. Teor. Fiz. 31, 876, 1956 [Sov. Phys. JETP 4, 730, 1957]. 2 Tong, H. et al. Res. Astron. Astrophys. 10, 553, 2010 3 Dubinov, A. E. Pis'ma v JTF 35, 25, 2009 [Tech. Phys. Lett. 35, 260, 2009].
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DYNAMICAL ANALYSIS OF VISUOSPATIAL SACCADIC SYSTEM APPLYING CHAOS DIAGNOSIS TESTS Corina Astefnoaeia, Dorina Creanga, Elena Pretegianib, Lance M. Opticanc
a
Faculty of Physics, Laboratory of Biophysics & Medical Physics, University Alexandru Ioan Cuza, 11 Bd. Carol I, 700506, Iasi, Romania, corina_astefanoaei@yahoo.com b Department of Neurological Neurosurgical and Behavioral Science, University of Siena, Siena 53100, Italy c Laboratory of Sensorimotor Research, National Eye Institute, Bethesda, MD, 20892, USA
The development of mathematical approach in biomedical domain has led to computational studies on the biological signals extracted from various physiological systems of interest in clinical diagnostic. The main purpose of such research is the design of specific computational tools to characterize pathological signals compared to the normal ones by means of some semi-quantitative parameters and also by qualitative tests application. The aim of the present study was to analyze the behavior of the saccadic signal using some algorithms based on the chaotic determinism theory. Saccadic eye movements are fast eye movements which redirect the line of sight to bring a new part of the visual scene onto the foveal region. These movements were recorded from normal human subject during a visually-guided saccade task using an infrared eye tracking system in a special experimental arrangement, the collected signal being investigated, considering both raw and the numerical smoothed data. Power spectrum, autocorrelation function and autocorrelation time, the phasespace reconstruction, the capacity dimension and Lyapunov exponent were applied for the diagnosis of saccadic system dynamics. The smoothed signal was hardly distinguishable from the initial one, but the application of the usual analysis strategy has led to somehow different results regarding the non-linear features of the underlying neurovisual physiological system. Given the experimental design, one could expect that quasi-periodic dynamical trend overlap chaotic one, but actually the capacity dimension and the autocorrelation function showed the dominancy of the complex dynamical component (chaotic pattern). The power spectrum test applied to raw signal revealed the chaotic component for law and medium frequencies while for smoothed data the same was revealed for high frequencies also. The phase-space reconstructed using delay coordinates (x(t), x(t-n)) showed the same complex dynamics, especially for higher n value (for instance for n=16, where the capacity dimension approaching its fractal geometrical feature - emphasized saturation tendency to a non-integer reliable value). The autocorrelation function decreased to zero almost identically for raw and smoothed data with much closed values of the autocorrelation time. The largest Lyapunov exponent calculated for embedding dimensions from one to ten showed small positive values closed to zero which reveals the sensitivity to initial conditions and suggests the system evolution toward an instable state, a bifurcation point. So, the chaotic dynamics seems to characterize the neuro-visual system involved in saccade preparation, triggering and accomplishment. The next objective in developing this study will focus on the non-linearity of biophysical processes underlying the generation and propagation of neural impulses that are mainly responsible for complex chaotic dynamics identified in the saccadic eye movements.
Acknowledgement: This research was supported by CERVISO 269263 FP7 IRSES-PEOPLE project.
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THE NUMERICAL SOLVE OF LANE-EMDEN EQUATION FOR THE SOLAR INTERNAL STRUCTURE
Lucian-Mihai Cosovanu
Faculty of Physics, "Al. I. Cuza" University, Bd. Carol I, 11, 700506, Iai, Romania, lucian.mihai.cosovanu@gmail.com
We are using numerical calculations for the Politropic model of stars of index n=3 known as Eddington Solar Model. By solving the Lane-Emden Equation, we have derived the distribution of temperature, density, pressure and mass fraction with radius. Finally comparisons were made with respect to Standard Solar Model (SSM) results.
References :
1 2
Professor William H. Press, Introduction to Astrophysics, Chapter 5, 1997 Professor Vik Dhillon, Department of physics & astronomy, University of Sheffield, Stellar structure & evolution course, http://www.vikdhillon.staff.shef.ac.uk/teaching/phy213/phy213_le.html, (accessed at 13.04.2013) 3 Professor Richard Fitzpatrick, The University of Texas at Austin, Eddington Solar Model, http://farside.ph.utexas.edu/teaching/336L/Fluidhtml/node140.html, (accessed at 29.04.2013) 4 Eugeniu Toma, Introducere n astrofizic, Structura i evoluia stelelor, Editura Tehnic, Bucureti, 1980 5 Vasile Ureche, Universul Vol. II, Astrofizic, Editura Dacia, Cluj-Napoca, 1987 6 A. S. Eddington, The internal Constitution of The Stars, Cambridge University Press, 1926 7 Standard Solar Model (BS2005-AGS,OP), astro-ph/0412440 http://www.sns.ias.edu/~jnb/SNdata/Export/BS2005/bs05_agsop.dat, (accessed at 14.04.2013) 8 Stellar Astrophysics: Stellar Modeling, www.astro.umass.edu/~wqd/astro640/model.pdf (accessed at 29.04.2013) 9 Eugeniu Toma, Introducere in astrofizic, Structura i evoluia stelelor, Editura Tehnic, Bucureti, 1980
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ON A SCHRDINGER-LIKE EQUATION WITH SOME SPECIAL POTENTIAL
Ciprian Creu
Faculty of Physics, Alexandru Ioan Cuza University of Iasi, Bd.Carol I, no. 11, 700506 Iai, Romania, ciprian_cretu@yahoo.com
The present paper is devoted to the time-evolving one-dimensional Schrdinger equation for stationary state with some special potential, version of the WheelerDe Witt equation. For small values of the cosmological scale factor the wave function of the Universe is expressed in terms of the Heun Double Confluent functions. For large values one gets the well-known Hermite associated functions
References: 1 Dariescu, C.; Dariescu, M.A.; Creu, C., Int. J. Theor. Phys. 2012, DOI 10.1007. 2 Wheeler, J.A., Batelle Recontres, Benjamin, New York, 1968. 3 De Witt, B., Phys. Rev. 1967, 116, 1113. 4 Arscot, F.M. Heuns Differntial Equations, Oxford University Press, Oxford,U.K, 1995
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S1-P2
ENERGY-MOMENTUM LOCALIZATION FOR A SPACE-TIME GEOMETRY EXTERIOR TO A BLACK HOLE IN THE BRANE WORLD
Irina Radinschia, Theophanes Grammenosb, Andromahi Spanouc
Gheorghe Asachi University of Iasi, Bd. D. Mangeron, no. 67, radinschi@yahoo.com b University of Thessaly, 383 34 Volos, Greece, thgramme@civ.uth.gr c National Technical University of Athens, 157 80, Athens, Greece, aspanou@central.ntua.gr
a
In general relativity one of the most fundamental issues consists in defining a generally acceptable definition for the energy-momentum density. As a consequence, many coordinate-dependent definitions have been presented, whereby some of them utilize appropriate energy-momentum complexes. We investigate the energy-momentum distribution for a metric exterior to a spherically symmetric black hole in the brane world by applying the Landau-Lifshitz and Weinberg prescriptions. In both the aforesaid prescriptions, the energy thus obtained depends on the radial coordinate, the mass of the black hole and a parameter , while all the momenta are found to be zero. It is shown that for a special value of the parameter , the Schwarzschild space-time geometry is recovered. Some particular and limiting cases are also discussed.
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TRAVELLING WAVES AND SHAPIRO STEPS IN A TUMOR - GROWTH MODEL
Clin Gheorghe Buzeaa, Mihaela Maria Opreab, Manuela Oprianb, Anioara Anghelacheb, Irina Butucb, Alina Rogojanub, Drago Iancuc
a
National Institute of Research and Development for Technical Physics, D. Mangeron 47, Iai 700050, Romania; calinb2003@yahoo.com b Regional Oncology Institute, G-ral Berthelot 2-4, Iai 700863, Romania c Gr. T. Popa University of Medicine and Pharmacy, University 16, Iai 700115, Romania
Starting from a simplified normalized time dependent derivative cancer growth model, proposed by Ivancevic, we propose a tumorgrowth model, which includes the temporal chaotic butterfly- attractor and some other interesting features. A numerical analysis of this model is performed using computational routines for solving non-linear PDEs in Wolfram Mathematica, which among other features indicates that the introduced model might exhibit travelling wave solutions for some choices of parameters. After some mathematical manipulations, a reduced travelling wave equations system results which exhibits an amplitude dependence on the pseudo-period, indicating a strong nonlinearity and an interesting increase in Shapiro steps.
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S1-P4
PERUMPANANIS MALIGNANT INVASION MODEL WITH A SMALL AMOUNT OF DIFFUSION IN THE FRAMEWORK OF SCALE RELATIVITY THEORY
Clin Gheorghe Buzeaa, Mihaela Maria Opreab, Manuela Oprianb, Anioara Anghelacheb, Irina Butucb, Alina Rogojanub, Drago Iancuc
a
National Institute of Research and Development for Technical Physics, D. Mangeron 47, Iai 700050, Romania, calinb2003@yahoo.com b Regional Oncology Institute, G-ral Berthelot 2-4, Iai 700863, Romania c Gr. T. Popa University of Medicine and Pharmacy, University 16, Iai 700115, Romania
We study a particular model of tumor progression, Perumpananis malignant invasion model with a small amount of diffusion, in the framework of Scale Relativity theory, namely, we assume the invasive cells, the connective tissue and the proteases are moving through a non-differential medium governed by the Scale Relativity theory. Furthermore, we consider an action-reaction law acting on the system formed by the extracellular matrix and the non-differential medium. As a result, cancer cell proliferation satisfies a logistic law accounting for the competition for space with the nondifferential medium and the time evolution of the concentration of the connective tissue increases proportional to the real fractal velocity, squared. Also, we find again that over small distances, even in avascular stages, malignant tumors might propagate and invade healthy tissues. Finally, we find exact solutions for Perumpananis malignant invasion model with a small amount of diffusion in terms of Scale Relativity theory, using the factorization and the tanh method. For small diffusion coefficients, we may conclude that there is a gap between the invasive cells front and the degraded connective tissue, the extracellular matrix is not continuously degraded by the concentration of proteases and the later one shows amplified followed by amortized oscillations and jumps between two distinct levels.
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NEW LANDMARK IN THE STUDY OF GEOMETRY AND PARALLEL COMPUTATION APPLIED TO NANO-WIRES MAGNETIC PROPERTIES
Sergiu Mohorianu
NIRDTP, Iasi, 47 Mangeron Boulevard, sergium@phys-iasi.ro
The outstanding success of magnetic materials for the last two decades may be ascribed to three relevant happenings in the last 10-15 years. The global realization of importance of nano-science and nano-technology (1); overall improvements in general expertise and techniques in sample synthesis (2); a dramatic refinement and development of new methods and probes for magnetic materials characterization (3). The increasing importance of nano-level studies has led to the ingenious ways of producing nanoparticle samples and the advent of powerful new techniques for element specific studies, layer-by-layer and even leading to atomic resolution, suitable for investigating magnetism of nanoclusters, bi- and trilayer systems and even single atoms at surfaces and interfaces. The success at the nano-level has opened-up new frontiers, namely magnetism of nanoclusters, surface and interface magnetism, low dimensional magnetism, interacting nanostructure magnetism and many others. In terms of theoretical research the rapid development of theoretical methods based on congruity of computer simulation has allowed the calculation of ever finer details of the formation and interaction of magnetic moments and has permitted a refined interpretation of experimental data. The new aspects studied in the last year, our latest research we specialize in improving techniques for high-level simulation in the design of nanomaterials with controlled magnetic properties. Thus, we used a free software package built on Linux called Nmag1 (with permission of Hans Fangohr&all) on a open source platform. The software package allows working with parallelized algorithms. The language used is Python2 suited for scientific applications. Restriction most imporatant in simulation were imposed by refining the mesh and the accuracy of resulting magnetization in magnetic nanowire model. The material magnetic properties and the geometry were prepared and designed in laboratory, based on the experimental data that results in works conducted in our own institute. Magnetic characteristics and experimental results were in good agreement validating the model given both theoretical and edge refinement algorithms.
References: 1 http://www.southampton.ac.uk/. 2 H. P. Langtangen, Python Scripting for Computational Science. 3rd Edition.
23
Section 2. Physics and Technology of Condensed Matter

S2-O1
TOWARDS A NEW TECHNOLOGY OF TAILORING ENHANCED SURFACE PARAMETERS OF STAINLESS ALLOYS
Corneliu Srbu
National Institute of R&D for Materials Physics (Mgurele-Bucharest, 105bis Atomistilor-street, POBox-MG7, 077125, Romania; crnl_srbu@yahoo.com
A newly developed low-temperature gas-atmosphere processing for carburization (LTCSS) of stainless steel (SS) AISI-316L was empirically developed, patented and commercially applied1. It was successful in dramatically improving the surface hardness, wear resistance2 and corrosion resistance of 316L steel3. When extended to the Ni-based superalloy Inconel-718 (IN-718)4 and to the E-BRITE (a registered trademark of ATI Allegheny Ludlum Corp., Brackenridge, PA) duplex SS, the method provided similar enhancements5, whereas when applied to the duplex-SS UNS-S32550 it failed in improving (unpublished results) the surface corrosion resistance. The academic research concerning the cause of surface properties modifications provided an explanation based exclusively on a model of massive interstitial diffusion (leading to a so-called colossal supersaturation, denying the classical thermodynamics) of C originating in the gas atmosphere, which occurs without carbides formation because the process is claimed to occur in paraequilibrium conditions. It was claimed that no other phenomenon is to be considered except for a dilatation of the preexisting alloy grains, whose incresed lattice parameters lead to a huge residual stress and therefore to the dramatic modification of surface properties. This explanation is based on a wrong way of interpretation of the experimentally observed peak shapes and intensities of the X-ray diffractograms acquired when scanning the carburized surfaces. We will present our most recent results, unpublished yet and based on atomic resolution HRTEM and analysis, showing that in the range of several microns below the alloy surface a very profound modification of its microstructure occurs. The initial grains microstructure of the alloys, as exists previous to the effect of LTCSS, is transformed to a nanostructure of crystallites and amorphous phase, with a massive presence of C, which is not simply diffused into the crystal lattice. The dramatic modification of the surface microstructure by means of the solid-state chemical reactions which probably occur when the alloy surface is LTCSS treated suggests that we have to look at this kind of processing as a possible ground for the development of a new technology for tailoring several technically important surface parameters. Our proposal is that, in first instance the understanding of basic chemical processes involved in the carburization should be the research objective, followed by the extension of gas mixture to other compositions than that for carburization.
Acknowledgements: The herewith reported results were obtained due to a financial funding offered by the ANCS to the institute by means of the Proiectul Nucleu. The author is grateful for the one year work stage at the Dept. of Materials Science and Engineering of the Case Western Reserve University, Cleveland, OH, USA, and for his involvement in the research of the effect of LTCSS on IN-718 and Ferallium-255 surfaces. References: 1 Williams, P.C. and Collins, S. R., JOM, 2008, 60(issue 12), 27 2 Michal, G. M. et al, Acta Materialia, 2006, 54, 1597 3 Martin, E. J. et al, Electrochem.Solid.St.Lett., 2007, 10(isuue 12), C76 4 Shargi-Moshtagin, R. et al, Metall.Mater.Trans., 2010, A41, 2022 5 Michal, G. M. et al, Metall.Mater.Trans., 2009, A40, 1781
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S2-P1
SEQUENTIAL PULSED LASER DEPOSITION OF AL-DOPED ZNO THIN FILMS: DOPING CONCENTRATION AND OXYGEN PARTIAL PRESSURE INFLUENCES
Cristian Ursu a, Tudor Coman b and Ovidiu Florin Caltun b
a
Polymer Materials Physics Laboratory, Petru Poni Institute of MacromolecularChemistry, 41 A Gr. Ghica Voda Alley, 700487 Iasi, Romania, e-mail: cristian.ursu@icmpp.ro b Faculty of Physics, Al. I. Cuza University, 11 Carol I Blvd., 700506 Iasi, Romania, e-mail: tbcoman@gmail.com
Thin films of Al-doped ZnO (AZO) were obtained through sequential pulsed laser deposition (SPLD) method at room temperature in reactive environment. By alternating ablation of individual metallic targets in oxygen atmosphere, zinc for the host and aluminum for dopant, two sets of samples were obtained: the first consisted of thin films with different dopant concentrations (from 0.3 to 4.4% at.) deposited at constant pressure (i.e., 5 x 10-2 mbar), while for the second one the oxygen partial pressure was varied (from 1 x 10-2 to 1 x 10-2 mbar) for a constant doping concentration (4.4% at.). The samples were investigated in terms of their structural, optical and electrical properties. X-ray diffraction data shows that the obtained AZO thin films were single phase with a polycrystalline structure. From the variation of the lattice constants with Al content we concluded that Al tends to be present in the host lattice mainly as interstitials. XPS depth profiles revealed a homogenous composition and the dopant percentage was found to be constant throughout the film. We could also verify that a fine tuning of the dopant can be achieved by carefully choosing the number of pulses used for Al laser ablation. Transmittance values were high (~ 90%) in the visible region and the photoluminescence (PL) signal intensity was improved upon doping. The electrical resistivity showed a decrease of four orders of magnitude with respect to undoped ZnO reference sample. When the deposition pressure was lowered, we noted a transition of the crystallites growth from a random to a (110) preferential orientation. Concomitantly there was a change of the morphology from a densely packed to a loosely packed granular structure. In addition, the band gap widened to 3.88 eV and the electrical resistivity dropped to 5.4 x 10-2 cm, which is the lowest value obtained in our experimental conditions. These modifications could be attributed primarily to effects triggered at low pressure, like the formation of oxygen vacancies (which act as donors) and the alteration of the film growth dynamics due to increased deposition rate.
Acknowledgement: This work was financially supported by the European Social Fund in Romania, under the responsibility of the Managing Authority for the Sectoral Operational Programme for Human Resources Development 2007-2013 [grant POSDRU/107/1.5/S/78342].
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STRUCTURAL PROPERTIES OF ZIRCONIA THERMAL BARRIERS FOR AEROSPACE APPLICATIONS OBTAINED BY PLASMA JET DEPOSITION
I. Mercioniu a, C. Ghica, A.M. Vlaicu a, V. S. Teodorescu a, A.V. Maraloiu a, R. Negrea, A. Stefanb, V. Manoliub, Gh. Ionescub
a National Institute of Materials Physics, Atomistilor str. 105bis,PO Box MG7, 077125 Magurele, Ilfov, Romania National Institute for Aerospace Research "Elie Carafoli",220, Iuliu Maniu Bd, Bucharest, Po Box 061099, Romania
Thermal barrier coatings (TBC) consisting of multilayers of yttrium stabilized zircon (YSZ) and (NiCo)CrAlY alloy bond layers on top of NIMONIC or stainless steel test specimens are prepared by plasma jet deposition. The effect of thermal shock cycles at 100C 1100 C followed by forced air cooling and water cooling on structural and morphological stability of TBC and substrate are investigated by transmission and scanning electron microscopy, X-ray diffraction spectroscopy prior and after thermal shock tests. Preliminary results of SEM and X-ray diffraction measurements on stainless steel specimens covered with TBC show thermal stability of the zirconia coatings. However, segregation of aluminium in the Ni-Cr-Al buffer layer, possibly causing critical failure of the TBC are also evidenced after thermal shock cycles.
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S2-P3
CAPACITIVE MEMS SWITCHES: THE MODIFICATION OF THE PULL-IN VOLTAGE BY THE TRAPPED SPACE CHARGE
E. R. Neagu1,2 and J. N. Marat-Mendes1
1
CENIMAT/I3N, Departamento de Cincia dos Materiais, Faculdade de Cincias e Tecnologia, Universidade Nova de Lisboa, 2829516 Caparica, Portugal 2 Department of Physics, Technical University of Iasi, B-dul D. Mangeron 67, Iasi 700050, Romania
Capacitive RF MEMS switches are one of the most promising applications in microelectromechanical systems (MEMS), but their commercialization is currently hampered by reliability problems. The most important problem is the charging of the dielectric material, employed as insulator, under the applied pull-in voltage Vpi. It was experimentally found that high dielectric permittivity materials (required for the high on /off capacitance ratio needed for RF applications) are prone to charging when an actuation voltage is applied. The parasitic charge stored in the dielectric material causes a drift in the device behavior, a modification of the action voltage and, ultimately, device failure [1]. The paper analyses how the electric charge injected/extracted at the metal-dielectric interface accumulates into the dielectric material used as insulator in a RF capacitive MEMS switch. Experimental data were taken in different ambient atmospheres, including a vacuum. It is proposed the employment of a triangular voltage signal [2] to measure the Vpi and the pull-off voltage Vpo. An estimate of the charge stored into the material and of the capacitance of the device was obtained by measuring the short-circuit and the open-circuit charging and discharging currents or the open-circuit voltage. A detailed analysis of the stored charge, including the landscape of the thermal activation energies involved, the electric charge amount stored under different experimental conditions and the relaxation time, was obtained by using the final thermally stimulated discharge current technique.
References: 1 E. R. Neagu, C. J. Dias, M. C Lana, P. Incio and J. N. Marat-Mendes, J. of Nanoscience and Nanotechnology, 10, 2503-2511, 2010. 2 E. R. Neagu, Appl. Phys. Letters, 92, 182904, 2008.
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MAGNETIC PROPERTIES AND THERMAL STABILITY OF Nd2Fe14B/SmCo-BASED HYBRID MAGNETS
Marian Grigorasa, Margaritis Gjokab, Mihaela Grigorasa, Nicoleta Lupua, Horia Chiriaca
a
National Institute of Research and Development for Technical Physics, 700050 Iasi, Romania, mgrigoras@phys-iasi.ro b IAMPPNM, N.C.S.R. Demokritos, Agia Paraskevi, 15310 Athens, Greece
A lot of single-phase permanent magnets have been developed for different applications in the last century. The application area of permanent magnets increased with their performance. When focusing on magnetic properties, each type of single-phase magnets comes with its own advantages and disadvantages. Nd-Fe-based magnets present high magnetization, but moderate Curie temperature, whereas Sm-Co-based magnets have high thermal stability, but their magnetization and energy product values are low compared to Nd-Fe-based magnets. The hybrid magnets combine the advantages of different types of magnets, therefore efforts to produce hybrid magnets increased enormously in the last decades [1-3]. In this paper, we will discuss our latest results on the magnetic properties and thermal stability of hybrid magnets prepared by spark plasma sintering (SPS) method from mixtures of ball-milled powders obtained from precursor Nd-Fe-B and Sm11.114(Co65.777Fe8.888Cu10.666Zr3.555)8 melt-spun ribbons. Nd-Fe-B melt-spun ribbons were first annealed at temperatures of 610-6900C for 20 min. to obtain the optimum nanocrystalline microstructure, whilst Sm-Co-based melt-spun ribbons were annealed at 800-9500C for 16 h in order to improve their microstructure and to enhance the magnetic properties. The annealed ribbons have been further used as precursors to prepare powders by high-energy ball-milling. The size of the micropowders varied between 10 and 150 m, depending on the milling time. The powders have been mixed in different weight ratios, and then sintered under vacuum by SPS technique at different pressures between 50 and 70 MPa applied during the heating to 6000C.
26
The optimum magnetic properties were obtained for [NdFeB]+15wt.%[Sm-(Co,Fe,Cu,Zr)] hybrid magnets consolidated at an applied pressure of 60 MPa: Hc = 9.5 kOe; 0Ms = 0.9 T; (BH)max = 295.7 kJ/m3. As compared to NdFeB, the coercivity of [NdFeB]+15wt.%[Sm-(Co,Fe,Cu,Zr)] hybrid magnets is with 22% lower, the remanence magnetization at 1500C is with 4% lower, whereas the Curie temperature increases with 720C. All the benefits given by the mixture of the two types of powders will be discussed in detail considering the composition and ratio of the mixed powders, as well as the compaction parameters.
Acknowledgement: Support from the Romanian NUCLEU Program (PN 09-43 02 01) is highly acknowledged. References: 1 Dapeng, W.; Narayan, P.; Chuanbing, R.; Ying, Z.; Kramer, M.J.; Ping, L.J. J. Magn. Magn. Mater. 2012, 324, 2836. 2 Lupu, N.; Grigoras, M.; Lostun, M.; Chiriac, H. 20th Workshop on Rare Earth Permanent Magnets and Aplication REPM08 Proceedings, 2008, 29. 3 Chiriac, H.; Grigoras, M.; Urse, M.; Lupu N. Sensor Letters, 2009, 7, 1.
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THE PROPERTIES OF FERROFLUID WITH MODIFIED STABILISANT
R. Badescu, D. Condurache, M. Ivanoiu
Departament of Physics,"Gheorghe Asachi" Tehnical University of Iasi, Romania
The ferrofluid are media composed of ferromagnetic particles dispersed in a base liquid. The clasic ferrofluid contained particles of magnetite, suspended in kerosene and stbilised with oleic acid. We describe the preparation method of a new ferrofluid in which the stabilizing agent (oleic acid) is partially replaced with silicon oil PDMS or PMFS. For the obtained proves we study: the density, the magnetic susceptibility and the viscosity. The studies show that the magnetic susceptibility is monotously decreasing as a function of silicon oil concentration. The density increases slowly and the viscosity increases as well as function of silicon oil concentration. The distinction with respect to the ferrofluid based on oleic acid stabilizing consist in the behavior of the viscosity in magnetic field.
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27
S2-P6
CHARACTERISTICS OF NEGATIVE PHOTOCONDUCTION AT SOME SCHOTTKY STRUCTURES WITH ELECTRIC FIELD EFFECT BASED ON PHOTOSYNTHETIC PIGMENTS
Magda Gherghel
Department of Physics, Technical University Gh. Asachi Iai
This paper presents the experimental results concerning the study of the photoelectric behaviour of a multijunction type multilayer mixed structure with photosynthetic pigments ( Chl ) having the form Al / pChl : C6H8O6 p+ Chl / Cu. Being constituted from more series-superposed and vertically-illuminated semiconductor junctions, the respective photosystem allows the selective usage of a part as large as possible from the spectrum of the solar radiations which is of interest for the photovoltaic conversion and optoelectronical devices. The experimental results obtained at the plotting of the photoelectric and photovoltaic characteristics at both structures have rendered evident both the presence of a Schottky-type interface micro(nano) barrier responsible for the potential fluctuations, photocurrent and photopotential behaviors. For the Schotty barrier height have been obtained mean values in the interval 0.85...0.95 eV and a fluctuation of the barrier height B = 0.012...0.25 eV. Simultaneously has been investigated the influence of both the electric field and the addition of C6H8O6 ascorbic acid on the energy transfer and electron transport through the Schotty barriers of Al / Chl and Al / Chl : C6H8O6 interfaces the field effect structure. We reveal that in the study of the interdependences between electric fields + the concentration of the C6H8O6 ascorbic acid proteic metabolism photocondution photovoltaic characteristics and the height B of the Schottky barrier at the interface photoactive region, it is necessary to take into account both the tunnelling and the recombination effects of the minority carriers and the influence of the imagine forces in the spatial charge region on the potential barrier. The photoelectrical measurements accomplished at room temperature for all the studied samples, have also made evident an interesting aspect of the photovoltaic behaviour at the Al / p+ pChl-Cu structure, namely, the appearence of a negative photoconduction phenomenon, corresponding to an illumination time of the sample ranging in the interval 1.5...2 min. During the experiments and for a time interval of approximately t 2 min, the negative photoconduction phenomenon ungergoes a saturation process, passing in a positive photoconduction regime with the establishing of the photovoltaic parameters. Thus, there have been found similitudes between the photoelectric behaviuor of this photosystem type and the specific electro-optical behavior of the electronical devices with charge transfer used as image sensors in the information optical processing. On taking into account this idea, the paper presents a means by which such a structure could be used to detect some noxious elements favouring some neuroviral epidemics: noxious elements (1) UCD (0.670 0.820 )V, JL (18 25 ) mA/ cm2 (2) neuroviral epidemics.
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S2-P7
CONSIDERATIONS ON SCATTERED FIELDS OF SOME EQUIPMENTS WORKING IN THE 75 3000 MHZ BANDS
Sorin-Bogdan Balmus1, Dumitru D. Sandu2
1
Physics Department, Gheorghe Asachi Technical University of Iasi, 67 Blvd D. Mangeron , 700050 Iasi, Romania, sorin.balmus@tuiasi.ro 2 Faculty of Physics, Al. I. Cuza University of Iasi, 700506, Romania
In many laboratories, offices and home rooms there exist devices and equipments working in the radio frequency (RF) and microwave bands. People working with these equipments may be exposed to electromagnetic fields of high density which can produce adverse effects on human health. It is necessary to perform measurements on scattered field, especially in the region where the power density may reach dangerous levels for occupational personnel and people living in the neighborhood. The equipments subjected to measurements are: microwave generator for supply a Transversal Electromagnetic (TEM) exposure cell; wireless communication devices; power microwave generator for plasma excitation; microwave oven and different mobile phones. In this work we report experimental data of measurements and a comparison of these results with the most recent protection standards.
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29

S3-O1
LASER LIGHT SCATTERING STUDY ON SALTED SOLUTIONS OF GRAFTED PULLULANS
Petru Poni Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda, 41A, 700487, Iasi, Romania, angrig@icmpp.ro
The physico-chemical properties of three grafted pullulans (P) bearing poly(3acrylamidopropyl)trimethylammonium chloride (pAPTAC) side chains (P-g-pAPTAC1, P-g-pAPTAC2 and P-g-pAPTAC3 with 22.53, 29.05, and 34.51 (wt. %) of pAPTAC content in polymer, respectively) and possessing polyelectrolyte character are determined by light scattering analysis. All grafted pullulan aqueous solutions are tested in the presence of NaCl, KCl, NaNO3 or KNO3. The biggest associations are recorded in 0.5 M NaCl aqueous solutions for P-g-pAPTAC1, P-g-pAPTAC2 and Pg-pAPTAC3 according to the maximum values for radius of gyration Rg extracted from batch mode multiangle laser light scattering (MALLS) measurements. Also, the positive values of second virial coefficient A2 reinforced the idea that salted aqueous solutions are good solvents for grafted pullulans and ensure laser light scattering measurements in proper conditions. The liniar shape of Zimm plots (Berry formalism) revealed that all grafted pullulans are quasimonodisperse.
Fig. 1: Chemical structure of grafted pullulans and Zimm plot for P-g-pAPTAC1 in 0.5M KNO3 aqueous solution.
Analysis of Debye and conformational plots for grafted pullulans suggest that the low molecular salts determine the macromolecular chains to adopt different conformations in those aggregates, especially the random coil ones, similar to pure pullulan. The study of solution properties of polymers using a noninvasive method such as laser light scattering offers the opportunity to consequently explore these pullulans for applications such as drug carriers, desalinization and purification of wasted waters or extensively fertilized soils.
Acknowledgement: Authors thank to dr. Marieta Constantin for synthesis of grafted pullulans. References: 1 Constantin, M., Mihalcea, I., Oanea, I., Harabagiu, V., & Fundueanu, Gh. Carbohydrate Polymers, 2011, 84, 926. 2 Podzimek, S. Light Scattering, Size Exclusion Chromatography and Asymmetric Flow Field Flow Fractionation. Powerful Tools for Characterization of Polymers, Proteins and Nanoparticles, New Jersey, Hoboken, John Wiley & Sons, Inc., 2011.
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S3-P1
SURFACE PROPERTIES OF SOME POLYSTYRENE-BASED NANOCOMPOSITES
Razvan Florin Barzica, Iuliana Stoicab, Luiza Madalina Gradinarub, Andreea Irina Barzicb, Gheorghe Dumitrascua
a
Faculty of Mechanics,Gheorghe Asachi Technical University, Iasi, 700050, Romania, barzicrazvan@tuiasi.ro b Petru Poni Institute of Macromolecular Chemistry, Iasi, 700487, Romania
Suspended particles of various morphologies dispersed in viscoelastic liquids form the basis of many products and product precursors of industrial and commercial interest, particularly polymer composites. This type of materials is obtained through the combination of materials with different structural, physical and chemical properties. The optimum design of composite component materials and manufacturing process to meet the target properties for specific engineering application is very important. The final properties of reinforced polymers are determined by the properties and content of components, dimensions of components and micro structure of composite and interfacial interactions between matrix and dispersed phase. The efficiency of properties improvements depends strongly on the characteristics of the filler, but also on the adhesion and interfacial properties between matrix and filler. This work presents the preparation routes of some polystyrene/barium titanate nanocomposites and their surface characterization. The dispersion of the metallic inclusions is achieved by ulltrasonication and homogenization of the system where the matrix is inserted is done by magnetic stirring. The surface tension is evaluated by means of contact angle method. The polar and dispersion component are slightly influenced by the composition of the introduced nanoinclusions. Also, the work of spreading allows determination of adhesion properties between the two phases. These aspects are conformed by the data derived from atomic force microscopy measurements.
Acknowledgement: This paper was realized with the support of POSDRU CUANTUMDOC Doctoral Studies for European Performances in Research and Innovation, ID79407, project funded by the European Social Fund and Romanian Government.
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MORPHOLOGY, DIELECTRIC, AND THERMAL PROPERTIES OF SOME P4VP/ALN NANOCOMPOSITES
Razvan Florin Barzica, Iuliana Stoicab, Andreea Irina Barzicb, Gheorghe Dumitrascua
a
Faculty of Mechanics,Gheorghe Asachi Technical University, Iasi, 700050, Romania, barzicrazvan@tuiasi.ro b Petru Poni Institute of Macromolecular Chemistry, Iasi, 700487, Romania
Polymer nanocomposites are the new class of hybrid materials, which are widely used at industrial level, due to their unique multifunctional and highly enhanced properties. Combination of filler nanoscale dimension and high aspect ratio with its nanoscale dispersion within polymer matrix leads to the significant improvements in the polymer properties at very low filler volume fractions. This paper presents the synthesis of some new nanocomposites by solution processing technique at room temperature. The stable nanosuspensions are casted on smooth substrates and dried in saturated solvent atmosphere. The resulting films are characterized by different approaches in order to evaluate some basis thermophysical properties. The morphology and local surface properties are analyzed by atomic force microscopy, revealing the influence of filler loading on the adhesion and phase contrast. The initial relatively sooth surface of the matrix is modified by the presence of the nanoparticles as reflected by the recorded values of root mean square roughness. The dielectric properties of the investigated nanocomposites are determined using Maxwell-Garnett and Lichtenecker methods. Thermal conductivity is determined by considering that this parameter is a function of composition. The good dielectric and heat transfer features of the nanocomposites here under analysis recommend them as potential candidates for high power electronics.
Acknowledgement: This paper was realized with the support of POSDRU CUANTUMDOC Doctoral Studies for European Performances in Research and Innovation, ID79407, project funded by the European Social Fund and Romanian Government.
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S3-P3
THERMAL BEHAVIOUR OF NOVEL TERNARY COPOLYAMIDE-CLAY HYBRID COMPOSITES
Madalina Zanoaga, Raluca Darie, Vasile Cristian Grigoras, Fulga Tanasa
Petru Poni Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, Iasi, Romania, ftanasa@icmpp.ro
Polymer-clay hybrid systems are successfully employed in a wide variety of industrial and academic applications, such as adsorbents for organic pollutants, pharmaceutical and cosmetic additives, water treatment, catalysts, reinforcing fillers for plastics, rheological control agents, nanocomposites, etc. [1]. Intercalation of polymer chains between the clay platelets, even below the tactoids level, gives rise to molecular ordering that changes both chains conformation and mobility, with respect to the bulk phase. A series of novel hybrid composites made of a ternary copolyamide and different clays (bentonite BTN, montmorillonite MMT and an organically modified clay I.30P) was obtained and subsequently studied in order to understand the interaction between matrix and clay particles. All composites were prepared via direct melt compounding using a HAAKE RHEOCORD 9000 mixer, equipped with two internal roller mixers and having the capacity of the mixing chamber of 50 cm3. This paper presents data concerning the thermal behaviour of the new hybrid composites studied by means of DSC and TGA. DSC results revealed that the main temperatures (Tg, Tc, Tm) of the hybrid composites slightly decreased compared to neat copolyamide. Clay particles act as nucleating agents and conne the movement of macromolecular chains, resulting in the decrease of crystallinity and Tg. As for the melt blending process, the parameters need further optimization in order to favor the intercalation of polymer chains within the clay tactoids, so clay particles don`t remain dispersed on a micrometer scale. This produced an increase in the free volume of the polymer, decrese of crystallinity, thus lowering the Tg of the hybrid composite materials.
Fig. 1: TG (left) and DTG (right) curves for neat coPA and its nanocomposites: coPA (red), coPA-BTN (green), coPA-K10 (violet) and coPA-I.30P (blue)
Thermogravimetry (TG) analysis results indicated that the presence of clay additives increased the thermally stability of copolyamide upon incorporation of only 5 wt% clay (thermal stability of samples: coPA-K10>coPABTN>coPA-I.30P>coPA). This behaviour is explained by the copolyamide stabilization with transition metals present in clays as impurities and by superior insulating features of layered silicates, well known as effective barriers to volatile byproducts generated during decomposition.
References: 1 Grandjean, J . Clay Minerals 2006, 41, 567.
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S3-P4
INFLUENCE OF COMPOSITION AND PROCESSING ON THE PROPERTIES OF SOME POLYAMIDE-POLYPROPYLENE BLENDS
Madalina Zanoaga, Raluca Darie, Fulga Tanasa
Petru Poni Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, Iasi, Romania, ftanasa@icmpp.ro
Polymer blends have attracted increasing attention from the R&D community due to their improved properties compared to raw polymers. Polyamide-polyolefin blends are of interest because both components are relatively cheap, versatile due to their properties, and are easily processable by melting. They are a successful example in terms of blending incompatible polymers in presence of compatibilizing agents. Simple blends are, usually, characterized by low dispersion of phases, high interfacial tension and poor adhesion. Use of compatibilizers favours the interfacial interactions during melt processing due to their chemical or/and physical interactions with polymers. The paper presents some correlations between the composition and properties of some polyamide-polypropylene blends. A series of blends were prepared using a ternary copolyamide (coPA) and isotactic polypropylene (PP), with or without compatibilizer, namely maleic anhydride functionalized isotactic polypropylene (PP-g-MA). Blends processing, thermal behaviour and morphology of were studied in order to establish the compatibility window. The obtained data showed the incompatibility of the binary coPA/PP blends. The good processability, due to the high melt flow index of coPA and increased mobility of PP macromolecules, was improved even more by compatibilization, which is an advantage when it comes to polymer waste recovery. Evaluation of processing and thermal behaviour indicated that up to 20 wt% coPA can be incorporated in PP and the morphology study confirmed the enhanced homogeneity of compatibilized blends.
Fig. 1: Microphotograph of composite sample 10 coPA/90 PP + 5%PP-g-MA
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S3-P5
SHEAR THINNING/STRUCTURE RELATIONSHIP AND BIOCOMPATIBILITY STUDIES OF QUATERNIZED POLYSULFONE/POLY(VINYLIDENE FLUORIDE) BLENDS
Luminita-Ioana Buruianaa, Ecaterina Avrama, Adriana Popab, Silvia Ioana
a Petru Poni Institute of Macromolecular Chemistry, 700487 Iasi, Romania. Institute of Chemistry Timisoara of Romanian Academy, 300223 Timisoara, Romania.
Blends of quaternized polysulfones with triphenylphosphonium pendant groups/poly(vinylidene fluoride) were analyzed for establishing their impact on the rheological and surface properties, as well as their interactions with some blood compounds. The flow behavior of the solutions, obtained in N,N-dimethylformamide for different compositions of the blend system, presents a shear thinning profile, while the loss modulus is dominant for the viscous domain of oscillations. Moreover, blend compositions of the corresponding films influence the surface tension parameters, increasing blend hydrophobicity and, implicitly, decreasing the polar surface tension parameters. The hydrophobic character of the films is predominant, being given both by the small dipole moment corresponding to the poly(vinylidene fluoride) structure, and by the triphenylphosphonium groups from modified polysulfone. Furthermore, because of the different interactions present in the systems, the electron donor interactions exceed the electron acceptor ones for all samples. The specific surface characteristics of polymer blends, such as wetting and adhesion, are related to their interactions with some blood constituents (Fig. 1). In this context, the spreading work values indicated that the red blood cells and platelets manifest a pronounced cohesion in both cases. At the same time, the PSFP/PVDF blends do not interact with platelets, thus preventing the activation of coagulation at the blood/biomaterial interface. Because the PSFP/PVDF blends would not cause any damage of blood cells, they may be suitable for bio-applications, especially in tissue engineering.
Fig. 1: Work of spreading of water, red blood cells and platelet over the surface of 100/0, 70/30, and 60/40 v/v PSFP/PVDF films Acknowledgment: This work was supported by a grant of the Romanian National Authority for Scientific Research, CNCS-UEFISCDI, project number PN-II-RU-TE-2012-3-0143 (2013 stage).
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S3-P6
NEWTONIAN AND THINNING PROCESSES INVOLVING SPECIFIC MORPHOLOGY OF NEW QUATERNIZED POLYSULFONE
Raluca Marinica Albu, Ecaterina Avram, Iuliana Stoica, Silvia Ioan
Petru Poni Institute of Macromolecular Chemistry,Grigore Ghica Voda alley, No. 41 A, alburaluca@yahoo.com
The rheological properties and morphological aspects of the quaternized polysulfones (PSF-DMOA), synthesized by the quaternization reaction of chloromethylated polysulfone (6.58 % chlorine content) with tertiary amine -N,Ndimethyloctylamine (DMOA), are studied in DMF/methanol (MeOH) and DMF/water solvent/nonsolvent mixtures at different compositions. Different obtained parameters, such as activation energy, and the rheological functions (dynamic viscosity versus shear rate, elastic and viscous shear moduli versus frequence) justify the appearance of thinning phenomenon in solvent mixture. In this context, there are established that the polymer solutions exhibit in some cases a Newtonian behavior or, in other cases, a thinning effect, revealing the importance of temperature and nature of chlorometilate polysulfone substituent, along with solvent mixture composition, in specific molecular rearrangement of the system. Also, atomic force microscopy shows influence of mixed solvents on the morphological properties. Increasing the MeOH content in the casting solution decreases average surface roughness and favors the increase of pore number and of their characteristics area, depth, diameter and mean width, whereas a higher water content decreases the thermodynamic quality of the DMF/water solvent mixtures, so that, for 60/40% v/v DMF/water, average surface roughness, the number of pores and their depths take maximum values within a minimum area. The obtained informations allowed optimization of different properties required for applications of quaternized polysulfones, for examples, as biomaterials and semipermeable membranes.
Acknowledgement: This work was supported by a grant of the Romanian National Authority for Scientific Research, CNCS UEFISCDI, project number PN-II-RU-TE-2012-3-0143 (2013 stage)
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S3-P7
MISCIBILITY OF POLY(N-VINYLCARBAZOLE) WITH NITROAROMATIC LOW-MOLECULAR COMPOUNDS. DSC STUDY.
Petru Poni Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda, 41A, Iasi, Romania, angrig@icmpp.ro
Miscibility of poly(N-vinylcarbazole) PVK with different low-molecular compounds bearing nitroaromatic groups was studied by differential scanning calorimetry DSC. The PVK from Sigma-Aldrich (secondary standard, M n = 2500050000 g/mol, polydispersity index about 2) was an electron donor polymer frequently used to design electroluminescent devices or photorefractive materials, but monofuctional and bifunctional nitroaromatic compounds (4,4dinitrodibenzyl DNDB, ethylene glycol-bis(3,5-dinitrobenzoate) DDNBEG and acetate (-hidroxyetyl-3,5-dinitrobenzoate) AHEDNB) were synthesized in Petru Poni Institute. The molar blends were casted from solution, and than analyzed with a Pyris Diamond DSC (Perkin Elmer, U.S.A.) instrument. Thermal behavior of the samples has considered physical processes such as melting and glass transition.
Fig. 1: Chemical structures of PVK and electron acceptors.
The DSC curves suggested that the specific parameters of DNDB (melting temperature Tm and heat of melting Hm) were varied in accordance with blend composition and this fact was due to the miscibility between PVK and DNDB. In the cases of PVK blends with DDNBEG or AHEDNB, the charge transfer interactions from solution blends does not effectively preserved in solid state (because of solvent evaporation) and were masked by a plasticizing effect.
Acknowledgement: The authors are grateful to Dr. Elena Scortanu and Dr. Mircea Grigoras from Petru Poni Institute of Macromolecular Chemistry of Iasi for the kind supply of the low-molecular compounds. References: 1 Grigoras, A.G.; Barboiu, V. Cen. Eur. J. Chem. 2012, 10, 313. 2 Grigoras, A.G.; Grigoras, V.C.; Barboiu, V. J. Opt. Adv. Mat. 2011, 13, 967. 3 Grigoras C.V.; Grigoras, A.G. J. Therm. Anal. Calorim. 2011, 103, 661.
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S3-P8
RELEASE ABILITY OF GLUCOSE EMBEDDED IN A POLYSACCHARIDE
Andreea Irina Barzica,b, Cristina Delia Nechiforc, Dana-Ortansa Dorohoib
Petru Poni Institute of Macromolecular Chemistry, Iasi, 700487, Romania, irina_cosutchi@yahoo.com b Alexandru Ioan Cuza University, Faculty of Physics, 11 Carol I Bdv., Iasi, 700506, Romania c Gheorghe Asachi Technical University, Faculty of Machine Manufacturing and Industrial Management, 67 Bdv. Dimitrie Mangeron, Iasi, 700050, Romania
a
The enhancement of oral bioavailability is one of the greatest challenges in the development of poorly watersoluble drugs. The need of polymeric carriers permitting controlled release of a desired drug following oral administration has led to the screening of a large variety of synthetic and natural polymers. In oral solid dosage forms, hydroxypropylcellulose (HPC) is widely used as binder due to its excellent physico-chemical characteristics combined with mucoadhesive properties. This is an odorless and tasteless, white to slightly off-white, fibrous or granular, free-flowing powder that is a synthetic modification of the natural polymer, cellulose. The reason for its widespread acceptance include (1) solubility characteristics of the polymer in gastrointestinal fluid, and in organic and aqueous solvent systems, (2) noninterference with tablet disintegration and drug availability, (3) flexibility, chip resistance and absence of taste and odor, (4) stability in the presence of heat, light, air or reasonable levels of moisture, (5) ability to incorporate color and other additives into the film without difficulty. This paper reports the in vitro evaluation of glucose release from the HPC foils. The dependence of the glucose release profile from HPC is made for different drug content from the polymer matrix. The mechanism involved in drug release process is evaluated using KorsmeyerPeppas empirical equation. The surface tension is determined by contact angle measurements using the sessile drop technique with different liquids and the changes induced by the glucose on the surface polarity are analyzed.
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S3-P9
MOLECULAR ROTATION DISPERSION OF A CHIROPTICAL POLYMER
Andreea Irina Barzica,b, Dana-Ortansa Dorohoib
a
Petru Poni Institute of Macromolecular Chemistry, Iasi, 700487, Romania, irina_cosutchi@yahoo.com b Alexandru Ioan Cuza University, Faculty of Physics, 11 Carol I Bdv., Iasi, 700506, Romania
Controlling and switching the chiroptical properties of polymers is of continued interest because of potential applications in sensor data storage, optical devices, and liquid crystalline displays. Chiroptical switch can be controlled by temperature, solvent, additives, irradiation, and electron redox, with thermo-driven chiroptical switching polymers being the most extensively studied. The present work investigates the chiroptical properties of isotropic solutions of a polysaccharide in different solvents. Their effect on specific rotation is plotted in Fig. 1.
0
specific rotation, deg ml/dm g
-10 -20 -30 -40 -50 -60 -70 water acetic acid cellosolve
400 nm 500 nm 700 nm
Fig. 1: Specific rotation of investigated polysaccharide in different solvents
The molecular rotation is evaluated from specific rotation and molecular mass of the structural unit. The dispersion of the molecular rotation offers information regarding the conformational changes or Cotton effect. Knowledge and understanding of the nature of the optical activity of such polymers might constitute a bridge between artificial polymers and biopolymers and will assist in designing and controlling new types of helical structures.
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THEORETICAL AND EXPERIMENTAL ASPECTS ON THE SPIN-COATED POLYAMIDE 6 THIN FILMS
M. Teodorescu
Petru Poni Institute of Macromolecular Chemistry Iasi, Aleea Grigore Ghica Voda, No. 41A, 700487, Iasi, Romania, teodorescu.mirela@icmpp.ro
In this paper, we present theoretical and experimental results of the spin-coating process in order to obtain polyamide 6 thin films with interesting optical properties. Polyamide 6 thin films, obtained from various solution concentrations, were deposited by spin-coating method, using different rotation speeds. Morphologic properties of these films have been investigated by means of scanning electron microscopy and atomic force microscopy. Analysis revealed that spin-coated films have a thickness dependent on solution concentration and its viscosity, rotation speed and also rotation time. In order to explain morphologic properties, a theoretical model that agrees with our experimental results have been developed, by means of multi-scale type theories.
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S3-P11
THEORETICAL AND EXPERIMENTAL ASPECTS ON THE ELECTRICAL CONDUCTIVITY IN PA6-CNT NANOWEBS
M. A. Clin1, L. Schacher2, D. Adolphe2, Nabyl Khenoussi2, M. Agop3,4
1
Faculty of Textile-Leather Engineering and Industrial Management, Technical Gheorghe Asachi University of Iasi Bvd. D. Mangeron No. 67, 700050, Romania 2 Laboratoire de Physique et Mcanique Textiles EAC 7189 CNRS/UHA,ENSISA, 11 rue Alfred Werner F-68093 Mulhouse Cedex France 3 Department of Physics, Technical Gh. Asachi University, Bvd. D. Mangeron No. 63, Iasi, 700050, Romania 4 Laboratoire de Physique des Lasers, Atomes et Molcules (UMR 8523), Universit des Sciences et Technologies de Lille, Villeneuve dAscq cedex 59655, France
The present paper studies the electrical conductivity modulus of polyamide 6 (PA6) carbon nanotubes (CNT) nanowebs, obtained by electrospinning process. Three different treatments (chemical, mechanical and mixed) were applied to the CNT in order to prepare the electrospinning solutions. For each of the applied treatments, the CNT contain was varied: 0.5%, 1%, 1.5% and 2%. A pristine PA6 sample was used to compare the influence of the CNT contain on the dielectric behaviour of the samples. The influence of both the applied treatment and the CNT contain was investigated by analysing the broadband dielectric spectroscopy of the samples. The experimental result of the behaviour of the electrical conductivity modulus |Sig| ( ) is theoretically explained.
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Section 4. Optics, Spectroscopy and Plasma Physics

S4-O1
CHARACTERIZATION OF PARTICLE EMISSION FROM CARBON LASER ABLATION USING A 3-GRIDS FARADAY CUP
Petru-Edward Nicaa, Cristian Ursub
b a
Gheorghe Asachi Technical University of Iasi, Blvd. Mangeron no.63, Iasi - 700050, Romania, pnica@tuiasi.ro Petru Poni Institute of Macromolecular Chemistry, 41A Gr. Ghica Voda Alley, 700487, Romania, cristiursu@gmail.com
Carbon laser produced plasma has been extensively studied in the past years due to its large potential applicability showed for the carbon allotropes (nanotubes, fullerenes and grapheme) that can be obtained in pulsed laser deposition systems. Since the properties of the resulted thin films depend on the plasma parameters, monitoring of plasma expansion process brings additional information on the thin film growing mechanism. In the present paper, using an electrostatic energy analyzer (a 3-grids Faraday cup at various biasing voltages) in both, time-of-flight (TOF) and retarding field analyzer (RFA) modes, respectively, some plasma parameters are derived from monitoring the ion species. The plasma has been generated by excimer laser ablation of the graphite in vacuum, at various laser fluences in a low laser fluence regime (< 5 J/cm2), i.e. in the usual range for thin films deposition. In TOF mode, the plasma temperature (112 eV) and centre of mass velocity (103104 m/s) evolutions have been derived. In RFA mode, a charge separation phenomenon was evidenced. TOF spectra recorded for different applied retarding voltage present separated peaks whose corresponding time values increase with the applied voltage. Moreover, a reheating effect of the plasma was evidenced as a consequence of decelerated and reflected ions.
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CHUAS CIRCUIT: CHAOTIC DYNAMICS AND CONTROL OF OSCILLATIONS
Stefan-Andrei Irimciuc, Ovidiu Vasilovici, Dan-Gheorghe Dimitriu
Faculty of Physics, Alexandru Ioan Cuza University, 11 Carol I Blvd., RO-700506 Iasi, Romania, irimiciuc_s@yahoo.com
Chuas circuit is considered a cornerstone in nonlinear electronic circuit. It is the simplest electronic circuit exhibiting chaos, as verified from numerous laboratory experiments, computer simulations and rigorous mathematical analysis. A Chua circuit must include at least 5 circuit elements. Four elements are linear passive electrical components: an inductance, a resistance and two capacitances. The fifth element is a nonlinear element, powered by a battery, characterized by a current-voltage characteristic whose slope must be negative somewhere on the curve. Here we report on the nonlinear dynamics analysis of a Chua circuit, schematically represented in Fig. 1. By using a variable resistor, we obtained different dynamical regimes of the oscillator, including regular oscillations, sub-harmonic bifurcations and chaos. In order to control the dynamics of the circuit, we applied a sinusoidal signal on the transistor Q1 (see Fig. 1). By changing the amplitude or the frequency of this signal we can control the dynamics of the circuit, even if this dynamics is chaotic. The obtained results are very important for the synchronization of two chaotic oscillators and secure communication (transmission of chaotic encoded data).
Fig. 1: Chua circuit
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S4-P1
HIGHLY SURFACE ENHANCED RAMAN ACTIVE SILVER AND GOLD NANOPARTICLES COVERED IN GLUCOSE
Radu A. Boitor, Nicolae Leopold
Faculty of Physics, Babe-Bolyai University, Koglniceanu 1, 400084 Cluj-Napoca, Romania, boitor.radu@gmail.com
There is an increasing interest in the use of metal nanoparticles for a variety of biological applications including their use as contrast agents, delivery vehicles and therapeutics. An important feature of metal nanoparticles for such applications is their biocompatibility, thus choosing the synthesizing agents becomes an important task. The main purpose of this study was to develop a novel method of synthesizing silver and gold nanoparticles by using entirely biocompatible materials that do not cause tissue toxicity to the organism. The here proposed nanoparticles are therefore coated in glucose, which is a polysaccharide that is actively sought out by cells. This should also give these nanoparticles the ability to be internalized more easily by most cells [1]. The nanoparticles were characterized using UV-Vis, TEM and surface-enhanced Raman scattering (SERS) spectroscopy. From the UV-Vis spectra we gathered that the silver nanoparticles have a diameter of about 85 nm and an absorption maximum at 468 nm. The gold nanoparticles, on the other hand, could be synthesized so that their diameter could be controlled in between the 20-50 nm range in accordance to the synthesizing conditions used and they had an absorption maximum at about 540 nm. In the past years, SERS has been used in different bio-medical applications as a spectroscopic detection tool. From the acquired SERS spectra we could easily observe that the nanoparticles are highly active for a wide range of analytes as shown for rose bengal (Rb), crystal violet (CV), rhodamine 6G (R6G) and cresyl violet (CrV) in Fig. 1, at micromolar analyte concentrations. It was found that both types of nanoparticles exhibited a SERS enhancement comparable to conventional metal colloids.
Fig. 1: SERS spectra of several analytes at 10-6 M concentrations.
Given the fact that these nanoparticles can be easily functionalized with different ligands and given their high SERS activity, they should provide a viable method for biodetection by means of SERS spectroscopy.
Acknowledgement: This work was supported by CNCSIS-UEFISCSU, project number PN-II-RU-TE-2012-3-0227 References: 1 Liu, J.; Qin, G.; Raveendran, P.; Ikushima, Y. Chem. Eur. J. 2006, 12, 2131.
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S4-P2
ALTERATION OF BOVINE SERUM ALBUMIN AGGREGATION CAPACITY AFTER EXPOSURE TO ATMOSPHERIC PRESSURE PLASMA, UV LASER AND PULSED ULTRASOUND FIELDS
A. Demeter, R. Jijie, I. Mihaila, V. Pohoata, I. Topala
Plasma Physics Laboratory, Faculty of Physics, Alexandru Ioan Cuza University of Iasi, Bd. Carol I No. 11 Iasi 700506, Romania, alexandra_demeter@yahoo.com
Protein aggregation process is a complex biological phenomenon triggered by physical and chemical agents. Lately, this phenomenon is related to some neurodegenerative diseases, such as Alzheimer's disease, Parkinson's disease or Creutzfeld Jacob disease. It is accepted that this phenomenon takes place during collective interaction of partially unfolded or misfolded protein molecules. Temperature is a physical agent largely used in order to induce protein aggregation in controlled and reproducible conditions. In this study we use the bovine serum albumin (BSA) capacity to self-assemble into amorphous or fibrilar during controlled heating, in order to test the effects of selected physical agents on protein powders or protein aqueous solutions. Thus, we report the action of an atmospheric pressure plasma jet in helium, of a pulsed laser beam with 266 nm wavelength and a 3 W/cm2 pulsed ultrasound field at 1 MHz. Using a broad spectrum of experimental parameters (e.g. power, exposure time) we modified the properties of BSA molecules. Then the protein solutions were subjected to controlled heating and the aggregation of proteins in solution was monitored by laser scattering (337 nm nitrogen laser). An exponential increase of scattered light intensity as function of elapsed time was found (Fig. 1).
Fig. 1: Typical kinetics of the thermal induced aggregation process as revealed by the intensity of the scattered laser radiation from protein solutions.
The aggregation curves are fitted using a compressed exponential function, and the parameters of this function being obtained from the analysis of experimental data using appropriate software. These parameters are represented by the value of the scattering signal at the end of the process, the characteristic time constant and the exponent of the function. Specific aspects of each energy source used in this study are stressed in relation with the protein aggregation capacity, after exposure to each physical agent.
Acknowledgement: This work was supported by the CNCS UEFISCDI (Romania) and by the SRDA (Slovakia) through the joint Romanian-Slovak Cooperation Program.
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42
S4-P3
POPCORN SHAPED GOLD NANOPARTICLES WITH ABSORBANCE IN NIR
IstvnSz. Tdor, Nicolae Leopold, Lszl Szab, Vasile Chi
Faculty of Physics, Babe-Bolyai University, Koglniceanu 1, 400084 Cluj-Napoca,Romania, istvan.todor88@gmail.com
In recent years nanoparticle synthesis has evolved substantially and now it is possible to control their shape, size and surface chemistry. Gold nanoparticles are one of the most important types of nanoparticles due to their applicability in live tissue as contrast agents, delivery vehicles, therapeutics etc., even though some of the coating agents can cause side effects (e.g. renal complications)[1]. In this study a new method for nanoparticle synthesis was developed. The nanoparticles were prepared at room temperature, their size being within the 50-150 nm range, varying with the experimental conditions.
Fig. 1: TEM images of hydroxylamine reduced GoldNPs.
The nanoparticles were characterized using UV-Vis, TEM and surface-enhanced Raman scattering (SERS) spectroscopy. From the UV-Vis spectra we found that the absorption maximum of the large gold nanoparticles was at around 720 nm and at 536 nm for the small particles. TEM measurements revealed the popcorn shape of the nanoparticles. The smaller nanoparticles have shown an at least ten times higher SERS activity than the conventional citrate reduced gold nanoparticles . Moreover, it has been reported that nonspherical nanoparticles have longer biodisponibility than those with spherical shapes. Considering the nonspherical shape and the possibility to modify the surface with highly biocompatible molecules, the proposed gold nanoparticles could become important transporting vehicles for drugs like heparin, C-reactive protein etc. Furthermore, due to the fact that these nanoparticles can be functionalized with different ligands and their absorption maximum is in the NIR region they should provide a viable option for photothermal therapy too.
Acknowledgement: This work was supported by CNCSIS-UEFISCSU, project number PN-II-RU-TE-2012-3-0227 References: 1 G. TAN, M. A. ONUR, N. SALAM., Turk J Biol, 2012, 36, 607-621
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43
S4-P4
MAIN PHYSICAL AND STRUCTURAL PROPERTIES OF PHENOBARBITAL MOLECULE
Andreea Celia Benchea, Liliana Mihaela Ivan, Dana Dorohoi
Faculty of Physics, Alexandru Ioan Cuza University of Iasi, 11 Carol I Boulevard, Iasi, Romania, mihaelaivan2002@yahoo.com
Phenobarbital is central nervous system depressant, belonging to the barbiturate family. It can produce many side effects (from mild sedation to total anesthesia) being used often as anticonvulsant. In this paper we analyzed the Phenobarbital molecule using the molecular modeling methods. After the geometrical optimization and a single point calculation, the main parameters like dipole moments, polarizability of this molecule were computed.
_____________________________________________________________________________ S4-P5
CHANGES IN POLARIZABILITY BY 1,6 DIPHENYL-1,3,5 HEXATRIENE (DPH) EXCITATION IN SOME HOMOGENEOUS SOLUTIONS
Ion Hurjui1, Liliana Mihaela Ivan2, Dana Dorohoi2
1
Biophysics and Medical Physics Department, Faculty of Medicine, Gr.T. Popa University, 16 University Street, Iasi, RO-700115 2 Faculty of Physics, Alexandru Ioan Cuza University, 11 Carol I Blv., Iasi, RO-700506
The electronic (absorption and fluorescence) spectra of 1,6 diphenyl-1,3,5 hexatriene (DPH) in some solvents were analysed from the mirror symmetry point of view. The electronic absorption spectra more shifted in the wavenumber scale and they can indicate the nature of the intermolecular interactions in DPH solutions. The influence of the solvent nature on of the changes in the DPH polarizability induced by excitation was established by the influence of the dispersive forces on the electronic absorption spectra.
_____________________________________________________________________________ S4-P6
SPECTRAL CHARACTERISTICS OF P-PHENYL-PYRIDAZINIUM-BENZOYL-2,4,6-PICRIL METHYLID (PPBPM) TERNARY HYDROXYL SOLUTIONS Daniela Babusca1, Mihaela Maria Dulcescu 2,3, Cristina Delia Nechifor4, Dana Ortansa Dorohoi2
Alexandru Vlahuta School , Iasi, Romania Alexandru Ioan Cuza University of Iasi, Faculty of Physics, Iasi, Romania 3 Clinical Emergency Sf. Spiridon Hospital, Department of Radiotherapy, RO-700111, Iasi, Romania 4 Gh.Asachi Technical University of Iasi,Faculty of Machine Manufacturing and Industrial Management, Department of Physics, Iasi, Romania
2 1
The wavenumbers in the maximum of the visible intramolecular charge transfer (ICT) band of p-phenylpyridazinium-benzoyl-2, 4, 6 picril methylid (PPBPM) were used to characterize the first solvation shell of the spectrally active compound in ternary solutions achieved with hydroxyl solvents water, ethanol and methanol. The average statistic weights, p1 , the excess function, (1) , and the preferential solvation constant, k12 , were estimated on the basis of the solvatochromic effects of binary hydroxyl solvents water + ethanol and water + methanol in ternary diluted solutions of PPBPM.
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S4-P7
CONTRIBUTION OF EACH TYPE OF INTERACTIONS TO THE TOTAL SPECTRAL SHIFT IN SOME CYCLOIMMONIUM-YLIDS SOLUTIONS
Valentina Closc, Dana Ortansa Dorohoi
2
Faculty of Physics, Alexandru Ioan Cuza University, 11 Carol I Blv., Iasi, RO-700506
The cycloimmonium ylids are important in pharmacy because they are precursors in obtaining new medicines and also they can be used as acid-basic indicators. The separation of each type of intermolecular interaction to the total spectral shift in each solvent can suggest new applications of these dipolar compounds in organic chemistry. The cycloimmonium ylids are zwitterionic compounds with a visible absorption band due to an intramolecular electronic transfer from the carbanion towards the heterocycle. This band is very sensitive to the solvent nature. So, cycloimmonium ylids are used as spectrally active molecules which offer information about the strength of the intermolecular interactions by the change of the electronic absorption spectra when these are passed from the gaseous phase to liquid state. In this paper the electronic absorption spectra of two cycloimmonium ylids in different aprotic and protic solvents were studied and the contribution of each type of intermolecular interactions to the spectral shifts was measured when the spectrally active substance is passed from the gaseous phase to solution.
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UV SPECTRA OF SOME DIPEPTIDES AND N-MUSTARDS
Corina Cheptea1, Dana Ortansa Dorohoi2, Mihaela Holban3 and Valeriu Sunel3
1
Gr.T.Popa University of Medicine and Pharmacy, Faculty of Medical Bioengineering, Iasi, Romania 2 Al.I.Cuza University of Iasi, Faculty of Physics, Iasi, Romania 3 Al.I.Cuza University of Iasi, Faculty of Chemistry, Iasi, Romania
Starting from p-amino-benzoyl-asparagic acid and p-amino-benzoyl-asparagine, several series of and some acilated dipeptides and N-mustards derived from p-amino- acylated dipeptides has been synthesized. The structures of the obtained compounds were proved by both chemical and spectral (NMR and IR) analyses. The electronic absorption spectra of benzoyl-asparagic acid and p-amino-benzoyl-asparagine were also analysed. The influence of the substitutes of the benzenic ring on the wavelengths of the * absorption bands of the studied compounds has been established. The electronic absorption bands of the studied compounds in low concentrations solutions ( 210 mol/L) verify Lambert Beer law, proving the absence of the specific interactions between the solutions components and permiting a protocol for determination of the analysed substances concetrations in a given solution.
4
_____________________________________________________________________________ S4-P9
METAMERIC COLOUR IN ART CONSERVATION
Andrei Hrib, Dana Ortansa Dorohoi
Faculty of Physics, Al.I. Cuza University, 11 Carol I Bdv., Iai, RO-700056, ddorohoi@uaic.ro ; restoration.ro@gmail.com
Metamerism in conservation-restoration is very important in terms of reintegration color paintings. Using synthetic pigments in the formation of mixtures restoration that will replace - colorimetric and spectral - lack pictorial layers has the advantage of being economical. The major disadvantage is the fact that reintegration interventions thus obtained are less noticeable and removed in violation of one of the principles of restoration, the reversibility of treatment.
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S4-P10
FINEMET-TYPE THIN FILMS OBTAINED BY HIPIMS: INFLUENCE OF DEPOSITION CONDITIONS ON THE DEPOSITION RATE
Ioana-Laura Velicu, Vasile Tiron, Gheorghe Popa
Faculty of Physics, Alexandru Ioan Cuza University, 700506, Iasi, Romania
High-power impulse magnetron sputtering (HiPIMS) is a promising, relatively new technique, which can be successfully used to grow high-quality amorphous thin films from a wide range of materials [1, 2]. Using HiPIMS, FeCuNbSiB amorphous thin films have been deposited from ribbons with the nominal composition Fe73.5Cu1Nb3Si15.5B7. The depositions were performed in pure argon atmosphere, maintaining the gas flow at 20 sccm and the target-substrate distance at 6 cm. The influence of argon pressure, average power and pulse duration on the deposition rate of the films has been investigated. The thickness of the films was measured using an interferometric method. During the deposition process, electrical diagnosis was performed by recording the discharge current and voltage temporal evolution. The onset of the selfsputtering regime and the plasma composition change in front of the target were highlighted by using the time-resolved fast imaging technique. The obtained results showed that for an average power of 30 W and pulse duration of 4 s the deposition rate reaches a maximum value (3.8 nm/min) at 10 mTorr argon pressure. For the same pulse duration, the deposition rate increases about three times with the effective power increment from 30 W to 90 W. Instead, due to the self-sputtering process, for the same effective power, the deposition rate decreases with the pulse length increment. Significant changes of the current and voltage pulse shapes were observed. The ICCD images showed that during initial phase (1-4 s from applied voltage), in the plasma volume between cathode and substrate, the optical radiation is dominated by neutral Ar excited atoms emission, while the excited Fe atoms emission is almost negligible. For long pulse durations (20 s), the plasma radiation is dominated by the light of excited sputtered iron atoms and ions, while the light corresponding to argon excited state is very weak.
References: 1 Daniel Lundin and Kostas Sarakinos, Journal of Materials Research 27 (2012) 780-792; 2 I.L. Velicu, M. Neagu, H. Chiriac, V. Tiron, M. Dobromir, IEEE Transactions on Magnetics 48 (2012) 1336-1339.
_____________________________________________________________________________ S4-P11
OPTICAL COMPENSATORS USED IN DETERMINING THE BIREFRINGENCE OF UNIAXIAL CRYSTALLINE PLATES
Irina Dumitrascua, Leonas Dumitrascu b, Dana Ortansa Dorohoic
Inspector for Physics, Vaslui District, Romania, irina_dumitrascu2000@yahoo.com b Stefan Procopiu High School, Vaslui, Romania, leonas_dumitrascu@yahoo.com c Alexandru Ioan Cuza University, Faculty of Physics, Iasi, Romania, ddorohoi@uaic.ro
a
Uniaxial plates of solid crystalline substances are characterized by two principal refractive (ordinary and extraordinary) indices. When polarized light passes through uniaxial plate perpendicularly on the optical axis, its birefringence can be determined by compensation of the pathway introduced between the ordinary and extraordinary components of the incident linearly polarized light. In order to estimate the birefringence of the samples collected from Carpathian Mountains, we used both a Babinet Compensatory and a standardized optical wedge in order to compensate the pathway at 589.3 nm introduced by layers cut perpendicular on their optical axis.
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46
S4-P12
BIREFRINGENCE OF SOME LIQUID CRYSTALLINE SAMPLES
Leonas Dumitrascua, Irina Dumitrascu, b Dana Ortansa Dorohoic
Stefan Procopiu High School, Vaslui, Romania, leonas_dumitrascu@yahoo.com Inspector for Physics, Vaslui District, Romania, irina_dumitrascu2000@yahoo.com c Alexandru Ioan Cuza University, Faculty of Physics, Iasi, Romania, ddorohoi@uiac.ro
b a
The birefringence at 589.3 nm of some uniaxial liquid crystalline samples kept in special cells was determined using a device consisting from two identical polarizers, a Babinet Compensatory and the special cell filled by the studied liquid crystal. The electric field influence on the liquid crystal birefringence at 589.3nm has been also established. The results were compared with those obtained by using a standardized optical wedge.
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47
S4-P13
A STUDY OF SOME URBAN AND INDUSTRIAL MIXTURES AEROSOLS OVER IASI REGION
Marius Mihai Cazacua, b, Florin Ungaa, Adrian Timofteb, c, Ioana Popovicia, Alin Ionut Pascarua, Dan Dimitriua, Silviu Gurluia
a
Alexandru Ioan Cuza University of Iasi, Faculty of Physics, Atmosphere Optics, Spectroscopy and Lasers Laboratory, 11 Carol I Blvd., 700506 Iasi, Romania, sgurlui@uaic.ro b Department of Physics, Gheorghe Asachi Technical University of Iasi, 59A Mangeron Blvd., 700050 Iasi, Romania, cazacumarius@gmail.com c National Meteorological Administration, Regional Forecast Center Bacau, 1 Cuza Voda Str., 600274 Bacau, Romania, timofte.adrian@gmail.com
Iasi is a municipality from North-Eastern part of Romania and one of the largest cities in the country. Being a city in continuous development, several urban projects were started in the spring of 2012, with the purpose of improving the citys infrastructure and restoration of some cultural buildings and parks. Urban and industrial aerosols type is a major component of the tropospheric aerosol load over IASI LOA-SL site monitoring station (47N, 27E). This study presents the results from optical properties analysis (May 2012 - February 2013 period) on biomass-burning, urban aerosols mixtures and Saharan dust by means of lidar and sun-photometer measurements. In order to both identify and categorize the biomass burning types influences, Aerosol Robotic Network (AERONET) Version 2 data criteria (Level 1.5, solar zenith angle larger than 50o and retrieval error less than 5%) have been used to compute parameters such as: optical thickness, spectral dependence of ngstrm exponent (), spectral dependence of Single Scattering Albedo and the dominating size mode. Both biomass burning and urban-industrial aerosols are characterized by very small particles, so that ne mode is predominating in the particle size distribution. The decreasing of Single Scattering Albedos total average with the increasing of the wavelength (440, 675, 870, 1020 nm) from 0.95 ( 0.1) to 0.81 ( 0.1) agree on dominant aerosol type (Fig. 1).
0.95
Single Scattering Albedo
0.90
0.85
0.80
May June July August September October November February
0.75 400 600 800 1000
Wavelenght (nm)
Fig. 1: Spectral single scattering albedo, monthly averages
An event on 5 July, 2012 shows that the AERONET lidar ratio calculated at 532 nm (S532aer) is between 55~75 sr with an ngstrm exponent between 1.3~1.7 for urban/industrial aerosol and 1.6~1.9 for biomass burning.
References: 1 Cazacu, M. M.; et al., J Opt and Adv Mat, 2012, 14, 5-6, 517-522. 2 Giles, D. M.; et al., Journal of Geophysical Research, 2012, 117, d17203. 3 Nicolae, D.; et al., J Opt and Adv Mat Rapid communications, 2008, 2, 405 412. 4 Russell, P.B.; et al., Atmos. Chem. Phys., 2010, 10, 11551169.
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S4-P14
AEROSOLS CHEMICAL COMPOSITIONS: DETECTION AND RANGING
Strat Mitachia, Marius Mihai Cazacua, b, Adrian Timoftea,c , Dan Dimitriua, Silviu Gurluia
a
Alexandru Ioan Cuza University of Iasi, Faculty of Physics, Atmosphere Optics, Spectroscopy and Lasers Laboratory, 11 Carol I Blvd., 700506 Iasi, Romania, sgurlui@uaic.ro b Department of Physics, Gheorghe Asachi Technical University of Iasi, 59A Mangeron Blvd., 700050 Iasi, Romania, cazacumarius@gmail.com c National Meteorological Administration, Regional Forecast Center Bacau, 1 Cuza Voda Str., 600274 Bacau, Romania, timofte.adrian@gmail.com
Depending on the space-time chemical composition, sources type activity or process, meteorological conditions, air pollutants (both organic and inorganic compounds), generally the air pollution causes significant damage to human health and environment and dramatically influencing the climate changes. As a complementary approach to the satellite measurement spectral data, ground based instruments as Sunphotometer, Radiometer, DOAS, LIDAR & DIAL, massspectroscopy & shadowgraphy - laser matter desorption, in a variety of configurations are extensively developed and some of these must be improved even to obtain UV-IR image remote investigated ice nucleation layer-atmospheric pattern, as following will be proposed in this paper. Moreover, in order to better understanding the fundamental of some critical physico-chemical transformation of the atmosphere compounds but also for applications point of view, we propose a new LIDAR power instrument as is shown in Fig. 1. This instrument is able to capture fast plume airborne image (2ns gate time) and may used to investigate in real time several chemical compound behaviour at a given point of the free atmosphere.
Fig. 1: LIDAR equipment, experimental set-up. References: 1 Hairston, P.; Ho, J.; Quant, F.; J Aerosol Sci. 1997, 28(3), 471-82. 2 Dengxin, H.; et al., Jpn. J. Appl. Phys. 2007, 46, 5849. 3 Gurlui, S.; Agop, M.; Nica, P.; Ziskind, M.; Focsa, C.; Phys. Rev. E, 2008, 78, 026405. 4 Krcher, B.; Koop, T.; Atmos. Chem. Phys., 2005, 5 (3), 703-714
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S4-P15
CORRELATIONS IN LIGHT INTENSITY FLUCTUATIONS INDUCED BY GAUSSIAN WHITE NOISE IN A SYMMETRICAL DISCHARGE PLASMA
Cristina Stana, Cristina Maria Cristescua, D. Alexandroaeib, C. P. Cristescua
a
Department of Physics, Politehnica University of Bucharest, 313 Spl. Independentei, RO-060042, Bucharest, Roumania b Department of Plasma Physics, Al. I. Cuza University of Iassy, RO-700506, Iassy, Roumania, d.alex@uaic.ro
We investigate the influence of white Gaussian noise on the fluctuations of light intensity emitted by the localized space charge structures in the plasma of a symmetrical discharge. Both the original and FFT filtered time-series were analyzed using the multifractal analysis. In the range of noise intensity considered, the multifractality strength is influenced by the noise, at all values of the inter-anode voltage. In the case of filtered data, the shuffling analysis demonstrates that the multifractality is purely a consequence of the correlations of the fluctuations. The position of the maximum in the singularity spectra is significantly influenced by noise. The multifractal detrended cross correlation between light intensity and current intensity demonstrates that the fluctuations in both cases are generated by the same physical processes. The change between the autocorrelation characteristics of the original and filtered series is remarkable: while the original series are positively correlated, the filtered series are negatively correlated. Based on the the fact that FFT filtering preserves the behavior of the discharge plasma in respect of the noise, we present a consistent validity test supporting the application of this type of filtering for removing the harmonic trend.
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CHANGES INDUCED BY SOLVENTS NATURE IN 1,6 - DIPHENYL - 1,3,5 -HEXATRIENE FLUORESCENCE SPECTRA: COMPUTATIONAL ARGUES
Ion Hurjui a,b , Andrei Neamtu c, Dana Ortansa Dorohoi a
a Faculty of Physics, Al. I. Cuza University, Bd. Carol I, Nr. 11A, 700506, Iasi, Romania Biophysical and Medical Physics , Faculty of Medicine, Gr. T. Popa University, 16, University Street, 700115, Iasi, Romania c Center for the Study and Therapy of Pain (CSTD), Gr. T. Popa University of Medicine and Pharmacy, 16, University Street, 700115, Iasi, Romania b
The changes induced by the solvent nature in fluorescence spectra of some 1,6-diphenyl-1,3,5-hexatriene (DPH) solutions were explained by molecular dynamic simulations. Concomitantly some quantum-mechanical calculations were made in order to obtain the electro-optical parameters of DPH. The simulations emphasized the auto-aggregation processes of DPH and THF multicomponent solutions.
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THEORETICAL AND EXPERIMENTAL STUDY OF B12 VITAMIN IN POLAR SOLVENTS
Cristina Marcela Rusua,Claudia Nadejdea, Cristina-Delia Nechiforb
Faculty of Physics, Al. I. Cuza University, Bd. Carol I, Nr. 11A, 700506, Iasi, Romania Department of Physics, Technical University of Iasi, B-dul D. Mangeron 67, Iasi 700050, Romania
a
The aim of this paper is the study of the influence of some solvents on the electronic absorbtion spectra and electro chemical properties of B12 vitamin by using the cell model of pure liquid proposed by Abe. It is calculate the radius of the first and second solvatation sphere, the number of particle from the first two solvatation sphere and then it is estimated the potential interaction by dispersion forces between the spectrally active molecule (vitamin B12) and the solvent molecules which surrounded it.
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S5-O1
OPTOGENETICS: NEW PARADIGM REQUESTING ADAPTED TOOLS AND TECHNOLOGIES
Aurel L. Strat a,b , Ryan Falk b , Ramin Pashaie b
University of Medecine Gr. T. Popa, Department of Pharmacology - Algesiology, Iasi, Romania, alstrat1@hotmail.com University of Wisconsin Milwaukee, Department of Electrical Engineering and Computer Science, Biological Inspired Science and Technologies Laboratory, Milwaukee, USA, pashaie@uwm.edu
a
Optogenetics is the combination of genetics and optics to control well-defined events within specific cells of living tissue. It includes the discovery and insertion into cells of genes that confer light responsiveness; it also includes the associated technologies for delivering light deep into organisms as complex as freely moving mammals, for targeting lightsensitive cells of interest, and for assessing specific readouts, or effects, of this optical control. Optogenetics necessarily includes 1) the development of genetic targeting strategies such as cell-specific promoters or other customized conditionally-active viruses, to deliver the light-sensitive probes to specific populations of neurons in the brain of living animals and 2) hardware (e.g. integrated fiberoptic and solid-state light sources) to allow specific cell types, even deep within the brain, to be controlled in freely behaving animals. Most commonly, the latter is now achieved using the fiberoptic-coupled diode technology introduced in 2007. To stimulate superficial brain areas such as the cerebral cortex, optical fibers or LEDs can be directly mounted to the skull of the animal. More deeply implanted optical fibers have been used to deliver light to deeper brain areas. A fiber optic based probe was developed to control/visualize neuronal activity deep in the brain of awake behaving animals. In this design a thin multimode optical fiber serves as the head of the probe to be inserted into the brain. This fiber is used to deliver excitation/stimulation optical pulses and guide a sample of the emission signal back to a detector. This is an example of how physics and engineering back up fundamental biological research and discovery.
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51
S5-P1
ELECTROMAGNETIC SHIELDING PROPERTIES OF MULTILAYERED GLASS COATED AMORPHOUS WIRES
Gabriel Ababei and Horia Chiriac
National Institute of Research and Development for Technical Physics, 47 Mangeron Blvd., Iasi, Romania, gababei@phys-iasi.ro
Glass coated amorphous magnetic microwires (GCAW) known as soft magnetic materials are intensively studied due to their large utilization in magnetic field sensors and electromagnetic (EM) shielding application 2. The development of amorphous microwires with multilayer structure is a new research field with numerous potential applications in the field of electromagnetic shields and smart composite materials to realize multifunctional materials for structural health monitoring. The glass coated amorphous wires have been prepared by drawing from CoFe-based melted alloy as continuous filaments with the diameter of the metallic nucleus ranging from m= 16 m to m= 64 m and glass thickness ranging from Gth= 7.25 m to Gth= 35 m. The multilayered GCAW are obtained from as-cast GCAW subsequently coated by RF sputtering deposition followed by electrochemical deposition with a Cu layer. The aim of this paper is to investigate the electromagnetic shielding properties in the microwave range of multilayers GCAW in order to develop an absorbent material with selective electromagnetic shielding properties based on these wires type. The structure, size and magnetic properties of MAW were investigated by SEM microscopy and VSM technique, respectively. The experimental set-ups used for high frequency characterisations involve the utilisation of the coaxial transmission line method and two horn antenna connected to a vector network analyzer2.
0.05
0.00
transmission(dB)
-0.05
-0.10
-0.15
-0.20
GCAW with length: 4 cm and 2 cm 3 cm and 2 cm 2 cm and 1.5 cm 3 cm and 1.5 cm
-0.25
4cm 3cm
2cm
1.5cm
-0.30 1 2 3 4 5 6 7 8 9
f (GHz)
Fig. 1: SEM image of a multilayered GCAW
Fig. 2: Absorption spectra for four sets of two microwires with the same m = 18 mm and Gth= 27.5 mm, placed in parallel position with different lengths L.
Experimental results show that the multilayered GCAW allows the development of a system for simultaneous selective shielding of several frequencies of the electromagnetic field which corresponds to various wire length.
Acknowledgement: This work was supported by a grant of Romanian National Authority for Scientific Research, CNCSIS UEFISCDI, project number PNII-RU-PD-2011-3-0228. References: 1 Vzquez M, Physica B, 2001, 299, 302. 2 Ababei G., David V., Dafinescu V., Nica I. , Pica A., and Chiriac H., Rev. of Scien. Instr., 2012, 83, 014701,
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53
AUTHORS INDEX- 211 PARTICIPANTS
A Acatrinei C. S. Aflori M.
Agheorghiesei C. Agop M.
Buruiana L. I. Buzea C. Buzescu F C Caltun O. Caraman I. Casian-Botez I. Cerntescu C. Chicina I. Chiriac H. Ciascai I. Ciobanu G. Ciobanu I. B. Ciobanu O. Ciuce C. Codjovi E. Coman T.
Dascalu C. F. Diaconescu R. Dias C. J. Dima M. Dobos A. M. Dobromir M. Dorohoi D. O. Dorolti E. Dragos O.G. Drobota M. Duginov V.N. Dulcescu M. M. Dulea M.
Aignatoaiei B. Akhter S. Albu R. M. Amano S. Andries D. V. Angheluta E. Apreotesei G. Aranghel D. Astefanoaei C. Avdanei M. Avram E.
F Fetecu C. Filimon A. Focanici E. Focea R. Foca C. Frunza M. D.
B Baban C. Badelita L. Bdescu R. Bdescu V. Balasoiu M. Baltag O. Barsan V. Bejan L. Benchea A. C. Bibire C. Bolat G. Bordianu I. Buhucianu O.
Constantin B. Costandache D. Cosutchi A. I. Craus M. L. Craus T. Creanga D. E. Cristescu C. P Cutrubinis M.
G Garcia Y. Gartu M. Geba M.
D Daraban L. Dariescu C. Dariescu M. A. 54
Georgescu P. Georgescu R. Gherghel M. Gottlieb I.
Graur A. Grigoras M. Gutoiu S. Mahmood T. Mamedov T.N. Manea M. Marat-Mendes J. N. H Homocianu M. Hulubei C. Mareci D. Matasaru D. Mitrica B. Mitrici S. I Iftemie A. Iftimie N. Inoue T. Ioan S. Ionescu D. Ionita D. Isnard O. Iustain C. Ivan L. M. N Ndejde C. K
Kokmaz F.
O Obreja Ursu L. Ojica S. Olaru L. Olaru M. A. Olaru N. Oniscu C. Oprea B.
Miyamoto S. Mocanu A. Mociutchi C. Mohorianu S., Moise M. Moise V. Munteanu C. Musteata V. E. P Palade P. A. Parghie C. Pun V. Perov T.N. Petreus O. Poll E. Ponta C. C. Ponta O. Pop M. Pop V. Popa F. Popa V. Postolache M. Postolache M. Profire L.
Nagano A. Nazar M. Neagu E. R.
L Latu M. Lazar G. Lazar I. Linares J. Lostun M. Lupu N. Lucanu M.
Neamu B. Nechifor C. D. Negut D. Nenciu A. Nica P. E. Nica S. L. Nica V. Niculescu A. Niculescu O.
R Racuciu M. Radinschi I. Radu T. Rau I. Rau M. Raut M. B. 55
M Magop D. Mahmood A.
Rotaru A. Rusu C. M. Stoica I. Stoica M. Stroia L. S Saavedra J. O. Salajan D. Scripcariu L.
Severcan F. Siddique I.
Ursache M. Ursu C.
Strugaru I. Sultan Q. Sunel V. Sutiman D. Suvaila R.
V Valeanu M. Varret F. Veresa R. Vica S. M. Virgolici M,
Simionescu B. Simon S. Simon V. Spinu L. Stamate M. Stana R. Stancu A. Stancu V. Stanculescu I. Stanculescu R. Sterian P. Sterian R.
T Talo F. Tarnauceanu S. Todica M. Trifu A. Tufescu F.
Vlad A. M. Vornicu L. Vornicu N. Vucan F. B.
Z Zafar A. A.
U Udrea L. E. Udrea M. Udrescu L.
Zelinschi B. C. Zet Ghe.
56
FOREING PARTICIPANTS
1) Akhter S., Department of Mathematcs, The Islamia University, Bahawalpur, Pakistan 2) Balasoiu M., Joint Institute for Nuclear Research, Dubna, Russia 3) Codjovi E., Groupe dEtude de la Matire Condense (GEMaC), Versailles Cedex, France 4) Craus M.-L., IUCN, Frank Laboratory for Neutron Physics (FLNP) Dubna, Moskovskaia, Russia 5) Dias C. J., Department of Materials Science, (CENIMAT/I3N), Faculty of Science and Technology, The New University of Lisbon, Portugal 6) Foca C., University of Sciences and Technologies of Lille, France 7) Garcia Y., Institut de la Matire Condense et des Nanosciences, Universit Catholique de Louvain, Belgium. 8) Inoue T., Laboratory of Advanced Science and Technology for Industry, University of Hyogo, Japan 9) Isnard O., Institut Nel, CNRS, Joseph Fourier University, Grenoble, Cdex 9, France 10) Iustain C., Physics of Pharmaceuticals" laboratory of Chemagis, API's division of Perrigo Company, Israel 11) Isnard O., Institut Nel, University J. Fourier, Grenoble, Cdex 9, France 12) Ortega Saavedra J., University of Las Palmas de Gran Canaria, Spain 13) Severcan F., Faculty of Biology, Middle East Technical University of Ankara, Turkey 14) Kokmaz F., Faculty of Biology, Middle East Technical University of Ankara, Turkey 15) Linares J., Groupe dEtude de la Matire Condense (GEMaC), 78035 Versailles Cedex, France 16) Mahmood A., Department of Mathematics COMSATS Institute of Information Technology, Lahore Pakistan 17) Mahmood T., Department of Mathematcs, The Islamia University, Bahawalpur, Pakistan 18) Marat-Mendes J. N., Department of Materials Science, (CENIMAT/I3N), Faculty of Science and Technology, The New University of Lisbon, Portugal 19) Miyamoto S., Laboratory of Advanced Science and Technology for Industry, University of Hyogo, Japan 20) Nagano A., Laboratory of Advanced Science and Technology for Industry, University of Hyogo, Japan 21) Nazar M., Centre for Advanced Studies in Pure and Applied Mathematics, Bahauddin Zakariya University,Multan, Pakistan 22) Neagu E. R., Department of Materials Science, (CENIMAT/I3N), Faculty of Science and Technology, The New University of Lisbon, Portugal 23) Perov T.N., Physics Department, Moscow State University, Moscow, Russia 24) Siddique I., Department of Mathematics COMSATS Institute of Information Technology, Lahore Pakistan 25) Spinu L. Advanced Materials Research Institute (AMRI), University of New Orleans, New Orleans, USA. 26) Sultan Q., Centre for Advanced Studies in Pure and Applied Mathematics, Bahauddin Zakariya University, Multan, Pakistan 27) Varret F.,Groupe dEtude de la Matire Condense (GEMaC), Versailles Cedex, France 28) Zafar A. A., Abdus Salam School of Mathematical Sciences, Lahore, Pakistan
57
Atractii turistice
Rezervatia Dealul Repedea Situata la 9 Km de Iasi, a fost infiintata in 1953, fiind prima rezervatie geologica din tara, Zona rezervatiei este de fapt o portiune din fundul Marii Sarmatice ce a existat acum 20 milioane de ani, dovada fiind fauna fosila din rocile calcaroase de aici. Gradina Botanica Prima Gradina Botanica din Iasi a fost infiintata in 1856 de medicul si naturalistul Anastasie Fatu. Actuala Gradina Botanica a fost infiintata aproximativ un secol mai tirziu, in 1963. Un loc favorit al vizitatorilor il reprezinta rozariul, unde sunt peste 800 de specii de trandafiri din diferite zone ale globului. Manastirea Cetatuia Minastirea Cetatuia este una din cele mai frumoase opere de arta bisericeasca din Moldova. A fost ctitorita de Duca Voda intre 1668-1672. Aici a functionat o cunoscuta tiparnita cu litere grecesti, adusa de la Venetia, in care au fost tiparite multe carti pentru crestinii din Orient. Teatrul National Vasile Alecsandri Teatrul a fost inaugurat in 1896, fiind una din cele mai frumoase cladiri de acest gen din tara. Uzina electrica a teatrului, pusa in functiune o data cu deschiderea tetrului, a reprezentat inceputul iluminatului electric la Iasi. Aici pot fi admirate opere de arta cum sunt: candelabrul din cristal de Venetia sau plafonul pictat de Al. Goltz. Palatul Culturii Lucrarile de constructie au inceput in 1906 iar inaugurarea a avut loc in 1926, in prezenta regelui Ferdinand al Romaniei. Putem admira orologiul, format dintr-un ansamblu de opt clopote ce reproduc, din ora in ora, Hora Unirii sau celebrele sali, Sala Voievozilor si Sala Gotica. Impresionanta cladire este astazi sediul Muzeului de Istorie a Moldovei, Muzeului Etnografic, Muzeului de Arta si al Muzeului Stiintei si Tehnici. Casa Memoriala Vasile Pogor Cladirea este monument de arhitectura si a fost construita de vornicul V. Pogor, intre 1855-1858. A fost locuinta acestuia si apoi sediul Societatii Junimea si al revistei Convorbiri Literare. In aceasta casa, Titu Maiorescu a citit, in 1870, pentru prima oara poezia Venere si Madona a lui Mihai Eminescu, necunoscut la acea vreme. In acesta cladire se afla azi Muzeul Literaturii Ramane. Biserica Sf. Nicolae Domnesc 58
Biserica initiala s-a construit in timpul lui Stefan cel Mare, intre 1481-1482. Fiind puternic avariata in urma unor incendii, a fost reconstruita din temelii intre 1888-1904. A fost Catedrala Mitropolitana pina la sfirsitul sec. al XVII lea si aici au fost unsi aproape toti domnii Moldovei.
59

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The 5-th National Conference of Applied Physics

Iasi, Romania, May 23 - 24, 2013

Local organizing committee:

Local Committee for Conference Programme:

Thursday 23 May 2013:

Low TC Fe-Nb-Cr-B Glassy Alloys for Medical 11.15-11.45 Applications

Plenary Session (Invited Talks) Chairman: dr. Mihai VLAICU

Friday, 24 May 2013

Section 3. Polymer Physics and Engineering

Section 4. Optics, Spectroscopy and Plasma Physics.

11.15-11.30 11.30-12.20 S4-O2 11.30-11.55

Oral Session (Section 4 and 5) Chairman: Silviu GURLUI

Section 5. Technical Physics and Interdisciplinary

Irina Radinschi, Theophanes Grammenos, Andromahi Spanou

Section 2. Physics and Technology of Condensed Matter.

Sorin-Bogdan Balmus , Dumitru D. Sandu2

Section 3. Polymer Physics and Engineering

Morphology, Dielectric, and Thermal Properties of Some P4VP/ALN Nanocomposites

Luminita-Ioana Buruianaa, Ecaterina Avrama, Adriana Popab, Silvia Ioana

Raluca Marinica Albu, Ecaterina Avram, Iuliana Stoica, Silvia Ioan

Release Ability of Glucose Embedded in a Polysaccharide

Molecular Rotation Dispersion of a Chiroptical Polymer

Monica. A. Clin, L. Schacher, D. Adolphe, Nabyl Khenoussi, M. Agop

Section 4. Optics, Spectroscopy and Plasma Physics

Alexandra Demeter, R. Jijie, I. Mihaila, V. Pohoata, I. Topala

UV Spectra of Some Dipeptides and N-Mustards

Section 5. Technical Physics and Interdisciplinary

III. LOW TC Fe-Nb-Cr-B GLASSY ALLOYS FOR MEDICAL APPLICATIONS

Section 1. Theoretical, Mathematical and Computational Physics

Section 2. Physics and Technology of Condensed Matter

Section 3. Polymer Physics and Engineering

Fig. 1: Microphotograph of composite sample 10 coPA/90 PP + 5%PP-g-MA

Fig. 1: Chemical structures of PVK and electron acceptors.

Fig. 1: Specific rotation of investigated polysaccharide in different solvents

Section 4. Optics, Spectroscopy and Plasma Physics

Fig. 1: Chua circuit

Fig. 1: SERS spectra of several analytes at 10-6 M concentrations.

Fig. 1: TEM images of hydroxylamine reduced GoldNPs.

Single Scattering Albedo

May June July August September October November February

0.75 400 600 800 1000

Fig. 1: Spectral single scattering albedo, monthly averages

Section 5. Technical Physics and Interdisciplinary

GCAW with length: 4 cm and 2 cm 3 cm and 2 cm 2 cm and 1.5 cm 3 cm and 1.5 cm

Fig. 1: SEM image of a multilayered GCAW

F Fetecu C. Filimon A. Focanici E. Focea R. Foca C. Frunza M. D.

Constantin B. Costandache D. Cosutchi A. I. Craus M. L. Craus T. Creanga D. E. Cristescu C. P Cutrubinis M.

G Garcia Y. Gartu M. Geba M.

D Daraban L. Dariescu C. Dariescu M. A. 54

Georgescu P. Georgescu R. Gherghel M. Gottlieb I.

O Obreja Ursu L. Ojica S. Olaru L. Olaru M. A. Olaru N. Oniscu C. Oprea B.

Nagano A. Nazar M. Neagu E. R.

L Latu M. Lazar G. Lazar I. Linares J. Lostun M. Lupu N. Lucanu M.

Neamu B. Nechifor C. D. Negut D. Nenciu A. Nica P. E. Nica S. L. Nica V. Niculescu A. Niculescu O.

R Racuciu M. Radinschi I. Radu T. Rau I. Rau M. Raut M. B. 55

Strugaru I. Sultan Q. Sunel V. Sutiman D. Suvaila R.

V Valeanu M. Varret F. Veresa R. Vica S. M. Virgolici M,

T Talo F. Tarnauceanu S. Todica M. Trifu A. Tufescu F.

Vlad A. M. Vornicu L. Vornicu N. Vucan F. B.

U Udrea L. E. Udrea M. Udrescu L.

Zelinschi B. C. Zet Ghe.

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