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Solutions to JEE Advanced - 3/JEE-2014/Paper - 1

[CHEMISTRY]



1.(B)
2
2 4 4
Ag CrO 2Ag CrO
+
+
Addition of
2
4
CrO

results in decrease of Ag
+
.
2.(B) Sparingly soluble salt :
1 sp
sp sp
3
2 2
1 2 3
sp
4
3
AB S K
Since K <<1 for sparingly soluble salts K
A B S
S S S 4
K
AB
27

=
`
< <

)


3.(C)
2 2 4 4 2
2 4 2
P MnO NaBr Na SO MnSO Q H O
H SO Br Brown fumes
+ + + + +
+
+














4.(D)









5.(B) Addition of Cryolite
3 6
(Na AlF ) and Fluorspar (CaF
2
) lower the fusion point of mixture and increases the
conductivity.

6.(C) If T constant, then according to PM = dRT ; as P is doubled, d also doubles.
Molecular mass is constant, so it can't be proportional to any parameter.

7.(C) Fraction of molecules with
mp
C ses + on sing | temperature.

Vidyamandir Classes

VMC/JEE-2014/Paper-1 2 JEE ADV-3/Solutions/Chemistry-Maths
8.(D) (A) Na
2
O
2
decolourises acidified potassium permanganate.

2 2 4 2 4 2 4 2 4 4 2 2
5Na O 2KMnO 8H SO 5Na SO K SO 2MnSO 8H O 5O + + + + + +
(B) Sodium superoxide is prepared by reacting
Na
2
O
2
with O
2
at 450 C and 300 atm pressure

2 2 2 2
Na O O NaO +
(C)
400 C
2 2 2
Na O Na Na O

+
(D)
2 2 2 2 2
Na O H O NaOH NaOH H O + + +

2 2 2 4 2 4 2 2
Na O H SO Na SO H O + +

9.(A) S
1
:
2 2 2
2 2 2
BeCl . 4H O BeO HCl H O
MgCl . 6H O MgO HCl H O
A
A

+ +

`

+ +
)
BeCl
2
, MgCl
2
undergoes surface hydrolysis (and thus form
oxides on heating rather than simple halides) due to small size of Mg
2+
, Be
2+
as compared to Ca
2+
.
S
2
: With the weakening of metallic bonding down the groups softness of alkali increases down the group.
S
3
: Plaster of Paris is
4 2
1
CaSO . H O
2

S
4
: True


10.(C)


11.(AC)
2 2
2 4 2 2 3 2
C O H O CO H O

+ +
n-factor = 2

2
2 4 2 3 2
HC O H O CO H O

+ +
n-factor = 2
millimoles of H
2
O
2
used = n
1
+ n
2


2
2 4 2 4 2
HC O KOH C O H O

+ +
n-factor = 1
millimoles of KOH used = n
2


12.(BD) Vapour Pressure of solution decreases on addition of a non-volatile solute
Only solvent molecules solidify at freezing point

13.(ABCD)































Vidyamandir Classes

VMC/JEE-2014/Paper-1 3 JEE ADV-3/Solutions/Chemistry-Maths


14.(ABC)



(I) (II) (III) (IV)
(A) (I) has centre of symmetry and (IV) has plane of symmetry so both are meso compounds.
(B) (II) and (III) are enantiomers.
(C) Since in (I), no hydrogen is anti with respect to the adjacent Br atom, so elimination is not feasible.
15.(ABCD)

SF
4
2 S F bonds are equatorial
2 S F bonds are axial

ClF
3
2 Cl F bond axial
1 Cl F bond equatorial

Bond angles not identical.

BF
2
Cl Due to un-symmetry, bond angles cannot be 120


16.(2) 12.2 g Benzoic Acid 0.1 mol.
100 gm water
Molality =
0.1
1000 1 molal
100
=

b b
T iK m A =

0.27 1
i
0.54 1 2
= =


Benzoic acid must be dimerised.

17.(8)
MgCl
MgCl
2
f
f
H 125
H 642

A =
A =

(i)
2
1
Mg Cl MgCl
2
+ H 125 KJ A =
(ii)
2 2
Mg Cl MgCl + H 642 KJ A =

2
2MgCl Mg MgCl + H 392KJ A =
( ) ( ) ii 2 i 642 250 +
= 392
For one mole of MgCl , H 196KJ A =
49x 196 =
x = 4

18.(7) Statement (1), (2) and (4) are correct.

19.(6)
2 4 3 3 2 3 2 2 7 2 4 2 3
H SO , H PO , H CO , H S O , H CrO , H SO are diprotic acids.

20.(2)
v V
q nC T = A
H
Br
Br H
H Br
Br H
H
Br
Br
H
H Br
Br
H
H Br
Br H
H
Br
Br
H
H
Br
Br H
H
Br
Br H
H
Br
Br
H
H
Br
Br
H H
Br
Br
H
H
Br Br
H
Vidyamandir Classes

VMC/JEE-2014/Paper-1 4 JEE ADV-3/Solutions/Chemistry-Maths

6 f R
12.5 10
22.4 2
=

6 f 2
12.5 10
22.4 2

=

28
5
6
~
Gas must be diatomic


Solutions to JEE Advanced - 3/JEE-2014/Paper - 1

[MATHEMATICS]




41.(A) If the robot is one unit away from its initial zero position, then it can be at either +1 or 1 . Since the robot has
taken 5 steps, it can be at +1 if it takes 3 steps right and 2 steps left. Similarly, it can be at 1 if it takes 3 steps left
and 2 steps right.
Pr (3 steps right and 2 steps left) =
3 2
5
3
3 2
5 5
C
| | | |
| |
\ . \ .

Pr (3 steps left and 2 steps right) =
3 2
5
3
2 3
5 5
C
| | | |
| |
\ . \ .

So, the required probability =
3 2 3 2
5 5
3 3
3 2 2 3
5 5 5 5
C C
| | | | | | | |
+
| | | |
\ . \ . \ . \ .


10 27 4 10 8 9 72
3125 3125 125

= + =

42.(B) Since the points of intersection lie on the hyperbola xy = 1, let their co-ordinates be

1
1
1
A t ,
t
| |
|
\ .
and
2
2
1
B t ,
t
| |
|
\ .

Since the above points also lie on a variable line with slope
2 1
2 1
1 1
t t
m, m
t t
| |

|
\ .
=

or
1 2
1
m
t t

= or
1 2
1
t t
m

= .
Let P(x, y) be the point which divides AB in the ratio 1 : 2, then

2 1
2
3
t t
x
+
= and
2 1 1 2
1 2
1 2
2
3 3
t t t t
y
t t
+
+
= =
or
1 2
3 2 x t t = + and
1 2 1 2
3 2 t t y t t = +
Putting the value of t
1
t
2
in the above equation, we get :

1 2
3 2 x t t = + and
1 2
3
2
y
t t
m

= +
Solving the above 2 equations for t
1
and t
2
, we get :

1
3
3 6
y
t x
m
= + and
2
6
3 3
y
t x
m

=
or
1
2
y
t x
m
= + and
2
2y
t x
m

=
Using
1 2
1
t t
m

= , we get :
2 1
2
y y
x x
m m m
| || |
+ =
| |
\ .\ .

or
2
2
2
4 2 1
2
xy y xy
x
m m m
m

=
Vidyamandir Classes

VMC/JEE-2014/Paper-1 5 JEE ADV-3/Solutions/Chemistry-Maths
or ( )
2 2 2
2 2 5 1 0 m x y xy m + + =
For the above second degree equation

( )
( )( ) ( )
2
2 2 2 2
5
2 2 2 0 0 0
2
m
abc fgh af bg ch m m m
| |
A = + = +
|
\ .


3 3 3
25 9
4 0
4 4
m m m = + = = as 0 m=
Also,
2
2 2
25
4
4
m
h ab m = > = The curve is a hyperbola.
43.(C)
( )
u v w u . v w
(
=


2 1 1 3 7
1 0 3

i j k

v w i j k = =

( ) ( )
2 2 2
3 7 3 7 1

u . v w u . i j k u cosu = = + +
Where u is the angle between u and 3 7

i j k

( )
1 59 u . v w cosu =
Maximum value of
( )
59 u . v w =
44.(A) Direction ratios of L
1
come from the following determinant
2 1 1
3 1 2

i j k

i j k = or the direction ratios are 1 1 1 , , .
(0, 0, 1) is a point which lies on both the planes (0, 0, 1) lies on L
1
.
So, the equation of L
1
becomes

1
1 1 1
x y z
k

= = =


The equation of L
2
is x y z = = =
Take points P and Q on L
1
and L
2
respectively. Then ( ) 1 P k, k, k and ( ) Q , , .
Direction ratios of PQ are 1 k, k, k + + .
Since we want the shortest distance between L
1
and L
2
,
1
PQ L and
2
PQ L
( ) ( ) ( ) 1 0 k k k + + = and ( ) ( ) ( ) 1 0 k k k + + + + =
3 1 0 k + = and 3 1 0 k + =
Solving the above two equations we get :
1 1
4 4
, k = =

1 1 3
4 4 4
P , ,
| |

|
\ .
and
1 1 1
4 4 4
Q , ,
| |

|
\ .

Shortest distance =
1
2
PQ =
45.(C)
2 2
3 2 18 0 x y xy xy + =
( ) 3 2 18 0 xy x y + =
Sides of triangle are 0 0 x , y = = and 3 2 18 0 x y + =
Vertices of triangle are (0, 0), (0, 9) and (6, 0)

0 0 6 0 9 0
3 3
G ,
+ + + + | |

|
\ .
or (2, 3).
Vidyamandir Classes

VMC/JEE-2014/Paper-1 6 JEE ADV-3/Solutions/Chemistry-Maths
Since G lies on 1 0 x y + = , the required circle touches the line 1 0 x y + = at (2, 3) and passes through (1, 1).
The equation of family of circles touching 1 0 x y + = at (2, 3) is
( ) ( ) ( )
2 2
2 3 1 0 x y k x y + + + =
Since the required circle passes through (1, 1)
( ) ( ) ( )
2 2
1 2 1 3 1 1 1 0 5 k k + + + = =
So, the equation of circle is ( ) ( ) ( )( )
2 2
2 3 5 1 0 x y x y + + + = or
2 2
9 8 0 x y x y + + =

46.(A) As angle in a semi-circle is a right angle, 90 ADB Z =
2 AD Rcosu =
180 DCB u Z = as ABCD is a cyclic quadrilateral.
CBA u Z = as ABCD is a trapezium.
2 BC AD Rcosu = =
Now, AB = 2R and from the figure we can see that
2
2 2 2 DC AB ADcos BCcos R Rcos u u u = =
Also 2 h ADsin Rcos sin u u u = =
area ( ) ( )
( )
2
1 1
2 2 4 2
2 2
ABCD AB DC h R R Rcos Rsin cos u u u = + = +

( )
( )
2 2 3
2 2 2 4 R Rcos Rsin cos R sin cos f u u u u u u = = = .
( ) ( )
( )
2 2 2 3
4 3 f R sin cos sin sin u u u u u ' = +
( ) 0 0 f sin u u ' = = or
2
3 tan u =
0 u = or 60 u =
But a maxima occurs at 60 u =
Maximum area ( )
3
2
2
3 1 3 3
4
2 2 4
R
ABCD R
| |
= =
|
|
\ .


47.(D) Since the slope of tangent to the curve y = f (x) at (x, f (x)) is 2x + 1
( ) 2 1 f x x ' = +
( )
2
f x x x C = + + , for some arbitrary constant C.
As the curve passes through (1, 3) f (1) = 3
C = 1 ( )
2
1 f x x x = + + .
( )
( )
1 2
1
y
y x sin sin x

= + + . . . .(i)
Let ( ) ( ) ( ) 1 1
y
g x log g ylog x = + = +
( ) ( ) ( )
1
d d
log g ylog x
dx dx
= +
or ( )
1
1
1
dg y dy
log x
g dx x dx
= + +
+

( ) ( ) 1 1
1
y dg y dy
x log x
dx x dx
(
= + + +
(
+


So, differentiating (i) w.r.t. x we get :
( ) ( ) ( )
4
1
1 1 2
1
1
y dy y dy
x log x sinxcos x
dx x dx
sin x
(
= + + + +
(
+



At x = 0, y = 1.
D
C
B
A
O
u
h
2R
Vidyamandir Classes

VMC/JEE-2014/Paper-1 7 JEE ADV-3/Solutions/Chemistry-Maths
1
dy
dx
= slope of normal = 1 .
Equation of normal is ( ) 1 1 y x = or 1 y x = +
For the area bounded by ( ) y f x = and 1 y x = + , we get the points of intersection as
2
1 1 x x x + + = +
or
2
2 0 x x + = or ( ) 2 0 x x + =
or 0 2 x , =
Area bounded ( )
( )
0
2
2
1 1 x x x dx

(
= + + +
(

}


( )
0
0
3
2 2
2 2
4 4
2 0
3 3 3
x
x x dx x

| |
= = = =
|
\ .
}

48.(B) Let
( )
2
2 1
1
x sin x
I dx
cos x
t
t
+
=
+
}


( ) ( )( )
( )
2 2
0
2 1 2 1
1 1
x sin x x sin x
I dx
cos x cos x
t
(
+
( = +
+ + (

}


2
0
4
1
x sin x
dx
cos x
t
(
=
(
+
}
. . . . (i)

( ) ( )
( )
( )
2 2
0 0
4 4
1 1
x sin x x sin x
I dx dx
cos x cos x
t t
t t t
t

= =
+ +
} }
. . . .(ii)
Adding (i) and (ii), we get :

( )
( )
2 2
0 0
4
4
2
1 1
sin x dx
sin xdx
I
cos x cos x
t t
t t
t
t

= =
+ +
} }


2
2
0
4
2 2
1
sin xdx
I
cos x
t
t
=
+
}

or
2 2 2
2 2
2
0 0 0
2
4 4 4
1 1
1
2
sin x dx
sin xdx cos xdx
I
cos x sin x
cos x
t t t
t
t t t
t
| |

|
\ .
= = =
| |
+ +
+
|
\ .
} } }

Put sinx t =
cos xdx dt =
( )
1
1
1 2
2
0
0
4 4 4 0
4
1
dt
I tan t
t
t
t t t t

| |
= = = =
|
+ \ .
}

49.(A)
4 2 2
3600 2 3 5 =
Number of integers divisible by 2 = 1800
Number of integers divisible by 3 = 1200
Number of integers divisible by 5 = 720
Number of integers divisible by 2 and 3 = 600
Number of integers divisible by 3 and 5 = 240
Number of integers divisible by 2 and 5 = 360
Number of integers divisible by 2, 3 and 5 = 120
Number of integers divisible by 2, 3 or 5
Vidyamandir Classes

VMC/JEE-2014/Paper-1 8 JEE ADV-3/Solutions/Chemistry-Maths
( ) ( ) 1800 1200 720 600 240 360 120 2640 = + + + + + =
Number of integers not divisible by 2, 3 or 5 3600 2640 960 = =
But these 960 integers include 1.
Excluding 1, we get there are such 959 integers.


50.(B) DECISION
+
I I, D, E, C, S, O, N
Case 1 : There is one letter between Is

Similarly,
Case 2 : There are 2 letters between 2 Is

5 2
1 1
5 5 2 120 1200 C C = =
Case 3 : There are 3 letters between 2 Is

4 3
1 1
5 4 3 120 1440 C C = =
Case 4 : There are 4 letters between 2 Is

3 4
1 1
5 3 4 120 1440 C C = =
Case 5 : There are 5 letters between 2 Is

2 5
1 1
5 2 5 120 1200 C C = =
Case 6 : There are 6 letters between 2 Is

1 6
1 1
5 1 6 120 720 C C = =
Total number of words = 2 (720 + 1200 + 1440) = 6720 =
8
3

51.(AD) ( )
1
1
4 2 1
x
e , if x
f x
x , if x
+

=

>



1
4 2 1
1 1
4 2 1
x
x , x
e , x
x , x
+

<

= s s

>



1
1
4 2 6 4
4 2 2 4 1
1 0
0 1
4 2 2 1 4
4 2 6 4
x
x
x x x
x x x
e x
e x
x x x
x x x
+
+
= s

+ = + < <

s s

=

< s

= + < <

= >


Vidyamandir Classes

VMC/JEE-2014/Paper-1 9 JEE ADV-3/Solutions/Chemistry-Maths

1
1
6 6
6 6 4
2 4 2
2 2 1
1 0
0 1
2 1 2
2 2 4
6 4 6
6 6
x
x
x x
x x
x x
x x
e x
e x
x x
x x
x x
x x
+
+
s

+ < s

< s

+ < <

s s

=

< s

+ < <

s <

+ s s

>


Plotting the graph of f (x), we get :

From the graph of f (x), we can see that f (x) is continuous everywhere and f (x) is not differentiable at the points
{ } 6 4 2 0 2 4 6 x , , , , , , e .
Note that
( )
1 1 x x
d
e e
dx
+ +
= which is equal to 1 at 1 x = . Similarly,
( )
1 1 x x
d
e e
dx
+ +
= which is equal to 1 at
x = 1.

52.(BD) The point
( )
2
, o o lies on
2
y x =
Solve 2 0 x y + = and
2
y x = to get :
2
2 x x + =
or
2
2 0 x x = or ( )( ) 2 1 0 x x + =
or 1 2 x , =
Similarly, solve 2 x y + = and
2
y x = to get :

2
2 x x = or
2
2 0 x x + =
or ( )( ) 2 1 0 x x + = or 2 1 x , =
So, from the graph we can see that for
( )
2
, o o to lie inside the required triangle ( ) 1 1 , o e .
53.(ABCD)
1 2
c
z z
a
= or
1 2
1
1
1
c
z z
a
= = =
or
2
1 1 = z or
2
1 z =

1 2
1
1
1
b b
b
z z
a a a

+ = = = = =
As ( )( )
2
1 2 1 2 1 2
z z z z z z + = + + we get :
( )( )
1 2 1 2
1 z z z z = + +
or ( )
1 2
1 2
1 1
1 z z
z z
| |
= + +
|
\ .
as
2
1 1 1
1 z z z = = and
2
2 2 2
1 z z z = =
Vidyamandir Classes

VMC/JEE-2014/Paper-1 10 JEE ADV-3/Solutions/Chemistry-Maths
or
( )
2
1 2
1 2
1
z z
z z
+
=
( )
2
1 2 1 2
z z z z + =
2
2
b c
b ac
a a
| |
= =
|
\ .


1 2 1 1
i
z z z z e
u
+ = + as
2
1 z = and POQ u Z = is given in the question.
or ( )
2
2
1 2 1
1 1 1
i
z z z e cos sin
u
u u + = + = + +

2
2 2 4 2
2 2
cos cos cos
u u
u
| |
= + = =
|
\ .

As
1 2
1 2 1 60
2 2
z z , cos
u u | |
+ = = =
|
\ .
or
2
120
3
t
u = =

1 2 1 1 1
1
i i
PQ z z z z e z e
u u
= = = ( ) ( )
2
2
1 1 2 2 60 3
2
cos sin sin sin
u
u u = + = = =
54.(ABCD) ( )
2
1
1
k k k k k
x x x x x
+
= + = +

( )
( )
( )
1
1
1 1 1 1
1 1 1
k k
k k k k k k k
x x
x x x x x x x
+
+
= = =
+ + +


1
1 1 1
1
k k k
x x x
+
=
+


1 2 100 1 2 2 3 100 101 1 101
1 1 1 1 1 1 1 1 1 1 1
1 1 1
. . . . . . . .
x x x x x x x x x x x
| | | | | |
+ + + = + + + =
| | |
+ + +
\ . \ . \ .

( ) ( )
1 2 1 1 3 2 2
1 1 3 3
1 1
2 2 2 4
x , x x x , x x x = = + = = = +

3 4 5 101
3 7 21
1 1 1 1
4 4 16
x x x . . . . . x = = > > > >

101
1
0 1
x
< <

1 101 101
1 1 1
2 1
x x x
( (
= =
( (


Similarly, we can prove that

1 2 101 102
1 1 1 1
2 1
1 1 1
. . . .
x x x x
( (
+ + + = =
( (
+ + +



1 2 102 103
1 1 1 1
2 1
1 1 1
. . . .
x x x x
( (
+ + + = =
( (
+ + +


and
1 2 103 104
1 1 1 1
2 1
1 1 1
. . . .
x x x x
( (
+ + + = =
( (
+ + +


55.(BD)
( )
1
2 2 x sin tan

=
Assume that ( )
1
2
2
2 2
1
tan
tan x sin
tan
u
u u
u

= = =
+


( )
2
2 2
4
5
1 2
= =
+


1
1 4
2 3
y sin tan

| |
=
|
\ .

Assume that
1
4 4
3 3
tan tan o o

= =
Vidyamandir Classes

VMC/JEE-2014/Paper-1 11 JEE ADV-3/Solutions/Chemistry-Maths

4
5
sino = and
3
5
coso =

2 2 2
1 2
2 2 2
cos cos sin sin
o o o
o = =

2 2
3 1 1
1 2
5 2 2 5 2 5
sin sin sin
o o o
= = =
Since
1
4
0 0
3 2 2
tan , sin
t o
o o

| |
= < < >
|
\ .

or
1
2 5
sin
o
=

1
5
y =
Putting the values of x and y in the options, we get
2
1 y x = and x y > .
56.(8) Question is Cancelled
Question should had been that a and b are relatively prime and c and d are relatively prime.
( )
( )
( )
( )
( )( )
( )
3 3
2 2
2
3
3 3 3
2 2 2
nx nx nx
nx nx nx
f x
nx nx nx nx
+ +
+ +
= =
+ + + +

Put nx t = to get :
( )
( )
( )
2
2 2
3 3 3
3 3 3
2 2
2 2
t t t
t t
g t y
t t
t t
+ +
+ +
= = =
+ +
+ +

( ) ( ) ( )
2
3 3 2 3 2 0 y t y t y + + = . . . .(i)
For the domain of f (x), x > 0 and ( )
2
2
2 0 nx nx + + = .
Taking nx t = , we get :
2
2 2 0 t t + + =
or ( )
2
1 1 0 t + + = which is true for all real values of t.
As x > 0, nx t = takes all real values.
So, we have to find out all possible values of y in (i) where t can take all real values.
As t R e , discriminant 0 >
( ) ( )( )
2
3 2 4 3 3 2 0 y y y > or ( ) ( ) ( ) 3 2 3 2 4 3 0 y y y ( >


or ( )( ) 3 2 9 2 0 y y + > or ( )( ) 2 3 2 9 0 y y s

3 9
2 2
y ,
(
e
(

.
As
3 9
3 2 9 2
2 2
a c
, , , a , b , c , d
b d
( (
= = = =
( (



3 2 9 2
8
2 2
a b c d + + + + + +
= =
57.(1) Let
0 1 2
0
0 2
3 3 3 3
n
n
cos nx cos x cos x cos x
S . . . .

=
= = + + +


Now, let
0 1 2
0
0 2
3 3 3 3
n
n
sinnx sin x sin x sin x
R . . . .

=
= = + + +


Consider
0 0 1 1 2 2
0 0 2 2
3 3 3 3 3 3
| | | | | |
+ = + + + + + +
| | |
\ . \ . \ .
cos x i sin x cos x i sinx cos x i sin x
S iR . . . .

0 1 2
0 2
0 1 2
3 3 3
3 3 3
i x ix i x ix ix ix
e e e e e e
. . . . . . .
| | | | | |
= + + + = + + + | | |
| | |
\ . \ . \ .

Vidyamandir Classes

VMC/JEE-2014/Paper-1 12 JEE ADV-3/Solutions/Chemistry-Maths
It is an infinite G.P. with first term =
0
1
3
ix
e
| |
= |
|
\ .
and common ratio =
3
ix
e
| |
|
|
\ .
such that
1
1
3 3 3
ix
ix e
e
= = <

( )
1 3 3
3
3
1
3
ix ix
S iR
cos x i sin x
e e
+ = = =
+



( )
( )
( )
( )
2
2
3 3
9 3 3
3
3 10 6
3
cos x i sin x
cos x i sin x
cos x i sin x cos x
cos x sin x
( +
+

= = =

+

Comparing the real part on both sides, we get :

1
9 3
9 3 9 1 3
1
1 10 6 10 2
10 6
3
cos x
S
cos x
| |

|

\ .
= = = =
| |

|
\ .

58.(2) Let
5
1
2 1 I x x dx =
}

Put 1 x t =
dx dt =

( )
4 4 4
2
0 0 0
1 2 1 1 I t t dt t dt t dt = + = =
} } }


( ) ( )
1 4
1 4
0 1 0 1
2 2 2 16 2
1 1 1 4 1
3 3 3 3 3
t t t t
t dt t dt t t
| | | |
| | | | | |
= + = + = +
| |
| | |
| |
\ . \ . \ .
\ . \ .
} }


1 4 1
2
3 3 3
| |
= + =
|
\ .


59.(8) 4 | o =

b
a
o | + = and
c
a
o| =
Now ( ) ( ) 3 2 3 2 2
c b
a c b
a a
o| o |
| |
= = = + +
|
\ .

Put 4 | o = , to get
( ) ( )
2 2
3 2 4 4 2 4 5 o o o o o = + + = +
2
8 10 3 0 o o + =
Solve to get :
10 14 1 3
16 4 2
, o

= =
1
4
o = as 0 4 1 o | o > = =
Now,
( )
2
0
r
r
S . . . . | o | |o |o

=
= = + + +

1 4
1
1 3
1
4
|
o
= = =


6 8 S =

60.(2) Let
( )
( )
1
0
x
x
x
lim tan x sec x

(
= +
(


Consider,
( )
( )
0 0
1
1
2 x x
n tan x
m lim x n tan x lim
x

= =
Apply L Hospital Rule to get :

2
0 0
1
1
1 1
2
2
x x
sec x
x x
tan x
m lim lim
cos x sin x
x x

= =



Vidyamandir Classes

VMC/JEE-2014/Paper-1 13 JEE ADV-3/Solutions/Chemistry-Maths

0 x
x
lim
cos x
=
0
As 1
x
sin x
lim
x
| |
=
|
\ .


( )
( )
0
0
1

= =


Hence,
( )
0
0 0
0 1
x
x x
lim x n tanx lim tan x e

= = =
Now, consider ( )
0
1
x
n lim n sec x
x
=
Apply L Hospital Rule to get :

0 0
1
0
1 x x
sec xtan x
sec x
n lim lim tan x

= = =
Hence, ( ) ( )
1
0
0 0
1
0 1
x
x x
lim n sec x lim sec x e
x
= = =
1 1 2 = + =

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